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D.J. Shultz

Publications and source records attributed to D.J. Shultz.

4 recordsLinked to original sources

Amino acid composition of suspended particles, sediment-trap material, and benthic sediment in the Potomac Estuary

Sediment trap deployments in estuaries provide a method for estimating the amount of organic material transported to the sediments from the euphotic zone. The amino acid composition of suspended particles, benthic sediment, and sediment-trap material collected at 2.4 m, 5.8 m, and 7.9 m depths in the Potomac Estuary was determined in stratified summer waters, and in well-mixed oxygenated waters (DO) in late fall. The total vertical flow, or flux, of material into the top traps ranged from 3 g m-2 d-1 in August to 4.9 g m-2 d-1 in October. The carbon and nitrogen fluxes increased in the deepest traps relative to the surface traps during both sampling periods, along with that of the total material flux (up to 47.3 g m-2 d-1 in the deepest trap), although the actual weight percent of organic carbon and organic nitrogen decreased with depth. Amino acid concentrations ranged from 129 mg g-1 in surface water particulate material to 22 mg g-1 in particulate material in 9-m-deep waters and in the benthic sediment. Amino acid concentrations from 2.4-mg-depth sediment traps averaged 104??29 mg g-1 in stratified waters and 164??81 mg g-1 in well-mixed waters. The deep trap samples averaed, 77.3??4.8 mg g-1 amino acids in summer waters and 37??16 mg g-1 in oxygenated fall waters. Amino acids comprised 13% to 39% of the organic carbon and 12% to 89% of the orgnaic nitrogen in these samples. Analysis of the flux results suggest that resuspension combined with lateral advection from adjacent slopes can account for up to 27% of the material in the deep traps when the estuary was well-mixed and unstratified. When the estuary was stratified in late summer, the amino acid carbon produced by primary productivity in the euphotic zone decreased by 85% (86% for total organic carbon) at the pycnocline at 6 m depth, leaving up to 15% of the vertical organic flux available for benthic sediment deposition. ?? 1993 Estuarine Research Federation.

Estuaries

Effect of discharge on the chlorophyll a distribution in the tidally-influenced Potomac River

In the tidal Potomac River, high river discharges during the spring are associated with high chlorophyll a concentrations in the following in the following summer, assuming that summertime light and temperature conditions are favorable. Spring floods deliver large loads of particulate N and P to the tidal river. This particulate N and P could be mineralized by bacteria to inorganic N and P and released to the water column where it is available for phytoplankton use during summertime. However, during the study period relatively low concentrations of chlorophyll a (less than 50 μg l −1 occurred in the tidal river if average monthly discharge during July or August exceeded 200 m 3 s −1 . Discharge and other conditions combined to produce conditions favorable for nuisance levels of chlorophyll a (greater than 100 μg l −1 approximately one year out of four. Chlorophyll a maxima occurred in the Potomac River transition zone and estuary during late winter (dinoflagellates) and spring (diatoms). Typical seasonal peak concentrations were achieved at discharges as high as 970 m 3 s −1 , but sustained discharges greater than 1,100 m 3 s −1 retarded development. Optimum growth conditions occurred following runoff events of 10 to 15 d duration which produced transit times to the transition zone of 7 to 10 d. Wet years with numerous moderate-sized runoff events, such as 1980, tend to produce greater biomass in the transition zone and estuary than do dry years such as 1981.

Potomac River

Fate of acetone in water

The physical, chemical, and biological processes that might affect the concentration of acetone in water were investigated in laboratory studies. Processes considered included volatilization, adsorption by sediments, photodecomposition, bacterial degradation, and absorption by algae and molds. It was concluded that volatilization and bacterial degradation were the dominant processes determining the fate of acetone in streams and rivers.

Chemosphere