Donald A. Walter | Search USGS

USGS2026

Modeling legacy nitrogen transport under instantaneous, steady-state, and transient groundwater flow conditions

In hydrologic settings where groundwater discharge contributes substantially to surface waters, legacy nitrogen in groundwater can confound surface water nitrogen loads estimated exclusively from current terrestrial sources. Additionally, legacy nitrogen in groundwater can contribute to lagged responses to nitrogen management efforts. Some methods of estimating groundwater contributions to surface water nitrogen loads account for legacy nitrogen, while others do not. The resulting differences are rarely quantified. We used a numerical modeling framework to compare three methods of estimating time-varying annual groundwater nitrogen loads to surface water receptors on eastern Long Island, New York. The instantaneous load method used steady-state contributing areas and includes no temporal groundwater lag. The second method used numerical simulations of nitrogen loads under steady-state flow, which captures groundwater transport lags but omits the annual variability in transient hydrologic stresses. The third method numerically simulated both transient groundwater flow and nitrogen transport to explicitly capture the effects of legacy nitrogen in groundwater. Depending on antecedent nitrogen and hydrologic conditions, historical nitrogen loads estimated from the numerical simulations were sometimes similar (<10% difference) and other times substantially different (±100%) from the instantaneous load estimates. Additionally, simulated future surface water nitrogen loads responded asymptotically over several decades following reductions in terrestrial nitrogen sources, further highlighting the effect of groundwater transport lag times. The comparison of the three methods, quantification of historical interannual variability, and prediction of lagged responses to nitrogen source reductions provide important context for decision makers using estimated groundwater nitrogen loads to help evaluate nitrogen management efficacy.

New York↗

USGS2025

Assessing legacy nitrogen in groundwater using numerical models of the Long Island aquifer system, New York

Nitrogen transported along groundwater flow paths in coastal aquifers can contribute substantially to nitrogen loading into surface water receptors, particularly in hydrologic systems dominated by groundwater discharge. Nitrogen entrained in the aquifer is a function of land use and associated nitrogen sources at the time of groundwater recharge, which may differ considerably from present-day sources. Legacy nitrogen can result in substantial discrepancies between observed present-day nitrogen loading to surface water receptors and loading estimated from present-day sources. Additionally, legacy nitrogen can continue to discharge into surface waters after nitrogen mitigation actions have been undertaken. Here, we use a numerical modeling framework to compare three methods of estimating time-varying historical nitrogen loads to four water bodies (receptors) on eastern Long Island, New York. The methods span a range of data requirements and process complexity, from instantaneous receptor loads calculated from steady-state groundwater contributing areas, to transient loads estimated by explicitly simulating legacy groundwater nitrogen transport over a century with large changes in nitrogen sources and hydrologic conditions. The effects of legacy nitrogen on estimated receptor loads varied temporally and spatially within the study area. Depending on antecedent nitrogen inputs and hydrologic conditions, historical annual nitrogen loads estimated from transient simulations accounting for legacy nitrogen can be quite similar (<10% difference) or substantially different (±100%) from those estimated from simpler instantaneous methods. Continued input of present-day nitrogen sources using methods that account for legacy nitrogen results in asymptotic increases in receptor nitrogen loads over time, indicating that simulated present-day receptor nitrogen loads are not in equilibrium with present-day inputs. For these receptors in disequilibrium, models simulating transient groundwater nitrogen transport could be used to account for legacy nitrogen lag times to help resource managers evaluate the potential effectiveness of proposed nitrogen mitigation actions.

EarthArXiv↗