David L. Nelms — Page 2

USGS2001

Apparent chlorofluorocarbon age of ground water of the shallow aquifer system, Naval Weapons Station Yorktown, Yorktown, Virginia

Apparent ages of ground water are useful in the analysis of various components of flow systems, and results of this analysis can be incorporated into investigations of potential pathways of contaminant transport. This report presents the results of a study in 1997 by the U.S. Geological Survey (USGS), in cooperation with the Naval Weapons Station Yorktown, Base Civil Engineer, Environmental Directorate, to describe the apparent age of ground water of the shallow aquifer system at the Station. Chlorofluorocarbons (CFCs), tritium ( 3 H), dissolved gases, stable isotopes, and water-quality field properties were measured in samples from 14 wells and 16 springs on the Station in March 1997. Nitrogen-argon recharge temperatures range from 5.9°C to 17.3°C with a median temperature of 10.9°C, which indicates that ground-water recharge predominantly occurs in the cold months of the year. Concentrations of excess air vary depending upon geohydrologic setting (recharge and discharge areas). Apparent ground-water ages using a CFC-based dating technique range from 1 to 48 years with a median age of 10 years. The oldest apparent CFC ages occur in the upper parts of the Yorktown-Eastover aquifer, whereas the youngest apparent ages occur in the Columbia aquifer and the upper parts of the discharge area setting, especially springs. The vertical distribution of apparent CFC ages indicates that groundwater movement between aquifers is somewhat retarded by the leaky confining units, but the elapsed time is relatively short (generally less than 35 years), as evidenced by the presence of CFCs at depth. The identification of binary mixtures by CFC-based dating indicates that convergence of flow lines occurs not only at the actual point of discharge, but also in the subsurface. The CFC-based recharge dates are consistent with expected 3 H concentrations measured in the water samples from the Station. The concentration of 3H in ground water ranges from below the USGS laboratory minimum reporting limit of 0.3 to 15.9 tritium units (TU) with a median value of 10.8 TU. Water-quality field properties are highly variable for ground water with apparent CFC ages less than 15 years because of geochemical processes within local flow systems. Ground water with apparent CFC ages greater than 15 years represents more stable conditions in subregional flow systems. The range of apparent CFC ages is slightly greater than the ranges in time of travel of ground water calculated for shallow wells (less than 60- feet deep) from flow-path analysis. Calculated travel times to springs can be up to two orders of magnitude greater than the CFC-based apparent ages. Reasonable assumptions of values for hydraulic parameters can result in substantial overestimates for time of travel to springs. Recharge rates computed from apparent CFC ages range from 0.29 to 0.89 feet per year (ft/ yr) with an average value of 0.54 ft/yr. The analysis of apparent CFC ages in conjunction with geohydrologic data indicates that young water (less than 50 years) is present at depth (nearly 120 feet) and that both local and subregional flow systems occur in the shallow aquifer system at the Station. The addition of the dimension of time to the three-dimensional framework of Brockman and others (1997) will benefit current (2001) and future remediation activities by providing estimates of advective transport rates and how these rates vary depending upon geohydrologic setting and position within the ground-water-flow system. Estimated ground-water apparent ages and recharge rates can be used as calibration criteria in simulations of ground-water flow on the Station to refine and constrain future ground-water-flow models of the shallow aquifer system.

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USGS1997

Base-flow characteristics of streams in the Valley and Ridge, the Blue Ridge, and the Piedmont physiographic provinces of Virginia

Growth within the Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces of Virginia has focused concern about allocation of surface-water flow and increased demands on the ground-water resources. The pur pose of this report is to (.1) describe the base-flow characteristics of streams, (2) identify the regional differences in these flow characteristics, and (3) describe, if possible, the potential surface-water and ground-water yields of basins on the basis of the base-flow characteristics. Base-flow characteristics are presented for streams in the Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces of Virginia. The provinces are separated into five regions: (1) Valley and Ridge, (2) Blue Ridge, (3) Piedmont/Blue Ridge transition, (4) Piedmont northern, and (5) Piedmont southern. Different flow statistics, which represent stream flows predominantly comprised of base flow, were determined for 217 continuous-record stream flow-gaging stations from historical mean daily discharge and for 192 partial-record streamflow gaging stations by means of correlation of discharge measurements. Variability of base flow is represented by a duration ratio developed during this investigation. Effective recharge rates were also calculated. Median values for the different flow statis tics range from 0.05 cubic foot per second per square mile for the 90-percent discharge on the streamflow-duration curve to 0.61 cubic foot per second per square mile for mean base flow. An excellent estimator of mean base flow for the Piedmont/Blue Ridge transition region and Piedmont southern region is the 50-percent discharge on the streamflow-duration curve, but it tends to underestimate mean base flow for the remaining regions. The base-flow variability index ranges from 0.07 to 2.27, with a median value of 0.55. Effective recharge rates range from 0.07 to 33 .07 inches per year, with a median value of 8.32 inches per year. Differences in the base-flow characteristics exist between regions. The median discharges for the Valley and Ridge, the Blue Ridge, and the Piedmont/Blue Ridge transition regions are higher than those for the Piedmont regions. Results from statistical analysis indicate that the regions can be ranked in terms of base-flow characteristics from highest to lowest as follows: (1) Piedmont/Blue Ridge transition, (2) Valley and Ridge and Blue Ridge, (3) Piedmont south ern, and (4) Piedmont northern. The flow statis tics are consistently higher and the values for base-flow variability are lower for basins within the Piedmont/Blue Ridge transition region relative to those from the other regions, whereas the basins within the Piedmont northern region show the opposite pattern. The group rankings of the base-flow characteristics were used to designate the potential surface-water yield for the regions. In addition, an approach developed for this investigation assigns a rank for potential surface-water yield to a basin according to the quartiles in which the values for the base-flow characteristics are located. Both procedures indicate that the Valley and Ridge, the Blue Ridge, and the Piedmont/ Blue Ridge transition regions have moderate-to high potential surface-water yield and the Piedmont regions have low-to-moderate potential surface-water yield. In order to indicate potential ground-water yield from base-flow characteristics, aquifer properties for 51 streamflow-gaging stations with continuous record of streamflow data were determined by methods that use streamflow records and basin characteristics. Areal diffusivity ranges from 17,100 to 88,400 feet squared per day, with a median value of38,400 feet squared per day. Areal transmissivity ranges from 63 to 830 feet squared per day, with a median value of270 feet squared per day. Storage coefficients, which were estimated by dividing areal transmissivity by areal diffusivity, range from approximately 0.001 to 0.019 (dimensionless), with a median value of 0.007. The median value for areal diffusivity decreases as potential surface-water yield of the basins increases. The ranking of a real diffusivity does not correspond with the ranking of potential surface-water yield for either the regions or the basins. Areal transmissivity generally increases as storage coefficient increases; however, basins with low potential surface-water yield generally have high values of areal transmissivity associated with low values of storage coefficient over a narrow range relative to those from basins designated as having moderate-to-high potential surface-water yield. Although the basins with high potential surface-water yield tend to have comparatively lower values for areal transmissivity, storage coefficients generally are large when compared to those from basins with similar values of a real transmissivity but different potential surface-water yield. Aquifer properties were grouped by potential surface-water yield and were related to hydro geologic units categorized by large, medium, and small well yields for the Valley and Ridge Physio graphic Province and for the Blue Ridge and the Piedmont Physiographic Provinces. Generally, no trend is evident between areal diffusivity and the hydrogeologic units. Some of the high values of a real diffusivity are associated with basins predominantly underlain by hydrogeologic units with small well yields, especially basins with a low potential surface-water yield. Areal transmissivity and storage coefficient tend to decrease, which is the expected trend, as more ofthe basin is underlain by the hydrogeologic unit with small well yields in the Valley and Ridge Physiographic Province. A similar trend is indicated for the hydrogeologic unit with medium well yields in the Blue Ridge and the Piedmont Physiographic Provinces. Areal transmissivity and storage coefficient tend to increase, which is not the expected trend, as more of the basin is underlain by the hydrogeologic unit with small well yields in the Blue Ridge and the Piedmont Physiographic Provinces. The base-flow characteristics of a basin may provide a relative indication of the potential ground-water yield; but other factors need to be considered, such as geologic structure, lithology, precipitation, relief, and degree of hydraulic interrconnection between the regolith and bedrock.

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