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D.J. Schnoebelen

Publications and source records attributed to D.J. Schnoebelen.

6 recordsLinked to original sources

Lagrangian mass-flow investigations of inorganic contaminants in wastewater-impacted streams

Understanding the potential effects of increased reliance on wastewater treatment plant (WWTP) effluents to meet municipal, agricultural, and environmental flow requires an understanding of the complex chemical loading characteristics of the WWTPs and the assimilative capacity of receiving waters. Stream ecosystem effects are linked to proportions of WWTP effluent under low-flow conditions as well as the nature of the effluent chemical mixtures. This study quantifies the loading of 58 inorganic constituents (nutrients to rare earth elements) from WWTP discharges relative to upstream landscape-based sources. Stream assimilation capacity was evaluated by Lagrangian sampling, using flow velocities determined from tracer experiments to track the same parcel of water as it moved downstream. Boulder Creek, Colorado and Fourmile Creek, Iowa, representing two different geologic and hydrologic landscapes, were sampled under low-flow conditions in the summer and spring. One-half of the constituents had greater loads from the WWTP effluents than the upstream drainages, and once introduced into the streams, dilution was the predominant assimilation mechanism. Only ammonium and bismuth had significant decreases in mass load downstream from the WWTPs during all samplings. The link between hydrology and water chemistry inherent in Lagrangian sampling allows quantitative assessment of chemical fate across different landscapes.

Environmental Science & Technology

Reef and nonreef aquifers - A comparison of hydrogeology and geochemistry, northwestern Indiana

The principal bedrock aquifer system across much of Indiana consists of carbonate rocks of Silurian and Devonian age. The Silurian-Devonian aquifer system is used extensively for irrigation in northwestern Indiana and is approximately 170 m thick. Reef and nonreef carbonate aquifers in northwestern Indiana were assessed using hydrogeology (lithology, geophysical logs, aquifer tests) and geochemistry (major ions and stable isotopes). The study showed differences in water quantity and quality between the reef and nonreef aquifers. The reef aquifer had few shales, abundant fossiliferous material (up to 100 m thick), and high porosities (10 to 15%). The nonreef aquifer had abundant shales, less fossiliferous material (a few meters thick), and low porosities. Total transmissivities at the reef sites were 697 m 2 /d, (meters squared per day) and 4831 m 2 /d, compared to 46 m 2 /d at the nonreef site. Flowpaths in the nonreef aquifer were associated with fractures and poorly connected moldic porosity with larger fractures and better connected vuggy porosity in the reef aquifer. Water chemistry data for the nonreef aquifer showed mean concentrations of sodium (235 mg/L [milligrams per liter]), sulfate (160 mg/L), sul-fide (13 mg/L), fluoride (2.7 mg/L), and dissolved solids (635 mg/L) approximately two to five times larger when compared to mean concentrations in the reef aquifer. Ground water at the nonreef site was classified as a sodium-bicarbonate type while that at the reef sites was calcium-magnesium bicarbonate. The oxygen/deuterium isotope data indicates recharge from modern precipitation and not Pleistocene-age recharge.

Groundwater

Hydrogeology and water quality in the Cedar Rapids area, Iowa, 1992-96

The U.S. Geological Survey (USGS) and the city of Cedar Rapids conducted a cooperative study from 1992 to 1996 to assess the hydrogeology and water quality in the Cedar River, Cedar River alluvial aquifer, Devonian aquifer, and Silurian aquifer in a 231-square-mile area of Benton and Linn Counties near Cedar Rapids, Iowa. The city of Cedar Rapids withdrew an average of 34 million gallons per day between July 1,1995, and June 30, 1996, from the Cedar River alluvial aquifer for its drinking-water supply. The ground-water flow system in the 231-square-mile area was simulated using a modular, three-dimensional, finite-difference groundwater flow model (MODFLOW) under steady-state conditions. The three-layer groundwater flow model simulates ground-water flow in layer 1 for unconsolidated deposits that include the Cedar River alluvial aquifer; in layer 2 for the Devonian aquifer and buried-channel aquifer; and in layer 3 for the Silurian aquifer. Primary sources of inflow to the ground-water flow system in the model area include infiltration of precipitation (63.5 percent) and leakage from the Cedar River (34.7 percent). Pumpage from municipal, industrial, and private wells accounts for about 48.3 percent of system outflow. Primary sources of inflow to the Cedar River alluvial aquifer include leakage from the Cedar River (74.2 percent), leakage from adjacent or underlying hydrogeologic units (20.9 percent), and infiltration of precipitation (4.9 percent). Pumpage by municipal water-supply wells from the alluvial aquifer accounts for about 78.0 percent of system outflow. Simulations of two hypothetical conditions using the steady-state ground-water flow model were conducted to evaluate quantitative changes on sources of water to the Cedar River alluvial aquifer. Results for the scenario representing a period of less-than-average annual precipitation for 1961-90 indicate a 32.0-percent reduction of total ground-water flow and a 5.7-percent increase in river leakage to the Cedar River alluvial aquifer. Results for the scenario representing increased pumping from the Cedar River alluvial aquifer, with pumping increased 68.3 percent from about 41 million gallons per day (for the calibrated model) to about 70 million gallons per day, indicate a 70.9-percent increase in simulated river leakage. Commonly used herbicides in Iowa such as atrazine (and the metabolite products deethylatrazine and deisopropylatrazine), cyanazine, and metolachlor, when detected in the Cedar River alluvial aquifer, were typically at small concentrations (less than 1.0 microgram per liter). Atrazine concentrations in 26 of the 64 wells sampled were less than the 0.05 microgram per liter minimum reporting level. Most ground-water samples collected from the Devonian and Silurian aquifers had herbicide concentrations less than 0.05 microgram per liter. Nitrite-plus-nitrate nitrogen (nitrate) concentrations in ground-water samples varied from less than the minimum reporting level (0.05 milligram per liter) to 15.0 milligrams per liter. Nitrate was not detected in samples from 18 wells, and nitrate concentrations greater than the Maximum Contaminant Level for nitrate as nitrogen (10 milligrams per liter) were detected in samples from 4 wells. Several areas in the Cedar River alluvial aquifer with large iron and manganese concentrations could be related to the original depositional environment of the sediment. In general, large iron and manganese concentrations in ground water are often associated with abundant organic and argillaceous material in sediment near old meander channels and sloughs.

Iowa

Selected hydrogeologic data from the Cedar Rapids Area, Benton and Linn counties, Iowa, October 1992 through March 1996

The city of Cedar Rapids, Iowa, obtains its water supply from shallow wells screened in the alluvial aquifer along the Cedar River. A cooperative study between the city of Cedar Rapids, Iowa, and the U.S. Geological Survey was started in March 1992 to assess the water quality and water quantity of the ground-water resource. This report summarizes selected hydrogeologic data collected from October 1992 through March 1996. Information collected includes water quality (major ions, nutrients, and pesticides), ground-water levels, multiprobe-instrument data (water levels, specific conductance, pH, water temperature, and dissolved oxygen monitored at 15-, 30-, or 60-minute intervals), well information (location, casing type, screen interval, and depth), and geophysical seismic-refraction and seismic-reflection data (estimated depth to bedrock and alluvial thickness along the Cedar River). Geologic, hydrologic, and water-quality data were collected from domestic, municipal, observation, and industrial wells and the Cedar River. Well-construction data for more than 300 wells in the Cedar Rapids area in Benton and Linn Counties, Iowa, were compiled primarily from records on file with the Iowa Department of Natural Resources, Geologic Survey Bureau (Iowa City).

Iowa