Geology topics

Christopher L. Braun

Publications and source records attributed to Christopher L. Braun.

35 records · Page 2Linked to original sources

USGS2012

Grain-size distribution and selected major and trace element concentrations in bed-sediment cores from the Lower Granite Reservoir and Snake and Clearwater Rivers, eastern Washington and northern Idaho, 2010

Lower Granite Dam impounds the Snake and Clearwater Rivers in eastern Washington and northern Idaho, forming Lower Granite Reservoir. Since 1975, the U.S. Army Corps of Engineers has dredged sediment from the Lower Granite Reservoir and the Snake and Clearwater Rivers in eastern Washington and northern Idaho to keep navigation channels clear and to maintain the flow capacity. In recent years, other Federal agencies, Native American governments, and special interest groups have questioned the negative effects that dredging might have on threatened or endangered species. To help address these concerns, the U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, collected and analyzed bed-sediment core samples (hereinafter cores) in Lower Granite Reservoir and impounded or backwater affected parts of the Snake and Clearwater Rivers. Cores were collected during the spring and fall of 2010 from submerged sampling locations in the Lower Granite Reservoir, and Snake and Clearwater Rivers. A total of 69 cores were collected by using one or more of the following corers: piston, gravity, vibrating, or box. From these 69 cores, 185 subsamples were removed and submitted for grain size analyses, 50 of which were surficial-sediment subsamples. Fifty subsamples were also submitted for major and trace elemental analyses. Surficial-sediment subsamples from cores collected from sites at the lower end of the reservoir near the dam, where stream velocities are lower, generally had the largest percentages of silt and clay (more than 80 percent). Conversely, all of the surficial-sediment subsamples collected from sites in the Snake River had less than 20 percent silt and clay. Most of the surficial-sediment subsamples collected from sites in the Clearwater River contained less than 40 percent silt and clay. Surficial-sediment subsamples collected near midchannel at the confluence generally had more silt and clay than most surficial-sediment subsamples collected from sites on the Snake and Clearwater Rivers or even sites further downstream in Lower Granite Reservoir. Two cores collected at the confluence and all three cores collected on the Clearwater River immediately upstream from the confluence were extracted from a thick sediment deposit as shown by the cross section generated from the bathymetric surveys. The thick sediment deposits at the confluence and on the Clearwater River may be associated with floods in 1996 and 1997 on the Clearwater River. Fifty subsamples from 15 cores were analyzed for major and trace elements. Concentrations of trace elements were low, with respect to sediment quality guidelines, in most cores. Typically, major and trace element concentrations were lower in the subsamples collected from the Snake River compared to those collected from the Clearwater River, the confluence of the Snake and Clearwater Rivers, and Lower Granite Reservoir. Generally, lower concentrations of major and trace elements were associated with coarser sediments (larger than 0.0625 millimeter) and higher concentrations of major and trace elements were associated with finer sediments (smaller than 0.0625 millimeter).

Idaho, Washington↗

USGS2011

Streamflow, groundwater hydrology, and water quality in the upper Coleto Creek watershed in southeast Texas, 2009–10

The U.S. Geological Survey (USGS), in cooperation with the Goliad County Groundwater Conservation District, Victoria County Groundwater Conservation District, Pecan Valley Groundwater Conservation District, Guadalupe-Blanco River Authority, and San Antonio River Authority, did a study to examine the hydrology and stream-aquifer interactions in the upper Coleto Creek watershed. Findings of the study will enhance the scientific understanding of the study-area hydrology and be used to support water-management decisions to help ensure protection of the Evangeline aquifer and surface-water resources in the study area. This report describes the results of streamflow measurements, groundwater-level measurements, and water quality (from both surface-water and groundwater sites) collected from three sampling events (July–August 2009, January 2010, and June 2010) designed to characterize groundwater (from the Evangeline aquifer) and surface water, and the interaction between them, in the upper Coleto Creek watershed upstream from Coleto Creek Reservoir in southeast Texas. This report also provides a baseline level of water quality for the upper Coleto Creek watershed. Three surface-water gain-loss surveys—July 29–30, 2009, January 11–13, 2010, and June 21–22, 2010—were done under differing hydrologic conditions to determine the locations and amounts of streamflow recharging or discharging from the Evangeline aquifer. During periods when flow in the reaches of the upper Coleto Creek watershed was common (such as June 2010, when 12 of 25 reaches were flowing) or probable (such as January 2010, when 22 of 25 reaches were flowing), most of the reaches appeared to be gaining (86 percent in January 2010 and 92 percent in June 2010); however, during drought conditions (July 2009), streamflow was negligible in the entire upper Coleto Creek watershed; streamflow was observed in only two reaches during this period, one that receives inflow directly from Audilet Spring and another reach immediately downstream from Audilet Spring. Water levels in the aquifer at this time declined to the point that the aquifer could no longer provide sufficient water to the streams to sustain flow. Groundwater-level altitudes were measured at as many as 33 different wells in the upper Coleto Creek watershed during three different survey events: August 4–7 and 12, 2009; January 12–14 and 22, 2010; and June 21–24, 2010. These data were used in conjunction with groundwater-level altitudes from three continuously monitored wells to generate potentiometric surface maps for each of the three sampling events to help characterize the groundwater hydrology of the Evangeline aquifer. The altitudes of potentiometric surface contours from all three sampling events are highest in the northeast part of the study area and lowest in the southwest part of the study area. Groundwater flow direction shifts from southeast to east across the watershed, roughly coinciding with the general flow direction of the main stem of Coleto Creek. Groundwater-level altitudes increased an average of 2.35 inches between the first and third sampling events as drought conditions in summer 2009 were followed by consistent rains the subsequent fall and winter, an indication that the aquifer responds relatively quickly to both the absence and relative abundance of precipitation. A total of 44 water-quality samples were collected at 21 different sites over the course of the three sampling events (August 4–7, 2009, January 12–14, 2010, and June 21–24, 2010). In most cases, samples from each site were analyzed for the following constituents: dissolved solids, major ions, alkalinity, nutrients, trace elements, and stable isotopes (hydrogen, oxygen, and strontium). Major-ion compositions were relatively consistent among most of the samples from the upper Coleto Creek watershed (generally calcium bicarbonate waters, with chloride often making a major contribution). Of the 23 trace elements that were analyzed in water samples as part of this study, only arsenic (in two samples) and manganese (in seven samples) had concentrations that exceeded public drinking-water standards or guidelines. At 3 of the 19 sites sampled—State wells 79-06-411, 79-14-204, and Audilet Spring—nitrate concentrations exceeded the threshold (2.0 milligrams per liter) associated with anthropogenic contributions. The majority of the water samples (36 out of 44) that were analyzed for stable isotopes of hydrogen and oxygen during the three sampling events plotted in a relatively tight cluster centered near the global meteoric water line. The eight remaining samples, which include the four surface-water samples collected in June 2010, the sample collected from Coleto Creek Reservoir in January 2010, and all three samples collected at State well 79-15-904, deviate from the global meteoric water line in a way that indicates evaporative losses. The isotopic signatures of the three samples collected at State well 79-15-904, when taken in conjunction with its proximity to Coleto Creek Reservoir, indicate that there is likely a hydraulic connection between the two. When all of the sites are examined as a whole, there is a general pattern in strontium concentrations across the entire watershed that indicates that both the surface-water and groundwater samples derive from a single source (the Evangeline aquifer) with relatively uniform water-rock interactions.

Texas↗

USGS2010

Polychlorinated Biphenyls in suspended-sediment samples from outfalls to Meandering Road Creek at Air Force Plant 4, Fort Worth, Texas, 2003-08

Meandering Road Creek is an intermittent stream and tributary to Lake Worth, a reservoir on the West Fork Trinity River on the western edge of Fort Worth, Texas. U.S. Air Force Plant 4 (AFP4) is on the eastern shore of Woods Inlet, an arm of Lake Worth. Meandering Road Creek gains inflow from several stormwater outfalls as it flows across AFP4. Several studies have characterized polychlorinated biphenyls (PCBs) in the water and sediments of Lake Worth and Meandering Road Creek; sources of PCBs are believed to originate primarily from AFP4. Two previous U.S. Geological Survey (USGS) reports documented elevated PCB concentrations in surficial sediment samples from Woods Inlet relative to concentrations in surficial sediment samples from other parts of Lake Worth. The second of these two previous reports also identified some of the sources of PCBs to Lake Worth. These reports were followed by a third USGS report that documented the extent of PCB contamination in Meandering Road Creek and Woods Inlet and identified runoff from outfalls 4 and 5 at AFP4 as prominent sources of these PCBs. This report describes the results of a fourth study by the USGS, in cooperation with the Lockheed Martin Corporation, to investigate PCBs in suspended-sediment samples in storm runoff from outfalls 4 and 5 at AFP4 following the implementation of engineering controls designed to potentially alleviate PCB contamination in the drainage areas of these outfalls. Suspended-sediment samples collected from outfalls 4 and 5 during storms on March 2 and November 10, 2008, were analyzed for selected PCBs. Sums of concentrations of 18 reported PCB congeners (Sigma PCBc) in suspended-sediment samples collected before and after implementation of engineering controls are compared. At both outfalls, the Sigma PCBc before engineering controls was higher than the Sigma PCBc after engineering controls. The Sigma PCBc in suspended-sediment samples collected at AFP4 before and after implementation of engineering controls also is compared to the threshold effect concentration (TEC), the concentration below which adverse effects to benthic biota rarely occur. Sigma PCBc exceeded the TEC for 75 percent of the samples collected at outfall 4 and 67 percent of the samples collected at outfall 5 before the implementation of engineering controls. Sigma PCBc did not exceed the TEC in samples collected at either outfall 4 or outfall 5 after the implementation of engineering controls. The relative prominence of 10 selected PCB congeners was evaluated by graphical analysis of ratios of individual concentrations of the 10 PCB congeners to the sum of these PCB congeners. An overall decrease in concentrations of PCB congeners at outfalls 4 and 5 after implementation of engineering controls, as well as a shift in prominence from lighter, less chlorinated congeners to a heavier, more chlorinated congener might have resulted from the implementation of engineering controls. Because of the small number of samples collected and lack of runoff and precipitation data to evaluate comparability of sampling conditions before and after implementation of engineering controls, all conclusions are preliminary.

Texas↗

USGS2008

Degree of contamination and sources of polychlorinated biphenyls in Meandering Road Creek and Woods Inlet of Lake Worth, Fort Worth, Texas, 2004 and 2006-07

Lake Worth is a reservoir on the West Fork Trinity River on the western edge of Fort Worth, Texas. Air Force Plant 4 (AFP4) is on the eastern shore of Woods Inlet, an arm of Lake Worth that extends south from the main body of the lake. Two previous reports documented elevated polychlorinated biphenyl (PCB) concentrations in surficial sediment in Woods Inlet relative to those in surficial sediment in other parts of Lake Worth. This report presents the results of another USGS study, done in cooperation with the U.S. Air Force, to indicate the degree of PCB contamination of Meandering Road Creek and Woods Inlet and to identify possible sources of PCBs in Meandering Road Creek and Woods Inlet on the basis of suspended, streambed, and lake-bottom sediment samples collected there in 2004 and 2006–07. About 40 to 80 percent of total PCB concentrations (depending on how total PCB concentration is computed) in suspended sediment exceed the threshold effect concentration, a concentration below which adverse effects to benthic biota rarely occur. About 20 percent of total PCB concentrations (computed as sum of three Aroclors) in suspended sediment exceed the probable effect concentration, a concentration above which adverse effects to benthic biota are expected to occur frequently. About 20 to 30 percent of total PCB concentrations in streambed sediment exceed the threshold effect concentration; and about 6 to 20 percent of total PCB concentrations in lake-bottom (Woods Inlet) sediment exceed the threshold effect concentration. No streambed or lake-bottom sediment concentrations exceed the probable effect concentration. The sources of PCBs to Meandering Road Creek and Woods Inlet were investigated by comparing the relative distributions of PCB congeners of suspended sediment to those of streambed and lake-bottom sediment. The sources of PCBs were identified using graphical analysis of normalized concentrations (congener ratios) of 11 congeners. For graphical analysis, the sampling sites were divided into three groups with each group associated with one of the three outfalls sampled: SSO, OF4, and OF5. The variations of normalized PCB congener concentrations from Woods Inlet, from outfalls along Meandering Road Creek, and from streambed sediment sampling sites along Meandering Road Creek generally form similar patterns within sample groups, which is indicative of a common source of PCBs to each group. Overall, the variations in congener ratios indicate that PCBs in surficial lake-bottom sediment of Woods Inlet probably entered Woods Inlet primarily from Meandering Road Creek, and that runoff from AFP4 is a prominent source of PCBs in Meandering Road Creek. Sixteen of the 20 box core sites in Woods Inlet had lower PCB concentrations in the 2006 cores compared to those in the 2003 cores.

Texas↗

USGS2007

Hydrogeologic characterization of the Brazos River Alluvium Aquifer, Bosque County to Fort Bend County, Texas

Introduction The Brazos River alluvium aquifer underlies the Brazos River in Texas from Bosque County to Fort Bend County. The aquifer, one of 21 minor aquifers in the State, supplies water for irrigation, domestic, stock, and commercial use. The Brazos River alluvium aquifer likely will become more important in the future as demand for water increases statewide. A thorough understanding of the hydrogeology of the alluvium aquifer will be the foundation for future studies in the area. During October 2006-April 2007, the U.S. Geological Survey, in cooperation with the Texas Water Development Board, conducted a study to delineate the altitude of the top, altitude of the base, and thickness of the Brazos River alluvium aquifer, and to compile and summarize available hydraulic property (specific capacity, transmissivity, and hydraulic conductivity) data. A digital elevation model was used as the altitude of the top of the aquifer. The altitude of the base of the aquifer was generated using data from wells. The study area encompasses the Brazos River alluvium aquifer in parts of Bosque, Hill, McLennan, Falls, Robertson, Milam, Brazos, Burleson, Grimes, Washington, Waller, Austin, and Fort Bend Counties and a 1.5-mile-wide lateral buffer adjacent to the aquifer. The results of this study will be used by the Texas Water Development Board for input into a ground-water availability model.

Scientific Investigations Map↗

USGS2005

Long-term changes in ground water chemistry at a phytoremediation demonstration site

A field-scale demonstration project was conducted to evaluate the capability of eastern cottonwood trees ( Populus deltoides ) to attenuate trichloroethene (TCE) contamination of ground water. By the middle of the sixth growing season, trees planted where depth to water was <3 m delivered enough dissolved organic carbon to the underlying aquifer to lower dissolved oxygen concentrations, to create iron-reducing conditions along the plume centerline and sulfate-reducing or methanogenic conditions in localized areas, and to initiate in situ reductive dechlorination of TCE. Apparent biodegradation rate constants for TCE along the centerline of the plume beneath the phytoremediation system increased from 0.0002/d to 0.02/d during the first six growing seasons. The corresponding increase in natural attenuation capacity of the aquifer along the plume centerline, from 0.0004/m to 0.024/m, is associated with a potential decrease in plume-stabilization distance from 9680 to 160 m. Demonstration results provide insight into the amount of vegetation and time that may be needed to achieve cleanup objectives at the field scale.

Ground Water↗

USGS2004

Lake Worth bottom sediments : A chronicle of water-quality changes in western Fort Worth, Texas, 1914-2001

In spring 2000, the Texas Department of Health issued a fish-consumption advisory for Lake Worth, Tex., because of elevated concentrations of polychlorinated biphenyls (PCBs) in fish (Texas Department of Health, 2000). In response to the advisory and in cooperation with the U.S. Air Force, the U.S. Geological Survey (USGS) collected 21 surficial samples and three deeper gravity core samples from the sediment deposited at the bottom of Lake Worth. The purpose of that study was to assess the spatial distribution and historical trends of selected hydrophobic contaminants, including PCBs, and to determine, to the extent possible, sources of selected metals and hydrophobic organic contaminants (HOCs) to Lake Worth. Hydrophobic (literally “water fearing”) contaminants tend to chemically adsorb to soils and sediments. Fifteen of the top 20 contaminants on the Agency for Toxic Substances and Disease Registry (2001) priority list of hazardous substances are hydrophobic. Chemical analysis of sediment cores is one method that can be used to determine trends in HOCs such as PCBs. As sediments accumulate in lakes and reservoirs, they generate a partial historical record of water quality. This fact sheet describes the collection of sediment cores, age-dating methods, and historical trends in PCBs in Lake Worth sediments. The fact sheet also describes the spatial distribution of PCBs in surficial sediments and concludes with objectives for the second phase of data collection and the approach that will be used to achieve these objectives. The USGS published a comprehensive report on the first phase of the study (Harwell and others, 2003). Lake Worth is a reservoir on the West Fork Trinity River on the western edge of Fort Worth in Tarrant County. In 1914, the City of Fort Worth completed the reservoir to serve as a municipal water supply. Lake Worth has a surface area of 13.2 square kilometers and a storage capacity of 47 million cubic meters. The drainage area to the reservoir is 5,350 square kilometers(Ruddy and Hitt, 1990). The surrounding area to the south and east is primarily urban, and the area to the north and northwest is mostly residential.

Texas↗

USGS2004

Demonstration-site development and phytoremediation processes associated with trichloroethene (TCE) in ground water, Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

A field-scale phytoremediation demonstration study was initiated in 1996 by the U.S. Geological Survey (USGS), in cooperation with the U.S. Air Force, at a site on Naval Air StationJoint Reserve Base Carswell Field (NAS–JRB) adjacent to Air Force Plant 4 (AFP4) in Fort Worth, Tex. (fig. 1). Trichloroethene (TCE) has been used at AFP4 in aircraft manufacturing processes for decades; spills and leaks from tanks in the manufacturing building have resulted in shallow ground-water contamination on-site and downgradient from the facility (Eberts and others, 2003). The objective of the study was to determine the effectiveness of eastern cottonwoods ( Populus deltoides ) in decreasing the mass of dissolved TCE in ground water through phytoremediation. Phytoremediation is a process by which plants decrease the mass of a contaminant through a variety of chemical, physical, and biological means. Before development of the phytoremediation demonstration site, natural attenuation of TCE at the site occurred by sorption, dispersion, dilution, and possibly volatilization (Eberts and others, 2003). Long-term, field-scale monitoring and evaluation of this site contribute to the understanding of the processes associated with phytoremediation and provide practical information about field-scale applications of the method. This fact sheet briefly summarizes the development of the phytoremediation demonstration site at NAS–JRB and describes some of the physical and chemical processes associated with phytoremediation. The phytoremediation demonstration site is on the southern edge of the central lobe of a TCE plume in the surficial (alluvial) aquifer. The plume originates at AFP4 about 0.9 mile upgradient from the site (fig. 1). The 9.5-acre site is in the northwestern corner of the golf course on NAS–JRB. The saturated thickness of the alluvial aquifer, which is composed of clay, silt, sand, and gravel, ranges from about 1.5 to 5 feet at the site. The total thickness of the alluvial aquifer ranges from about 6 to 15 feet. The Goodland-Walnut confining unit, composed of massively bedded shaley limestone, underlies the alluvial aquifer. The general direction of ground-water flow in the study area (fig. 2) is from northwest to southeast, approximately perpendicular to the long sides of the cottonwood plantations. Ground water flows toward Farmers Branch Creek in the area southwest of the golf cart path. At the time of site characterization in August 1996, depth to water ranged from 8 to 13 feet below land surface.

Texas↗

USGS2004

Reductive dechlorination of chlorinated ethenes under oxidation-reduction conditions and potentiometric surfaces in two trichloroethene-contaminated zones at the Double Eagle and Fourth Street Superfund sites in Oklahoma City, Oklahoma

The Double Eagle Refining Superfund site and the Fourth Street Abandoned Refinery Superfund site are in northeast Oklahoma City, Oklahoma, adjacent to one another. The Double Eagle facility became a Superfund site on the basis of contamination from lead and volatile organic compounds; the Fourth Street facility on the basis of volatile organic compounds, pesticides, and acid-base neutral compounds. The study documented in this report was done to investigate whether reductive dechlorination of chlorinated ethenes under oxidation-reduction conditions is occurring in two zones of the Garber-Wellington aquifer (shallow zone 30–60 to 75 feet below land surface, deep zone 75 to 160 feet below land surface) at the sites; and to construct potentiometric surfaces of the two water-yielding zones to determine the directions of groundwater flow at the sites. The presence in some wells of intermediate products of reductive dechlorination, dichloroethene and vinyl chloride, is an indication that reductive dechlorination of trichloroethene is occurring. Dissolved oxygen concentrations (less than 0.5 milligram per liter) indicate that consumption of dissolved oxygen likely had occurred in the oxygen-reducing microbial process associated with reductive dechlorination. Concentrations of nitrate and nitrite nitrogen (generally less than 2.0 and 0.06 milligrams per liter, respectively) indicate that nitrate reduction probably is not a key process in either aquifer zone. Concentrations of ferrous iron greater than 1.00 milligram per liter in the majority of wells sampled indicate that iron reduction is probable. Concentrations of sulfide less than 0.05 milligram per liter in all wells indicate that sulfate reduction probably is not a key process in either zone. The presence of methane in ground water is an indication of strongly reducing conditions that facilitate reductive dechlorination. Methane was detected in all but one well. In the shallow zone in the eastern part of the study area, ground water flowing from the northwest and south coalesces in a potentiometric trough, then moves westward and ultimately northwestward. In the western part of the study area, ground water in the shallow zone flows northwest. In the deep zone in the eastern part of the study area, ground water generally flows northwestward; and in the western part of the study area, ground water in the deep zone generally flows northward.

Oklahoma↗

USGS2004

Water-level variations and their effects on tree growth and mortality and on the biogeochemical system at the phytoremediation demonstration site in Fort Worth, Texas, 1996-2003

In 1996, a field-scale phytoremediation demonstration project was initiated and managed by the U.S. Air Force at a site in western Fort Worth, Texas, using a plantation of 1-year-old stems harvested from branches of eastern cottonwoods during the dormant season (whips) and a plantation of 1-year-old eastern cottonwood seedlings (calipers). The primary objective of the demonstration project was to determine the effectiveness of eastern cottonwoods at reducing the mass of dissolved trichloroethene transported within an alluvial aquifer. The U.S. Geological Survey conducted a study, in cooperation with the U.S. Air Force, to determine water-level variations and their effects on tree growth and mortality and on the biogeochemical system at the phytoremediation site. As part of the study, water-level and water-quality data were collected throughout the duration of the project. This report presents water-level variations at periodic sampling events; data from August 1996 to January 2003 are presented in this report. Water levels are affected by aquifer properties, precipitation, drawdown attributable to the trees in the study area, and irrigation. This report also evaluates the effects of ground-water depth on tree growth and mortality rates and on the biogeochemical system including subsurface oxidation-reduction processes. Overall, both whips and calipers showed a substantial increase in height, canopy diameter, and trunk diameter over the first 3 years of the study. By the fifth growing season (September 2000), the height of the calipers varied predictably with height decreasing with increasing depth to ground water. Percent mortality was relatively constant at about 25 percent in the whip plantation in January 2003 where ground-water levels were less than 10 feet below land surface during the drought in September 2000. The mortality rate increased where the ground-water levels were greater than 10 feet below land surface and approached 90 percent where ground-water levels were between 12 and 13 feet. A decrease in molar ratio of trichloroethene to cis -dichloroethene was measured in ground water within and downgradient from the planted area over time. Decreases in these ratios appeared to be related to ground-water depth. The molar ratios of trichloroethene to cis -dichloroethene during the third growing season were relatively constant, between 3.0 and 4.0, in samples collected from wells across the site. By the end of the fifth growing season the lowest ratio was measured in areas where ground-water depth was less than 10 feet below land surface; these same areas had the lowest dissolved oxygen concentrations (0.93 to 1.7 milligrams per liter) and the highest dissolved organic carbon concentrations (1.6 to 1.8 milligrams per liter). This indicates that between the third and fifth growing seasons, a labile fraction of dissolved organic carbon had been introduced into the aquifer by the planted trees that was capable of stimulating reductive dechlorination of trichloroethene.

Texas↗

USGS2004

Analyses and estimates of hydraulic conductivity from slug tests in alluvial aquifer underlying Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

This report describes the collection, analyses, and distribution of hydraulic-conductivity data obtained from slug tests completed in the alluvial aquifer underlying Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas, during October 2002 and August 2003 and summarizes previously available hydraulic-conductivity data. The U.S. Geological Survey, in cooperation with the U.S. Air Force, completed 30 slug tests in October 2002 and August 2003 to obtain estimates of horizontal hydraulic conductivity to use as initial values in a ground-water-flow model for the site. The tests were done by placing a polyvinyl-chloride slug of known volume beneath the water level in selected wells, removing the slug, and measuring the resulting water-level recovery over time. The water levels were measured with a pressure transducer and recorded with a data logger. Hydraulic-conductivity values were estimated from an analytical relation between the instantaneous displacement of water in a well bore and the resulting rate of head change. Although nearly two-thirds of the tested wells recovered 90 percent of their slug-induced head change in less than 2 minutes, 90-percent recovery times ranged from 3 seconds to 35 minutes. The estimates of hydraulic conductivity range from 0.2 to 200 feet per day. Eighty-three percent of the estimates are between 1 and 100 feet per day.

Texas↗

USGS2003

Oxidation-reduction processes in ground water at Naval Weapons Industrial Reserve Plant, Dallas, Texas

Concentrations of trichloroethene in ground water at the Naval Weapons Industrial Reserve Plant in Dallas, Texas, indicate three source areas of chlorinated solvents?building 1, building 6, and an off-site source west of the facility. The presence of daughter products of reductive dechlorination of trichloroethene, which were not used at the facility, south and southwest of the source areas are evidence that reductive dechlorination is occurring. In places south of the source areas, dissolved oxygen concentrations indicated that reduction of oxygen could be the dominant process, particularly south of building 6; but elevated dissolved oxygen concentrations south of building 6 might be caused by a leaking water or sewer pipe. The nitrite data indicate that denitrification is occurring in places; however, dissolved hydrogen concentrations indicate that iron reduction is the dominant process south of building 6. The distributions of ferrous iron indicate that iron reduction is occurring in places south-southwest of buildings 6 and 1; dissolved hydrogen concentrations generally support the interpretation that iron reduction is the dominant process in those places. The generally low concentrations of sulfide indicate that sulfate reduction is not a key process in most sampled areas, an interpretation that is supported by dissolved hydrogen concentrations. Ferrous iron and dissolved hydrogen concentrations indicate that ferric iron reduction is the primary oxidation-reduction process. Application of mean first-order decay rates in iron-reducing conditions for trichloroethene, dichloroethene, and vinyl chloride yielded half-lives for those solvents of 231, 347, and 2.67 days, respectively. Decay rates, and thus half-lives, at the facility are expected to be similar to those computed. A weighted scoring method to indicate sites where reductive dechlorination might be likely to occur indicated strong evidence for anaerobic biodegradation of chlorinated solvents at six sites. In general, scores were highest for samples collected on the northeast side of the facility.

Texas↗

USGS2002

Subsurface evaluation of the west parking lot and landfill 3 areas of Air Force Plant 4, Fort Worth, Texas, using two-dimensional direct-current resistivity profiling

During September 1999, the U.S. Geological Survey made 10 two-dimensional direct-current resistivity profile surveys in the west parking lot and landfill 3 areas of Air Force Plant 4, Fort Worth, Texas, to identify subsurface areas of anomalously high or low resistivity that could indicate potential contamination, contaminant pathways, or anthropogenic structures. Six of the 10 surveys (transects) were in the west parking lot. Each of the inverted sections of these transects had anomalously high resistivities in the terrace alluvium/fill (the surficial subsurface layer) that probably were caused by highly resistive fill material. In addition, each of these transects had anomalously low resistivities in the Walnut Formation (a bedrock layer immediately beneath the alluvium/fill) that could have been caused by saturation of fractures within the Walnut Formation. A high-resistivity anomaly in the central part of the study area probably is associated with pea gravel fill used in construction of a French drain. Another high resistivity anomaly in the west parking lot, slightly southeast of the French drain, could be caused by dense nonaqueous-phase liquid in the Walnut Formation. The inverted sections of the four transects in the landfill 3 area tended to have slightly higher resistivities in both the alluvium/fill and the Walnut Formation than the transects in the west parking lot. The higher resistivities in the alluvium/fill could have been caused by drier conditions in grassy areas relative to conditions in the west parking lot. Higher resistivities in parts of the Walnut Formation also could be a function of drier conditions or variations in the lithology of the Walnut Formation. In addition to the 10 vertical sections, four horizontal sections at 2-meteraltitude intervals show generally increasing resistivity with decreasing altitude that most likely results from the increased influence of the Walnut Formation, which has a higher resistivity than the terrace alluvium/fill.

Texas↗

USGS2000

Borehole geophysical logs at Naval Weapons Industrial Reserve Plant, Dallas, Texas

Texas↗

USGS2000

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas↗

USGS2000

Computer-model analysis of ground-water flow and simulated effects of contaminant remediation at Naval Weapons Industrial Reserve Plant, Dallas, Texas

In June 1993, the Department of the Navy, Southern Division Naval Facilities Engineering Command (SOUTHDIV), began a Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) of the Naval Weapons Industrial Reserve Plant (NWIRP) in north-central Texas. The RFI has found trichloroethene, dichloroethene, vinyl chloride, as well as chromium, lead, and other metallic residuum in the shallow alluvial aquifer underlying NWIRP. These findings and the possibility of on-site or off-site migration of contaminants prompted the need for a ground-water-flow model of the NWIRP area. The resulting U.S. Geological Survey (USGS) model: (1) defines aquifer properties, (2) computes water budgets, (3) delineates major flowpaths, and (4) simulates hydrologic effects of remediation activity. In addition to assisting with particle-tracking analyses, the calibrated model could support solute-transport modeling as well as help evaluate the effects of potential corrective action. The USGS model simulates steadystate and transient conditions of ground-water flow within a single model layer. The alluvial aquifer is within fluvial terrace deposits of Pleistocene age, which unconformably overlie the relatively impermeable Eagle Ford Shale of Late Cretaceous age. Over small distances and short periods, finer grained parts of the aquifer are separated hydraulically; however, most of the aquifer is connected circuitously through randomly distributed coarser grained sediments. The top of the underlying Eagle Ford Shale, a regional confining unit, is assumed to be the effective lower limit of ground-water circulation and chemical contamination. The calibrated steady-state model reproduces long-term average water levels within +5.1 or –3.5 feet of those observed; the standard error of the estimate is 1.07 feet with a mean residual of 0.02 foot. Hydraulic conductivity values range from 0.75 to 7.5 feet per day, and average about 4 feet per day. Specific yield values range from 0.005 to 0.15 and average about 0.08. Simulated infiltration rates range from 0 to 2.5 inches per year, depending mostly on local patterns of ground cover. Computer simulation indicates that, as of December 31, 1998, remediation systems at NWIRP were removing 7,375 cubic feet of water per day from the alluvial aquifer, with 3,050 cubic feet per day coming from aquifer storage. The resulting drawdown prevented 1,800 cubic feet per day of ground water from discharging into Cottonwood Bay, as well as inducing another 1,325 cubic feet per day into the aquifer from the bay. An additional 1,200 cubic feet of water per day (compared to pre-remediation conditions) was prevented from discharging into the west lagoon, east lagoon, Mountain Creek Lake, and Mountain Creek swale. Particle-tracking simulations, assuming an aquifer porosity of 0.15, were made to delineate flowpath patterns, or contaminant “capture zones,” resulting from 2.5- and 5-year periods of remediation activity at NWIRP. The resulting flowlines indicate three such zones, or areas from which ground water is simulated to have been removed during July 1996–December 1998, as well as extended areas from which ground water would be removed during the next 2.5 years (January 1999– June 2001). Simulation indicates that, as of December 31, 1998, the recovery trench was intercepting about 827 cubic feet per day of ground water that—without the trench—would have discharged into Cottonwood Bay. During this time, the trench is simulated to have removed about 3,221 cubic feet per day of water from the aquifer, with about 934 cubic feet per day (29 percent) coming from the south (Cottonwood Bay) side of the trench.

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USGS2000

Use of borehole geophysical logs for improved site characterization at Naval Weapons Industrial Reserve Plant, Dallas, Texas

A shallow alluvial aquifer at the Naval Weapons Industrial Reserve Plant near Dallas, Texas, has been contaminated by organic solvents used in the fabrication and assembly of aircraft and aircraft parts. Natural gamma-ray and electromagnetic-induction log data collected during 1997 from 162 wells were integrated with existing lithologic and cone-penetrometer test log data to improve characterization of the subsurface alluvium at the site. The alluvium, consisting of mostly fine-grained, low-permeability sediments, was classified into low, intermediate, and high clay-content sediments on the basis of the gamma-ray logs. Low clay-content sediments were interpreted as being relatively permeable, whereas high clay-content sediments were interpreted as being relatively impermeable. Gamma-ray logs, cone-penetrometer test logs, and electromagnetic-induction logs were used to develop a series of intersecting sections to delineate the spatial distribution of low, intermediate, and high clay-content sediments and to delineate zones of potentially contaminated sediments. The sections indicate three major sedimentary units in the shallow alluvial aquifer at NWIRP. The lower unit consists of relatively permeable, low clay-content sediments and is absent over the southeastern and northwestern part of the site. Permeable zones in the complex, discontinuous middle unit are present mostly in the western part of the site. In the eastern and southeastern part of the site, the upper unit has been eroded away and replaced by fill material. Zones of potentially contaminated sediments are generally within the uppermost clay layer or fill material. In addition, the zones tend to be local occurrences.

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