Geology topics

Edward G. Stets

Publications and source records attributed to Edward G. Stets.

At least 19 recordsLinked to original sources

USGS2026

Local water use and climate variability drive water stress and alter ecological flows over the conterminous United States

Consistent, large-scale estimates of water availability are needed to identify and avoid potential conflicts among human and ecosystem uses of water. We present an assessment of water limitation, defined as the monthly balance (difference) between water supply ( ws ) and human consumptive water use ( wc ), for the conterminous United States (CONUS) during water years 2010–2020. We estimate that 26.7 million Americans, 8% of CONUS population, live in areas with chronic high or severe water limitation. Although ws greatly exceeds wc at the CONUS scale, water is limited locally or regionally due to spatial and temporal patterns in climate and wc . Our water limitation metric, the monthly supply and use index (SUI), peaked in 2012 during a widespread drought when 38% of the CONUS land area experienced elevated water stress. The central and Southwestern U.S. experienced the highest SUI due to the combination of low ws and high wc , especially for irrigation. Spatial overlays of SUI and fish habitat ranges, including those of conservation concern, revealed that several species had notable proportions of their habitat exposed to high or severe water limitation during spawning season over the modeled time period, especially the Arkansas River shiner. ws was calculated from two CONUS, physically-based, hydrologic models while wc was calculated from three CONUS models of water use for crop irrigation, thermoelectric power generation, and public supply. The ws and wc values were routed through a stream network and compared to calculate water limitation and SUI for human populations and fish species at the scale of 12-digit hydrologic unit codes. Evaluation of water availability at higher spatial and temporal resolution promotes more comprehensive analyses of the drivers of water availability and can be combined with complementary studies of water quality and water limiting thresholds to better understand the limitations on water availability.

conterminous United States↗

USGS2025

The National integrated water availability assessment, water years 2010–20

Water availability is fundamentally important to human well-being, economic vitality, and ecosystem health. Because of its central importance, the U.S. Congress tasked the U.S. Geological Survey (USGS) and other Federal agencies with conducting regular, comprehensive assessments of water availability in the United States through the requirements under the SECURE Water Act. In response to this mandate, the USGS has developed the U.S. Geological Survey Integrated Water Availability Assessment—2010–20, which addresses aspects of water supply, quality, and use related to water availability in the United States. This is the first chapter of that report. The major climatic factors affecting water availability are also described. Multiple aspects of water availability are integrated to produce a more comprehensive analysis of water availability in the United States. This chapter enumerates the development, organization, and tools used in the USGS Integrated Water Availability Assessment. SECURE Water Act reports, developed by the Department of Energy Hydropower Climate Change Assessment and the Bureau of Reclamation West-Wide Climate and Hydrology Assessment, are also described. A distilled list of key findings from the overall report is also provided, serving as an introduction to each topic along with the most important high-level information.

conterminous United States↗

USGS2025

Water supply in the conterminous United States, Alaska, Hawaii, and Puerto Rico, water years 2010–20

We present an assessment of water supply across the conterminous United States (CONUS), Alaska, Hawaii, and Puerto Rico covering water years 2010–20. Our analysis drew on two national hydrologic models, the National Hydrologic Model Precipitation-Runoff Modeling System and the Weather Research and Forecasting model hydrologic modeling system. Both models produced estimates of streamflow, evapotranspiration, soil moisture, snow water equivalent, and other hydrologic states and fluxes. The models were driven by the bias-adjusted 4-kilometer-resolution, long-term regional hydroclimate simulation over the conterminous United States dataset (CONUS404). We assessed spatial and temporal error distributions by comparing monthly simulations at the 12-digit hydrologic unit code and regional scale from both models against external benchmarking datasets. Results showed that average annual rainfall across the CONUS was 857 millimeters per year for the period of analysis, with water year 2012 the driest year (729 millimeters) and water year 2019 the wettest year (995 millimeters). Key interannual variability results included the following: (1) the California–Nevada hydrologic region had the highest variability in precipitation and snow accumulation, and (2) the Texas hydrologic region was among hydrologic regions with the highest variability in precipitation. We related interannual variability in precipitation to storage volumes in soil moisture, snow water equivalent, and lakes and reservoirs to highlight areas with little storage and large year-to-year variability in precipitation. These areas included the Southern High Plains, Central High Plains, Texas, Souris–Red–Rainy, Mississippi Embayment, and Midwest regions. Our analysis of groundwater-level data showed that several of these areas overlap aquifers where groundwater levels were considerably lower than historical averages, including the Colorado Plateaus aquifers, the Rio Grande aquifer system, and the Central and Southern regions of the High Plains aquifer. Many of these lowered groundwater levels are continuations of decades-long declines from overpumping that started well before the assessment period. The resulting water budgets and their analyses provide a high-resolution foundational assessment of the mean state and variability of the terrestrial hydrologic cycle across the CONUS and Alaska, Hawaii, and Puerto Rico to support a wide range of water resource management applications.

Professional Paper↗

USGS2025

Integrated water availability in the conterminous United States, 2010–20

Water availability is defined as the spatial and temporal distribution of water quantity and quality as it relates to the needs of humans and ecosystems. Broad assessment of water availability requires the consideration of multiple indicators because water users have different sensitivities to the degradation of water conditions. This chapter draws upon estimates of water supply, water use, and water quality to develop an integrated assessment of water availability in the conterminous United States (CONUS) for water years 2010–2020. The surface water-supply and use index (SUI) was used to express limitation arising from high water consumption in relation to water supply. Ecological stress was also assessed using indicators of ecologically detrimental flow alteration. Benchmarks of human and ecological health were used to assess water quality in relation to several key uses nationwide. In all, we find that 10 of 18 hydrologic regions have severe water stress in at least 1 indicator. Furthermore, it was common for regions to have high or severe stress in more than one indicator, which emphasizes that limitations often co-occur. For example, regions with high SUIs may also have an increased tendency to experience water quality degradation or ecologically detrimental flow alteration. Furthermore, we compared the spatial distribution of water availability against the Centers for Disease Control Social Vulnerability Index (SVI) to examine the relative distribution of socially vulnerable populations in relation to limitations on water availability. We found a tendency for an increasing segment of the population exposed to elevated SUI or water-quality degradation to be from socially vulnerable groups, as defined by SVI. This finding is similar to other studies that have noted greater water-availability limitations among socially vulnerable groups. By considering multiple indicators of water availability as a whole, greater insight into the distribution of limitations affecting water availability was gained and contributed to a more comprehensive assessment.

conterminous United States↗

USGS2025

Local water use and climate drive water stress over the conterminous United States with substantial impacts to fish species of conservation concern

There is a growing need for consistent, large-scale estimates of water availability to identify and avoid potential conflicts among human and ecosystem uses of water. We present an assessment of water limitation, defined as the monthly balance (difference) between water supply ( ws ) and human consumptive water use ( wc ), for the conterminous United States (CONUS) during water years 2010–2020. We estimate that 26.7 million Americans, 8% of CONUS population, live in areas with chronic high or severe water limitation. Although ws greatly exceeds wc at the CONUS scale, water is limited locally or regionally due to spatial and temporal patterns in climate and wc . Our water limitation metric, the monthly supply and use index (SUI), peaked in 2012 during a widespread drought when 38% of the CONUS land area experienced elevated water stress. The central and southwestern U.S. experienced the highest SUI due to the combination of low ws and high wc , especially for crop irrigation. Spatial overlays of SUI and habitat ranges for fish species, including those of conservation concern, revealed that several species had notable proportions of their habitat exposed to high or severe water limitation during spawning season over the modeled time period, especially the Arkansas River shiner. Water supply ( ws ) was calculated from two CONUS, physically based, hydrologic models while wc was calculated from three CONUS models of water use for crop irrigation, thermoelectric power generation, and public supply. The ws and wc values were routed through a stream network and used to calculate water limitation for human populations and fish species at the scale of 12-digit hydrologic unit codes (HUC12s, 50-100 km 2 catchments) and then analyzed using SUI. Evaluation of water availability at higher spatial and temporal resolution promotes more comprehensive analyses of the drivers of water availability and can be combined with complementary studies of water quality and water limiting thresholds to better understand the limitations on water availability.

conterminous United States↗

USGS2024

Urbanization and water management control stream water quality along a mountain to plains transition

Urbanization can have substantial effects on water quality due to altered hydrology and introduction of constituents to water bodies. In arid and semi-arid environments, streams are further stressed by dewatering as a result of diversions. We conducted a high-resolution synoptic survey of two streams in Colorado, USA that transition abruptly from granitic/metamorphic forested mountains to sedimentary urbanized plains and are both highly managed for water supply, yet differ in degree of urbanization. A synoptic mass balance approach developed for mine drainage applications was adapted to elucidate effects of urbanization, geology, and diversions on stream chemistry during baseflow conditions. Urbanization was a more important driver of stream concentrations than geology. The urban area was a strong source of bromide, calcium, chloride, and manganese, while lanthanum and dissolved organic carbon were primarily sourced from the mountains. A majority of streamflow was removed by diversions near the mountains/plains interface. Groundwater accounted for 31% of the subsequent flow increase to the urbanized stream, and delivered at least 33% of chloride loading. Constituents that were primarily urban-derived (bromide, calcium, chloride, and manganese) were 2–3 times higher in the urban region due to diversions; without diversions, stream water quality would have largely retained characteristics of forested streams through the urban reach. This study provides insights into processes that affect water quality in highly managed streams of the semi-arid western USA.

Colorado↗

USGS2023

Integrated water resources trend assessments: State of the science, challenges, and opportunities for advancement

Water is vital to human life and healthy ecosystems. Here we outline the current state of national-scale water resources trend assessments, identify key gaps, and suggest advancements to better address critical issues related to changes in water resources that may threaten human development or the environment. Questions like, “Do we have less suitable drinking water now than we had 20 years ago?” or “Are flood events more common now than they were in the past?” prompted improvements in data, trend estimation methods, and modeling frameworks to track changes in, and better understand how land use and climate influence four water resources domains: surface and groundwater quantity and quality. However, continued advancement in trend assessments to better address issues related to changes in water availability is needed. Areas of need include more timely and efficient delivery of water resources trend results and improved capacity to estimate trends at unmonitored locations. Additional integration pieces include increased understanding of groundwater–surface water interactions, incorporation of both quantity and quality trends into water availability estimates, and the refinement of trend metrics to account for the competing needs of society and ecological integrity. Coupled with improved driver attribution studies, these components will better inform current and future water resources management.

Journal of the American Water Resource Association↗

USGS2023

Watershed carbon yield derived from gauge observations and river network connectivity in the United States

River networks play a critical role in the global carbon cycle. Although global/continental scale riverine carbon cycle studies demonstrate the significance of rivers and streams for linking land and coastal regions, the lack of spatially distributed riverine carbon load data represents a gap for quantifying riverine carbon net gain or net loss in different regions, understanding mechanisms and factors that influence the riverine carbon cycle, and testing simulations of aquatic carbon cycle models at fine scales. Here, we (1) derive the riverine load of particulate organic carbon (POC) and dissolved organic carbon (DOC) for over 1,000 hydrologic stations across the Conterminous United States (CONUS) and (2) use the river network connectivity information for over 80,000 catchment units within the National Hydrography Dataset Plus (NHDPlus) to estimate riverine POC and DOC net gain or net loss for watersheds controlled between upstream-downstream hydrologic stations. The new riverine carbon load and watershed net gain/loss represent a unique contribution to support future studies for better understanding and quantification of riverine carbon cycles.

Scientific Data↗

USGS2023

Dissolved carbon export by large river systems is influenced by source area heterogeneity

Rivers and streams export inorganic and organic carbon derived from contributing landscapes and so downstream carbon fluxes are important quantitative indicators of change in ecosystem function and for the full accounting of terrestrial carbon budgets. Carbon concentration-discharge ( C-Q ) relationships in rivers provide important information about carbon source and behavior in watersheds and are useful for estimating carbon export. However, C-Q relationships are complex in large river systems because of spatial and temporal heterogeneity in carbon dynamics across the watershed and river networks. We quantified dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) fluxes in the Upper Mississippi River basin and investigated their relationships with land cover and hydrology. The magnitude of dissolved carbon yields ranged widely among stations, 0.6–5.7 g DOC m −2 yr −1 and 2.9–11.8 g DIC m −2 yr −1 . Spatial patterns in carbon fluxes were strongly related to land cover, with agricultural sites having high DIC/low DOC exports and forested and wetland areas having the opposite. DIC was always negatively related to discharge ( Q ), while the DOC- Q relationship varied with land cover. Differential behavior of carbon across the basin resulted in Q having a weak relationship with DOC and DIC at the basin outlet. Hence, there is a need to improve understanding of headwater terrestrial-to-aquatic carbon connections in order to improve basin-to-continental-scale carbon export estimates. Our results demonstrate that quantitative understanding of carbon export by large rivers can be improved by incorporating stream network information, such as the timing, location, and source of constituent flux, rather than relying solely upon relationships between constituent behavior and seasonality or discharge at the basin outlet.

Minnesota, Wisconsin↗

USGS2023

Bioavailability of dissolved organic matter varies with anthropogenic landcover in the Upper Mississippi River Basin

Anthropogenic conversion of forests and wetlands to agricultural and urban landcovers impacts dissolved organic matter (DOM) within streams draining these catchments. Research on how landcover conversion impacts DOM molecular level composition and bioavailability, however, is lacking. In the Upper Mississippi River Basin (UMRB), water from low-order streams and rivers draining one of three dominant landcovers (forest, agriculture, urban) was incubated for 28 days to determine bioavailable DOC (BDOC) concentrations and changes in DOM composition. The BDOC concentration averaged 0.49 ± 0.30 mg L −1 across all samples and was significantly higher in streams draining urban catchments (0.72 ± 0.34 mg L −1 ) compared to streams draining agricultural (0.28 ± 0.15 mg L −1 ) and forested (0.47 ± 0.17 mg L −1 ) catchments. Percent BDOC was significantly greater in urban (10% ± 4.4%) streams compared to forested streams (5.6% ± 3.2%), corresponding with greater relative abundances of aliphatic and N-containing aliphatic compounds in urban streams. Aliphatic compound relative abundance decreased across all landcovers during the bioincubation (average -4.1% ± 10%), whereas polyphenolics and condensed aromatics increased in relative abundance across all landcovers (average of +1.4% ± 5.9% and +1.8% ± 10%, respectively). Overall, the conversion of forested to urban landcover had a larger impact on stream DOM bioavailability in the UMRB compared to conversion to agricultural landcover. Future research examining the impacts of anthropogenic landcover conversion on stream DOM composition and bioavailability needs to be expanded to a range of spatial scales and to different ecotones, especially with continued landcover alterations.

Minnesota, Iowa, North Dakota, South Dakota, Wisco↗

USGS2021

Anthropogenic landcover impacts fluvial dissolved organic matter composition in the Upper Mississippi River Basin

Landcover changes have altered the natural carbon cycle; however, most landcover studies focus on either forest conversion to agriculture or urban, rarely both. We present differences in dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) molecular composition within Upper Mississippi River Basin low order streams and rivers draining one of three dominant landcovers (forest, agriculture, and urban). Streams draining forest and urban landcovers have greater DOC concentrations, likely driven by differences in carbon sourcing, microbial processing, and soil disturbance. Using Fourier transform-ion cyclotron resonance mass spectrometry, 24% of assigned molecular formulae are common across all landcovers. Relative abundances of N-,S- heteroatomic formulae (CHON, CHOS, CHONS) are higher for agricultural and urban streams, with agricultural stream DOM having more N-containing formulae compared to urban stream DOM, which has more S-containing formulae. Higher N-,S- heteroatomic formulae abundance, along with enrichment in aliphatic, N-aliphatic, and highly unsaturated and phenolic (low O/C) compound categories within agricultural and urban stream DOM are likely to result from increased anthropogenic inputs, autochthonous production, and microbial processing associated with agricultural and urban impacts. Reduced N-,S- heteroatomic formulae abundances in forested stream DOM, along with enrichments in condensed aromatics, polyphenolics, and highly unsaturated phenolic (high O/C) compound categories, likely reflect greater contributions from surrounding organic-rich forest soil and vegetation. Overall, landcover change from forested to agriculture lowers DOC concentrations and changes from forested to agriculture or urban increases autochthonous, and presumably more biolabile, DOM contributions with ramifications for stream biogeochemical cycling.

Iowa, Minnesota, Wisconsin↗

USGS2021

Aquatic-terrestrial linkages control metabolism and carbon dynamics in a mid-sized, urban stream influenced by snowmelt

Freshwater streams can exchange nutrients and carbon with the surrounding terrestrial environment through various mechanisms including physical erosion, flooding, leaf drop, and snowmelt. These aquatic-terrestrial interactions are crucial in carbon mobilization, transformation, ecosystem productivity, and have important implications for the role of freshwater ecosystems in the global carbon budget. We utilized high-frequency oxygen, temperature, and carbon dioxide (CO 2 ) data to infer watershed connectivity in Boulder Creek, a mid-sized (1160 km 2 ) watershed located in Colorado, USA. Daily modeled gross primary production (GPP), ecosystem respiration (ER), net ecosystem production (NEP), and reaeration coefficients ( K 600 ) were paired with high-frequency, in-situ dissolved CO 2 data to characterize changes in metabolic regime and carbon flux on a stream influenced by seasonal snowmelt. GPP and ER were correlated ( ρ = −0.72, p ≪ 0.001) during the non-snowmelt period and NEP was frequently negative. Mean F CO2 during the non-snowmelt period was approximately 302 (±171) mmol C m −2 d −1 and was primarily supported by watershed CO 2 inputs. During snowmelt, GPP and ER were not significantly correlated ( ρ = −0.22, p = 0.05), and mean NEP was significantly more negative than during non-snowmelt. Watershed connectivity was higher during snowmelt, as evidenced by significantly higher F CO2 (843 ± 338 mmol C m −2 d −1 ) and greater allochthonous CO 2 inputs than during non-snowmelt periods, emphasizing the effects of seasonal differences in aquatic-terrestrial linkages in this stream. We suggest that our understanding of watershed carbon budgets is subject to temporal dynamics which control the degree of connectivity between terrestrial and aquatic ecosystems.

Colorado↗

USGS2020

Nitrate in streams during winter low‐flow conditions as an indicator of legacy nitrate

Winter low‐flow (LF) conditions in streams provide a potential opportunity to evaluate the importance of legacy nitrate in catchments due to the dominance of slow‐flow transport pathways and lowered biotic activity. In this study, the concentration, flux, and trend of nitrate in streams during winter low‐flow conditions were analyzed at 320 sites in the conterminous United States. LF flow‐normalized nitrate concentrations varied from <0.1 to >20 mg‐N L ‐1 and LF conditions contributed between 2% and 98% of the winter nitrate flux. LF nitrate concentrations generally exceeded 2.5 mg‐N L ‐1 in the upper Midwest, with smaller regions of high LF nitrate concentrations in eastern Texas and along the northern mid‐Atlantic coast. Groundwater was inferred to be the primary or sole contributor of nitrate to streams during winter LF conditions at 140 of our 320 sites. Among these 140 sites, nitrate from groundwater comprised 45% or more of the winter nitrate flux at a quarter of the sites. Among the same 140 sites, concentrations of nitrate in streams during winter LF conditions generally increased between 2002 and 2012 at sites where 40% or more of the winter flux was from groundwater, suggesting that concentrations of nitrate in the contributing groundwater system were increasing. Using metrics developed herein, we characterize the potential importance of legacy nitrate at sites in this study and discuss methods to characterize sites with fewer samples than required by our models or at sites without continuous stream discharge measurements.

Water Resources Research↗

USGS2020

Challenges in quantifying air-water carbon dioxide flux using estuarine water quality data: Case study for Chesapeake Bay

Estuaries play an uncertain but potentially important role in the global carbon cycle via CO 2 outgassing. The uncertainty mainly stems from the paucity of studies that document the full spatial and temporal variability of estuarine surface water partial pressure of carbon dioxide ( p CO 2 ). Here, we explore the potential of utilizing the abundance of pH data from historical water quality monitoring programs to fill the data void via a case study of the mainstem Chesapeake Bay (eastern United States). We calculate p CO 2 and the air-water CO 2 flux at monthly resolution from 1998 to 2018 from tidal fresh to polyhaline waters, paying special attention to the error estimation. The biggest error is due to the pH measurement error, and errors due to the gas transfer velocity, temporal sampling, the alkalinity mixing model, and the organic alkalinity estimation are 72%, 27%, 15%, and 5%, respectively, of the error due to pH. Seasonal, interannual, and spatial variability in the air-water flux and surface p CO 2 is high, and a correlation analysis with oxygen reveals that this variability is driven largely by biological processes. Averaged over 1998–2018, the mainstem bay is a weak net source of CO 2 to the atmosphere of 1.2 (1.1, 1.4) mol m −2 yr −1 (best estimate and 95% confidence interval). Our findings suggest that the abundance of historical pH measurements in estuaries around the globe should be mined in order to constrain the large spatial and temporal variability of the CO 2 exchange between estuaries and the atmosphere.

Maryland, Virginia↗

USGS2020

Landscape drivers of dynamic change in water quality of US rivers

Water security is a top concern for social well-being and dramatic changes in the availability of freshwater have occurred as a result of human uses and landscape management. Elevated nutrient loading and perturbations to major ion composition have resulted from human activities and have degraded freshwater resources. This study addresses the emerging nature of stream water quality in the 21st century through analysis of concentrations and trends in a wide variety of constituents in streams and rivers of the U.S. Concentrations of fifteen separate water quality parameters including nutrients, major ions, sediment, and specific conductance were analyzed over the period 1982-2012 and a targeted trend analysis was performed from 1992-2012. Although environmental policy is geared toward addressing the long-standing problem of nutrient overenrichment, these efforts have had uneven success, with decreasing nutrient concentrations at urbanized sites and little to no change at agricultural sites. However, freshwaters are being salinized rapidly in all human-dominated land use types. Increasing salinity negatively affects biodiversity, mobilizes sediment-bound contaminants, and increases lead contamination of drinking water but the effects are poorly quantified. Therefore, while efforts to control nutrients are ongoing, rapid salinity increases are ushering in a new set of poorly-defined issues.

Environmental Science & Technology↗

USGS2020

Calcite precipitation in Lake Powell reduces alkalinity and total salt loading to the Lower Colorado River Basin

Reservoirs can retain and transform carbon, nitrogen, phosphorus, and silica, but less is known about their effects on other biogeochemically relevant solutes. The salinization of freshwater ecosystems is a growing concern in many regions, and the role of reservoirs in salinity transport is an important research frontier. Here, we examine how a large desert southwest reservoir, Lake Powell, has altered the downstream transport of total dissolved solids (TDSs) as well as the dominant cations and anions comprising the TDS pool ( , , and Ca 2+ ). Average downstream TDS concentrations have declined significantly since river impoundment and seasonal fluctuations in TDS concentrations have become more modulated, but year to year variation in TDS concentrations has remained similar. While some of the reductions in TDS concentration can be attributed to watershed management, we find that Lake Powell retains about 10% of the TDS loaded to the system (1991 Mg TDS d −1 ). Much of this retention is occurring in the forms of calcium and bicarbonate, likely via calcite precipitation, and is equivalent to an average burial of 522 mg C m −2 d −1 , thus reducing the alkalinity of downstream water. Flow‐weighted modeling suggests that, in the absence of Lake Powell, downstream salinity limits would be surpassed at the outflow to Lake Powell 41% of the time (vs. 0% of the time currently). Understanding the dominant mechanisms regulating solute transport through the reservoir is important given the relevance for downstream drinking water and irrigation concerns, biogeochemical cycling, and the high potential for reduced flows in the future.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

USGS2020

Alkalinity in tidal tributaries of the Chesapeake Bay

Despite the important role of alkalinity in estuarine carbon cycling, the seasonal and decadal variability of alkalinity, particularly within multiple tidal tributaries of the same estuary, is poorly understood. Here we analyze more than 26,000 alkalinity measurements, mostly from the 1980s and 1990s, in the major tidal tributaries of the Chesapeake Bay, a large, coastal-plain estuary of eastern North America. The long-term means of alkalinity in tidal-fresh waters vary by a factor of 6 among seven tidal tributaries, reflecting the alkalinity of non-tidal rivers draining to these estuaries. At 25 stations, mostly in the Potomac River Estuary, we find significant long-term increasing trends that exceed the trends in the non-tidal rivers upstream of those stations. Box model calculations in the Potomac River Estuary indicate that the main cause of the estuarine trends is a declining alkalinity sink. The magnitude of this sink is consistent with a simple model of calcification by the invasive bivalve Corbicula fluminea. More generally, in tidal tributaries fed by high-alkalinity non-tidal rivers, alkalinity is consumed, with sinks ranging from 8 to 27% of the upstream input. In contrast, tidal tributaries that are fed by low-alkalinity non-tidal rivers have sources of alkalinity amounting to 34 to 171% of the upstream input. For a single estuarine system, the Chesapeake Bay has diverse alkalinity dynamics and can thus serve as a laboratory for studying the numerous processes influencing alkalinity among the world’s estuaries.

Maryland, Virginia↗

USGS2020

Influence of land use and region on glyphosate and aminomethylphosphonic acid in streams in the USA

Glyphosate is the most widely used herbicide in the United States for agricultural and non-agricultural weed control. Many studies demonstrate possible effects of glyphosate and its degradate AMPA on human and ecological health. Although glyphosate is thought to have limited mobility in soil, it is found year-round in many rivers and streams throughout the world in both agricultural and developed environments. It is vitally important to continue to increase the knowledge base of glyphosate use, distribution, transport, and impacts on human health and the environment. Here we show that glyphosate and AMPA are found in nearly all of 70 streams throughout the United States at concentrations far below human health or ecological benchmarks, with less occurrence in the Northeast and that undeveloped land, classified as such by land use near the sampling station, has lower concentrations compared to other types of land. Results also show that sites with large watersheds tend to have more AMPA than glyphosate and the opposite is true for small watersheds. Travel times and opportunity for glyphosate to degrade to AMPA and for reservoirs of AMPA to grow are greater in large watersheds. Factors that promoted quick movement of glyphosate to streams, such as subsurface tile or storm drains, sewers, overland flow from developed landscapes, and arid landscapes were associated with sites that had greater concentrations of glyphosate compared to AMPA. These results contribute contemporary information and generalized interpretations adding to the knowledge base of the fate of glyphosate on a national scale and provide a springboard for further exploration of technical processes controlling transport to streams.

Science of the Total Environment↗