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Clive Oppenheimer

Publications and source records attributed to Clive Oppenheimer.

8 recordsLinked to original sources

Assessment of leachable elements in volcanic ashfall: A review and evaluation of a standardized protocol for ash hazard characterization

Volcanic ash presents a widespread and common hazard during and after eruptions. Complex interactions between solid ash surfaces and volcanic gases lead to the formation of soluble salts that may be mobilized in aqueous environments. A variety of stakeholders may be concerned about the effects of ash on human and animal health, drinking water supplies, crops, soils and surface runoff. As part of the immediate emergency response, rapid dissemination of information regarding potentially hazardous concentrations of soluble species is critical. However, substantial variability in the methods used to characterize leachable elements makes it challenging to compare datasets and eruption impacts. To address these challenges, the International Volcanic Health Hazard Network ( www.ivhhn.org ) organized a two-day workshop to define appropriate methods for hazard assessment. The outcome of this workshop was a ‘consensus protocol’ for analysis of volcanic ash samples for rapid assessment of hazards from leachable elements, which was subsequently ratified by leading volcanological organizations. The purpose of this protocol is to recommend clear, standard and reliable methods applicable to a range of purposes during eruption response, such as assessing impacts on drinking-water supplies and ingestion hazards to livestock, and also applicable to research purposes. Where possible, it is intended that the methods make use of commonly available equipment and require little training. To evaluate method transferability, an interlaboratory comparison exercise was organized among six laboratories worldwide. Each laboratory received a split of pristine ash, and independently analyzed it according to the protocol for a wide range of elements. Collated results indicate good repeatability and reproducibility for most elements, thus indicating that the development of this protocol is a useful step towards providing standardized and reliable methods for ash hazard characterization. In this article, we review recent ash leachate studies, report the outcomes of the comparison exercise and present a revised and updated protocol based on the experiences and recommendations of the exercise participants. The adoption of standardized methods will improve and facilitate the comparability of results among studies and enable the ongoing development of a global database of leachate information relevant for informing volcanic health hazards assessment.

Journal of Volcanology and Geothermal Research

A global synthesis of lava lake dynamics

Active lava lakes represent a variety of open-vent volcanism in which a sizeable body of lava accumulates at the top of the magma column, constrained by the vent and/or crater geometry. The longevity of lava lakes reflects a balancing of cooling and outgassing occurring at the surface by input of hot and gas-rich magma from below. Due to their longevity and relative accessibility, lava lakes provide a natural laboratory for studying fundamental volcanic processes such as degassing, convection and cooling. This article examines all seven lakes that existed at the time of writing, located in the Pacific, Antarctica, Africa, and South and Central America. They span all tectonic environments, and a range of magma compositions. We focus on analysis of the lake surface motion using image velocimetry, which reveals both similarities and contrasts in outgassing and lake dynamics when comparing the different lakes. We identify two categories of lake behavior: Organized (Erta ’Ale, Nyiragongo, K¯ılauea after 2011, and Erebus) and Chaotic (Villarrica,Masaya, Marum). This division does not map directly to lake size, viscosity, gas emission rate, or temperature. Instead, when examined together, we find that the lakes follow a linear relationship between average surface speed and the ratio of total gas flux to lake surface area. This relationship points to the importance of both flux and lake size in addition to the total volumetric outgassing rate, and suggests a shared deep mechanism controls the supply of heat and gas to all lakes. On the other hand, the differences between Chaotic and Organized lakes highlight the important role of the geometry of the conduit-lake transition, which superimposes a shallow signal on that of the deep circulation. The spatial patterns of surface motion we document suggest the release of gas bubbles at Chaotic lakes is more efficient (i.e., bubbles are less likely to be retained and recycled) compared with Organized lakes. In addition, the data presented here indicate that the solidified crust of Organized lakes plays a role in regulating convection and outgassing in lava lakes.

Journal of Volcanology and Geothermal Research

Radiocarbon and geologic evidence reveal Ilopango volcano as source of the colossal 'mystery' eruption of 539/40 CE

Ilopango volcano (El Salvador) erupted violently during the Maya Classic Period (250–900 CE) in a densely-populated and intensively-cultivated region of the southern Maya realm, causing regional abandonment of an area covering more than 20,000 km 2 . However, neither the regional nor global impacts of the Tierra Blanca Joven (TBJ) eruption in Mesoamerica have been well appraised due to limitations in available volcanological, chronological, and archaeological observations. Here we present new evidence of the age, magnitude and sulfur release of the TBJ eruption, establishing it as one of the two hitherto unidentified volcanic triggers of a period of stratospheric aerosol loading that profoundly impacted Northern Hemisphere climate and society between circa 536 and 550 CE. Our chronology is derived from 100 new radiocarbon measurements performed on three subfossil tree trunks enveloped in proximal TBJ pyroclastic deposits. We also reassess the eruption magnitude using terrestrial (El Salvador, Guatemala, Honduras) and near-shore marine TBJ tephra deposit thickness measurements. Together, our new constraints on the age, eruption size (43.6 km 3 Dense Rock Equivalent of magma, magnitude = 7.0) and sulfur yield (∼9–90 Tg), along with Ilopango's latitude (13.7° N), squarely frame the TBJ as the major climate-forcing eruption of 539 or 540 CE identified in bipolar ice cores and sourced to the tropics. In addition to deepening appreciation of the TBJ eruption's impacts in Mesoamerica, linking it to the major Northern Hemisphere climatic downturn of the mid-6th century CE offers another piece in the puzzle of understanding Eurasian history of the period.

Guazapa

Evidence for partial melt in the crust beneath Mt. Paektu (Changbaishan), Democratic People’s Republic of Korea and China

Mt. Paektu (also known as Changbaishan) is an enigmatic volcano on the border between the Democratic People’s Republic of Korea (DPRK) and China. Despite being responsible for one of the largest eruptions in history, comparatively little is known about its magmatic evolution, geochronology, or underlying structure. We present receiver function results from an unprecedented seismic deployment in the DPRK. These are the first estimates of the crustal structure on the DPRK side of the volcano and, indeed, for anywhere beneath the DPRK. The crust 60 km from the volcano has a thickness of 35 km and a bulk V P / V S of 1.76, similar to that of the Sino-Korean craton. The V P / V S ratio increases ~20 km from the volcano, rising to >1.87 directly beneath the volcano. This shows that a large region of the crust has been modified by magmatism associated with the volcanism. Such high values of V P / V S suggest that partial melt is present in the crust beneath Mt. Paektu. This region of melt represents a potential source for magmas erupted in the last few thousand years and may be associated with an episode of volcanic unrest observed between 2002 and 2005.

Mt. Paektu

Quantifying gas emissions from the 946 CE Millennium Eruption of Paektu volcano, Democratic People's Republic of Korea/China

Paektu volcano (Changbaishan) is a rhyolitic caldera that straddles the border between the Democratic People's Republic of Korea (DPRK) and China. Its most recent large eruption was the Millennium Eruption (ME; 23 km3 DRE) circa 946 CE, which resulted in the release of copious magmatic volatiles (H2O, CO2, sulfur, and halogens). Accurate quantification of volatile yield and composition is critical in assessing volcanogenic climate impacts but is elusive, particularly for pre-historic or unmonitored eruptions. Here we employ a geochemical technique to quantify volatile composition and yield from the ME by examining trends in incompatible trace and volatile element concentrations in crystal-hosted melt inclusions. We estimate a maximum of 45 Tg S was injected into the stratosphere during the ME. If true yields are close to this maximum, this equates to more than 1.5 times the S released during the 1815 eruption of Tambora, which contributed to the "Year Without a Summer". Our maximum gas yield estimates place the ME among the strongest emitters of climate forcing gases in recorded human history in stark contrast to ice core records that indicate minimal atmospheric sulfate loading after the eruption. We conclude that the potential lack of strong climate forcing occurred in spite of the substantial S yield and suggest that other factors predominated in minimizing climatic effects. This paradoxical case in which high S emissions do not result in substantial climate forcing may present a way forward in building more generalized models for predicting which volcanic eruptions will produce large climate impacts.

Paektu volcano

Protocol for analysis of volcanic ash samples for assessment of hazards from leachable elements

Volcanic eruptions can produce a wide range of hazards. Although phenomena such as pyroclastic density currents and surges, sector collapses, lahars and ballistic blocks are the most destructive and dangerous, volcanic ash is by far the most widely distributed eruption product1 and the most likely to be encountered by the public. Following an eruption, the public, civil authorities and agricultural producers will often have major concerns about the effects of volcanic ash on human and animal health, drinking water supplies, crops, soils and surface runoff. Freshly‐erupted ash contains a range of potentially toxic soluble elements, which may be released either rapidly or more slowly upon contact with water or body fluids.

Report

The 2010 explosive eruption of Java's Merapi volcano—A ‘100-year’ event

Merapi volcano (Indonesia) is one of the most active and hazardous volcanoes in the world. It is known for frequent small to moderate eruptions, pyroclastic flows produced by lava dome collapse, and the large population settled on and around the flanks of the volcano that is at risk. Its usual behavior for the last decades abruptly changed in late October and early November 2010, when the volcano produced its largest and most explosive eruptions in more than a century, displacing at least a third of a million people, and claiming nearly 400 lives. Despite the challenges involved in forecasting this ‘hundred year eruption’, we show that the magnitude of precursory signals (seismicity, ground deformation, gas emissions) was proportional to the large size and intensity of the eruption. In addition and for the first time, near-real-time satellite radar imagery played an equal role with seismic, geodetic, and gas observations in monitoring eruptive activity during a major volcanic crisis. The Indonesian Center of Volcanology and Geological Hazard Mitigation (CVGHM) issued timely forecasts of the magnitude of the eruption phases, saving 10,000–20,000 lives. In addition to reporting on aspects of the crisis management, we report the first synthesis of scientific observations of the eruption. Our monitoring and petrologic data show that the 2010 eruption was fed by rapid ascent of magma from depths ranging from 5 to 30 km. Magma reached the surface with variable gas content resulting in alternating explosive and rapid effusive eruptions, and released a total of ~ 0.44 Tg of SO 2 . The eruptive behavior seems also related to the seismicity along a tectonic fault more than 40 km from the volcano, highlighting both the complex stress pattern of the Merapi region of Java and the role of magmatic pressurization in activating regional faults. We suggest a dynamic triggering of the main explosions on 3 and 4 November by the passing seismic waves generated by regional earthquakes on these days.

Merapi volcano

Comparison of COSPEC and two miniature ultraviolet spectrometer systems for SO 2 measurements using scattered sunlight

The correlation spectrometer (COSPEC), the principal tool for remote measurements of volcanic SO 2 , is rapidly being replaced by low-cost, miniature, ultraviolet (UV) spectrometers. We compared two of these new systems with a COSPEC by measuring SO 2 column amounts at Kīlauea Volcano, Hawaii. The two systems, one calibrated using in-situ SO 2 cells, and the other using a calibrated laboratory reference spectrum, employ similar spectrometer hardware, but different foreoptics and spectral retrieval algorithms. Accuracy, signal-to-noise, retrieval parameters, and precision were investigated for the two configurations of new miniature spectrometer. Measurements included traverses beneath the plumes from the summit and east rift zone of Kīlauea, and testing with calibration cells of known SO 2 concentration. The results obtained from the different methods were consistent with each other, with <8% difference in estimated SO 2 column amounts up to 800 ppm m. A further comparison between the COSPEC and one of the miniature spectrometer configurations, the &lsquo;FLYSPEC&rsquo;, spans an eight month period and showed agreement of measured emission rates to within 10% for SO 2 column amounts up to 1,600 ppm m. The topic of measuring high SO 2 burdens accurately is addressed for the Kīlauea measurements. In comparing the foreoptics, retrieval methods, and resultant implications for data quality, we aim to consolidate the various experiences to date, and improve the application and development of miniature spectrometer systems.`

Bulletin of Volcanology