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D. Moore

Publications and source records attributed to D. Moore.

5 recordsLinked to original sources
USGS2000

15N NMR study of nitrate ion structure and dynamics in hydrotalcite-like compounds

We report here the first nuclear magnetic resonance (NMR) spectroscopic study of the dynamical and structural behavior of nitrate on the surface and in the interlayer of hydrotalcite-like compounds (15NO3--HT). Spectroscopically resolvable surface-absorbed and interlayer NO3- have dramatically different dynamical characteristics. The interlayer nitrate shows a well defined, temperature independent uniaxial chemical shift anisotropy (CS A) powder pattern. It is rigidly held or perhaps undergoes rotation about its threefold axis at all temperatures between -100 ??C and +80 ??C and relative humidities (R.H.) from 0 to 100% at room temperature. For surface nitrate, however, the dynamical behavior depends substantially on temperature and relative humidity. Analysis of the temperature and R.H. dependences of the peak width yields reorieritational frequencies which increase from essentially 0 at -100 ??C to 2.6 ?? 105 Hz at 60 ??C and an activation energy of 12.6 kJ/mol. For example, for samples at R.H. = 33%, the surface nitrate is isotropically mobile at frequencies greater than 105 Hz at room temperature, but it becomes rigid or only rotates on its threefold axis at -100 ??C. For dry samples and samples heated at 200 ??C (R.H. near 0%), the surface nitrate is not isotropically averaged at room temperature. In contrast to our previous results for 35Cl--containing hydrotalcite (35Cl--HT), no NMR detectable structural phase transition is observed for 15NO3--HT. The mobility of interlayer nitrate in HT is intermediate between that of carbonate and chloride.

American Mineralogist↗
USGS1999

Aeromagnetic legacy of early Paleozoic subduction along the Pacific margin of Gondwana

Comparison of the aeromagnetic signatures and geology of southeastern Australia and northern Victoria Land, Antarctica, with similar data from ancient subduction zones in California and Japan, provides a framework for reinterpretation of the plate tectonic setting of the Pacific margin of early Paleozoic Gondwana. In our model, the plutons in the Glenelg (south-eastern Australia) and Wilson (northern Victoria Land) zones formed the roots of continental-margin magmatic arcs. Eastward shifting of arc magmatism resulted in the Stavely (south-eastern Australia) and Bowers (northern Victoria Land) volcanic eruptions onto oceanic forearc crust. The turbidites in the Stawell (southeastern Australia) and Robertson Bay (northern Victoria Land zones) shed from the Glenelg and Wilson zones, respectively, were deposited along the trench and onto the subducting oceanic plate. The margin was subsequently truncated by thrust faults and uplifted during the Delamerian and Ross orogenies, leading to the present-day aeromagnetic signatures.

Geology↗
USGS1997

Frictional strength and velocity-dependence of serpentine gouges under hydrothermal conditions and their seismogeological implications

The velocity - dependence of frictional strength of serpentine gouges has been measured at constant normal stress of 110 MPa, pore pressure of 10 MPa, temperature 25, 100 and 200??C , and at sliding rate ranging from 0. 001 to 10??m/s. At 25??C, the coefficient of friction of chrysotile gouge is very low (?????0. 2-0. 25), while lizardite and antigorite gouge are much stronger, with ?????0. 39 and 0. 45, respectively. The frictional strengths of chrysotile and antigorite gouges change little with a temperature increase to 200??C, whereas the strength of lizardite gouge increases substantially with increasing temperature. At 25??C, all three gouges show a transition from weak velocity weakening at high slip rates to velocity strengthening at low slip rates. With increasing temperature, the velocity dependence of each gouge shifts towards more positive values, especially at high slip rates. Based on this study and previous results, we suggest that the presence of serpentine in the fault zone may contribute to the occurrence of stable creep rather than earthquakes, but this effect may be limited to shallow depths. Although chrysotile is one of the weakest rock - forming minerals, it is still too strong to explain the weakness of the San Andreas fault deduced from heat flow data.

Dizhen Dizhi↗
USGS1991

Fractal patterns of fractures in granites

Fractal measurements using the Cantor's dust method in a linear one-dimensional analysis mode were made on the fracture patterns revealed on two-dimensional, planar surfaces in four granites. This method allows one to conclude that: (1)|The fracture systems seen on two-dimensional surfaces in granites are consistent with the part of fractal theory that predicts a repetition of patterns on different scales of observation, self similarity. Fractal analysis gives essentially the same values of D on the scale of kilometres, metres and centimetres (five orders of magnitude) using mapped, surface fracture patterns in a Sierra Nevada granite batholith (Mt. Abbot quadrangle, Calif.). (2)|Fractures show the same fractal values at different depths in a given batholith. Mapped fractures (main stage ore veins) at three mining levels (over a 700 m depth interval) of the Boulder batholith, Butte, Mont. show the same fractal values although the fracture disposition appears to be different at different levels. (3)|Different sets of fracture planes in a granite batholith, Central France, and in experimental deformation can have different fractal values. In these examples shear and tension modes have the same fractal values while compressional fractures follow a different fractal mode of failure. The composite fracture patterns are also fractal but with a different, median, fractal value compared to the individual values for the fracture plane sets. These observations indicate that the fractal method can possibly be used to distinguish fractures of different origins in a complex system. It is concluded that granites fracture in a fractal manner which can be followed at many scales. It appears that fracture planes of different origins can be characterized using linear fractal analysis.

Earth and Planetary Science Letters↗