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Christopher E. Neuzil

Publications and source records attributed to Christopher E. Neuzil.

11 recordsLinked to original sources

Multiphase flow and underpressured shale at the Bruce nuclear site, Ontario, Canada

Hydraulic testing has revealed dramatic underpressures in Paleozoic shales and carbonates at the Bruce nuclear site in Ontario. Although evidence from both laboratory and field studies suggests that a small amount of gas-phase methane could be present in the shale, previous studies examining causal linkages between the gas phase and the underpressure have been inconclusive. To better elucidate processes in such a system, we used a highly simplified 1D representation of the site to test, by using iTOUGH2-EOS7C, the effects of various factors on the evolution of gas-phase methane and pressures within the system. Heterogeneity was represented by three stratigraphic regions with slightly different capillary pressure characteristics and, in one case, three thin distinct zones with very different characteristics. Underpressure occurred only when gas pressures set as an initial condition required it, and even in this case it was geologically short-lived. We conclude that the presence of multiple fluid phases is unlikely to explain the underpressure at the site; we suggest that the influence of gas-phase methane on porewater flow is minimal. This is consistent with prior conceptualizations of the underpressured section as a thick aquiclude, in which solute transport occurs extremely slowly, bounded by aquifers of significantly higher permeability.

Ontario

Reexamining ultrafiltration and solute transport in groundwater

Geologic ultrafiltration—slowing of solutes with respect to flowing groundwater—poses a conundrum: it is consistently observed experimentally in clay-rich lithologies, but has been difficult to identify in subsurface data. Resolving this could be important for clarifying clay and shale transport properties at large scales as well as interpreting solute and isotope patterns for applications ranging from nuclear waste repository siting to understanding fluid transport in tectonically active environments. Simulations of one-dimensional NaCl transport across ultrafiltering clay membrane strata constrained by emerging data on geologic membrane properties showed different ultrafiltration effects than have often been envisioned. In relatively high-permeability advection-dominated regimes, salinity increases occurred mostly within membrane units while their effluent salinity initially fell and then rose to match solute delivery. In relatively low-permeability diffusion-dominated regimes, salinity peaked at the membrane upstream boundary and effluent salinity remained low. In both scenarios, however, only modest salinity changes (up to ∼3 g L −1 ) occurred because of self-limiting tendencies; membrane efficiency declines as salinity rises, and although sediment compaction increases efficiency, it is also decreases permeability and allows diffusive transport to dominate. It appears difficult for ultrafiltration to generate brines as speculated, but widespread and less extreme ultrafiltration effects in the subsurface could be unrecognized. Conditions needed for ultrafiltration are present in settings that include topographically-driven flow systems, confined aquifer systems subjected to injection or withdrawal, compacting basins, and accretionary complexes.

Water Resources Research

Interpreting fluid pressure anomalies in shallow intraplate argillaceous formations

Investigations have revealed several instances of apparently isolated highs or lows in pore fluid potential in shallow (< ~ 1&thinsp;km depth) argillaceous formations in intraplate settings. Formations with the pressure anomalies are distinguished by (1) smaller ratios of hydraulic conductivity to formation thickness and (2) smaller hydraulic (or pressure) diffusivities than those without anomalies. This is consistent with transient Darcian flow caused by strain at rates of ~ 10 &minus;17 to 10 -16 &thinsp;s -1 , by significant perturbing events in the past 10 4 to 10 6 &thinsp;annum or by some combination of the two. Plausible causes include erosional downwasting, tectonic strain, and glaciation. In this conceptualization the anomalies provide constraints on formation-scale flow properties, flow history, and local geological forcing in the last 10 6 &thinsp;annum and in particular indicate zones of low permeability (10 &minus;19 &ndash;10 &minus;22 &thinsp;m 2 ) that could be useful for isolation of nuclear waste.

Geophysical Research Letters

Ice sheet load cycling and fluid underpressures in the Eastern Michigan Basin, Ontario, Canada

Strong fluid underpressures have been detected in Paleozoic strata in the eastern Michigan Basin, with hydraulic heads reaching ~400&thinsp;m below land surface (~4&thinsp;MPa underpressure) and ~200&thinsp;m below sea level in strata where unusually low permeabilities (~10 &minus;20 &ndash;10 &minus;23 &thinsp;m 2 ) were measured in situ. Multiple glaciations, including three with as much as 3&thinsp;km of ice cover at the site in the last 120&thinsp;ka, suggest a causal link with the underpressures. We examined this possibility using a one-dimensional groundwater flow model incorporating mechanical loading from both ice weight and lithospheric flexure. Because hydrologic and mechanical changes during glaciation are not well characterized and subsurface properties are imperfectly known, the model was used inversely to estimate flexural loads and loosely constrained permeabilities by matching observed pressures. Acceptable matches were obtained for a surprisingly wide range of scenarios with permeabilities close to measured values and plausible flexural loads. Matches were not obtained when too many parameters were preselected, or when permeabilities were constrained to be significantly larger than measured values. In successful model runs groundwater expulsion under glacial-mechanical loads caused the underpressuring, and flexural loads were important if aquifer and sub-glacial pressures were significantly elevated during glaciation. Simulated fluid pressures in the low-permeability strata fluctuated by 30&ndash;40&thinsp;MPa during glacial cycles but resulted in advective transport of only tens of meters or less. Although other mechanisms cannot be ruled out, we conclude that glacial-mechanical forcing of a water-saturated system can explain the observed underpressures.

Ontario

Science is the first step to siting nuclear waste repositories

As Shaw [2014] notes, U.S. research on shale as a repository host was halted before expending anything close to the effort devoted to studying crystalline rock, salt, and - most notably - tuff at Yucca Mountain. The new political reality regarding Yucca Mountain may allow reconsideration of the decision to abandon research on shale as a repository host.

Eos, Earth and Space Science News

Shale: an overlooked option for US nuclear waste disposal

Toss a dart at a map of the United States and, more often than not, it will land where shale can be found underground. A drab, relatively featureless sedimentary rock that historically attracted little interest, shale (as used here, the term includes clay and a range of clay-rich rocks) is entering Americans&rsquo; consciousness as a new source of gas and oil. But shale may also offer something entirely different&mdash;the ability to safely and permanently house high-level nuclear waste.

Bulletin of the Atomic Scientists

Ground-water flow in low permeability environments

Certain geologic media are known to have small permeability; subsurface environments composed of these media and lacking well developed secondary permeability have groundwater flow sytems with many distinctive characteristics. Moreover, groundwater flow in these environments appears to influence the evolution of certain hydrologic, geologic, and geochemical systems, may affect the accumulation of pertroleum and ores, and probably has a role in the structural evolution of parts of the crust. Such environments are also important in the context of waste disposal. This review attempts to synthesize the diverse contributions of various disciplines to the problem of flow in low-permeability environments. Problems hindering analysis are enumerated together with suggested approaches to overcoming them. A common thread running through the discussion is the significance of size- and time-scale limitations of the ability to directly observe flow behavior and make measurements of parameters. These limitations have resulted in rather distinct small- and large-scale approaches to the problem. The first part of the review considers experimental investigations of low-permeability flow, including in situ testing; these are generally conducted on temporal and spatial scales which are relatively small compared with those of interest. Results from this work have provided increasingly detailed information about many aspects of the flow but leave certain questions unanswered. Recent advances in laboratory and in situ testing techniques have permitted measurements of permeability and storage properties in progressively “tighter” media and investigation of transient flow under these conditions. However, very large hydraulic gradients are still required for the tests; an observational gap exists for typical in situ gradients. The applicability of Darcy's law in this range is therefore untested, although claims of observed non-Darcian behavior appear flawed. Two important nonhydraulic flow phenomena, osmosis and ultrafiltration, are experimentally well established in prepared clays but have been incompletely investigated, particularly in undisturbed geologic media. Small-scale experimental results form much of the basis for analyses of flow in low-permeability environments which occurs on scales of time and size too large to permit direct observation. Such large-scale flow behavior is the focus of the second part of the review. Extrapolation of small-scale experimental experience becomes an important and sometimes controversial problem in this context. In large flow systems under steady state conditions the regional permeability can sometimes be determined, but systems with transient flow are more difficult to analyze. The complexity of the problem is enhanced by the sensitivity of large-scale flow to the effects of slow geologic processes. One-dimensional studies have begun to elucidate how simple burial or exhumation can generate transient flow conditions by changing the state of stress and temperature and by burial metamorphism. Investigation of the more complex problem of the interaction of geologic processes and flow in two and three dimensions is just beginning. Because these transient flow analyses have largely been based on flow in experimental scale systems or in relatively permeable systems, deformation in response to effective stress changes is generally treated as linearly elastic; however, this treatment creates difficulties for the long periods of interest because viscoelastic deformation is probably significant. Also, large-scale flow simulations in argillaceous environments generally have neglected osmosis and ultrafiltration, in part because extrapolation of laboratory experience with coupled flow to large scales under in situ conditions is controversial. Nevertheless, the effects are potentially quite important because the coupled flow might cause ultra long lived transient conditions. The difficulties associated with analysis are matched by those of characterizing hydrologic conditions in tight environments; measurements of hydraulic head and sampling of pore fluids have been done only rarely because of the practical difficulties involved. These problems are also discussed in the second part of this paper.

Water Resources Research

Development of a probabilistic assessment methodology for evaluation of carbon dioxide storage

This report describes a probabilistic assessment methodology developed by the U.S. Geological Survey (USGS) for evaluation of the resource potential for storage of carbon dioxide (CO 2 ) in the subsurface of the United States as authorized by the Energy Independence and Security Act (Public Law 110-140, 2007). The methodology is based on USGS assessment methodologies for oil and gas resources created and refined over the last 30 years. The resource that is evaluated is the volume of pore space in the subsurface in the depth range of 3,000 to 13,000 feet that can be described within a geologically defined storage assessment unit consisting of a storage formation and an enclosing seal formation. Storage assessment units are divided into physical traps (PTs), which in most cases are oil and gas reservoirs, and the surrounding saline formation (SF), which encompasses the remainder of the storage formation. The storage resource is determined separately for these two types of storage. Monte Carlo simulation methods are used to calculate a distribution of the potential storage size for individual PTs and the SF. To estimate the aggregate storage resource of all PTs, a second Monte Carlo simulation step is used to sample the size and number of PTs. The probability of successful storage for individual PTs or the entire SF, defined in this methodology by the likelihood that the amount of CO 2 stored will be greater than a prescribed minimum, is based on an estimate of the probability of containment using present-day geologic knowledge. The report concludes with a brief discussion of needed research data that could be used to refine assessment methodologies for CO 2 sequestration.

Open-File Report

A method to estimate groundwater depletion from confining layers

Although depletion of storage in low‐permeability confining layers is the source of much of the groundwater produced from many confined aquifer systems, it is all too frequently overlooked or ignored. This makes effective management of groundwater resources difficult by masking how much water has been derived from storage and, in some cases, the total amount of water that has been extracted from an aquifer system. Analyzing confining layer storage is viewed as troublesome because of the additional computational burden and because the hydraulic properties of confining layers are poorly known. In this paper we propose a simplified method for computing estimates of confining layer depletion, as well as procedures for approximating confining layer hydraulic conductivity ( K ) and specific storage ( S s ) using geologic information. The latter makes the technique useful in developing countries and other settings where minimal data are available or when scoping calculations are needed. As such, our approach may be helpful for estimating the global transfer of groundwater to surface water. A test of the method on a synthetic system suggests that the computational errors will generally be small. Larger errors will probably result from inaccuracy in confining layer property estimates, but these may be no greater than errors in more sophisticated analyses. The technique is demonstrated by application to two aquifer systems: the Dakota artesian aquifer system in South Dakota and the coastal plain aquifer system in Virginia. In both cases, depletion from confining layers was substantially larger than depletion from the aquifers.

Water Resources Research

Groundwater in geologic processes, 2nd edition

Interest in the role of Groundwater in Geologic Processes has increased steadily over the past few decades. Hydrogeologists and geologists are now actively exploring the role of groundwater and other subsurface fluids in such fundamental geologic processes as crustal heat transfer, ore deposition, hydrocarbon migration, earthquakes, tectonic deformation, diagenesis, and metamorphism. Groundwater in Geologic Processes is the first comprehensive treatment of this body of inquiry. Chapters 1 to 4 develop the basic theories of groundwater motion, hydromechanics, solute transport, and heat transport. Chapter 5 applies these theories to regional groundwater flow systems in a generic sense, and Chapters 6 to 13 focus on particular geologic processes and environments. Relative to the first edition of Groundwater in Geologic Processes , this second edition includes a much more comprehensive treatment of hydromechanics (the coupling of groundwater flow and deformation). It also includes new chapters on "compaction and diagenesis," "metamorphism," and "subsea hydrogeology." Finally, it takes advantage of the substantial body of published research that has appeared since the first edition in 1998. The systematic presentation of theory and application, and the problem sets that conclude each chapter, make this book ideal for undergraduate- and graduate-level geology courses (assuming that the students have some background in calculus and introductory chemistry). It also serves as an invaluable reference for researchers and other professionals in the field

Book