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Geology topics

Donald O. Rosenberry

Publications and source records attributed to Donald O. Rosenberry.

At least 37 records · Page 2Linked to original sources

Using halogens (Cl, Br, I) to understand the hydrogeochemical evolution of drought-derived saline porewater beneath a prairie wetland

Numerous closed-basin prairie wetlands throughout the Prairie Pothole Region (PPR) of North America maintain moderate surface pond salinities (total dissolved solids [TDS] from 1 to 10 g L − 1 ) under semiarid climate by accumulation of gypsum and saline lenses of sulfate-rich porewater (TDS > 10 g L − 1 ) in wetland sediments during droughts. In order to understand the hydrogeochemical origin and composition of these saline porewaters, we made a detailed geochemical survey of Cl − , SO 4 2 − , Br, and I in the porewater, pondwater, and upland groundwater of a typical closed-basin prairie wetland (P1 in the Cottonwood Lake study area, North Dakota). Concentrations of Cl − ranged up to 5.9 mM in the saline porewaters, and was strongly correlated with SO 4 2 − and Br (Pearson's r > 0.7, p < 0.05; concentrations ranging up to 131 mM and 39 μM, respectively) due to the conservative effects of surface water evaporation. In contrast, total dissolved I was not significantly correlated with Cl − (Pearson's r = 0.18, p = 0.273) and was concentrated in porewaters located above the saline lenses with a peak concentration of 4.1 μM beneath the center of the wetland— the highest value for dissolved I ever measured in a terrestrial aquatic system and an order of magnitude above that of seawater. We hypothesize that chromatographic separation between more mobile anions (Cl − , SO 4 2 − , Br − ) and I occurs during droughts when wetland ponds dry and sedimentary iodide (I − ) oxidizes to its less-mobile form, iodate (IO 3 − ). Understanding the origin and geochemical composition of porewater salinity that develops beneath prairie wetlands during drought can help to fingerprint sources of salinity to wetland ponds during wet climate and elucidate halogen systematics in saline and organic-rich subsurface environments associated with hydrocarbon generation.

North Dakota↗

Long-term changes in pond permanence, size, and salinity in Prairie Pothole Region wetlands: The role of groundwater-pond interaction

Study Region Cottonwood Lake area wetlands, North Dakota, U.S.A. Study Focus Fluctuations in pond permanence, size, and salinity are key features of prairie-pothole wetlands that provide a variety of wetland habitats for waterfowl in the northern prairie of North America. Observation of water-level and salinity fluctuations in a semi-permanent wetland pond over a 20-year period, included periods when the wetland occasionally was dry, as well as wetter years when the pond depth and surface extent doubled while volume increased 10 times. New hydrological insights for the study region Compared to all other measured budget components, groundwater flow into the pond often contributed the least water (8–28 percent) but the largest amount (>90 percent) of specific solutes to the water and solute budgets of the pond. In drier years flow from the pond into groundwater represented > 10 percent of water loss, and in 1992 was approximately equal to evapotranspiration loss. Also during the drier years, export of calcium, magnesium, sodium, potassium, chloride, and sulfate by flow from the pond to groundwater was substantial compared with previous or subsequent years, a process that would have been undetected if groundwater flux had been calculated as a net value. Independent quantification of water and solute gains and losses were essential to understand controls on water-level and salinity fluctuations in the pond in response to variable climate conditions.

Journal of Hydrology: Regional Studies↗

Drought-induced recharge promotes long-term storage of porewater salinity beneath a prairie wetland

Subsurface storage of sulfate salts allows closed-basin wetlands in the semiarid Prairie Pothole Region (PPR) of North America to maintain moderate surface water salinity (total dissolved solids [TDS] from 1 to 10 g L −1 ), which provides critical habitat for communities of aquatic biota. However, it is unclear how the salinity of wetland ponds will respond to a recent shift in mid-continental climate to wetter conditions. To understand better the mechanisms that control surface-subsurface salinity exchanges during regional dry-wet climate cycles, we made a detailed geoelectrical study of a closed-basin prairie wetland (P1 in the Cottonwood Lake Study Area, North Dakota) that is currently experiencing record wet conditions. We found saline lenses of sulfate-rich porewater (TDS > 10 g L −1 ) contained in fine-grained wetland sediments 2–4 m beneath the bathymetric low of the wetland and within the currently ponded area along the shoreline of a prior pond stand ( c . 1983). During the most recent drought (1988–1993), the wetland switched from a groundwater discharge to recharge function, allowing salts dissolved in surface runoff to move into wetland sediments beneath the bathymetric low of the basin. However, groundwater levels during this time did not decline to the elevation of the saline lenses, suggesting these features formed during more extended paleo-droughts and are stable in the subsurface on at least centennial timescales. We hypothesize a “drought-induced recharge” mechanism that allows wetland ponds to maintain moderate salinity under semiarid climate. Discharge of drought-derived saline groundwater has the potential to increase the salinity of wetland ponds during wet climate.

North Dakota↗

Estimating daily lake evaporation from biweekly energy‐budget data

Estimates of daily lake evaporation based on energy‐budget data are poor because of large errors associated with quantifying change in lake heat storage over periods of less than about 10 days. Energy‐budget evaporation was determined during approximately biweekly periods at a northern Minnesota, USA, lake for 5 years. Various combinations of shortwave radiation, air temperature, wind speed, lake‐surface temperature, and vapour‐pressure difference were related to energy‐budget evaporation using linear‐regression models in an effort to determine daily evaporation without requiring the heat‐storage term. The model that combined the product of shortwave radiation and air temperature with the product of vapour‐pressure difference and wind speed provided the second best fit based on statistics but provided the best daily data based on comparisons with evaporation determined with the eddy‐covariance method. Best‐model daily values ranged from −0.6 to 7.1 mm/day over a 5‐year period. Daily averages of best‐model evaporation and eddy‐covariance evaporation were nearly identical for all 28 days of comparisons with a standard deviation of the differences between the two methods of 0.68 mm/day. Best‐model daily evaporation also was compared with two other evaporation models, Jensen–Haise and a mass‐transfer model. Best‐model daily values were substantially improved relative to Jensen–Haise and mass‐transfer values when daily values were summed over biweekly energy‐budget periods for comparison with energy‐budget results.

Northern Minnesota↗

Evidence for a climate-induced ecohydrological state shift in wetland ecosystems of the southern Prairie Pothole Region

Changing magnitude, frequency, and timing of precipitation can influence aquatic-system hydrological, geochemical, and biological processes, in some cases resulting in system-wide shifts to an alternate state. Since the early 1990s, the southern Prairie Pothole Region has been subjected to an extended period of increased wetness resulting in marked changes to aquatic systems defining this region. We explored numerous lines of evidence to identify: (1) how the recent wet period compared to historical variability, (2) hydrological, geochemical, and biological responses, and (3) how these responses might represent a state shift in the region’s wetland ecosystems. We analyzed long-term climate records and compared how different hydrological variables responded in this wet period compared to decades before the observed shift. Additionally, we used multi-decadal records of waterfowl population and subsurface tile drain records to explore wildlife and human responses to a shifting climate. Since 1993, a novel precipitation regime corresponded with increased pond numbers, ponded-water depths, lake levels, stream flows, groundwater heights, soil-moisture, waterfowl populations, and installation of subsurface tile drains in agricultural fields. These observed changes reflect an alteration in water storage and movement across the landscape that in turn has altered solute sources and concentrations of prairie-pothole wetlands and has increased pond permanence. Combined, these changes represent significant evidence for a state shift in the ecohydrological functioning of the region’s wetland ecosystems, a shift that may require a significant refinement of the previously developed “wetland continuum” concept.

Prairie Pothole Region↗

Groundwater connectivity of upland-embedded wetlands in the Prairie Pothole Region

Groundwater connections from upland-embedded wetlands to downstream waterbodies remain poorly understood. In principle, water from upland-embedded wetlands situated high in a landscape should flow via groundwater to waterbodies situated lower in the landscape. However, the degree of groundwater connectivity varies across systems due to factors such as geologic setting, hydrologic conditions, and topography. We use numerical models to evaluate the conditions suitable for groundwater connectivity between upland-embedded wetlands and downstream waterbodies in the prairie pothole region of North Dakota (USA). Results show groundwater connectivity between upland-embedded wetlands and other waterbodies is restricted when these wetlands are surrounded by a mounding water table. However, connectivity exists among adjacent upland-embedded wetlands where water–table mounds do not form. In addition, the presence of sand layers greatly facilitates groundwater connectivity of upland-embedded wetlands. Anisotropy can facilitate connectivity via groundwater flow, but only if it becomes unrealistically large. These findings help consolidate previously divergent views on the significance of local and regional groundwater flow in the prairie pothole region.

North Dakota↗

Nutrient processes at the stream-lake interface for a channelized versus unmodified stream mouth

Inorganic forms of nitrogen and phosphorous impact freshwater lakes by stimulating primary production and affecting water quality and ecosystem health. Communities around the world are motivated to sustain and restore freshwater resources and are interested in processes controlling nutrient inputs. We studied the environment where streams flow into lakes, referred to as the stream-lake interface (SLI), for a channelized and unmodified stream outlet. Channelization is done to protect infrastructure or recreational beach areas. We collected hydraulic and nutrient data for surface water and shallow groundwater in two SLIs to develop conceptual models that describe characteristics that are representative of these hydrologic features. Water, heat, and solute transport models were used to evaluate hydrologic conceptualizations and estimate mean residence times of water in the sediment. A nutrient mass balance model is developed to estimate net rates of adsorption and desorption, mineralization, and nitrification along subsurface flow paths. Results indicate that SLIs are dynamic sources of nutrients to lakes and that the common practice of channelizing the stream at the SLI decreases nutrient concentrations in pore water discharging along the lakeshore. This is in contrast to the unmodified SLI that forms a barrier beach that disconnects the stream from the lake and results in higher nutrient concentrations in pore water discharging to the lake. These results are significant because nutrient delivery through pore water seepage at the lakebed from the natural SLI contributes to nearshore algal communities and produces elevated concentrations of inorganic nutrients in the benthic zone where attached algae grow.

Water Resources Research↗

Climatic drivers for multidecadal shifts in solute transport and methane production zones within a large peat basin

Northern peatlands are an important source for greenhouse gases, but their capacity to produce methane remains uncertain under changing climatic conditions. We therefore analyzed a 43 year time series of the pore-water chemistry to determine if long-term shifts in precipitation altered the vertical transport of solutes within a large peat basin in northern Minnesota. These data suggest that rates of methane production can be finely tuned to multidecadal shifts in precipitation that drive the vertical penetration of labile carbon substrates within the Glacial Lake Agassiz Peatlands. Tritium and cation profiles demonstrate that only the upper meter of these peat deposits was flushed by downwardly moving recharge from 1965 to 1983 during a Transitional Dry-to-Moist Period. However, a shift to a moister climate after 1984 drove surface waters much deeper, largely flushing the pore waters of all bogs and fens to depths of 2 m. Labile carbon compounds were transported downward from the rhizosphere to the basal peat at this time producing a substantial enrichment of methane in Δ 14 C with respect to the solid-phase peat from 1991 to 2008. These data indicate that labile carbon substrates can fuel deep production zones of methanogenesis that more than doubled in thickness across this large peat basin after 1984. Moreover, the entire peat profile apparently has the capacity to produce methane from labile carbon substrates depending on climate-driven modes of solute transport. Future changes in precipitation may therefore play a central role in determining the source strength of peatlands in the global methane cycle.

Minnesota↗

Influence of groundwater on distribution of dwarf wedgemussels (Alasmidonta heterodon) in the upper reaches of the Delaware River, northeastern USA

The remaining populations of the endangered dwarf wedgemussel (DWM) ( Alasmidonta heterodon ) in the upper Delaware River, northeastern USA, were hypothesized to be located in areas of greater-than-normal groundwater discharge to the river. We combined physical (seepage meters, monitoring wells and piezometers), thermal (fiber-optic distributed temperature sensing, infrared, vertical bed-temperature profiling), and geophysical (electromagnetic-induction) methods at several spatial scales to characterize known DWM habitat and explore this hypothesis. Numerous springs were observed using visible and infrared imaging along the river banks at all three known DWM-populated areas, but not in adjacent areas where DWM were absent. Vertical and lateral groundwater gradients were toward the river along all three DWM-populated reaches, with median upward gradients 3 to 9 times larger than in adjacent reaches. Point-scale seepage-meter measurements indicated that upward seepage across the riverbed was faster and more consistently upward at DWM-populated areas. Discrete and areally distributed riverbed-temperature measurements indicated numerous cold areas of groundwater discharge during warm summer months; all were within areas populated by DWM. Electromagnetic-induction measurements, which may indicate riverbed geology, showed patterning but little correlation between bulk streambed electromagnetic conductivity and areal distribution of DWM. In spite of complexity introduced by hyporheic exchange, multiple lines of research provide strong evidence that DWM are located within or directly downstream of areas of substantial focused groundwater discharge to the river. Broad scale thermal-reconnaissance methods (e.g., infrared) may be useful in locating and protecting other currently unknown mussel populations.

Delaware River↗

Statistical analysis of lake levels and field study of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015: Chapter A of Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

Water levels declined from 2003 to 2011 in many lakes in Ramsey and Washington Counties in the northeast Twin Cities Metropolitan Area, Minnesota; however, water levels in other northeast Twin Cities Metropolitan Area lakes increased during the same period. Groundwater and surface-water exchanges can be important in determining lake levels where these exchanges are an important component of the water budget of a lake. An understanding of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area has been limited by the lack of hydrologic data. The U.S. Geological Survey, in cooperation with the Metropolitan Council and Minnesota Department of Health, completed a field and statistical study assessing lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes. This report documents the analysis of collected hydrologic, water-quality, and geophysical data; and existing hydrologic and geologic data to (1) assess the effect of physical setting and climate on lake-level fluctuations of selected lakes, (2) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (3) estimate general ages for waters extracted from the wells, and (4) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Statistical analyses of lake levels during short-term (2002–10) and long-term (1925–2014) periods were completed to help understand lake-level changes across the northeast Twin Cities Metropolitan Area. Comparison of 2002–10 lake levels to several landscape and geologic characteristics explained variability in lake-level changes for 96 northeast Twin Cities Metropolitan Area lakes. Application of several statistical methods determined that (1) closed-basin lakes (without an active outlet) had larger lake-level declines than flow-through lakes with an outlet; (2) closed-basin lake-level changes reflected groundwater-level changes in the Quaternary, Prairie du Chien, and Jordan aquifers; (3) the installation of outlet-control structures, such as culverts and weirs, resulted in smaller multiyear lake-level changes than lakes without outlet-control structures; (4) water levels in lakes primarily overlying Superior Lobe deposits were significantly more variable than lakes primarily overlying Des Moines Lobe deposits; (5) lake-level declines were larger with increasing mean lake-level elevation; and (6) the frequency of some of these characteristics varies by landscape position. Flow-through lakes and lakes with outlet-control structures were more common in watersheds with more than 50 percent urban development compared to watersheds with less than 50 percent urban development. A comparison of two 35-year periods during 1925–2014 revealed that variability of annual mean lake levels in flow-through lakes increased when annual precipitation totals were more variable, whereas variability of annual mean lake levels in closed-basin lakes had the opposite pattern, being more variable when annual precipitation totals were less variable. Oxygen-18/oxygen-16 and hydrogen-2/hydrogen-1 ratios for water samples from 40 wells indicated the well water was a mixture of surface water and groundwater in 31 wells, whereas ratios from water sampled from 9 other wells indicated that water from these wells receive no surface-water contribution. Of the 31 wells with a mixture of surface water and groundwater, 11 were downgradient from White Bear Lake, likely receiving water from deeper parts of the lake. Age dating of water samples from wells indicated that the age of water in the Prairie du Chien and Jordan aquifers can vary widely across the northeast Twin Cities Metropolitan Area. Estimated ages of recharge for 9 of the 40 wells sampled for chlorofluorocarbon concentrations ranged widely from the early 1940s to mid-1970s. The wide range in estimated ages of recharge may have resulted from the wide range in the open-interval lengths and depths for the wells. Results from stable isotope analyses of water samples, lake-sediment coring, continuous seismic-reflection profiling, and water-level and flow monitoring indicated that there is groundwater inflow from nearshore sites and lake-water outflow from deep-water sites in White Bear Lake. Continuous seismic-reflection profiling indicated that deep sections of White Bear, Pleasant, Turtle, and Big Marine Lakes have few trapped gases and little organic material, which indicates where groundwater and lake-water exchanges are more likely. Water-level differences between White Bear Lake and piezometer and seepage measurements in deep waters of the lake indicate that groundwater and lake-water exchange is happening in deep waters, predominantly downgradient from the lake and into the lake sediment. Seepage fluxes measured in the nearshore sites of White Bear Lake generally were higher than seepage fluxes measured in the deep-water sites, which indicates that groundwater-inflow rates at most of the nearshore sites are higher than lake-water outflow from the deep-water sites.

Minnesota↗

Changes in pond water levels and surface extent due to climate variability alter solute sources to closed-basin Prairie-Pothole wetland ponds, 1979 to 2012

Wetter conditions beginning in 1993 resulted in marked changes in water levels and surface extent of prairie-pothole region wetland ponds, including closed-basin wetlands in the Cottonwood Lake area of North Dakota, U.S.A. Pond water levels after 1993 were consistently 0.5 to 2 m higher than during 1979–1993 (≤ 1 m deep) in wetlands lacking surface or substantial groundwater outlets, and ponds of some wetlands merged. Pond surface areas after 1993 were as much as twice pre-1993 areas. Weathered glacial till in the inundated uplands provided a source of solutes from the subsurface beyond the extent of the weathered wetland periphery and wetland sediments that existed before 1993. Increased pond peripheries also provided for more movement of solutes from shallow groundwater into wetland ponds during the wetter period. Long periods of higher water levels during pronounced wetter conditions can be associated with increased specific conductance for some wetland ponds. In wetlands receiving no groundwater input, specific conductance values of ponded waters were indistinguishable between wetter and preceding conditions. Thus, changes in specific conductance in wetland ponds during wetter climate conditions cannot be assumed to be uniform, a result of changing watershed solute sources.

Wetlands↗

Hydrology of prairie wetlands: Understanding the integrated surface-water and groundwater processes

Wetland managers and policy makers need to make decisions based on a sound scientific understanding of hydrological and ecological functions of wetlands. This article presents an overview of the hydrology of prairie wetlands intended for managers, policy makers, and researchers new to this field (e.g., graduate students), and a quantitative conceptual framework for understanding the hydrological functions of prairie wetlands and their responses to changes in climate and land use. The existence of prairie wetlands in the semi-arid environment of the Prairie-Pothole Region (PPR) depends on the lateral inputs of runoff water from their catchments because mean annual potential evaporation exceeds precipitation in the PPR. Therefore, it is critically important to consider wetlands and catchments as highly integrated hydrological units. The water balance of individual wetlands is strongly influenced by runoff from the catchment and the exchange of groundwater between the central pond and its moist margin. Land-use practices in the catchment have a sensitive effect on runoff and hence the water balance. Surface and subsurface storage and connectivity among individual wetlands controls the diversity of pond permanence within a wetland complex, resulting in a variety of eco-hydrological functionalities necessary for maintaining the integrity of prairie-wetland ecosystems.

Wetlands↗

Combined use of thermal methods and seepage meters to efficiently locate, quantify, and monitor focused groundwater discharge to a sand-bed stream

Quantifying flow of groundwater through streambeds often is difficult due to the complexity of aquifer-scale heterogeneity combined with local-scale hyporheic exchange. We used fiber-optic distributed temperature sensing (FO-DTS), seepage meters, and vertical temperature profiling to locate, quantify, and monitor areas of focused groundwater discharge in a geomorphically simple sand-bed stream. This combined approach allowed us to rapidly focus efforts at locations where prodigious amounts of groundwater discharged to the Quashnet River on Cape Cod, Massachusetts, northeastern USA. FO-DTS detected numerous anomalously cold reaches one to several m long that persisted over two summers. Seepage meters positioned upstream, within, and downstream of 7 anomalously cold reaches indicated that rapid groundwater discharge occurred precisely where the bed was cold; median upward seepage was nearly 5 times faster than seepage measured in streambed areas not identified as cold. Vertical temperature profilers deployed next to 8 seepage meters provided diurnal-signal-based seepage estimates that compared remarkably well with seepage-meter values. Regression slope and R 2 values both were near 1 for seepage ranging from 0.05 to 3.0 m d −1 . Temperature-based seepage model accuracy was improved with thermal diffusivity determined locally from diurnal signals. Similar calculations provided values for streambed sediment scour and deposition at subdaily resolution. Seepage was strongly heterogeneous even along a sand-bed river that flows over a relatively uniform sand and fine-gravel aquifer. FO-DTS was an efficient method for detecting areas of rapid groundwater discharge, even in a strongly gaining river, that can then be quantified over time with inexpensive streambed thermal methods.

Massachusetts↗

Groundwater exchanges near a channelized versus unmodified stream mouth discharging to a subalpine lake

The terminus of a stream flowing into a larger river, pond, lake, or reservoir is referred to as the stream-mouth reach or simply the stream mouth . The terminus is often characterized by rapidly changing thermal and hydraulic conditions that result in abrupt shifts in surface water/groundwater (sw/gw) exchange patterns, creating the potential for unique biogeochemical processes and ecosystems. Worldwide shoreline development is changing stream-lake interfaces through channelization of stream mouths, i.e., channel straightening and bank stabilization to prevent natural meandering at the shoreline. In the central Sierra Nevada (USA), Lake Tahoe's shoreline has an abundance of both &ldquo;unmodified&rdquo; (i.e., not engineered though potentially impacted by broader watershed engineering) and channelized stream mouths. Two representative stream mouths along the lake's north shore, one channelized and one unmodified, were selected to compare and contrast water and heat exchanges. Hydraulic and thermal properties were monitored during separate campaigns in September 2012 and 2013 and sw/gw exchanges were estimated within the stream mouth-shoreline continuum. Heat-flow and water-flow patterns indicated clear differences in the channelized versus the unmodified stream mouth. For the channelized stream mouth, relatively modulated, cool-temperature, low-velocity longitudinal streambed flows discharged offshore beneath warmer buoyant lakeshore water. In contrast, a seasonal barrier bar formed across the unmodified stream mouth, creating higher-velocity subsurface flow paths and higher diurnal temperature variations relative to shoreline water. As a consequence, channelization altered sw/gw exchanges potentially altering biogeochemical processing and ecological systems in and near the stream mouth.

California, Nevada↗

From submarine to lacustrine groundwater discharge

Submarine groundwater discharge (SGD) and its role in marine nutrient cycling are well known since the last decade. The freshwater equivalent, lacustrine groundwater discharge (LGD), is often still disregarded, although first reports of LGD are more than 50 years old. We identify nine different reasons why groundwater has long been disregarded in both freshwater and marine environments such as invisibility of groundwater discharge, the size of the interface and its difficult accessibility. Although there are some fundamental differences in the hydrology of SGD and LGD, caused primarily by seawater recirculation that occurs only in cases of SGD, there are also a lot of similarities such as a focusing of discharge to near-shore areas. Nutrient concentrations in groundwater near the groundwater–surface water interface might be anthropogenically enriched. Due to spatial heterogeneity of aquifer characteristics and biogeochemical processes, the quantification of groundwater-borne nutrient loads is challenging. Both nitrogen and phosphorus might be mobile in near-shore aquifers and in a lot of case studies large groundwater-borne nutrient loads have been reported.

Conference Paper↗

Groundwater – The disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer-lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater-borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N 2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer-lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater-borne P loads vary from 0.74 to 2900 mg PO 4 -P m −2 year −1 ; for N, these loads vary from 0.001 to 640 g m −2 year −1 . Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management.

Hydrological Processes↗

Groundwater: The disregarded component in lake water and nutrient budgets, Part 1: Effects of groundwater on hydrology

Lake eutrophication is a large and growing problem in many parts of the world, commonly due to anthropogenic sources of nutrients. Improved quantification of nutrient inputs is required to address this problem, including better determination of exchanges between groundwater and lakes. This first of a two-part review provides a brief history of the evolution of the study of groundwater exchange with lakes, followed by a listing of the most commonly used methods for quantifying this exchange. Rates of exchange between lakes and groundwater compiled from the literature are statistically summarized for both exfiltration (flow from groundwater to a lake) and infiltration (flow from a lake to groundwater), including per cent contribution of groundwater to lake-water budgets. Reported rates of exchange between groundwater and lakes span more than five orders of magnitude. Median exfiltration is 0.74 cm/day, and median infiltration is 0.60 cm/day. Exfiltration ranges from near 0% to 94% of input terms in lake-water budgets, and infiltration ranges from near 0% to 91% of loss terms. Median values for exfiltration and infiltration as percentages of input and loss terms of lake-water budgets are 25% and 35%, respectively. Quantification of the groundwater term is somewhat method dependent, indicating that calculating the groundwater component with multiple methods can provide a better understanding of the accuracy of estimates. The importance of exfiltration to a lake budget ranges widely for lakes less than about 100 ha in area but generally decreases with increasing lake area, particularly for lakes that exceed 100 ha in area. No such relation is evident for lakes where infiltration occurs, perhaps because of the smaller sample size. Copyright © 2014 John Wiley & Sons, Ltd.

Hydrological Processes↗

Riverbed clogging associated with a California riverbank filtration system: An assessment of mechanisms and monitoring approaches

An experimental field study was performed to investigate riverbed clogging processes and associated monitoring approaches near a dam-controlled riverbank filtration facility in Northern California. Motivated by previous studies at the site that indicated riverbed clogging plays an important role in the performance of the riverbank filtration system, we investigated the spatiotemporal variability and nature of the clogging. In particular, we investigated whether the clogging was due to abiotic or biotic mechanisms. A secondary aspect of the study was the testing of different methods to monitor riverbed clogging and related processes, such as seepage. Monitoring was conducted using both point-based approaches and spatially extensive geophysical approaches, including: grain-size analysis, temperature sensing, electrical resistivity tomography, seepage meters, microbial analysis, and cryocoring, along two transects. The point monitoring measurements suggested a substantial increase in riverbed biomass (2 orders of magnitude) after the dam was raised compared to the small increase (∼2%) in fine-grained sediment. These changes were concomitant with decreased seepage. The decreased seepage eventually led to the development of an unsaturated zone beneath the riverbed, which further decreased infiltration capacity. Comparison of our time-lapse grain-size and biomass datasets suggested that biotic processes played a greater role in clogging than did abiotic processes. Cryocoring and autonomous temperature loggers were most useful for locally monitoring clogging agents, while electrical resistivity data were useful for interpreting the spatial extent of a pumping-induced unsaturated zone that developed beneath the riverbed after riverbed clogging was initiated. The improved understanding of spatiotemporally variable riverbed clogging and monitoring approaches is expected to be useful for optimizing the riverbank filtration system operations.

Journal of Hydrology↗