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D. A. John

Publications and source records attributed to D. A. John.

At least 19 recordsLinked to original sources
USGS2011

Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO 2 ) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO 2 ) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO 2 ), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the axis of the modern arc in northeastern California, suggesting that the Cascade arc south of modern Mount Shasta migrated west during the Late Miocene and Pliocene, while the arc north of Mount Shasta remained in essentially the same position. We interpret these patterns as evidence for an Eocene to Miocene tear in the subducting slab, with a more steeply dipping plate segment to the north, and an initially more gently dipping segment to the south that gradually steepened from the Middle Miocene to the present.

California↗
USGS2008

Characteristics, extent and origin of hydrothermal alteration at Mount Rainier Volcano, Cascades Arc, USA: Implications for debris-flow hazards and mineral deposits

Hydrothermal alteration at Mount Rainier waxed and waned over the 500,000-year episodic growth of the edifice. Hydrothermal minerals and their stable-isotope compositions in samples collected from outcrop and as clasts from Holocene debris-flow deposits identify three distinct hypogene argillic/advanced argillic hydrothermal environments: magmatic-hydrothermal, steam-heated, and magmatic steam (fumarolic), with minor superimposed supergene alteration. The 3.8 km 3 Osceola Mudflow (5600 y BP) and coeval phreatomagmatic F tephra contain the highest temperature and most deeply formed hydrothermal minerals. Relatively deeply formed magmatic-hydrothermal alteration minerals and associations in clasts include quartz (residual silica), quartz–alunite, quartz–topaz, quartz–pyrophyllite, quartz–dickite/kaolinite, and quartz–illite (all with pyrite). Clasts of smectite–pyrite and steam-heated opal–alunite–kaolinite are also common in the Osceola Mudflow. In contrast, the Paradise lahar, formed by collapse of the summit or near-summit of the edifice at about the same time, contains only smectite–pyrite and near-surface steam-heated and fumarolic alteration minerals. Younger debris-flow deposits on the west side of the volcano (Round Pass and distal Electron Mudflows) contain only low-temperature smectite–pyrite assemblages, whereas the proximal Electron Mudflow and a < 100 y BP rock avalanche on Tahoma Glacier also contain magmatic-hydrothermal alteration minerals that are exposed in the avalanche headwall of Sunset Amphitheater, reflecting progressive incision into deeper near-conduit alteration products that formed at higher temperatures. The pre-Osceola Mudflow alteration geometry is inferred to have consisted of a narrow feeder zone of intense magmatic-hydrothermal alteration limited to near the conduit of the volcano, which graded outward to more widely distributed, but weak, smectite–pyrite alteration within 1 km of the edifice axis, developed chiefly in porous breccias. The edifice was capped by a steam-heated alteration zone, most of which resulted from condensation of fumarolic vapor and oxidation of H 2 S in the unsaturated zone above the water table. Weakly developed smectite–pyrite alteration extended into the west and east flanks of the edifice, spatially associated with dikes that are localized in those sectors; other edifice flanks lack dikes and associated alteration. The Osceola collapse removed most of the altered core and upper east flank of the volcano, but intensely altered rocks remain on the uppermost west flank. Major conclusions of this study are that: (1) Hydrothermal–mineral assemblages and distributions at Mount Rainier can be understood in the framework of hydrothermal processes and environments developed from studies of ore deposits formed in analogous settings. (2) Frequent eruptions supplied sufficient hot magmatic fluid to alter the upper interior of the volcano hydrothermally, despite the consistently deep (≥ 8 km) magma reservoir which may have precluded formation of economic mineral deposits within or at shallow depths beneath Mount Rainier. The absence of indicator equilibrium alteration-mineral assemblages in the debris flows that effectively expose the volcano to a depth of 1–1.5 km also suggests a low potential for significant high-sulfidation epithermal or porphyry-type mineral deposits at depth. (3) Despite the long and complex history of the volcano, intensely altered collapse-prone rocks were spatially restricted to near the volcano's conduit system and summit, and short distances onto the upper east and west flanks, due to the necessary supply of reactive components carried by ascending magmatic fluids. (4) Intensely altered rocks were removed from the summit, east flank, and edifice interior by the Osceola collapse, but remain on the upper west flank in the Sunset Amphitheater area and present a continuing collapse hazard. (5) Visually conspicuous rocks on the lower east and mid-to-lower west flanks are not intensely altered and probably have not significantly weakened the rock, and thus do not present significant collapse hazards. (6) Alteration developed most intensely within breccia units, because of their high permeability and porosity. Volcanoes with abundant near-conduit upper-edifice breccias are prone to alteration increasing the possibility of collapse, whereas those that are breccia-poor (e.g., massive domes) are less prone to alteration.

Journal of Volcanology and Geothermal Research↗
USGS2007

Three-dimensional geophysical mapping of rock alteration and water content at Mount Adams, Washington: Implications for lahar hazards

[1] Hydrothermally altered rocks, particularly if water saturated, can weaken stratovolcanoes, thereby increasing the potential for catastrophic sector collapses that can lead to far-traveled, destructive debris flows. Evaluating the hazards associated with such alteration is difficult because alteration has been mapped on few active volcanoes and the distribution and intensity of subsurface alteration are largely unknown on any active volcano. At Mount Adams, some Holocene debris flows contain abundant hydrothermal minerals derived from collapse of the altered edifice. Intense hydrothermal alteration significantly reduces the resistivity and magnetization of volcanic rock, and therefore hydrothermally altered rocks can be identified with helicopter electromagnetic and magnetic measurements. Electromagnetic and magnetic data, combined with geological mapping and rock property measurements, indicate the presence of appreciable thicknesses of hydrothermally altered rock in the central core of Mount Adams north of the summit. We identify steep cliffs at the western edge of this zone as the likely source for future large debris flows. In addition, the electromagnetic data identified water in the brecciated core of the upper 100–200 m of the volcano. Water helps alter the rocks, reduces the effective stress, thereby increasing the potential for slope failure, and acts, with entrained melting ice, as a lubricant to transform debris avalanches into lahars. Therefore knowing the distribution of water is also important for hazard assessments. Our results demonstrate that high-resolution geophysical and geological observations can yield unprecedented views of the three-dimensional distribution of altered rock and shallow pore water aiding evaluation of the debris avalanche hazard.

Journal of Geophysical Research B: Solid Earth↗
USGS2007

Crustal controls on magmatic-hydrothermal systems: A geophysical comparison of White River, Washington, with Goldfield, Nevada

The White River altered area, Washington, and the Goldfield mining district, Nevada, are nearly contemporaneous Tertiary (ca. 20 Ma) calc-alkaline igneous centers with large exposures of shallow (<1 km depth) magmatic-hydrothermal, acid-sulfate alteration. Goldfield is the largest known high-sulfidation gold deposit in North America. At White River, silica is the only commodity exploited to date, but, based on its similarities with Goldfield, White River may have potential for concealed precious and/or base metal deposits at shallow depth. Both areas are products of the ancestral Cascade arc. Goldfield lies within the Great Basin physiographic province in an area of middle Miocene and younger Basin and Range and Walker Lane faulting, whereas White River is largely unaffected by young faults. However, west-northwest–striking magnetic anomalies at White River do correspond with mapped faults synchronous with magmatism, and other linear anomalies may reflect contemporaneous concealed faults. The White River altered area lies immediately south of the west-northwest–striking White River fault zone and north of a postulated fault with similar orientation. Structural data from the White River altered area indicate that alteration developed synchronously with an anomalous stress field conducive to left-lateral, strike-slip displacement on west-northwest–striking faults. Thus, the White River alteration may have developed in a transient transtensional region between the two strike-slip faults, analogous to models proposed for Goldfield and other mineral deposits in transverse deformational zones. Gravity and magnetic anomalies provide evidence for a pluton beneath the White River altered area that may have provided heat and fluids to overlying volcanic rocks. East– to east-northeast–striking extensional faults and/or fracture zones in the step-over region, also expressed in magnetic anomalies, may have tapped this intrusion and provided vertical and lateral transport of fluids to now silicified areas. By analogy to Goldfield, geophysical anomalies at the White River altered area may serve as proxies for geologic mapping in identifying faults, fractures, and intrusions relevant to hydrothermal alteration and ore formation in areas of poor exposure.

Nevada, Washington↗
USGS2003

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

The Mule Canyon mine exploited shallow, low - sulfidation , epithermal Au-Ag deposits that lie near the west side of the Northern Nevada rift in northern Lander County, Nevada . Mule Canyon consists of six small deposits that contained premining reserves of about 8.2 Mt at an average grade of 3.81 g Au/tonne. It is an uncommon mafic end member of low - sulfidation Au-Ag deposits associated with tholeiitic bimodal basalt-rhyolite magmatism. The ore is hosted by a basalt-andesite eruptive center that formed between about 16.4 to 15.8 Ma during early mafic eruptions related to regionally extensive bimodal magmatism. Hydrothermal alteration and Au-Ag ores formed at about 15.6 Ma and were tightly controlled by north -northwest- to north -striking high-angle fault and breccia zones developed during rifting, emplacement of mafic dikes, and eruption of mafic lava flows. Hydrothermal alteration assemblages are zoned outward from fluid conduits in the sequence silica-adularia, adularia-smectite, smectite (intermediate argillic), and smectite-carbonate (propylitic). All alteration types contain abundant pyrite and/or marcasite ± arsenopyrite. Field relations indicate that silica-adularia alteration is superimposed on argillic and propylitic alteration. Little or no steam-heated acid-sulfate alteration is present, probably the result of a near-surface water table during hydrothermal alteration and ore deposition. Two distinct ore types are present at Mule Canyon : early replacement and later open-space filling. Replacement ores consist of disseminated and vesicle-filling pyrite, marcasite, and arsenopyrite in argillically altered or weakly silicified rocks. Ore minerals consist of Au-bearing arsenopyrite and arsenian pyrite overgrowths on earlier-formed pyrite and marcasite. Open-space filling ores include narrow stockwork quartz-adularia veins, banded and crustiform opaline and chalcedonic silica-adularia veins, silica-adularia cemented breccias, and sparse carbonate-pyrite and/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200°C). Calculated isotopic compositions of ore fluids are δ 18 O H2O = -3 to -7 per mil, δD H2O = -107 to -124 per mil, δ 13 C CO2 = 0 to -6 per mil, and δ 34 S H2S = -3 to +8 per mil. The ore fluids obtained much of their H 2 S and CO 2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H 2 S and CO 2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H 2 S-rich, and CO 2 -bearing. Peak temperatures in ore zones reached 230° to 265°C at nearly lithostatic pressures when some crystalline quartz ± adularia precipitated, but most ore formed at temperatures <200°C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ± adularia ± calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H 2 S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H 2 S to the vapor phase, and cooling. Mule Canyon is similar to most other low - sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are the high Fe sulfide contents of some ores and altered wall rocks, the paucity of silicification, and the presence of only narrow and discontinuous gold -bearing siliceous veins. These differences primarily are due to the mafic composition of the host rocks. Mule Canyon differs from low - sulfidation deposits associated with subduction-related calc-alkaline porphyry intrusions, such as the Comstock lode, in that a much smaller proportion of water, salts, and metals was derived from crystallizing magmas.

Nevada↗
USGS1989

Geology and K-Ar geochronology of the Paradise Peak Mine and the relationship of pre-Basin and Range extension to Early Miocene precious metal mineralization in west-central Nevada

The Paradise Peak mine is a major gold-silver-mercury deposit located in the southwestern part of the Paradise Range near the eastern edge of the Walker Lane in the western Great Basin, Nevada. The Tertiary volcanic rocks of the area can be divided into a sequence of 26- to 24-Ma intermediate lavas, a sequence of 24- to 22-Ma silicic ash-flow tuffs, and a sequence of 20- to 15-Ma intermediate lavas. We classify these rocks as the older, middle, and younger sequences. Sedimentary rocks, and latites and basalts 12 Ma old or younger, locally overlie the younger intermediate lavas south of the mine. Silicified rhyolite tuff in the lower part of the middle tuff sequence is the principal host of the precious metal ore. Most ore occurs under an acid-leached zone of alunitic alteration and is contained in hydrothermal breccias that crosscut early quartz-pyrite and alunite alteration.Field relations and K-Ar ages of hypogene alunite indicate that precious metal mineralization and alunitic and silicic alteration formed at about 19 to 18 Ma, several million years after eruption of the main host rock. Mineralization formed during high-angle faulting related to crustal extension. Low-angle normal faults are present 5 km northeast of the Paradise Peak mine, but they formed more than 2 Ma after formation of the Paradise Peak deposit. Silicic and alunitic alteration and precious metal mineralization are generally absent in areas of low-angle faulting.Regional stratigraphic relations and K-Ar ages indicate that volcanism changed from silicic ash-flow tuffs to intermediate lavas at about 20 to 19 Ma. Regionally extensive angular unconformities indicate that a period of "pre-Basin and Range" crustal extension occurred between about 22 to 19 Ma. This extension was penecontemporaneous with the shift in the style of volcanism and with gold-silver mineralization in the Paradise Peak mine and in the Goldfield and Tonopah districts of western Nevada. The close temporal and spatial relationships of precious metal mineralization with pre-Basin and Range extension suggest that extension was a major factor in the genesis of early Miocene precious metal deposits in the western Great Basin.

Economic Geology↗
USGS1989

Geologic setting, depths of emplacement, and regional distribution of fluid inclusions in intrusions of the central Wasatch Mountains, Utah

Nine mid-Tertiary calc-alkaline stocks, a subvolcanic porphyry system, and coeval volcanic rocks are exposed in a 45-km-long east-trending belt across the central Wasatch Mountains, Utah. The intrusions vary systematically from west to east in texture, style of emplacement, extent of contact metamorphism, hydrothermal alteration, and mineralization. Pressure-depth estimates based on metamorphic mineral assemblages, stratigraphic reconstructions, and fluid inclusion data indicate a regular variation in paleodepths ranging from about 11 km on the west to less than 1 km on the east. These data indicate that the central Wasatch Mountains have been tilted down to the east about 20 degrees during the late Cenozoic. Fluid inclusion populations in igneous quartz also vary systematically with paleodepth; high-salinity (halite-saturated) fluid inclusions are present in the eastern porphyry stocks and in the upper parts of the Alta and Clayton Peak stocks in the center of the belt but are absent in the deeper parts of the Alta and Clayton Peak stocks and in the Little Cottonwood stock on the west side of the belt. In the Alta and Clayton Peak stocks, nearly planar high-paleosalinity horizons, presently dipping 15 degrees to 20 degrees east, separate rocks containing high-salinity fluid inclusions (above the high-paleosalinity horizon) from those lacking such fluid inclusions. Comparison of fluid-inclusion populations in igneous and vein quartz in the Alta and Clayton Peak stocks indicates that high-salinity fluids predated most of the vein-forming hydrothermal activity and provide the earliest record of fluids to circulate in these stocks. High-salinity fluids probably formed either by boiling of fluids released during the late stages of crystallization in the parts of the intrusions where pressure was less than about 1,300 bars or by exsolution of immiscible high-salinity brines from the crystallizing magmas. Most hydrothermal mineralization associated with the intrusions, including Ag-Pb-Zn ores in the Park City district, are associated spatially with parts of the intrusions where high-salinity fluids were present. The major exception is the porphyry molybdenum system in the eastern part of the Little Cottonwood stock, which probably was at too great a depth (approximately 7 km) to form high-salinity brines and is dominated by low-salinity CO 2 -rich fluids.

Economic Geology↗