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Geology topics

Donald H. Campbell

Publications and source records attributed to Donald H. Campbell.

23 records · Page 2Linked to original sources
USGS2002

Rocky Mountain snowpack chemistry network: History, methods, and the importance of monitoring mountain ecosystems

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey to more thoroughly determine the quality of precipitation and to identify sources of atmospherically deposited pollution in a network of high-elevation sites. Depth-integrated samples of seasonal snowpacks at 52 sampling sites, in a network from New Mexico to Montana, were collected and analyzed each year since 1993. The results of the first 5 years (1993–97) of the program are discussed in this report. Spatial patterns in regional data have emerged from the geographically distributed chemical concentrations of ammonium, nitrate, and sulfate that clearly indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Snowpacks in northern Colorado that lie adjacent to both the highly developed Denver metropolitan area to the east and coal-fired powerplants to the west had the highest overall concentrations of nitrate and sulfate in the network. Ammonium concentrations were highest in northwestern Wyoming and southern Montana.

Rocky Mountains↗
USGS2001

Chemical and isotopic evidence of nitrogen transformation in the Mississippi River, 1997-98

Nitrate (NO 3 ) and other nutrients discharged by the Mississippi River are suspected of causing a zone of depleted dissolved oxygen (hypoxic zone) in the Gulf of Mexico each summer. The hypoxic zone may have an adverse affect on aquatic life and commercial fisheries. The amount of NO 3 delivered by the Mississippi River to the Gulf of Mexico is well documented, but the relative contributions of different sources of NO 3 , and the magnitude of subsequent in-stream transformations of NO 3 , are not well understood. Forty-two water samples collected in 1997 and 1998 at eight stations located either on the Mississippi River or its major tributaries were analysed for NO 3 , total nitrogen (N), atrazine, chloride concentrations and NO 3 stable isotopes (δ 15 N and δ 18 O). These data are used to assess the magnitude and nature of in-stream N transformation and to determine if the δ 15 N and δ 18 O of NO 3 provide information about NO 3 sources and transformation processes in a large river system (drainage area 2 900 000 km 2 ) that would otherwise be unavailable using concentration and discharge data alone. Results from 42 samples indicate that the δ 15 N and δ 18 O ratios between sites on the Mississippi River and its tributaries are somewhat distinctive, and vary with season and discharge rate. Of particular interest are two nearly Lagrangian sample sets, in which samples from the Mississippi River at St Francisville, LA, are compared with samples collected from the Ohio River at Grand Chain, II, and the Mississippi River at Thebes, IL. In both Lagrangian sets, mass-balance calculations indicate only a small amount of in-stream N loss. The stable isotope data from the samples suggest that in-stream N assimilation and not denitrification accounts for most of the N loss in the lower Mississippi River during the spring and early summer months.

Illinois, Iowa, Kentucky, Louisiana, Mississippi, ↗
USGS2000

Timescales for migration of atmospherically derived sulphate through an alpine/subalpine watershed, Loch Vale, Colorado

Sulphur 35, a cosmogenically produced radioisotope with a short half‐life (87 days), was measured in snowpack during 1993–1997 and at four locations within the Loch Vale watershed during 1995–1997. The four sites include the two main drainages in the watershed, Andrews Creek and Icy Brook, a small south facing catchment flowing into Andrews Creek (Andrews Spring 1), and a similar north facing catchment flowing out of a scree field into Icy Brook (Spring 19). Concentrations ranged from a high of almost 50 mBq/L for a sample from Spring 19 in June 1996 to a concentration near the detection limit for a sample from Andrews Creek in April 1997. Sulphur 35 concentrations were normalized to sulphate (as mBq/mg SO 4 −2 ) and were decay‐corrected to a Julian day of 90 (April 1) for each year. Snowpack had the highest 35 S concentration with an average concentration of 53 mBq/mg SO 4 −2 . Concentrations in the streams were much lower, even when corrected for decay relative to JD 90. The large 35 S concentrations found in Spring 19 were the result of increases in concentration due to sublimation and/or evapotranspiration and were lower than snowpack when normalized to sulphate. Using 35 S concentrations found in snowpack as of JD 90 as a beginning concentration, the fraction of sulphate in streamflow that was derived from atmospheric deposition within the prior water year was estimated. For Icy Brook and Andrews Creek the fraction of the sulphate in streamflow derived from that year's snowpack and precipitation was low prior to the beginning of the main spring melt, reached a maximum during the period of maximum flow, and decreased as the summer progressed. A calculation of the seasonal flux indicated that about 40% of the sulphate that flowed out of the watershed was derived from atmospheric sulphate deposited during the previous year. This suggests that more than half of the sulphate deposited in the watershed by atmospheric processes during the previous year was removed during the following summer. Thus sulphate retention in alpine watersheds like Loch Vale is very limited, and changes in sulphate deposition should be quickly reflected in stream chemistry.

Colorado↗
USGS2000

Controls on nitrogen flux in alpine/subalpine watersheds of Colorado

High‐altitude watersheds in the Front Range of Colorado show symptoms of advanced stages of nitrogen excess, despite having less nitrogen in atmospheric deposition than other regions where watersheds retain nitrogen. In two alpine/subalpine subbasins of the Loch Vale watershed, atmospheric deposition of NO 3 − plus NH 4 + was 3.2–5.5 kg N ha −1 , and watershed export was 1.8–3.9 kg N ha −1 for water years 1992–1997. Annual N export increased in years with greater input of N, but most of the additional N was retained in the watershed, indicating that parts of the ecosystem are nitrogen‐limited. Dissolved inorganic nitrogen (DIN) concentrations were greatest in subsurface water of talus landscapes, where mineralization and nitrification augment high rates of atmospheric deposition of N. Tundra landscapes had moderately high DIN concentrations, whereas forest and wetland landscapes had low concentrations, indicating little export of nitrogen from these landscapes. Between the two subbasins the catchment of Icy Brook had greater retention of nitrogen than that of Andrews Creek because of landscape and hydrologic characteristics that favor greater N assimilation in both the terrestrial and aquatic ecosystems. These results suggest that export of N from alpine/subalpine watersheds is caused by a combination of direct flushing of N from atmospheric deposition and release of N from ecosystem biogeochemical processes (N cycling). Sensitivity of alpine ecosystems in the western United States to atmospheric deposition of N is a function of landscape heterogeneity, hydrologic flow paths, and climatic extremes that limit primary productivity and microbial activity, which, in turn, control retention and release of nitrogen. Conceptual and mechanistic models of N excess that have been developed for forested ecosystems need to be modified in order to predict the response of alpine ecosystems to future changes in climate and atmospheric deposition of N.

Water Resources Research↗