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E.E. Foord

Publications and source records attributed to E.E. Foord.

At least 37 records · Page 2Linked to original sources

Lithium-bearing fluor-arfvedsonite from Hurricane Mountain, New Hampshire: A crystal-chemical study

The structures of two crystals of Li-bearing fluor-arfvedsonite (1) (K0.32Na0.68)Na2(Li0.48Fe 2+2.83Mn2+0.10Zn 0.06Fe3+1.46Ti0.07) (Si7.88Al0.12)O22[Fu1.15(OH) 0.85] and (2) (K0.25Na0.75)Na2(Li0.48Fe 2+2.84Mn2+0.11Zn 0.05Fe3+1.45Ti0.07)(Si 7.89Al0.11)O22[F1.35(OH) 0.65] from a granitic pegmatite, Hurricane Mountain, New Hampshire, have been refined to R indices of 1.5(1.6)% based on 1380(1387) reflections measured with MoK?? X-radiation. The unit cell parameters are (1) a 9.838(4), b 17.991(6), c 5.315(2) A??, 103.78(3)??, V 913.7 A??3 and (2) a 9.832(3), b 17.990(7), c 5.316(3) A??, ?? 103.79(3)??, V 913.2 A??3. Site-scattering refinement shows Li to be completely ordered at the M(3) site in these crystals. The amphibole composition is intermediate between fluor-arfvedsonite and fluor-ferro-leakeite with a small component (???10%) of fluor-ferro-ferri-nybo??ite. These amphibole crystals project into miarolitic cavities in a pegmatitic phase of a riebeckite granite. The early-crystallizing amphibole is close to fluor-ferro-leakeite in composition, but becomes progressively depleted in Li and F as crystals project out into miarolitic cavities; the final amphibole to crystallize is a fibrous Li-poor riebeckite. Li plays a significant role in late-stage fractionation involving the crystallization of alkali amphibole in peralkaline granitic environments.

Canadian Mineralogist↗

Calcioaravaipaite: A new mineral and associated lead fluoride minerals from the Grand Reef mine, Graham County, Arizona

The Grand Reef mine in southeastern Arizona, best known to collectors for superb crystals of linarite, is also the type locality far a unique suite of lead fluoride minerals. Grandreefite, pseudograndreefite, laurelite, aravaipaite, and artroeite have been found nowhere else; added to this group is calcioaravaipaite, described here for the first time.

Mineralogical Record↗

The atomic arrangement of iimoriite-(Y), Y2(SiO4)(CO3)

Iimoriite-(Y) from Bokan Mountain, Prince of Wales Island, Alaska has been studied using single-crystal X-ray-diffraction techniques. The mineral, ideally Y2(SiO4)(CO3), crystallizes in space group P1, with a 6.5495(13), b 6.6291(14), c 6.4395(11)A??, ?? 116.364(15), ?? 92.556(15) and ?? 95.506(17)??. The atomic arrangement has been solved and refined to an R value of 0.019. The arrangement of atoms consists of alternating (011) slabs of orthosilicate groups and carbonate groups, with no sharing of oxygen atoms between anionic complexes in adjacent slabs. Y1 atoms separate adjacent tetrahedra along [100] within the orthosilicate slab, and Y2 atoms separate adjacent carbonate groups along [100] within the carbonate slab. Adjacent orthosilicate and carbonate slabs are linked in (100) by bonding Y atoms from each slab to oxygen atoms of adjacent slabs, in the form of YO8 polyhedra. The Y1 atoms exist in Y12O14 dimers in the orthosilicate slab, and the Y2 atoms exist in continuous [011] ribbons of edge-sharing Y2O8 polyhedra in the carbonate slab.

Canadian Mineralogist↗

Mineralogical and geochemical evolution of micas from miarolitic pegmatites of the anorogenic pikes peak batholith, Colorado

A suite of 29 micas from miarolitic pegmatites associated with granitic units of the anorogenic Pikes Peak batholith (1.08-1.02 Ga), Colorado range in composition, and follow in paragenetic sequence, from 1M siderophyllite (N = 1), and 3T or 2M1 lithian biotite (N = 5) to 1M zinnwaldite (N = 20) and 1M ferroan lepidolite (N = 1). Locally, 1M (?) phlogopite (N = 1) and ferroan 2M1 muscovite (N = 1) are also present. Pervasive, late-stage hydrothermal alteration along with possible supergene weathering of many of these micas produced vermiculite. Additionally, some vugs and cavities were filled with chlorite and/or smectite. Early crystallized micas form tapered columnar crystals in graphic pegmatite, growing toward, and adjacent to the miarolitic cavity zone which contains the later crystallized micas. Principal associated minerals are quartz, microcline perthite (mostly amazonite), and albite, with local topaz or fluorite, and rarely tourmaline (schorl-elbaite). Progressively younger micas of the main crystallization sequence display increasing Si, Li, F, and Al/Ga, and decreasing total Fe, Mg, and octahedral occupancy. The zinc content of all micas is considerably elevated, whereas Mn, Rb, Cs, and Sc are moderate and T1 is very low. Early siderophyllite and lithian biotite show a narrow range of FeO/Fe2O3 (5.6-8.0), whereas later zinnwaldite is much more variable (2.4-40.3). Annite of the host granite and early graphic pegmatite is compositionally homogeneous, but most mica crystals from cavities show remarkable compositional and abrupt, sharp and distinct color zoning. Most cavity-grown zinnwaldite crystals show a decrease, from core to rim, in total Fe and Mg, whereas Si, Li and F increase and Mn, Rb, Cs and Na are essentially constant. A few to more than 100 color zones have been identified in some mica crystals. The zones are well correlated with the Ti content (<0.2 wt. % TiO2 colorless, 0.4-0.6 wt.% TiO2 red-brown). The total Fe content may or may not correlate with color zoning, whereas Zn variations (up to 1.1 wt. %) are entirely independent. The dark color zones probably reflect Fe-Ti charge transfer. The mica composition sequence described here is typical of the extreme fractionation observed in pegmatites of the NYF family, associated with anorogenec granites. Elevated Fe, Zn, and enhanced Sc contents are characteristic of this family. Strong enrichment in Li, Rb, and F is present, particularly in the micas of the miarolitic cavities. Sharp color zonation and compositional variation in cavity-grown zinnwaldite and ferroan lepidolite crystals suggest rapid changes in the intensive parameters, particularly the f(O2), of the parent fluid during the final stages of pegmatite consolidation ?? 1995 Springer-Verlag.

Mineralogy and Petrology↗

A new U-Ti-Ca-HREE hydrated oxide and associated niobian rutile from Topaz Valley, Utah

In October of 1988, specimens of yellow and/or white acicular needles growing out of equant to platy hematite were collected from the east side of Topaz Valley. For the past five years, attempts have been made by all of the authors to completely characterize what is believed to be a new mineral species. Because of several major factors the space group, exact formula, and structure are still unknown. The potentially new mineral and some associated minerals are described here with the hope that elsewhere in the world better and more material exists that will allow complete characterization. -from Authors

Mineralogical Record↗

Pink topaz from the Thomas Range, Juab County, Utah

The Thomas Range is world-famous for its production of topaz Al2SiO4(F,OH)2, occurring in lithophysal cavities in rhyolite. Topaz Valley, at the southern end of the range, is perhaps the single most famous locality. While fine-quality, sherry-orange crystals to 5 cm or more in length occur at various localities, pale to medium pink crystals were first reported from the Thomas Range in 1934. The cause of the unusual coloration, unknown for 60 years, is now believed to be substitution of Mn3+ ?? Fe3+ for Al3+. -Authors

Mineralogical Record↗

McCrillisite, NaCs(Be,Li)Zr2(PO4)4.1-2H2O, a new mineral species from Mount Mica, Oxford County, Maine, and new data for gainesite

McCrillisite, a member of the gainesite group, occurs in the Mount Mica granitic pegmatite, South Paris, Oxford County, Maine. The mineral is a product of late-stage hydrothermal alteration and is associated with approximately 20 other silicate, oxide, carbonate, arsenite and phosphate minerals. Crystals occur in mm- to cm-sized cavities, and individuals are up to 1.2 mm in maximum dimension. The crystallography and mineral chemistry of McCrillisite are described. -from Authors

Canadian Mineralogist↗

Plumboan crichtonite: from the Fazenda Guariba, Minas Gerais, Brazil

Senaite, Pb(Ti,Fe,Mn)21O38, a member of the crichtonite group, was first described from alluvial gravels near Dattas, Minas Gerais, Brazil. It was subsequently reported (always from alluvial stream gravels) from about seven additional localities. "Senaite' from the first in situ source in Brazil, at the Fazenda Guariba, Minas Gerais, Brazil was described by Cassedanne (1988). Approximately 20 crystals of "senaite' from the Fazenda Guariba were examined chemically and all were found to be plumboan crichtonite rather than senaite. -from Authors

Mineralogical Record↗

Thortveitite and associated Sc-bearing minerals from Ravalli County, Montana

The rare Sc mineral thortveitite, (Sc,Y)2Si2O7, occurs as ??m- to mm-sized crystals in fluorite-bearing granitic pegmatites and the host melagabbro within the Crystal Mountain fluorite deposit, Ravalli County, Montana. Thortveitite is found as colorless and clear to smoky and translucent, subhedral to euhedral prisms up to 3 mm in length in the massive fluroite, as mm-sized anhedra to subhedra in diopside and edenite, and as ??m-sized droplet-like crystals in actinolite. Micrometric textures suggest that some thortveitite exsolved from actinolite, which contains between 1.2 and 2.9 wt.% Sc2O3. The source of the Sc is believed to be magmatic. The physical, optical and crystallographic properties of thortveitite are described. -from Authors

Canadian Mineralogist↗

Kosnarite, KZr2(PO4)3, a new mineral from Mount Mica and Black Mountain, Oxford County, Maine

Kosnarite, ideally KZr2(PO4)3, has been identified as part of a late-stage, secondary phosphate mineral assemblage from the Mount Mica pegmatite at Paris, and from the Black Mountain pegmatite, Rumford, Oxford County, Maine. Kosnarite from Mount Mica occurs as pseudocubic rhombohedral crystals, as much as 0.9 mm in maximum dimension, that display the dominant {102} form. Color ranges from pale blue to blue-green to nearly colorless. The mineral has a white streak, is transparent, has a vitreous luster, and is nonfluorescent in ultraviolet light. It has a hardness of 4.5, is brittle with a conchoidal fracture, and has perfect {102} cleavage. Kosnarite from Black Mountain is almost pure KZr2(PO4)3 with only trace amounts of Hf, Mn, Na, and Rb. The mineral is one of three known alkali zirconium phosphates; the others are gainesite and the Cs analogue of gainesite. -from Author

American Mineralogist↗

A monoclinic, pseudo-orthorhombic Au-Hg mineral of potential economic significance in Pleistocene Snake River alluvial deposits of southeastern Idaho

A mineral with the approximate composition of Au94Hg6 - Au88Hg12 (atomic %) has been identified in Pleistocene Snake River alluvial deposits. The gold-mercury mineral occurs as very small grains or as polycrystalline masses composed of subhedral to nearly euhedral attached crystals. Vibratory cold-polishing techniques with 0.05-??m alumina abrasive for polished sections revealed a porous internal texture for most subhedral crystals after 48-72 hours of treatment. Thus, optical character (isotropic or anisotropic) could not be determined by reflected-light microscopy, and pore-free areas were too small for measurement of reflectance. X-ray-diffraction lines rather than individual reflections (spots), on powder camera X-ray films of unrotated spindles of single grains that morphologically appear to be single crystals, indicate that individual subhedral or euhedral crystals are composed of domains in random orientation. Thus, no material was found suitable for single-crystal X-ray diffraction studies. -from Authors

Canadian Mineralogist↗

Boromuscovite, a new member of the mica group, from the Little Three mine pegmatite, Ramona district, San Diego County, California

Boromuscovite, ideally KAl2(Si3B)O10(OH,F)2, in which [4]Al is replaced by B relative to muscovite, occurs as a late-stage, postpocket rupture mineral within the New Spaulding Pocket, main Little Three pegmatite dike. The mineral is white to cream colored and occurs as a porcelaneous veneer and coating on primary minerals. The average grain size is less than 3-4 ??m, but the coatings may be as much as 1 cm or more thick. Fragments of topaz, albite, elbaite, and other pocket minerals are included in the coating. The boromuscovite precipitated from a late-stage hydothermal fluid; it occurs only as a snowlike coating. Chemical composition, unit-cell parameters, Mohs hardness, cleavage, fracture, and optical properties are reported. -from Authors

American Mineralogist↗

Magnesioferrite from the Cretaceous-Tertiary boundary, Caravaca, Spain

Magnesioferrite grading toward magnetite has been identified as a very small but meaningful constituent of the basal iron-rich portion of the Cretaceous-Tertiary (K-T) boundary clay at the Barranco del Gredero section, Caravaca, Spain. This spinel-type phase and others of the spinel group, found in K-T boundary clays at many widely separated sites, have been proposed as representing unaltered remnants of ejecta deposited from an earth-girdling dust cloud formed from the impact of an asteroid or other large bolide at the end of the Cretaceous period. The magnesioferrite occurs as euhedral, frequently skeletal, micron-sized octahedral crystals. The magnesioferrite contains29 ± 11 ppb Ir, which accounts for only part of the Ir anomaly at this K-T boundary layer(52 ± 1 ppb Ir). Major element analyses of the magnesioferrite show variable compositions. Some minor solid solution exists toward hercynite-spinel and chromite-magnesiochromite. A trevorite-nichromite (NiFe 2 O 4 -NiCr 2 O 4 ) component is also present. The analyses are very similar to those reported for sites at Furlo and Petriccio, Umbria, Italy. On the basis of the morphology and general composition of the magnesioferrite grains, rapid crystallization at high temperature is indicated, most likely directly from a vapor phase and in an environment of moderate oxygen fugacity. Elemental similarity with metallic alloy injected into rocks beneath two known impact craters suggests that part of the magnesioferrite may be derived from the vaporized chondritic bolide itself, or from the mantle; there is no supporting evidence for its derivation from crustal target rocks.

Earth and Planetary Science Letters↗