Geology topics

Collin A. Eagles-Smith

Publications and source records attributed to Collin A. Eagles-Smith.

At least 19 recordsLinked to original sources

USGS2025

The effects of forest harvesting on total and methylmercury concentrations in surface waters depend on harvest practices and physical site characteristics

Forest harvesting can lead to mercury (Hg) mobilization from soils to aquatic habitats and promote the transformation of inorganic Hg to highly neurotoxic and bioaccumulative methyl-Hg (MeHg). Multiple past studies reveal broad variation of stream water MeHg and total Hg (THg) concentrations responses to forest harvesting, which has confounded messaging to forest and resource managers. To advance beyond divergent and sometimes contradictory findings, we synthesize information for 23 previously studied catchments in North America and Fennoscandia, and compiled a uniform set of soil, landscape, and harvesting properties to identify forest management, riparian, and hillslope factors that influence responses of stream water MeHg and THg concentrations. From this synthesis, we found catchments with high soil moisture and organic soil layers > 100 cm to be at highest risk for disturbance-induced increases in MeHg formation after harvest, but not necessarily affecting concentrations of MeHg in stream waters. Instead, the combination of MeHg formation in soils along with factors that affect mobilization with runoff to streams most influenced how forest harvest affects MeHg concentrations in stream waters.

Environmental Science and Technology↗

USGS2025

Independent and interactive effects of disease and methylmercury on demographic rates across multiple amphibian populations

Disease, alone or combined with other stressors such as habitat loss and contaminants, affects wildlife populations worldwide. However, interactions among stressors and how they affect demography and populations remain poorly understood. The amphibian chytrid fungus ( Batrachochytrium dendrobatidis ; Bd) is a sometimes-lethal pathogen linked with population declines and extirpations of amphibians globally. Laboratory evidence shows ubiquitous contaminants like methylmercury (MeHg) can reduce vigor and survival of amphibians, but population-level effects remain unclear. We used non-lethal sampling to assess how Bd and MeHg affected survival of juvenile and adult amphibians in 20 populations across the USA. Survival of several species declined with increasing Bd loads, including some species previously considered resistant to Bd (e.g., eastern newt [ Notophthalmus viridescens ]). Although our sampling for MeHg was less intensive than for Bd, we found MeHg can both directly reduce survival and synergistically magnify the effects of Bd infection. For a population of foothill yellow-legged frogs ( Rana boylii ), the estimated reduction in survival from MeHg exceeded that from Bd. Although effects varied widely among populations and species, our results help clarify the potential for synergistic effects of disease and contaminants and emphasize the complexity of identifying and quantifying the population-level effects of interactions among stressors.

Scientific Reports↗

USGS2025

Climate-driven deoxygenation of lakes alters the nutrient-toxin profile of a food fish

Climate change is rapidly altering fisheries supporting aquatic ecosystems. The implications for food security depend not only on harvest biomass but also concentrations of nutrients and toxins in fish. Using brook trout from Adirondack lakes (New York, USA), we tested whether ongoing lake deoxygenation trends will affect fish muscle omega-3 fatty acids, selenium, and mercury concentrations. Across space (16 lakes: 1 year) and time (6 years: 1 lake), anoxia decreased selenium and was associated with elevated fish mercury, with no effect on omega-3 content. Because selenium may mitigate some end points of mercury toxicity, highly variable Se:Hg molar ratios (0.70–35.79) in neighboring lakes may have health risk implications. For fish consumers, ongoing lake deoxygenation under climate change could potentially reduce selenium intake while enhancing mercury exposure. Simultaneous alteration of beneficial compounds and toxins by environmental change complicates the development of fish consumption advisories to safeguard public health in a warming world.

New York↗

USGS2025

Sampling dragonflies for mercury analysis in Grand Canyon National Park, 2018–2024: A contribution of the Dragonfly Mercury Project

The Dragonfly Mercury Project is a collaborative initiative that utilizes dragonfly larvae as biosentinels to monitor mercury concentrations across 180 national parks and other protected lands, including Grand Canyon National Park (GRCA). These indicators serve as surrogates for environmental risk and can indicate where fish consumption could pose health risks through exposure to mercury. From 2018–2024, citizen scientists and staff from the National Park Service and U.S. Geological Survey helped collect close to 400 larvae from 25 GRCA sites across nearly 300 river miles, revealing mercury concentrations ranging 3.0–1337 ng/g (parts per billion) dry weight. Results were available for 20 sites. Upon comparing mercury concentrations to an impairment index, most sites were classified as low or no risk for ecological impairment, though 10% (2 sites) exceeded moderate or severe risk benchmarks (Pete’s Pocket and Buck Farm Canyon, respectively). Sources of mercury to GRCA likely stem from a combination of atmospheric deposition, upstream discharge from Lake Powell, and other watershed contributions. In addition, food web dynamics, underlying water chemistry, and environmental disturbances (e.g., floods) contribute to mercury mobilization, production, and bioaccumulation. Report findings provide a baseline for connecting ongoing science in the Colorado River watershed, informing management actions, and enhancing public engagement through citizen science.

Arizona↗

USGS2025

Selenium differentially influences methylmercury retention across mayfly life stages

Though high mercury and selenium concentrations are individually toxic to organisms, there is a hypothesized antagonistic relationship. This potential mercury–selenium interaction is under-studied in aquatic macroinvertebrates, particularly in relation to complex life histories. We examined the proposed effect of selenium on methylmercury accumulation between four life stages for a parthenogenetic mayfly ( Neocloeon triangulifer ). We exposed diatoms to elevated methylmercury concentrations and fed them to mayflies exposed to elevated aqueous selenomethionine. We found some support for the mercury–selenium antagonism hypothesis, but it was context-specific. Selenium reduced methylmercury accumulation in high but not low methylmercury environments. Though terrestrial adult life stages had higher mercury concentrations compared to aquatic larval life stages, cumulative life history transfer factor (LHTF; ratio of methylmercury in adult imago to late instar larvae) differed by treatment. LHTF was constant for all aqueous selenium exposure levels at high dietary methylmercury (selenium impacts on methylmercury uptake and loss) but increased with aqueous selenium exposures at low dietary methylmercury (selenium impacts on methylmercury uptake only), suggesting a synergistic enhancement of MeHg transfer between life stages with increased aqueous Se exposure levels. These results suggest that animals eating adult aquatic insects are exposed to higher concentrations of methylmercury than those feeding on larval insects across selenium and methylmercury levels, but interference of selenium on methylmercury accumulation is only present at high methylmercury environments.

Environmental Science and Technology↗

USGS2025

Mercury trophic transfer to a freshwater biosentinel: Quantifying controlled bioaccumulation in larval dragonflies

Mercury bioavailability and biomagnification in freshwater systems can be highly variable; thus, tissue data from biosentinel taxa can be useful to assess risk. Dragonfly larvae have emerged as biological indicators of mercury impairment, yet their mercury biodynamics over time and across exposure levels are not well understood. Evaluating these attributes using controlled experimental approaches is an important step to validate larval dragonflies as biosentinels for spatial and temporal trends in mercury risk. We conducted an experimental series quantifying methylmercury trophic transfer from dosed prey to predatory dragonfly larvae at environmentally relevant concentrations. Dragonfly total mercury concentrations increased proportionally by factors of 2.7 to 4.2 with each doubling of prey methylmercury concentration, responding to dietary treatments in 7–28 days and reaching equilibrium in as little as 40 days, supporting their utility to indicate changing mercury exposure regimes. Dosed dragonflies biomagnified methylmercury by factors of 1.0 ± 0.1 to 3.4 ± 0.2 relative to their prey, and biomagnification efficiency decreased by over 40% for each doubling of prey methylmercury concentration. Dragonfly development had dose-dependent effects on bioaccumulation: mercury concentrations increased with growth and decreased with age in higher exposure treatments, whereas they decreased with growth and increased with age in lower exposure treatments. Bioaccumulation also varied taxonomically; within treatments, mean mercury concentrations for each genus varied up to 10% from family-level means. Dragonfly sex, size, and body condition did not significantly affect mercury concentrations. These results help validate and expand the utility of dragonfly larvae as biosentinels to monitor mercury risk and better protect wildlife and human health.

Oregon↗

USGS2025

Contrasting magnitude and timing of pulsed aqueous methylmercury bioaccumulation across a reservoir food web

Water column hypoxia is a key process influencing methylmercury (MeHg) production and availability in waterbodies worldwide. During seasonal destratification, large, short-lived pulses of aqueous MeHg may be released into the subsequently mixed water column, but little is known about the fate of these pulses, particularly whether there are concomitant increases in MeHg uptake into aquatic food webs. We examined the magnitude and timing of MeHg uptake across several trophic guilds relative to the reservoir stratification status using biweekly mercury data from water, zooplankton, and fish (Bluegill, Lepomis macrochirus and Smallmouth Bass, Micropterus dolomieu ). Zooplankton MeHg concentrations increased by up to 250% during destratification, concurrent with increases in aqueous MeHg concentrations. Zooplankton and filter-passing MeHg concentrations were positively correlated when the reservoir was mixed ( R 2 = 0.95) and destratifying ( R 2 = 0.57) but not while the reservoir was stratified ( R 2 = 0.21). Mercury concentrations in adult bluegill and juveniles of both fish species increased 20–70% following destratification, with responses lagging 4–8 weeks behind those in water and zooplankton MeHg. Mercury concentrations in piscivorous adult bass varied little over the course of the study. Our findings demonstrate the responsiveness of reservoir food webs to pulses in MeHg availability, suggesting that these pulses could play an important role in biotic MeHg exposure within and downstream of reservoirs.

Idaho, Oregon↗

USGS2025

Ecosystem drivers of freshwater mercury bioaccumulation are context-dependent: Insights from continental-scale modeling

Significant variation in mercury (Hg) bioaccumulation is observed across the diversity of freshwater ecosystems in North America. While there is support for the major drivers of Hg bioaccumulation, the relative influence of different external factors can vary widely among waterbodies, which makes predicting Hg risk across large spatial scales particularly challenging. We modeled Hg bioaccumulation by coupling Hg concentrations in more than 21,000 dragonflies collected across the United States from 2008 to 2021 with a suite of chemical (e.g., dissolved organic carbon (DOC), pH, sulfate) and landscape (e.g., soil characteristics, land cover) variables representing external drivers of Hg methylation, transport, and uptake. Model predictions explained 85% of the variation in dragonfly Hg concentrations across the United States. Certain predictor variables were more important than others (e.g., DOC, pH, and percent wetland), and they varied among waterbodies. Variation in Hg bioaccumulation was explained by including habitat and ecosystem type in a hierarchical modeling framework, which confirms the context-dependency of external factors in explaining Hg bioaccumulation across disparate freshwater ecosystems. This continent-scale model provides valuable insights into the processes underlying landscape-scale patterns in Hg exposure risk and demonstrates that drivers of Hg methylation and bioaccumulation are habitat- and ecosystem-dependent.

Environmental Science and Technology↗

USGS2025

Methylmercury in subarctic amphibians: Environmental gradients, bioaccumulation, and estimated flux

Rapid warming in polar regions is causing large changes to ecosystems, including altering environmentally available mercury (Hg). Although subarctic freshwater systems have simple vertebrate communities, Hg in amphibians remains unexplored. We measured total Hg (THg) in wetland sediments and methylmercury (MeHg) in multiple life-stages (eggs to adults) of wood frogs ( Rana sylvatica ) and larval boreal chorus frogs ( Pseudacris maculata ) from up to 25 wetlands near Churchill, Manitoba (Canada), during the summers of 2018–2019. We used egg mass counts for wood frogs from 24 wetlands (2015–2019) and per-ovum MeHg concentrations to estimate site-level MeHg flux by metamorphs from wetlands to the terrestrial environment. Total Hg in wetland sediment was unrelated to MeHg concentrations of amphibian larvae, but sediment THg increased with from coastal tundra vegetation to inland boreal forests. Methylmercury concentrations of wood frog eggs (geometric mean = 35.9; range: 6.7–77.9 ng/g dry wt) exceeded previous reports for amphibians, including from sites contaminated by industrial sources of Hg. Methylmercury concentrations of adult wood frogs (298.9 ng/g dry wt) were also higher than that for frogs included in a recent assessment of MeHg in amphibians across the contiguous United States. Within wetlands, MeHg concentrations of wood frog larvae were strongly correlated with MeHg concentrations in eggs earlier in the summer, and concentrations increased with each life stage. We estimate there would have been 1,971.8–3,286.4 ng MeHg exported from wetlands by wood frog metamorphs, which is 3.4–5.6 times more MeHg than inputted by eggs. Collectively, these data provide an initial assessment of Hg concentrations, body burdens, and dynamics in subarctic food webs that are expected to experience large changes from climate warming.

Manitoba↗

USGS2024

Imperiled Great Basin terminal lakes: Synthesizing ecological and hydrological science gaps and research needs for waterbird conservation

Terminal lakes are declining globally because of human water demands, drought, and climate change. Through literature synthesis and feedback from the resource and conservation community, we review the state of research for terminal lakes in the Great Basin of the United States, which support millions of waterbirds annually, to prioritize ecological and hydrologic information needs. From an ecological perspective, research priorities include measuring the underlying differences in waterbird resource selection and distribution, migratory connectivity, abiotic factors that interact with prey densities to affect prey availability, and waterbird fitness or demography. Integrated links between water availability, water quality, and food webs are lacking in the literature. Scarce water availability data hinder the current knowledge of water extraction and evapotranspiration rates. Research that can address these priorities would help advance our understanding of how the Great Basin terminal lakes function as an interrelated system and support conservation efforts to reverse the decline of these critical lakes.

California, Nevada, Oregon, Utah↗

USGS2024

Riparian methylmercury production increases riverine mercury flux and food web concentrations

The production and uptake of toxic methylmercury (MeHg) impacts aquatic ecosystems globally. Rivers can be dynamic and difficult systems to study for MeHg production and bioaccumulation, hence identifying sources of MeHg to these systems is both challenging and important for resource management within rivers and main-stem reservoirs. Riparian zones, which are known biogeochemical hotspots for MeHg production, are understudied as potential sources of MeHg to rivers. Here, we present a comprehensive quantification of the hydrologic and biogeochemical processes governing MeHg concentrations, loads, and bioaccumulation at 16 locations along 164 km of the agriculturally intensive Snake River (Idaho, Oregon USA) during summer baseflow conditions, with emphasis on riparian production of MeHg. Approximately one-third of the MeHg load of the Snake River could not be attributed to inflowing waters (upgradient, tributaries, or irrigation drains). Across the study reach, increases in MeHg loads in surface waters were significantly correlated with MeHg concentrations in riparian porewaters, suggesting riparian zones were likely an important source of MeHg to the Snake River. Across all locations, MeHg concentrations in surface waters positively correlated with MeHg concentrations in benthic snails and clams, supporting that riparian produced MeHg was assimilated into local aquatic food webs. This study contributes new insights into riparian MeHg production within rivers which can inform mitigation efforts to reduce MeHg bioaccumulation in fish.

Idaho, Oregon↗

USGS2024

A meta-analysis of mercury biomagnification in freshwater predatory invertebrates: Community diversity and dietary exposure drive variability

Accurate estimates of methylmercury (MeHg) exposure are valuable to actionably assess risk and protect wildlife and human health. MeHg trophic transfer is a critical driver of risk: MeHg is generally biomagnified by a factor of 8.3 ± 7.5 from one trophic level to the next, averaged across freshwater communities (mean ± standard deviation). This variability can produce disparate risks even where basal MeHg concentrations are similar. Taxonomy may be one driver of this variability: physiologically diverse groups, like vertebrates and invertebrates, may assimilate MeHg differently. To determine whether taxonomy affects trophic transfer efficiency, we conducted a meta-analysis characterizing predatory invertebrate MeHg biomagnification. Our analyses estimated that freshwater predatory invertebrates biomagnify MeHg by factors of 2.1 ± 0.2 to 4.3 ± 0.3, with a 98.9 ± 0.4% posterior probability that factors are below 5 (mean ± standard error). When vertebrates or primary producers were included, a site’s trophic magnification factor was 18.6 ± 6.2 to 54.1 ± 7.7% higher than estimates for invertebrates alone. Biomagnification was inversely correlated to prey MeHg concentration and varied among systematic and functional groups. These data suggest that predatory invertebrates biomagnify MeHg less efficiently than vertebrates and that a community’s diversity and structure determine its biomagnification efficiency. Incorporating organismal variation in trophic transfer estimates may improve the assessment, communication, and management of MeHg risk.

Environmental Science & Technology↗

USGS2024

Continental-scale nutrient and contaminant delivery by Pacific salmon

The movement of large amounts of nutrients by migrating animals has ecological benefits for recipient food webs1,2 that may be offset by co-transported contaminants3,4. Salmon spawning migrations are archetypal of this process, carrying marine-derived materials to inland ecosystems where they stimulate local productivity but also enhance contaminant exposure5,6,7. Pacific salmon abundance and biomass are higher now than in the last century, reflecting substantial shifts in community structure8 that probably altered nutrient versus contaminant delivery. Here we combined nutrient and contaminant concentrations with 40 years of annual Pacific salmon returns to quantify how changes in community structure influenced marine to freshwater inputs to western North America. Salmon transported tonnes of nutrients and kilograms of contaminants to freshwaters annually. Higher salmon returns (1976–2015) increased salmon-derived nutrient and contaminant inputs by 30% and 20%, respectively. These increases were dominated by pink salmon, which are short-lived, feed lower in marine food webs than other salmon species, and had the highest nutrient-to-contaminant ratios. As a result, the delivery of nutrients increased at a greater rate than the delivery of contaminants, and salmon inputs became more ecologically beneficial over time. Even still, contaminant loadings may represent exposure concerns for some salmon predators. The Pacific salmon example demonstrates how long-term environmental changes interact with nutrient and contaminant movement across large spatial scales and provides a model for exploring similar patterns with other migratory species.

Nature↗

USGS2024

Wildfires influence mercury transport, methylation, and bioaccumulation in headwater streams of the Pacific Northwest

The increasing frequency and severity of wildfires are among the most visible impacts of climate change. However, the effects of wildfires on mercury (Hg) transformations and bioaccumulation in stream ecosystems are poorly understood. We sampled soils, water, sediment, in-stream leaf litter, periphyton, and aquatic invertebrates in 36 burned (one-year post fire) and 21 reference headwater streams across the northwestern U.S. to evaluate the effects of wildfire occurrence and severity on total Hg (THg) and methylmercury (MeHg) transport and bioaccumulation. Suspended particulate THg and MeHg concentrations were 89 and 178% greater in burned watersheds compared to unburned watersheds and increased with burn severity, likely associated with increased soil erosion. Concentrations of filter-passing THg were similar in burned and unburned watersheds, but filter-passing MeHg was 51% greater in burned watersheds, and suspended particles in burned watersheds were enriched in MeHg but not THg, suggesting higher MeHg production in burned watersheds. Among invertebrates, MeHg in grazers, filter-feeders, and collectors was 33, 48, and 251% greater in burned watersheds, respectively, but did not differ in shredders or predators. Thus, increasing wildfire frequency and severity may yield increased MeHg production, mobilization, and bioaccumulation in headwaters and increased transport of particulate THg and MeHg to downstream environments.

Idaho, Oregon, Washington↗

USGS2024

Mercury concentrations in Seaside Sparrows and Marsh Rice Rats differ across the Mississippi River Estuary

Mercury (Hg) concentrations and their associated toxicological effects in terrestrial ecosystems of the Gulf of Mexico are largely unknown. Compounding this uncertainty, a large input of organic matter from the 2010 Deepwater Horizon oil spill may have altered Hg cycling and bioaccumulation dynamics. To test this idea, we quantified blood concentrations of total mercury (THg) in Seaside Sparrows ( Ammospiza maritima ) and Marsh Rice Rats ( Oryzomys palustris ) in marshes west and east of the Mississippi River in 2015 and 2016. We also tested for a difference in THg concentrations between oiled and non-oiled sites. To address the potential confounding effect of diet variation on Hg transfer, we used stable nitrogen (δ 15 N) and carbon (δ 13 C) isotope values as proxies of trophic position and the source of primary production, respectively. Our results revealed that five to six years after the spill, THg concentrations were not higher in sites oiled by the spill compared to non-oiled sites. In both species, THg was higher at sites east of the Mississippi River compared to control and oiled sites, located west. In Seaside Sparrows but not in Marsh Rice Rats, THg increased with δ 15 N values, suggesting Hg trophic biomagnification. Overall, even in sites with the most elevated THg, concentrations were generally low. In Seaside Sparrows, THg concentrations were also lower than previously reported in this and other closely related passerines, with only 7% of tested birds exceeding the lowest observed effect concentration associated with toxic effects across bird species (0.2 µg/g ww ) . The factors associated with geographic heterogeneity in Hg exposure remain uncertain. Clarification could inform risk assessment and future restoration and management actions in a region facing vast anthropogenic changes.

Ecotoxicology↗

USGS2024

Geographic drivers of mercury entry into aquatic food webs revealed by mercury stable isotopes in dragonfly larvae

Atmospheric mercury (Hg) emissions and subsequent transport and deposition are major concerns within protected lands, including national parks, where Hg can bioaccumulate to levels detrimental to human and wildlife health. Despite this risk to biological resources, there is limited understanding of the relative importance of different Hg sources and delivery pathways within protected regions. Here, we used Hg stable isotope measurements of a single aquatic bioindicator, dragonfly larvae, to determine if these tracers can resolve spatial patterns in Hg sources, delivery mechanisms, and aquatic cycling at a national scale. Mercury isotope values in dragonfly tissues varied among habitat types (e.g., lentic, lotic, wetland) and geographic location. Photochemical-derived isotope fractionation was habitat-dependent and influenced by factors that impact light penetration directly or indirectly, including dissolved organic matter, canopy cover, and total phosphorus. Strong patterns for Δ 200 Hg emerged in the western US, highlighting the relative importance of wet deposition sources in arid regions in contrast to dry deposition delivery in forested regions. This work highlights the efficacy of dragonfly larvae as biosentinels for Hg isotope studies due to their ubiquity across freshwater ecosystems and ability to track variation in Hg sources and processing attributed to small-scale habitat and large-scale regional patterns.

Environmental Science and Technology↗

USGS2024

Global mercury concentrations in biota: Their use as a basis for a global biomonitoring framework

An important provision of the Minamata Convention on Mercury is to monitor and evaluate the effectiveness of the adopted measures and its implementation. Here, we describe for the first time currently available biotic mercury (Hg) data on a global scale to improve the understanding of global efforts to reduce the impact of Hg pollution on people and the environment. Data from the peer-reviewed literature were compiled in the Global Biotic Mercury Synthesis (GBMS) database (>550,000 data points). These data provide a foundation for establishing a biomonitoring framework needed to track Hg concentrations in biota globally. We describe Hg exposure in the taxa identified by the Minamata Convention: fish, sea turtles, birds, and marine mammals. Based on the GBMS database, Hg concentrations are presented at relevant geographic scales for continents and oceanic basins. We identify some effective regional templates for monitoring methylmercury (MeHg) availability in the environment, but overall illustrate that there is a general lack of regional biomonitoring initiatives around the world, especially in Africa, Australia, Indo-Pacific, Middle East, and South Atlantic and Pacific Oceans. Temporal trend data for Hg in biota are generally limited. Ecologically sensitive sites (where biota have above average MeHg tissue concentrations) have been identified throughout the world. Efforts to model and quantify ecosystem sensitivity locally, regionally, and globally could help establish effective and efficient biomonitoring programs. We present a framework for a global Hg biomonitoring network that includes a three-step continental and oceanic approach to integrate existing biomonitoring efforts and prioritize filling regional data gaps linked with key Hg sources. We describe a standardized approach that builds on an evidence-based evaluation to assess the Minamata Convention’s progress to reduce the impact of global Hg pollution on people and the environment.

Ecotoxicology↗

USGS2024

Wildfire burn severity and stream chemistry influence aquatic invertebrate and riparian avian mercury exposure in forested ecosystems

Terrestrial soils in forested landscapes represent some of the largest mercury (Hg) reserves globally. Wildfire can alter the storage and distribution of terrestrial-bound Hg via reemission to the atmosphere or mobilization in watersheds where it may become available for methylation and uptake into food webs. Using data associated with the 2007 Moonlight and Antelope Fires in California, we examined the long-term direct effects of wildfire burn severity on the distribution and magnitude of Hg concentrations in riparian food webs. Additionally, we quantified the cross-ecosystem transfer of Hg from aquatic invertebrate to riparian bird communities; and assessed the influence of biogeochemical, landscape variables, and ecological factors on Hg concentrations in aquatic and terrestrial food webs. Benthic macroinvertebrate methylmercury (MeHg) and riparian bird blood total mercury (THg) concentrations varied by 710- and 760-fold, respectively, and Hg concentrations were highest in predators. We found inconsistent relationships between Hg concentrations across and within taxa and guilds in response to stream chemical parameters and burn severity. Macroinvertebrate scraper MeHg concentrations were influenced by dissolved organic carbon (DOC); however, that relationship was moderated by burn severity (as burn severity increased the effect of DOC declined). Omnivorous bird Hg concentrations declined with increasing burn severity. Overall, taxa more linked to in situ energetic pathways may be more responsive to the biogeochemical processes that influence MeHg cycling. Remarkably, 8 years post-fire, we still observed evidence of burn severity influencing Hg concentrations within riparian food webs, illustrating its overarching role in altering the storage and redistribution of Hg and influencing biogeochemical processes.

Ecotoxicology↗