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David F. Ufnar

Publications and source records attributed to David F. Ufnar.

8 recordsLinked to original sources

Precipitation rates and atmospheric heat transport during the Cenomanian greenhouse warming in North America: Estimates from a stable isotope mass-balance model

Stable isotope mass-balance modeling results of meteoric ??18O values from the Cenomanian Stage of the Cretaceous Western Interior Basin (KWIB) suggest that precipitation and evaporation fluxes were greater than that of the present and significantly different from simulations of Albian KWIB paleohydrology. Sphaerosiderite meteoric ??18O values have been compiled from the Lower Tuscaloosa Formation of southwestern Mississippi (25??N paleolatitude), The Dakota Formation Rose Creek Pit, Fairbury Nebraska (35??N) and the Dunvegan Formation of eastern British Columbia (55??N paleolatitude). These paleosol siderite ??18O values define a paleolatitudinal gradient ranging from - 4.2??? VPDB at 25??N to - 12.5??? VPDB at 55??N. This trend is significantly steeper and more depleted than a modern theoretical siderite gradient (25??N: - 1.7???; 65??N: - 5.6??? VPDB ), and a Holocene meteoric calcite trend (27??N: - 3.6???; 67??N: - 7.4??? VPDB). The Cenomanian gradient is also comparatively steeper than the Albian trend determined for the KWIB in the mid- to high latitudes. The steep latitudinal trend in meteoric ??18O values may be the result of increased precipitation and evaporation fluxes (amount effects) under a more vigorous greenhouse-world hydrologic cycle. A stable-isotope mass-balance model has been used to generate estimates of precipitation and evaporation fluxes and precipitation rates. Estimates of Cenomanian precipitation rates based upon the mass-balance modeling of the KWIB range from 1400??mm/yr at 25??N paleolatitude to 3600??mm/yr at 45??N paleolatitude. The precipitation-evaporation (P-E) flux values were used to delineate zones of moisture surplus and moisture deficit. Comparisons between Cenomanian P-E and modern theoretical siderite, and Holocene calcite latitudinal trends shows an amplification of low-latitude moisture deficits between 5-25??N paleolatitude and moisture surpluses between 40-60??N paleolatitude. The low-latitude moisture deficits correlate with a mean annual average heat loss of 48??W/m2 at 10??N paleolatitude (present, 8??W/m2 at 15??N). The increased precipitation flux and moisture surplus in the mid-latitudes corresponds to a mean average annual heat gain of 180??W/m2 at 50??N paleolatitude (present, 17??W/m2 at 50??N). The Cenomanian low-latitude moisture deficit is similar to that of the Albian, however the mid-latitude (40-60??N) precipitation flux values and precipitation rates are significantly higher (Albian: 2200??mm/yr at 45??N; Cenomanian: 3600??mm/yr at 45??N). Furthermore, the heat transferred to the atmosphere via latent heat of condensation was approximately 10.6?? that of the present at 50??N. The intensified hydrologic cycle of the mid-Cretaceous greenhouse warming may have played a significant role in the poleward transfer of heat and more equable global conditions. Paleoclimatological reconstructions from multiple time periods during the mid-Cretaceous will aid in a better understanding of the dynamics of the hydrologic cycle and latent heat flux during greenhouse world conditions.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

Recognizing the Albian-Cenomanian (OAE1d) sequence boundary using plant carbon isotopes: Dakota Formation, Western Interior Basin, USA

Analysis of bulk sedimentary organic matter and charcoal from an Albian-Cenomanian fluvial-estuarine succession (Dakota Formation) at Rose Creek Pit (RCP), Nebraska, reveals a negative excursion of ???3???, in late Albian strata. Overlying Cenomanian strata have ??13C values of -24???, to -23???, that are similar to pre-excursion values. The absence of an intervening positive excursion (as exists in marine records of the Albian-Cenomanian boundary) likely results from a depositional hiatus. The corresponding positive ??13C event and proposed depositional hiatus are concordant with a regionally identified sequence boundary in the Dakota Formation (D2), as well as a major regressive phase throughout the globe at the Albian-Cenomanian boundary. Data from RCP confirm suggestions that some positive carbon-isotope excursions in the geologic record are coincident with regressive sea-level phases. We estimate using isotopic correlation that the D2 sequence boundary at RCP was on the order of 0.5 m.y. in duration. Therefore, interpretations of isotopic events and associated environmental phenomena, such as oceanic anoxic events, in the shallow-marine and terrestrial record may be influenced by stratigraphic incompleteness. Further investigation of terrestrial ??13C records may be useful in recognizing and constraining sea-level changes in the geologic record. ?? 2006 Geological Society of America.

Geology↗

Reconstructing a mid-Cretaceous landscape from paleosols in western Canada

The Albian Stage of the mid-Cretaceous was a time of equable climate conditions with high sea levels and broad shallow epeiric seas that may have had a moderating affect on continental climates. A Late Albian landscape surface that developed during a regression and subsequent sea-level rise in the Western Canada Foreland Basin is reconstructed on the basis of correlation of paleosols penetrated by cores through the Paddy Member of the Peace River Formation. Reconstruction of this landscape refines chronostratigraphic relationships and will benefit future paleoclimatological studies milizing continental sphaerosiderite proxy records. The paleosols developed in estuarine sandstones and mudstones, and they exhibit evidence of a polygenetic history. Upon initial exposure and pedogenesis, the Paddy Member developed deeply weathered, well-drained cumulative soil profiles. Later stages of pedogenesis were characterized by hydromorphic soil conditions. The stages of soil development interpreted for the Paddy Member correlate with inferred stages of pedogenic development in time-equivalent formations located both basinward and downslope (upper Viking Formation), and landward and upslope (Boulder Creek Formation). On the basis of the genetic similarity among paleosols in these three correlative formations, the paleosols are interpreted as having formed along a single, continuous landscape surface. Results of this study indicate that the catena concept of pedogenesis along sloping landscapes is applicable to ancient successions. Sphaerosiderites in the Paddy Mem ber paleosols are used to provide proxy values for meteoric ??18O values at 52?? N paleolatitude in the Cretaceous Western Interior Basin. The meteoric ??18O values are used to refine existing interpretations about the mid-Cretaceous paleolatitudinal gradient in meteoric ?? 18O values, and the mid-Cretaceous hydrologic cycle. Copyright ?? 2005, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

Diagenetic overprinting of the sphaerosiderite palaeoclimate proxy: are records of pedogenic groundwater δ 18 O values preserved?

Meteoric sphaerosiderite lines (MSLs), defined by invariant ??18O and variable ??13C values, are obtained from ancient wetland palaeosol sphaerosiderites (millimetre-scale FeCO3 nodules), and are a stable isotope proxy record of terrestrial meteoric isotopic compositions. The palaeoclimatic utility of sphaerosiderite has been well tested; however, diagenetically altered horizons that do not yield simple MSLs have been encountered. Well-preserved sphaerosiderites typically exhibit smooth exteriors, spherulitic crystalline microstructures and relatively pure (> 95 mol% FeCO3) compositions. Diagenetically altered sphaerosiderites typically exhibit corroded margins, replacement textures and increased crystal lattice substitution of Ca2+, Mg2+ and Mn2+ for Fe2+. Examples of diagenetically altered Cretaceous sphaerosiderite-bearing palaeosols from the Dakota Formation (Kansas), the Swan River Formation (Saskatchewan) and the Success S2 Formation (Saskatchewan) were examined in this study to determine the extent to which original, early diagenetic ??18O and ??13C values are preserved. All three units contain poikilotopic calcite cements with significantly different ??18O and ??13C values from the co-occurring sphaerosiderites. The complete isolation of all carbonate phases is necessary to ensure that inadvertent physical mixing does not affect the isotopic analyses. The Dakota and Swan River samples ultimately yield distinct MSLs for the sphaerosiderites, and MCLs (meteoric calcite lines) for the calcite cements. The Success S2 sample yields a covariant ??18O vs. ??13C trend resulting from precipitation in pore fluids that were mixtures between meteoric and modified marine phreatic waters. The calcite cements in the Success S2 Formation yield meteoric ??18O and ??13C values. A stable isotope mass balance model was used to produce hyperbolic fluid mixing trends between meteoric and modified marine end-member compositions. Modelled hyperbolic fluid mixing curves for the Success S2 Formation suggest precipitation from fluids that were < 25% sea water. ?? 2004 International Association of Sedimentologists.

Sedimentology↗

High latitude meteoric δ 18 O compositions: Paleosol siderite in the Middle Cretaceous Nanushuk Formation, North Slope, Alaska

Siderite-bearing pedogenic horizons of the Nanushuk Formation of the North Slope, Alaska, provide a critical high paleolatitude oxygen isotopic proxy record of paleoprecipitation, supplying important empirical data needed for paleoclimatic reconstructions and models of "greenhouse-world" precipitation rates. Siderite ??18O values were determined from four paleosol horizons in the National Petroleum Reserve Alaska (NPR-A) Grandstand # 1 Core, and the values range between -17.6??? and -14.3??? Peedee belemnite (PDB) with standard deviations generally less than 0.6??? within individual horizons. The ??13C values are much more variable, ranging from -4.6??? to +10.8??? PDB. A covariant ??18O versus ??13C trend in one horizon probably resulted from mixing between modified marine and meteoric phreatic fluids during siderite precipitation. Groundwater values calculated from siderite oxygen isotopic values and paleobotanical temperature estimates range from -23.0??? to -19.5??? standard mean ocean water (SMOW). Minor element analyses show that the siderites are impure, having enrichments in Ca, Mg, Mn, and Sr. Minor element substitutions and Mg/Fe and Mg/ (Ca + Mg) ratios also suggest the influence of marine fluids upon siderite precipitation. The pedogenic horizons are characterized by gleyed colors, rare root traces, abundant siderite, abundant organic matter, rare clay and silty clay coatings and infillings, some preservation of primary sedimentary stratification, and a lack of ferruginous oxides and mottles. The pedogenic features suggest that these were poorly drained, reducing, hydromorphic soils that developed in coal-bearing delta plain facies and are similar to modern Inceptisols. Model-derived estimates of precipitation rates for the Late Albian of the North Slope, Alaska (485-626 mm/yr), are consistent with precipitation rates necessary to maintain modern peat-forming environments. This information reinforces the mutual consistency between empirical paleotemperature estimates and isotope mass balance models of the hydrologic cycle and can be used in future global circulation modeling (GCM) experiments of "greenhouse-world" climates to constrain high latitude precipitation rates in simulations of ancient worlds with decreased equator-to-pole temperature gradients. ?? 2004 Geological Society of America.

Geological Society of America Bulletin↗

Evidence for increased latent heat transport during the Cretaceous (Albian) greenhouse warming

Quantitative estimates of increased heat transfer by atmospheric H 2O vapor during the Albian greenhouse warming suggest that the intensified hydrologic cycle played a greater role in warming high latitudes than at present and thus represents a viable alternative to oceanic heat transport. Sphaerosiderite ??18O values in paleosols of the North American Cretaceous Western Interior Basin are a proxy for meteoric ??18O values, and mass-balance modeling results suggest that Albian precipitation rates exceeded modern rates at both mid and high latitudes. Comparison of modeled Albian and modern precipitation minus evaporation values suggests amplification of the Albian moisture deficit in the tropics and moisture surplus in the mid to high latitudes. The tropical moisture deficit represents an average heat loss of ???75 W/m2 at 10??N paleolatitude (at present, 21 W/m2). The increased precipitation at higher latitudes implies an average heat gain of ???83 W/m2 at 45??N (at present, 23 W/m2) and of 19 W/m2 at 75??N (at present, 4 W/m2). These estimates of increased poleward heat transfer by H2O vapor during the Albian may help to explain the reduced equator-to-pole temperature gradients. ?? 2004 Geological Society of America.

Geology↗

Aggradation of gravels in tidally influenced fluvial systems: Upper Albian (Lower Cretaceous) on the cratonic margin of the North American Western Interior foreland basin

Alluvial conglomerates were widely distributed around the margin of the Early Cretaceous North American Cretaceous Western Interior Seaway (KWIS). Conglomerates, sandstones, and lesser amounts of mudstones of the upper Albian Nishnabotna Member of the Dakota Formation were deposited as fill-in valleys that were incised up to 80 m into upper Paleozoic strata. These paleovalleys extended southwestward across present-day northwestern Iowa into eastern Nebraska. Conglomerate samples from four localities in western Iowa and eastern Nebraska consist mostly of polycrystalline quartz with lesser amounts of microcrystalline (mostly chert), and monocrystalline quartz. Previous studies discovered that some chert pebbles contain Ordovician-Pennsylvanian invertebrate fossils. The chert clasts analyzed in this study were consistent with these findings. In addition, we found that non-chert clasts consist of metaquartzite, strained monocrystalline quartz and 'vein' quartz from probable Proterozic sources, indicating that parts of the fluvial system's sediment load must have travelled distances of 400-1200 km. The relative tectonic stability of this subcontinent dictated that stream gradients were relatively low with estimates ranging from 0.3 to 0.6 m/km. Considering the complex sedimentologic relationships that must have been involved, the ability of low-gradient easterly-sourced rivers to entrain gravel clasts was primarily a function of paleodischarge rather than a function of steep gradients. Oxygen isotopic evidence from Albian sphaerosiderite-bearing paleosols in the Dakota Formation and correlative units from Kansas to Alaska suggest that mid-latitude continental rainfall in the Albian was perhaps twice that of the modern climate system. Hydrologic fluxes may have been related to wet-dry climatic cycles on decade or longer scales that could account for the required water supply flux. Regardless of temporal scale, gravels were transported during 'high-energy' pulses, under humid climatic conditions in large catchment areas. An overall rising sea level during the late Albian created accommodation space for the gravelly lithofacies equivalent to the Kiowa-Skull Creek rocks. As Western Interior sea level rose, regional stream gradients were reduced, resulting in regional fluvial aggradation. The conglomeratic lower parts of the Nishnabotna Member of the Dakota Formation formed the transgressive systems tract within an upper Albian sequence that is defined by two unconformities that can be traced from marine Kiowa strata in western Kansas northeastward into western Iowa (Brenner et al., 2000). Mud-draped cross-bedded sandstone bodies, laminated mudstone intervals, and vertical burrows in the lower strata of the Nishnabotna Member indicate that estuarine conditions existed at the mouths of the river system, and tidal effects were transmitted at least 200 km inland from the interpreted late Albian coast. These observations suggest that estuarine conditions stepped up the incised valleys as fluvial sediments aggraded in response to regional transgression that continued through the Late Albian. ?? 2003 Elsevier Ltd. All rights reserved.

Cretaceous Research↗

The mid-cretaceous water bearer: Isotope mass balance quantification of the Albian hydrologic cycle

A latitudinal gradient in meteoric ??18O compositions compiled from paleosol sphaerosiderites throughout the Cretaceous Western Interior Basin (KWIB) (34-75??N paleolatitude) exhibits a steeper, more depleted trend than modern (predicted) values (3.0??? [34??N latitude] to 9.7??? [75??N] lighter). Furthermore, the sphaerosiderite meteoric ??18O latitudinal gradient is significantly steeper and more depleted (5.8??? [34??N] to 13.8??? [75??N] lighter) than a predicted gradient for the warm mid-Cretaceous using modern empirical temperature-??18O precipitation relationships. We have suggested that the steeper and more depleted (relative to the modern theoretical gradient) meteoric sphaerosiderite ??18O latitudinal gradient resulted from increased air mass rainout effects in coastal areas of the KWIB during the mid-Cretaceous. The sphaerosiderite isotopic data have been used to constrain a mass balance model of the hydrologic cycle in the northern hemisphere and to quantify precipitation rates of the equable 'greenhouse' Albian Stage in the KWIB. The mass balance model tracks the evolving isotopic composition of an air mass and its precipitation, and is driven by latitudinal temperature gradients. Our simulations indicate that significant increases in Albian precipitation (34-52%) and evaporation fluxes (76-96%) are required to reproduce the difference between modern and Albian meteoric siderite ??18O latitudinal gradients. Calculations of precipitation rates from model outputs suggest mid-high latitude precipitation rates greatly exceeded modern rates (156-220% greater in mid latitudes [2600-3300 mm/yr], 99% greater at high latitudes [550 mm/yr]). The calculated precipitation rates are significantly different from the precipitation rates predicted by some recent general circulation models (GCMs) for the warm Cretaceous, particularly in the mid to high latitudes. Our mass balance model by no means replaces GCMs. However, it is a simple and effective means of obtaining quantitative data regarding the mid-Cretaceous hydrologic cycle in the KWIB. Our goal is to encourage the incorporation of isotopic tracers into GCM simulations of the mid-Cretaceous, and to show how our empirical data and mass balance model estimates help constrain the boundary conditions. ?? 2002 Elsevier Science B.V. All rights reserved.

Palaeogeography, Palaeoclimatology, Palaeoecology↗