Geology topics

D.J. Graczyk

Publications and source records attributed to D.J. Graczyk.

11 recordsLinked to original sources

USGS2010

A fresh look at road salt: Aquatic toxicity and water-quality impacts on local, regional, and national scales

A new perspective on the severity of aquatic toxicity impact of road salt was gained by a focused research effort directed at winter runoff periods. Dramatic impacts were observed on local, regional, and national scales. Locally, samples from 7 of 13 Milwaukee, Wisconsin area streams exhibited toxicity in Ceriodaphnia dubia and Pimephales promelas bioassays during road-salt runoff. Another Milwaukee stream was sampled from 1996 to 2008 with 72% of 37 samples exhibiting toxicity in chronic bioassays and 43% in acute bioassays. The maximum chloride concentration was 7730 mg/L. Regionally, in southeast Wisconsin, continuous specific conductance was monitored as a chloride surrogate in 11 watersheds with urban land use from 6.0 to 100%. Elevated specific conductance was observed between November and April at all sites, with continuing effects between May and October at sites with the highest specific conductance. Specific conductance was measured as high as 30 800 ??S/cm (Cl = 11 200 mg/L). Chloride concentrations exceeded U.S. Environmental Protection Agency (USEPA) acute (860 mg/L) and chronic (230 mg/L) water-quality criteria at 55 and 100% of monitored sites, respectively. Nationally, U.S. Geological Survey historical data were examined for 13 northern and 4 southern metropolitan areas. Chloride concentrations exceeded USEPA water-quality criteria at 55% (chronic) and 25% (acute) of the 168 monitoring locations in northern metropolitan areas from November to April. Only 16% (chronic) and 1% (acute) of sites exceeded criteria from May to October. At southern sites, very few samples exceeded chronic water-quality criteria, and no samples exceeded acute criteria. ?? 2010 American Chemical Society.

Environmental Science & Technology↗

USGS2001

Evaluation of nonpoint-source contamination, Wisconsin: water year 1999

The objective of the watershed-management evaluation monitoring program in Wisconsin is to evaluate the effectiveness of best-management practices (BMPs) for controlling nonpoint-source pollution in rural and urban watersheds. This progress report provides a summary of the data collected by the U.S Geological Survey for the program and a discussion of the results from several different detailed analyses conducted within this program. A land-use and best-management-practice inventory is ongoing for each evaluation monitoring project to track the different sources of nonpointsource pollution in each watershed and to document implementation of best-management programs that may cause changes in the water quality of streams. Updated information is gathered each year, mapped, and stored in a geographic-information-system database. Summaries of BMP-implementation data collected through the 1999 water year are presented in this report. Suspended sediment and total phosphorus storm-load and annual-load data are summarized for eight rural sites. For all 8 rural sites a sufficient number of pre-BMP storm samples have been collected; for two of the sites (Brewery and Garfoot Creeks), a sufficient number of post-BMP storm samples have been collected to allow for a final assessment of the effectiveness of the BMPs. For the remaining sites, numerous transitional storm samples have been collected, but in all cases BMP implementation has lagged such that there are insufficient post-BMP storm samples for final analysis. For two sites (Rattlesnake and Kuenster Creeks) there are not enough planned BMPs to warrant further data collection. Continuous dissolved-oxygen data collected at 5 rural sites are summarized. In terms of instantaneous concentrations when comparing pre-BMP data to transitional and post-BMP data, the general trend is a reduction in the number of days that the dissolved oxygen concentration was less than the state standard. These results are anecdotal, however; the differences have not been rigorously tested statistically. For a level of dissolved oxygen sustained over a continuous hour, the results are mixed. In general the number of days with standard violations has decreased, but there are notable exceptions. For the four urban streams, the pre-BMP data were examined to determine the level of improvement that could potentially be detected with a statistical analysis. Regression analyses were performed relating constituent loads of suspended solids, total phosphorus and total copper to various independent variables, including seasonal terms and variables related to rainfall. On the basis of the residuals from the regressions, there is a wide range of potential change that could be detected with an analysis of pre- and post-BMP loads. This is likely a result of the high degree of variability in the data, particularly from site to site. For suspended solids, total phosphorus, and total recoverable copper the minimum detectable changes ranges from 20-80, 30-70 and 30-90 percent, respectively. For two of the eight rural streams (Rattlesnake and Kuenster Creeks) minimal BMP implementation has occurred, hence a comparison of pre- BMP and data collected after BMP implementation began is not warranted. For two other rural streams (Brewery and Garfoot Creeks), BMP implementation is complete. For the four remaining rural streams (Bower, Otter, Eagle, and Joos Valley Creeks), the pre-BMP load data were compared to the transitional data to determine if significant reductions in the loads have occurred as a result of the BMP implementation to date. For all sites, the actual constituent loads for suspended solids and total phosphorus exhibit no statistically significant reductions after BMP installation. Multiple regressions were used to remove some of the natural variability in the data. Based on the residual analysis, for Otter Creek, there is a significant difference in the suspended-solids regression residuals between the pre-BMP and transitional periods, indicating a potential reduction as a result of the BMP implementation after accounting for natural variability. For Joos Valley Creek, the residuals for suspended solids and total phosphorus both show a significant reduction after accounting for natural variability. It is possible that the other sites will also show statistically significant reductions in suspended solids and total phosphorus if additional BMPs are implemented.

Wisconsin↗

USGS1996

Sediment transport, particle size, and loads in North Fish Creek in Bayfield County, Wisconsin, water years 1990-91

North Fish Creek is underused as a trout and salmon hatchery despite its excellent water quality. The shifting-sand streambed in the lower 9 miles of the stream inhibits successful spawning and is a poor habitat for macroinvertebrates, the primary food for juvenile trout and salmon. To provide data necessary for evaluation of potential sand-loading-control practices, the U.S. Geological Survey determined total-sediment transport, particle size, and loads for three sites, designated A, B, and C, on North Fish Creek during water years 1990-91. At site C, the most upstream site, all sediment was transported as suspended sediment. The average annual total-sediment load during 1990- 91 was 479 tons. About 88 percent of the load was transported during periods of snowmelt or storm runoff. About 75 percent of the sediment load was silt- and clay-size particles; the remainder was sand. Total-sediment discharge was calculated by the modified-Einstein procedure to determine total sediment transport-rate relations for site A, the most downstream site, and for site B. Annual totalsediment load was 11,960 tons in water year 1990 and 18,430 tons in water year 1991 at site B. About 97 percent of the total load was transported during periods of snowmelt and storm runoff. About 60 percent of the total-sediment load was sand-size particles. Annual total-sediment loads were 20,690 tons and 33,100 tons in water years 1990 and 1991, respectively, at site A. About 67 percent of the total-sediment load was sand-size particles. Annual average streamflow, as indicated by flow in the Bois Brule River, was about 16 percent below average in water year 1990, and about 4 percent above average in water year 1991. There was little relation between watershed area and sediment loads for the three sites. The watershed of site C is about 41 percent of that of site A, but the sand load at site C was only 1 percent of that at site A. The watershed area between sites B and C is 40 percent of that above site A, but this area yielded 49 percent of the sand load at site A. Nineteen percent of the watershed above site A is between sites A and B, yet this area yielded about 50 percent of the sand load at site A.

Wisconsin↗

USGS1995

Evaluation of nonpoint-source contamination, Wisconsin; selected streamwater-quality data, land-use and best-management practices inventory, and quality assurance and quality control, water year 1993

The objective of the watershed-management evaluation monitoring program in Wisconsin is to evaluate the effectiveness of the best-management practices (BMPs) for rural streams, urban streams, and urban storm sewers. This report is an annual summary of the data collected for the program and a report of the results from several different special studies conducted within this program. Suspended sediment and total phosphorus storm-load data are summarized for eight rural sites and suspended sediment, total phosphorus, total recoverable lead, total recoverable copper, total recoverable zinc, and total recoverable cadmium storm-load data are summarized for four urban sites. Dissolved-oxygen data is summarized and compared with Wisconsin's waterquality standards for summer 1993 for seven rural sites. The dissolved-oxygen concentrations declined to levels below these standards at least one time at all seven sites during summer 1993. Total-recoverable hardness concentrations were compared with dissolved-hardness concentrations at two urban streams and two urban storm sewers. Least-squared linear regressions resulted in stronger relations for low-flow conditions than for high-flow conditions, indicating that most hardness during low flow is dissolved hardness. Pesticide data are summarized for four urban sites and six rural sites. Herbicides were detected at urban and rural sites; whereas insecticides were detected only at urban sites. A land-use and best-management-practice inventory is ongoing for each evaluation monitoring project to track the different sources of nonpoint pollution in each watershed and to document implementation of best-management programs that may cause changes in water quality of streams. Updated information is gathered each year, mapped, and stored in a geographic-information-system data base. The quality-assurance/quality-control plan for the urban watershed-management evaluation program consisted of a series of blank samples. These blank samples were used to identify and isolate contamination by inorganic and organic components throughout the collection and processing of urban streamwater samples. A dissolved trace-metal contamination problem was identified and resolved by using different laboratory- supplied sample bottles. A special study was done to determine the effect of holding time on fecal coliform colony counts. A linear regression indicated that the mean decrease in colony counts over 72 hours was 8.2 percent per day. Results after 24 hours showed that colony counts increased in some samples and decreased in others.

Wisconsin↗

USGS1995

Evaluation of nonpoint-source contamination, Wisconsin: Land-use and Best-Management-Practices inventory, selected streamwater-quality data, urban-watershed quality assurance and quality control, constituent loads in rural streams, and snowmelt-runoff analysis, water year 1994

The objective of the watershed-management evaluation monitoring program in Wisconsin is to evaluate the effectiveness of best-management practices (BMP) for controlling nonpoint-source contamination in rural and urban watersheds. This report is an annual summary of the data collected for the program by the U.S Geological Survey and a report of the results of several different detailed analyses of the data. A land-use and BMP inventory is ongoing for 12 evaluation monitoring projects to track the sources of nonpoint-source pollution in each watershed and to document implementation of BMP's that may cause changes in the water quality of streams. Updated information is gathered each year, mapped, and stored in a geographic-information-system data base. Summaries of data collected during water years 1989-94 are presented. A water year is the period beginning October 1 and ending September 30; the water year is designated by the calendar year in which it ends. Suspended-sediment and total-phosphorus data (storm loads and annual loads) are summarized for eight rural sites. For all sites, the annual suspended-sediment or suspended-solids load for water year 1993 exceeded the average for the period of data collection; the minimum annual loads were transported in water year 1991 or 1992. Continuous dissolved-oxygen data were collected at seven rural sites during water year 1994. Data for water years 1990-93 are summarized and plotted in terms of percentage of time that a particular concentration is equaled or exceeded. Dissolved-oxygen concentrations in four streams were less than 9 mg/L at least 50 percent of the time, a condition that fails to meet suggested criterion for coldwater streams. The dissolved-oxygen probability curve for one of the coldwater streams is markedly different than the curves for the other streams, perhaps because of differences in aquatic biomass. Blank quality-assurance samples were collected at two of the urban evaluation monitoring sites to isolate contamination in the sample bottle, the automatic sampler and splitter, and the filtration system. Significant contamination caused excessive concentrations of dissolved chloride, alkalinity, and biochemical oxygen demand. The level of contamination may be large enough to affect data for water samples in which these analytes are present at low concentration. Further investigation is being done to determine the source of contamination and take measures to minimize its effect on the sampling. A preliminary regression analysis was done for the rural sites using data collected during water years 1989-93. Loads of suspended solids and total phosphorus in stormflow were regressed against various precipitation-related measures. The results indicate that, for most sites, changes in constituent load on the order of 40 to 50 percent could be detected with a statistical test. For two sites, the change would have to be 60 to 70 percent to be detected. A detailed comparison of snowmelt runoff and rainfall stormflow in urban and rural areas was done using data collected during water years 1985-93. For the rural sites where statistically significant differences were found between constituent loads in snowmelt and storm runoff, the loads of suspended solids and total phosphorus in snowmelt runoff were greater than those in storm runoff. For the urban sites where statistically significant differences were found between snowmelt and storm runoff, the loads of suspended solids and total phosphorus in storm runoff were greater than those in snowmelt runoff. The importance of including snowmelt runoff in designing and analyzing the effects of BMP's on streamwater quality, particularly in rural areas, is emphasized by these results.

Wisconsin↗

USGS1993

Preliminary evaluation of effects of best management practices in the Black Earth Creek, Wisconsin, priority watershed

Nonpoint-source contamination accounts for a substantial part of the water quality problems in many watersheds. The Wisconsin Nonpoint Source Water Pollution Abatement Program provides matching money for voluntary implementation of various best management practices (BMPs). The effectiveness of BMPs on a drainage-basin scale has not been adequately assessed in Wisconsin by use of data collected before and after BMP implementation. The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, monitored water quality in the Black Earth Creek watershed in southern Wisconsin from October 1984 through September 1986 (pre-BMP conditions). BMP implementation began during the summer of 1989 and is planned to continue through 1993. Data collection resumed in fall 1989 and is intended to provide information during the transitional period of BMP implementation (1990-93) and 2 years of post-BMP conditions (1994-95). Preliminary results presented for two subbasins in toe Black Earth Creek watershed (Brewery and Garfoot Creeks) are based on data collected during pre-BMP conditions and the first 3 years of the transitional period. The analysis includes the use of regressions to control for natural variability in the data and, hence, enhance the ability to detect changes. Data collected to date (1992) indicate statistically significant differences in storm mass transport of suspended sediment and ammonia nitrogen at Brewery Creek. The central tendency of the regression residuals has decreased with the implementation of BMPs; hence, the improvement in water quality in the Brewery Creek watershed is likely a result of BMP implementation. Differences in storm mass transport at Garfoot Creek were not detected, primarily because of an insufficient number of storms in the transitional period. As practice implementation continues, the additional data will be used to determine the level of management which results in significant improvements in water quality in the two watersheds. Future research will address techniques for including snowmelt runoff and early spring storms.Nonpoint-source contamination accounts for a substantial part of the water quality problems in many watersheds. The Wisconsin Nonpoint Source Water Pollution Abatement Program provides matching money for voluntary implementation of various best management practices (BMPs). The effectiveness of BMP s on a drainage-basin scale has not been adequately assessed in Wisconsin by use of data collected before and after BMP implementation. The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, monitored water quality in the Black Earth Creek watershed in southern Wisconsin from October 1984 through September 1986 (pre-BMP conditions). BMP implementation began during the summer of 1989 and is planned to continue through 1993. Data collection resumed in fall 1989 and is intended to provide information during the transitional period of BMP implementation (1990-93) and 2 years of post-BMP conditions (1994-95). Preliminary results presented for two subbasins in the Black Earth Creek watershed (Brewery and Garfoot Creeks) are based on data collected during pre-BMP conditions and the first 3 years of the transitional period. The analysis includes the use of regressions to control for natural variability in the data and, hence, enhance the ability to detect changes. Data collected to date (1992) indicate statistically significant differences in storm mass transport of suspended sediment and ammonia nitrogen at Brewery Creek. The central tendency of the regression residuals has decreased with the implementation of BMPs; hence, the improvement in water quality in the Brewery Creek watershed is likely a result of BMP implementation. Differences in storm mass transport at Garfoot Creek were not detected, primarily because of an insufficient number of storms in the transitional period. As practice implementation continues, the addit

Conference Paper↗

USGS1990

Hydrology, aquatic macrophytes, and water quality of Black Earth Creek and its tributaries, Dane County, Wisconsin, 1985-86

An intensive data-collection program for the Black Earth Creek basin in southern Wisconsin was conducted from October 1984 through September 1986 to assess the hydrology, aquatic macrophytes, and water quality in Black Earth Creek by the U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources. Three sites on two cold-water trout streams Black Earth Creek at Cross Plains, Black Earth Creek near Cross Plains, and Garfoot Creek near Cross Plains were continuously monitored for streamflow and water-quality data. One site in a warm-water stream, Brewery Creek at Cross Plains, also was monitored. Aquatic macrophyte biomass was determined for three sites on Black Earth Creek. Streamflow at Black Earth Creek at Black Earth during the 1985 and 1986 water years (WY) were 44 and 60 percent greater than the long-term mean discharge of 33.3 ft3/s (cubic feet per second) for the period 1955-86. Water year 1986 had the highest annual mean discharge, 53.4 ft3/s, since records began in 1954 at the most downstream site Black Earth Creek at Black Earth. Although there have been considerable fluctuations in streamflow, it has tended to increase since WY 1965 as a result of above-average precipitation and consequent rising ground-water levels. Trout population densities may be related to annual mean streamflow. A regression analysis of adult trout populations and the 3-year moving annual mean discharge had a correlation coefficient of 0.75 with a standard error of 83 percent. Aquatic macrophyte biomass in Black Earth Creek was substantially less in 1986 than in 1985 as a result of substrate scouring from the flood of July 25, 1985. The frequency of occurrence of species during 1985 and 1986 was similar to that of 1981, and seasonal succession of species also was similar; Potamogeton crispus dominated early in the year and senesced in July. P. crispus and P. pectinatus, both indicative of eutrophic conditions, dominated upstream and downstream, respectively; neither species is native to the area. In 1985, the greatest biomass was found upstream from Cross Plains. This large biomass caused diurnal fluctuations in dissolved-oxygen concentration of 5 to 6 mg/L (milligrams per liter) as a result of photosynthesis and respiration. Many of the dissolved-oxygen minimums, recorded at night, were less than the State 6.0-mg/L water-quality standard for trout waters. Discharge from point sources may adversely affect Black Earth Creek's water quality. Warm water discharged to Black Earth Creek from a gravel pit operation upstream from Cross Plains increased water temperatures 2 to 4 degrees Celsius and decreased the dissolved oxygen about 1 mg/L at a site 1.8 miles downstream. Runoff from a settling pond from a landfill operation in the headwaters of the Black Earth Creek basin drains through a wetland that drains to Black Earth Creek and contained as much as 60 mg/L ammonia nitrogen, 980 mg/L biochemical oxygen demand, and 1,300 mg/L chemical oxygen demand, which may be detrimental to trout. Garfoot Creek had the highest suspended-sediment and phosphorus yields per unit area of the three upstream basins during low to moderate runoff. Detention ponds in the Brewery Creek basin appear to be less effective in controlling suspended-sediment and phosphorus loads during periods of high runoff than during moderate runoff. Brewery Creek had the highest concentrations of suspended sediment and total phosphorus during low and high flows. The water quality at the Black Earth Creek gaging station at Black Earth was affected by Garfoot Creek and unnamed tributaries. As a result, yields of suspended sediment, phosphorus, and nitrogen increased between Cross Plains and Black Earth. High streamflows during WY 1985 resulted in suspendedsediment yields at Black Earth Creek at Black Earth that were 29 percent greater than the 12-year (1955-65, 85-86) mean; yields ranged from 69.5 ton/mi2 (tons per square mile) in Black Earth Creek at Cross Plains to 116 ton/mi2 in the Brewery Creek basin. Phosphorus yields ranged from 312 lb/mi2 (pounds per square mile) in Black Earth Creek at Cross Plains to 628 lb/mi2 in the Brewery Creek basin. Total nitrogen yields ranged from 3,280 lb/mi2 in the Brewery Creek basin to 6,920 lb/mi2 in the Garfoot Creek basin. An increase in oxygen demand, caused by agricultural runoff, has resulted in reduced dissolved-oxygen content of the water in both Black Earth and Garfoot Creeks. The most substantial reduction occurred at Black Earth Creek at Cross Plains on July 25, 1985, as a result of the largest storm runoff event during the study. A rainfall of 5.54 inches caused streamflow discharges to increase from 9 to 122 ft3/s and dissolved-oxygen concentrations to decline to 3.0 mg/L; the dissolved-oxygen concentration was less than 6.0 mg/L for 30 hours.

Wisconsin↗

USGS1989

Preparation of average annual runoff map of the United States, 1951-80

Average annual runoff was computed or estimated for 2,148 hydrologic cataloging units in the United States and Puerto Rico , for the period 1951-80. Runoff was computed from the recorded streamflow at 5,951 U.S. Geological Survey gaging stations. The runoff at more than 3,000 of these stations was estimated by correlation with other nearby stations to adjust for missing data. These runoff data were used to draw a map depicting the variation of runoff throughout the nation. Average annual runoff varied from less than 0.01 inch in parts of the Great Basin (Utah, parts of Nevada, Oregon, and California) to more than 240 inches in southeastern Alaska. (USGS)

Open-File Report↗

USGS1987

Maps of runoff in the northeastern region and the southern Blue Ridge Province of the United States during selected periods in 1983-85

Maps of annual runoff for two regions in the eastern United States were prepared by the U.S. Geological Survey for the Direct/Delayed Response Project being conducted by the U.S. EPA. These maps show annual runoff during water year 1984 in the northeastern region and in the Southern Blue Ridge Province. Runoff from the northeastern region during the 1984 water yr ranged from 12 to 55 in.; this was 25 to 55% > average runoff for the 1951-80 period. Runoff from the Southern Blue Ridge Province during the 1984 water year ranged from 14 to 60 in.; this was 10 to 30% > the average runoff for the 1951-80 period. A split sample analysis of the data for New York was conducted to evaluate the accuracy of the runoff mapping procedure used in this report. A runoff map was prepared using one-half of the data base. The map was then used to estimate runoff at the gaging stations that were not used to develop the map. The values estimated from the split-sample map were found to differ from the actual recorded values by 9.9%. The runoff maps are most accurate in areas with a relatively large concentration of gaging stations and little topographic variability. Conversely, the maps are least accurate in areas with few gaging stations and high topographic variability. Based on these criteria, those parts of the maps covering Connecticut, Massachusetts, New Jersey, and Rhode Island, are the most reliable. The least reliable parts of the maps are those along the North Carolina-Tennessee border and in parts of Maine.

Connecticut, Georgia, Maine, Massachusetts, New Ha↗

USGS1986

A history of annual streamflows from the 21 water-resource regions in the United States and Puerto Rico, 1951-83

Annual streamflows from the 21 water-resource regions in the United States and Puerto Rico were calculated for the period 1951-83. The total streamflow discharging to the oceans from the conterminous United States during this period averaged 1,270 billion gallons per day. The outflow from the Lower Mississippi Water-Resource Region (08), which drains 41 percent of the land area of the conterminous United States, contributes 34 percent of the total streamflow to the oceans, which is the most of any region. A 15-year moving average of the annual streamflow was also calculated for each region. The Mid-Atlantic (Region 02) shows a decreasing trend in streamflow since the mid-1970's whereas the Upper Mississippi (Region 07), the Missouri (Region 10), the Rio Grande (Region 13), the Upper Colorado (Region 14), the Lower Colorado (Region 15), the Great Basin (Region 16), and California (Region 18) all show an increasing trend in streamflows. Streamflow from the Upper and Lower Colorado (Regions 14 and 15) appear to be heavily affected by large storage reservoirs. Streamflow from the Upper Colorado (Region 14) shows a decreasing streamflow in 1963 and 1964, which may be due to filling of Lake Powell.

Puerto Rico↗

USGS1986

Water quality in the St Croix National Scenic Riverway, Wisconsin

The U.S. Geological Survey conducted a water-quality study of the St. Croix National Scenic Riverway. This report documents the water quality during the period 1975-83. The water quality is good for most uses and is a calcium bicarbonate type. Concentrations of most constituents analyzed were less than most sites in Wisconsin. Constituent loads and yields were alsg lower in the Sceiilc Riverway than in other Wisconsin streams. Water-quality samples were collected at 10 stations throughout the study area and were compared to analyses of samples from selected National Stream Quality Accounting Network stations (NASQAN) and the Hydrologic Bench-Mark NetWork (HBMN) station in Wisconsin. The average suspended-sediment concentration for 9 of the 10 stations in this study was 7.7 milligrams per liter. This compared with an average suspended-sediment concentration of 11 milligrams per liter for two other stations in the scenic riverway and an average suspended-sediment concentration of 110 milligrams per liter for Wisconsin. Concentrations of major cations and anions were generally below concentrations at other stations in the State. The concentrations of major cations and anions at two of the stations were similar to concentrations at the HBMN station Popple River near Fence. Mean total phosphorus concentrations ranged from 0. 02 to 0. 08 milligram per liter at the study stations and from 0.03 to 0.16 milligram per liter at selected NASQAN stations. Concentrations of trace metals were below safe drinking water standards at all the study sites except for iron and manganese which exceeded drinking water standards at some of the study sites. Pesticides were sampled at the St. Croix River at St. Croix Falls and above and below cranberry bogs that drain into the Namekagon River. No pesticides were detected in the water/suspended-sediment mixture or bottom material. Average annual loads of suspended sediment, total phosphorus, total nitrogen, and dissolved solids were calculated by a flow-duration curve method. Annual suspended-sediment loads ranged from 580 to 25,000 tons per year at the study stations. Annual suspended-sediment loads at the HBMN station and NASQAN stations ranged from 720 tons at the Popple River near Fence to 443,000 tons at the Chippewa River near Durand. Average annual total phosphorus loads ranged from 6,800 to 900,000 pounds at the study stations compared with 145,000 to 1 ,600,000 pounds at selected Wisconsin NASQAN stations. Yields for suspended sediment, total phosphorus, total nitrogen, and dissolved solids at the study stations were consistently lower than at other stations in the State. Suspendedsediment yields ranged from 1.9 to 13.3 tons per square mile. The average suspended-sediment yield for Wisconsin is 80 tons per square mile. Total phosphorous and the other constituents exhibited the same trend.

Wisconsin, Minnesota↗