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D.L. Orange

Publications and source records attributed to D.L. Orange.

8 recordsLinked to original sources
USGS2005

High-resolution surveys for geohazards and shallow gas: NW Adriatic (Italy) and Iskenderun Bay (Turkey)

The need for quantifying and understanding the distribution of shallow gas is both of academic interest and of relevance to offshore facilities. The combination of seafloor mapping, subbottom profiling, and multi-channel seismic data can provide information on regions of possible shallow gas, where the gas impacts the acoustic properties of the host material and the seafloor. In this paper, we present two case studies - one academic and one industry - that evaluate the distribution of shallow gas in two field areas in the Mediterranean. In the first case study, geophysical data from Iskenderun Bay, southeastern Turkey, indicate the presence and distribution of shallow gas. Pockmarks on the seafloor are associated with acoustic wipeout in the shallow subbottom data. Although deeper seismic data do not show bright spots or other indicators of possible gas, instantaneous frequency analysis clearly shows laterally restricted anomalies indicating gas-rich zones. The interpretation of possible shallow gas resulted in moving a proposed drilling location to a nearby area characterized by fewer (but still present) shallow gas signatures. In the second case study, cores acquired in the Po Delta, Adriatic Sea, provide quantitative ground-truthing of shallow gas - as suggested by geophysical data - and provide minimum estimates of the percentage of gas in the subsurface. Cores targeted on anomalous subbottom data yielded up to 41,000 ppm methane; cores with anomalous gas content are associated with thick recent flood deposits which may effectively isolate reactive terrigenous organic matter from biologic and physical re-working. ?? Springer 2005.

Marine Geophysical Research↗
USGS2003

Headless submarine canyons and fluid flow on the toe of the Cascadia accretionary complex

Headless submarine canyons with steep headwalls and shallowly sloping floors occur on both the second and third landward vergent anticlines on the toe of the Cascadia accretionary complex off central Oregon (45 °N, 125° 30′W). In September 1993, we carried out a series of nine deep tow camera sled runs and nine ALVIN dives to examine the relationship between fluid venting, structure and canyon formation. We studied four canyons on the second and third landward vergent anticlines, as well as the apparently unfailed intercanyon regions along strike. All evidence of fluid expulsion is associated with the canyons; we found no evidence of fluid flow between canyons. Even though all fluid seeps are related to canyons, we did not find seeps in all canyons, and the location of the seeps within the canyons differed. On the landward facing limb of the second landward vergent anticline a robust cold seep community occurs at the canyon’s inflection point. This seep is characterized by chemosynthetic vent clams, tube worms and extensive authigenic carbonate. Fluids for this seep may utilize high-permeability flow paths either parallel to bedding within the second thrust ridge or along the underlying thrust fault before leaking into the overriding section. Two seaward facing canyons on the third anticlinal ridge have vent clam communities near the canyon mouths at approximately the intersection between the anticlinal ridge and the adjacent forearc basin. No seeps were found along strike at the intersection of the slope basin and anticlinal ridge. We infer that the lack of seepage along strike and the presence of seeps in canyons may be related to fluid flow below the forearc basin/slope unconformity (overpressured by the impinging thrust fault to the west?) directed toward canyons at the surface.

Basin Research↗
USGS2002

Hydrocarbon geochemistry of cold seeps in the Monterey Bay National Marine Sanctuary

Samples from four geographically and tectonically discrete cold seeps named Clam Flat, Clamfield, Horseshoe Scarp South, and Tubeworm City, within the Monterey Bay National Marine Sanctuary were analyzed for their hydrocarbon content. The sediment contains gaseous hydrocarbons and CO2, as well as high molecular weight aliphatic and aromatic hydrocarbons with various combinations of thermogenic and biogenic contributions from petroleum, marine, and terrigenous sources. Of particular interest is the cold seep site at Clamfield which is characterized by the presence of thermogenic hydrocarbons including oil that can likely be correlated with oil-saturated strata at Majors Creek near Davenport, CA, USA. At Clam Flat, the evidence for thermogenic hydrocarbons is equivocal. At Horseshoe Scarp South and Tubeworm City, hydrocarbon gases, mainly methane, are likely microbial in origin. These varied sources of hydrocarbon gases highlight the diverse chemical systems that appear at cold seep communities. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Geology↗
USGS1999

Subsurface gas offshore of northern California and its link to submarine geomorphology

The northern California continental margin contains evidence of abundant subsurface gas and numerous seafloor features that suggest a causative link between gas expulsion and geomorphology. Analyses of seismic reflection, sidescan sonar, and high-resolution multibeam bathymetric data show that the occurrence of subbottom gas and the migration processes beneath the shelf differ from those beneath the slope. Subsurface gas, inferred from enhanced reflectors and other geophysical indicators, is spatially variable and related more to total depth and stratigraphy than to underlying structure, with the exception of one band of gas that follows the regional structural trend. Shallow depressions on the seafloor (pockmarks) are used to infer expulsion sites. The largest zone of acoustically impenetrable subsurface gas occurs between water depths of 100 m and 300 m, where expulsion features are rare. The upper slope (water depths 400-600 m) has a high concentration of pockmarks (diameter 10-20 m), in contrast to a near-absence of pockmarks at water depths shallower than 400 m. Of nearly 4000 pockmarks observed on sidescan sonar records, more than 95% are located in water depths deeper than 400 m. Bottom simulating reflectors (BSRs) on some seismic reflection profiles indicate the possible presence of gas hydrate. We find that gas and pore-fluid migration in the offshore Eel River Basin is: (1) correlated to surface morphology; (2) a contributor to seabed roughness; (3) a significant mode of sediment redistribution on the upper slope; and (4) potentially a factor in large slope failures.

Marine Geology↗
USGS1998

Gas hydrate formation in the deep sea: In situ experiments with controlled release of methane, natural gas, and carbon dioxide

We have utilized a remotely operated vehicle (ROV) to initiate a program of research into gas hydrate formation in the deep sea by controlled release of hydrocarbon gases and liquid CO 2 into natural sea water and marine sediments. Our objectives were to investigate the formation rates and growth patterns of gas hydrates in natural systems and to assess the geochemical stability of the reaction products over time. The novel experimental procedures used the carrying capacity, imaging capability, and control mechanisms of the ROV to transport gas cylinders to depth and to open valves selectively under desired P − T conditions to release the gas either into contained natural sea water or into sediments. In experiments in Monterey Bay, California, at 910 m depth and 3.9 °C water temperature we find hydrate formation to be nearly instantaneous for a variety of gases. In sediments the pattern of hydrate formation is dependent on the pore size, with flooding of the pore spaces in a coarse sand yielding a hydrate cemented mass, and gas channeling in a fine-grained mud creating a veined hydrate structure. In experiments with liquid CO 2 the released globules appeared to form a hydrate skin as they slowly rose in the apparatus. An initial attempt to leave the experimental material on the sea floor for an extended period was partially successful; we observed an apparent complete dissolution of the liquid CO 2 mass, and an apparent consolidation of the CH 4 hydrate, over a period of about 85 days.

Energy and Fuels↗
USGS1997

Chemical and isotopic evidence of gas-influenced flow at a transform plate boundary: Monterey Bay, California

Chemical and isotopic compositions of pore fluids document upward flow through communities of vesicomyid clams in Monterey Bay, California. Within the clam communities, the sulfate reduction zone is only 10 cm thick, and Ca and Mg concentrations decrease to values as low as 2.2 m M and 34.5 m M , respectively, at depths less than 30 cm below the sediment-water interface. Less than 5 m outside the communities, the base of the sulfate reduction zone is deeper than the greatest penetration of the cores (∼30 cm), and Ca and Mg exhibit only minor changes from seawater values. The sediment exhibits no significant variation in grain size, mineralogy, organic carbon, nitrogen, or carbonate content throughout the region. The composition of pore fluid within clam communities results from upward flow of altered fluid rather than different diagenetic reactions within and outside the communities. Isotopically light dissolved inorganic carbon (DIC), with δ 13 C values ranging from −3.2 to −54.1‰, could reflect carbon sources from either oxidized thermogenic methane and/or a mixture of oxidized microbial methane and solid organic carbon. The C 1 /(C 2 +C 3 ) ratios (ranging from 34 to 1142) and the hydrogen and carbon isotopic compositions of methane (δD values of −109 to −156‰; δ 13 C values of −30.6 to −86.6‰) suggest that methane is primarily microbial but that a minor component could be thermally generated. Any thermogenic methane would have migrated from great depths, possibly >2 km. The presence of methane is likely to contribute to fluid flow by reducing the density of the fluids. Past fluid migration and venting are reflected by widespread carbonate mineralization at the sediment-water interface. This mineralization and the geographic distribution and proportions of microbial and thermogenic methane suggest that vent sites migrate when permeability is reduced during carbonate cementation. These results demonstrate that along with convergent and divergent plate boundaries, transform plate boundaries are characterized by fluid flow and that the flow may be widespread, occurring at sites away from fault zones.

Journal of Geophysical Research B: Solid Earth↗
USGS1997

Deep-ocean field test of methane hydrate formation from a remotely operated vehicle

We have observed the process of formation of clathrate hydrates of methane in experiments conducted on the remotely operated vehicle (ROY) Ventana in the deep waters of Monterey Bay. A tank of methane gas, acrylic tubes containing seawater, and seawater plus various types of sediment were carried down on Ventana to a depth of 910 m where methane gas was injected at the base of the acrylic tubes by bubble stream. Prior calculations had shown that the local hydrographic conditions gave an upper limit of 525 m for the P-T boundary defining methane hydrate formation or dissociation at this site, and thus our experiment took place well within the stability range for this reaction to occur. Hydrate formation in free sea-water occurred within minutes as a buoyant mass of translucent hydrate formed at the gas-water interface. In a coarse sand matrix the Filling of the pore spaces with hydrate turned the sand column into a solidified block, which gas pressure soon lifted and ruptured. In a fine-grained black mud the gas flow carved out flow channels, the walls of which became coated and then filled with hydrate in larger discrete masses. Our experiment shows that hydrate formation is rapid in natural seawater, that sediment type strongly influences the patterns of hydrate formation, and that the use of ROV technologies permits the synthesis of large amounts of hydrate material in natural systems under a variety of conditions so that fundamental research on the stability and growth of these substances is possible.

Geology↗