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Charles N. Alpers

Publications and source records attributed to Charles N. Alpers.

At least 19 recordsLinked to original sources
USGS2026

Widespread occurrence of Magnéli phases in wildland-urban interface fire ashes

The increasing activity of wildland–urban interface (WUI) fires has raised concerns regarding the potential environmental and human health impacts of residual ash remaining after burning. In this study, we investigated the concentration and speciation of titanium in WUI fire ash. Total titanium concentrations in WUI fire ash ranged from 0.53 to 80 g kg –1 . Synchrotron-based macro- and microscale X-ray absorption near-edge structure (XANES and μXANES, respectively) spectroscopy were used to quantify the relative abundance of major Ti phases in the fire ash, and the results were corroborated by high resolution-transmission electron microscopy (HR-TEM) measurements. Rutile (α-TiO 2 ), anatase (β-TiO 2 ), ilmenite (FeTiO 3 ), and titanium(III) oxide (Ti 2 O 3 ) were detected in all 20 ashes investigated by XANES and accounted for 0.26–0.83, 0.19–0.83, 0.33, and 0.17–0.72 of the spectral weight, respectively. Deeper analysis by μXANES of one sample demonstrated that Ti-bearing particles occurred as a mixture of rutile (α-TiO 2 ), anatase (β-TiO 2 ), ilmenite (FeTiO 3 ), and titanium(III) oxide Ti 2 O 3, with the absence of a pure Ti 2 O 3 phase. The presence of Ti 2 O 3 in the WUI fire ash is ascribed to the reduction of rutile and anatase to Magnéli titania (Ti n O 2 n– 1 , n = 4–9), which is estimated to be the dominant phase of titanium in the 20 WUI fire ashes investigated by XANES. The occurrence of Magnéli titania was corroborated by HR-TEM. Our findings demonstrate the impact of WUI fires on titanium speciation; fires convert titanium dioxides (e.g., rutile and anatase) to reduced titanium phases (e.g., Magnéli titania). Based on HR-TEM analyses, most of the titanium-bearing particles were less than 500 nm in size. Magnéli particles have been shown to be more toxic than rutile and anatase and have been linked to reduced lung function. Therefore, this study provides critical insights into the pollution characteristics and potential health risks of WUI fire ashes and associated particles, which are currently poorly understood.

California↗
USGS2026

Wildland-Urban Interface Wildfire Increases Metal Contributions to Stormwater Runoff in Paradise, California

The 2018 Camp Fire was a large late-year (November) wildfire that produced an urban firestorm in the Town of Paradise, California, USA, and destroyed more than 18,000 structures. Runoff from burned wildland areas is known to contain ash, which can transport contaminants including metals into nearby watersheds. However, due to historically infrequent occurrences, the effect of wildland urban interface (WUI) fires, such as the Camp Fire, on surface water quality has not been well-characterized. Therefore, this study investigated the effects of widespread urban burning on surface water quality in major watersheds of the Camp Fire area. Between November 2018 and May 2019, 140 surface water samples were collected, including baseflow and stormflow, from burned and unburned watersheds with varying extent of urban development. Samples were analyzed for total and filter-passing metals, dissolved organic carbon, major anions, and total suspended solids. Ash and debris from the Camp Fire contributed metals to downstream watersheds via runoff throughout the storm season. Increases in concentration up to 200-fold were found for metals Cr, Cu, Ni, Pb, and Zn in burned watersheds compared to pre-fire values. Total concentrations of Al, Cd, Cu, Pb, and Zn exceeded EPA aquatic habitat acute criteria by up to 16-fold for up to five months after the fire. To assess possible transport mechanisms and bioavailability, a subset of 18 samples was analyzed using four filters with nominal pore sizes ranging from 0.22 to 1.2 µm to determine the particulate size distribution of metals. Trace and major metals (Al, Ba, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, and Zn) were found mostly associated with larger grain sizes (>0.45 µm), and some metals (Al, Cr, Fe, and Pb) also included a substantial colloidal phase (0.22 µm to 0.45 µm). This study suggests that fires in the wildland-urban interface increase metal concentrations, mainly through particulate driven transport. The metals with largest increases are likely from anthropogenic disaster materials, though biomass ash contributions are also a major contributor to overall water quality. The increase in metals following WUI burning may have adverse ecological impacts.

California↗
USGS2026

Transient methylmercury formation during wetland soil rewetting is governed by organic matter availability rather than coagulant history

Rewetting of previously drained wetland soils can induce rapid redox shifts that influence mercury (Hg) cycling and methylmercury (MeHg) production. We investigated how prior exposure to common metal-salt and biopolymer coagulants influences Hg transformations during wetland soil rewetting and whether organic matter (OM) availability modulates these effects. Wetland soils (∼300 µg kg −1 total Hg) were incubated in triplicate soil-water microcosms for 16 days following rewetting. Treatments included soils previously exposed to ferric sulfate, polyaluminum chloride, or a chitosan-based coagulant, alongside untreated controls. Upon rewetting without additional OM, redox potential declined to ∼250 mV, consistent with manganese-reducing conditions, and MeHg concentrations remained relatively low in water (0.05–0.18 ng L −1 ) and soils (1–2 µg kg −1 ) across all treatments. In contrast, addition of algal-derived OM (Spirulina powder) rapidly decreased redox potential to 0–100 mV and produced a short-lived pulse of MeHg formation in all treatments, with aqueous MeHg peaking at ∼30–40 ng L −1 and soil MeHg at ∼6–8 µg kg −1 on days 2–4 before declining. Coagulant treatments increased transient inorganic Hg concentrations in overlying water (45–75 ng L −1 ) relative to controls (∼30 ng L −1 ) but did not enhance higher MeHg production. Results demonstrate that OM-driven redox dynamics, rather than prior coagulant exposure, control transient MeHg production during wetland soil rewetting, highlighting how episodic carbon inputs can regulate mercury transformation in managed and natural wetlands.

California↗
USGS2025

Comparative study of the elemental composition of metal(loid)-bearing nanomaterials in wildland-urban interface fire ashes using icp-TOF-MS

This study investigates the abundance and elemental composition of metal(loid) incidental nanomaterials (INMs) in wildland–urban interface (WUI) fire ashes from different sources, including vegetation, structures, and vehicles, collected following the 2020 LNU (the Sonoma-Lake-Napa unit) Lightning Complex Fire in California. Particle number concentrations, elemental compositions and ratios, and size distributions were determined by single particle inductively coupled plasma-time of flight-mass spectrometry (SP-ICP-TOF-MS) coupled with automated two-stage hierarchical clustering analysis. Iron- and Mn-bearing INMs accounted for >80% of INMs detected in vegetation and atmospheric deposition ashes but they represented <50% of all INMs in structural and vehicle ashes. Together, Al, Ba, Cr, Cu, Ti, Pb, and Zn-bearing INMs accounted for 45 to 75% of all INMs in structural and vehicle ashes and 7 to 13% in vegetation and atmospheric deposition ashes. The sizes of INMs varied between a few tens to a few hundreds of nanometers with larger Ba, Cr, Fe, Ti, Pb, and Zn-bearing INMs in structural and vehicles ashes than in vegetation ashes. Several types of multi-element INMs were identified by SP-ICP-TOF-MS including chromated-copper-arsenate-related NMs ( e.g. , CuCrO 2 , CuCr 2 O 4 , CrAsO 4 ); CuSn and CuPb alloys; SnPb, SbPb, and SnSb alloys; and CoAl alloys. Overall, this study demonstrates the abundance and elemental makeup of various metal(loid) INMs in WUI fire ashes. This study highlights the research opportunities into the discovery, transformation, reactivity, fate, and effects of INMs during and following WUI fires.

Environmental Science: Nano↗
USGS2024

A multidisciplinary approach that considers occurrence, geochemistry, bioavailability, and toxicity to prioritize critical minerals for environmental research

Critical minerals (or critical elements) are minerals or elements that are essential to global security and development and have supply chains vulnerable to disruption. In general, knowledge of the environmental behavior and health effects of critical elements is needed to support the development of safe and environmentally responsible supplies. This knowledge includes identifying potential consequences of increased critical element production and use, alternative critical element sources such as mine wastes, and adverse effects of critical elements on ecosystem condition and organismal health. Here we identify significant data gaps in the understanding of critical elements in surficial and aquatic environments, and the need, given the large number of commodities (50) identified on the 2022 critical minerals list for the United States, for an approach to prioritize them for study of their environmental fate and effects. We propose a multidisciplinary approach for this prioritization, considering measures of occurrence, geochemistry, bioavailability, and toxicity. We describe relatively easy-to-obtain metrics for each of these topic areas and demonstrate the utility of this integrated prioritization approach using indium and zinc as examples. This approach facilitates prioritizing research with a focus on those critical elements that are most mobile in the environment, bioavailable, toxic, or simply lacking data in these categories.

Environmental Science & Technology↗
USGS2023

A call for strategic water-quality monitoring to advance assessment and prediction of wildfire impacts on water supplies

Wildfires pose a risk to water supplies in the western U.S. and many other parts of the world, due to the potential for degradation of water quality. However, a lack of adequate data hinders prediction and assessment of post-wildfire impacts and recovery. The dearth of such data is related to lack of funding for monitoring extreme events and the challenge of measuring the outsized hydrologic and erosive response after wildfire. Assessment and prediction of post-wildfire surface water quality would be strengthened by the strategic monitoring of key parameters, and the selection of sampling locations based on the following criteria: (1) streamgage with pre-wildfire data; (2) ability to install equipment that can measure water quality at high temporal resolution, with a focus on storm sampling; (3) minimum of 10% drainage area burned at moderate to high severity; (4) lack of major water management; (5) high-frequency precipitation; and (6) availability of pre-wildfire water-quality data and (or) water-quality data from a comparable unburned basin. Water-quality data focused on parameters that are critical to human and (or) ecosystem health, relevant to water-treatment processes and drinking-water quality, and (or) inform the role of precipitation and discharge on flow paths and water quality are most useful. We discuss strategic post-wildfire water-quality monitoring and identify opportunities for advancing assessment and prediction. Improved estimates of the magnitude, timing, and duration of post-wildfire effects on water quality would aid the water resources community prepare for and mitigate against impacts to water supplies.

Frontiers in Water↗
USGS2022

Environmentally persistent free radicals and other paramagnetic species in wildland-urban interface fire ashes

Wildland-urban interface (WUI) fires consume fuels, such as vegetation and structural materials, leaving behind ash composed primarily of pyrogenic carbon and metal oxides. However, there is currently limited understanding of the role of WUI fire ash from different sources as a source of paramagnetic species such as environmentally persistent free radicals (EPFRs) and transition metals in the environment. Electron paramagnetic resonance (EPR) was used to detect and quantify paramagnetic species, including organic persistent free radicals and transition metal spins, in fifty-three fire ash and soil samples collected following the North Complex Fire and the Sonoma-Lake-Napa Unit (LNU) Lightning Complex Fire, California, 2020. High concentrations of organic EPFRs ( e.g., 1.4 × 10 14 to 1.9 × 10 17 spins g −1 ) were detected in the studied WUI fire ash along with other paramagnetic species such as iron and manganese oxides, as well as Fe 3+ and Mn 2+ ions. The mean concentrations of EPFRs in various ash types decreased following the order: vegetation ash (1.1 × 10 17 ± 1.1 × 10 17 spins g −1 ) > structural ash (1.6 × 10 16 ± 3.7 × 10 16 spins g −1 ) > vehicle ash (6.4 × 10 15 ± 8.6 × 10 15 spins g −1 ) > soil (3.2 × 10 15 ± 3.7 × 10 15 spins g −1 ). The mean concentrations of EPFRs decreased with increased combustion completeness indicated by ash color; black (1.1 × 10 17 ± 1.1 × 10 17 spins g −1 ) > white (2.5 × 10 16 ± 4.4 × 10 16 spins g −1 ) > gray (1.8 × 10 16 ± 2.4 × 10 16 spins g −1 ). In contrast, the relative amounts of reduced Mn 2+ ions increased with increased combustion completeness. Thus, WUI fire ash is an important global source of EPFRs and reduced metal species ( e.g., Mn 2+ ). Further research is needed to underpin the formation, transformation, and environmental and human health impacts of these paramagnetic species in light of the projected increased frequency, size, and severity of WUI fires.

California↗
USGS2022

Discovery and potential ramifications of reduced iron-bearing nanoparticles — Magnetite, wüstite, and zero-valent iron — In wildland–urban interface fire ashes

The increase in fires at the wildland–urban interface has raised concerns about the potential environmental impact of ash remaining after burning. Here, we examined the concentrations and speciation of iron-bearing nanoparticles in wildland–urban interface ash. Total iron concentrations in ash varied between 4 and 66 mg g −1 . Synchrotron X-ray absorption near-edge structure (XANES) spectroscopy of bulk ash samples was used to quantify the relative abundance of major Fe phases, which were corroborated by transmission electron microscopy measurements. Maghemite (γ-(Fe 3+ ) 2 O 3 ) and magnetite (γ-Fe 2+ (Fe 3+ ) 2 O 4 ) were detected in most ashes and accounted for 0–90 and 0–81% of the spectral weight, respectively. Ferrihydrite (amorphous Fe( III )–hydroxide, (Fe 3+ ) 5 HO 8 ·4H 2 O), goethite (α-Fe 3+ OOH), and hematite (α-Fe 3+ 2 O 3 ) were identified less frequently in ashes than maghemite and magnetite and accounted for 0–65, 0–54, and 0–50% of spectral weight, respectively. Other iron phases identified in ashes include wüstite (Fe 2+ O), zerovalent iron, FeS, FeCl 2 , FeCl 3 , FeSO 4 , Fe 2 (SO 4 ) 3 , and Fe(NO 3 ) 3 . Our findings demonstrate the impact of fires at the wildland–urban interface on iron speciation; that is, fires can convert iron oxides ( e.g. , maghemite, hematite, and goethite) to reduced iron phases such as magnetite, wüstite, and zerovalent iron. Magnetite concentrations ( e.g. , up to 25 mg g −1 ) decreased from black to gray to white ashes. Based on transmission electron microscopy (TEM) analyses, most of the magnetite nanoparticles were less than 500 nm in size, although larger particles were identified. Magnetite nanoparticles have been linked to neurodegenerative diseases as well as climate change. This study provides important information for understanding the potential environmental impacts of fires at the wildland–urban interface, which are currently poorly understood.

Environmental Science Nano↗
USGS2021

Critical review of mercury methylation and methylmercury demethylation rate constants in aquatic sediments for biogeochemical modeling

Mercury is a toxin that causes neurological impairments in adults, is particularly harmful for fetuses and children, and is deadly in severe cases, making it a worldwide health concern. Methylmercury (MeHg) is the environmentally relevant form of mercury (Hg) because it biomagnifies along the food chain. Methylmercury is mainly produced in aquatic sediments via methylation of inorganic Hg (Hg(II)) and transformed back via demethylation. Because transformation rates determine MeHg concentrations, quantification of methylation and demethylation rates is needed to inform management of MeHg. Published rate constants for Hg(II) methylation ( 𝑘 𝑚 ) and MeHg demethylation ( 𝑘 𝑑 ) vary greatly, stemming partly from differences in experimental methods. We conducted a comprehensive review of rate laws, evaluated published rate constants, and performed biogeochemical simulations to assess variability in reported 𝑘 𝑚 and 𝑘 𝑑 . Based on selected studies employing the same pseudo-first-order rate law and similar experimental methods, we found that 𝑘 𝑚 = 0.04 ± 0.03 d −1 is a reasonable range for wetland sediments. Over a number of environments, maximum 𝑘 𝑑 was smaller at sites without Hg source ( 𝑘 𝑑 = 0.5 d −1 ) than at sites with identified Hg source ( 𝑘 𝑑 = 1.8 d −1 ). Larger variability and higher uncertainty in 𝑘 𝑑 compared to 𝑘 𝑚 highlight the need for more research on MeHg demethylation rates. This critical review: (a) aids the design of future experimental studies of 𝑘 𝑚 and 𝑘 𝑑 ; (b) provides guidance for comparing rate constants from different studies; (c) presents a biogeochemical reaction model to assess rate constants; and (d) informs selection of 𝑘 𝑚 and 𝑘 𝑑 values from the literature for use in model simulations.

Critical Reviews in Environmental Science and Tech↗
USGS2020

Formation and prevention of pipe scale from acid mine drainage at Iron Mountain and Leviathan Mines, California, USA

Pipelines carrying acid mine drainage (AMD) to treatment plants commonly form pipe scale, an Fe(III)-rich precipitate that forms inside the pipelines and requires periodic and costly cleanout and maintenance. Pipelines at Iron Mountain Mine (IMM) and Leviathan Mine (LM) in California carry acidic water from mine sources to a treatment plant and have developed pipe scale. Samples of scale and AMD were collected from both mine sites for mineralogical, microbiological, and chemical analysis. The scale mineralogy was primarily schwertmannite with minor amounts of poorly crystalline goethite. Although the bulk composition of the scale was similar along the length of the pipeline at IMM, the number of iron-oxidizing bacteria and concentrations of associated trace elements decreased along the flow-path inside the pipeline. Laboratory batch experiments with unfiltered AMD from IMM and LM showed that Fe(II) oxidation was driven by microbial activity when the pH was <5. A remediation strategy of decreasing the pH to <2.2 was tested through geochemical modeling and laboratory experiments. These experiments indicated that scale formation could be prevented by decreasing the pH, which could be achieved at IMM by mixing source waters. However, the presence of Fe(III)-rich scale in a pipeline buffers the pH to higher values that may affect the efficacy of this remedial approach.

California↗
USGS2020

PFHydro: A new watershed-scale model for post-fire runoff simulation

Runoff increases after wildfires that burn vegetation and create a condition of soil-water repellence (SWR). A new post-fire watershed hydrological model, PFHydro, was created to explicitly simulate vegetation interception and SWR effects for four burn severity categories: high, medium, low severity and unburned. The model was applied to simulate post-fire runoff from the Upper Cache Creek Watershed in California, USA. Nash–Sutcliffe modeling efficiency (NSE) was used to assess model performance. The NSE was 0.80 and 0.88 for pre-fire water years (WY) 2000 and 2015, respectively. NSE was 0.88 and 0.93 for WYs 2016 (first year post-fire) and 2017 respectively. The simulated percentage of surface runoff in total runoff of WY 2016 was about six times that of pre-fire WY 2000 and three times that of WY 2015. The modeling results suggest that SWR is an important factor for post-fire runoff generation. The model was successful at simulating SWR behavior.

California↗
USGS2020

Effects of montane watershed development on vulnerability of domestic groundwater supply during drought

Climate change is expected to reduce recharge to montane aquifers in the western United States, but it is unclear how this will impact groundwater resources in watersheds where intensive surface-water development has disrupted the natural hydrologic regime. To better understand sources of recharge and associated vulnerabilities of groundwater supply in this setting, we made a detailed geochemical survey of domestic wells finished in fractured bedrock throughout the Yuba and Bear River watersheds (Sierra Nevada foothills, northern California)during historic drought (2015–2016). Stable isotopes of water and noble gas recharge temperatures closely tracked atmospheric lapse rates across a broad elevation gradient (100–2000 m), indicating groundwater inputs are dominated by local precipitation that rapidly recharges fractured bedrock during the winter wet-season. However, nearly one-quarter of wells had water isotopes that were fractionated by evaporation and warm recharge temperatures, indicative of mixing with dry-season recharge by surface water. Monte Carlo mixing models suggest evaporation-impacted groundwater samples are mixtures of local rain with an average of 28% ± 13% from diverted surface water that can recharge bedrock aquifers during the dry-season by either irrigation return flow or seepage from extensive distribution infrastructure. Wells that received recharge subsidies from diverted surface water had elevated levels of nitrate and coliform bacteria compared to those replenished exclusively by local precipitation, which are more vulnerable to supply shortage during drought. It is important to consider the impacts of increased surface-water development on the quantity and quality of groundwater recharge in rapidly developing montane watersheds.

California↗
USGS2019

Quantifying erosion rates by using terrestrial laser scanning at Malakoff Diggins State Historic Park, Nevada County, California, 2014–17

The abandoned hydraulic mine pit at Malakoff Diggins near Grass Valley, California, can produce large volumes of eroded sediment transportable by storm runoff. Sediment-laden water discharged from the pit is a major source of heavy metals to Humbug Creek and the South Yuba River. To develop a comprehensive sediment budget for the Malakoff Diggins mine pit and identify sources of sediment and metals within the pit that can become entrained as suspended sediment in runoff discharged from the pit, the U.S. Geological Survey, working in cooperation with the California Department of Water Resources, the California Department of Parks and Recreation, and the Nevada Irrigation District, used terrestrial laser scanning technology to quantify eroded volumes and erosion rates of sedimentary units exposed in the pit walls. The results for eroded volumes and rates reported here are part one of a three-part study. High-resolution terrestrial laser scanning surveys were repeated annually from 2014 through 2017, including before and after dry and wet winters, measuring centimeter-scale topographic changes to quantify the volume of sediment eroded from outcrops at Malakoff Diggins State Historic Park, located on the western slope of the northern Sierra Nevada about 17 kilometers northeast of Grass Valley, California. Terrestrial laser scanning enabled construction of three-dimensional maps of the complex outcrop surfaces, which could not be mapped non-destructively or in sufficient detail with traditional surveying techniques. Eroded volumes from discrete sedimentary units were calculated at four study sites (numbered 1, 2, 4, and 5) throughout the mine pit for the December 2014 to August 2017 period. Eroded volumes at the four study sites during the 32-month study ranged from 288 plus or minus (±) 13 cubic meters (m 3 ) of sediment at site 1 to 8,517±145 m 3 at site 4. Annual erosion rates at the four study sites ranged from 0.06±0.01 cubic meters per square meter per year (m 3 /m 2 /yr) at site 4 to 0.14±0.01 m 3 /m 2 /yr at site 2. The total eroded volume documented with terrestrial laser scanning at all four study sites from December 2014 to August 2017 was 12,934±334 m 3 of sediment, and the average annual erosion rate for the four study sites was 0.10±0.04 m 3 /m 2 /yr. Horizontal erosional-change maps indicate that a variety of erosional processes were responsible for the eroded sediment volume. These included areally broad and smaller-scale processes such as persistent dry ravel, periodic sheet wash, and frost heave and more localized and larger-scale processes such as coalescing fluvial incision, rotational landslides, and translational block-fall failures.

California↗
USGS2019

Quantifying the eroded and deposited mass of mercury-contaminated sediment by using terrestrial laser scanning at the confluence of Humbug Creek and the South Yuba River, Nevada County, California, 2011–13

High-resolution, terrestrial laser scanning, also known as ground-based lidar (light detection and ranging), was used to quantify the volume of mercury-contaminated sediment eroded from an outcrop of historical placer-mining debris at the confluence of Humbug Creek and the South Yuba River in the Sierra Nevada foothills, about 17 kilometers northeast of Grass Valley, California, and delivered to a zone below an observed flood stage of the South Yuba River. Substantial quantities of mercury were used and lost to the environment from historical placer gold mining activities on the western slope of the Sierra Nevada, California, and recent studies have documented continued persistence of mercury and methylmercury concentrations in water, sediment, fish, and predatory invertebrates in the Yuba River drainage basin in relation to suspected mercury sources. To identify areas that have high levels of mercury contamination as possible remediation targets in the Yuba River drainage basin and other areas in the Sierra Nevada, the U.S. Geological Survey worked in cooperation with the Bureau of Land Management on this and other detailed studies. Malakoff Diggings, one of the largest hydraulic gold mines in the Sierra Nevada, is 3.5 kilometers north of the study site in the Humbug Creek subbasin. Terrestrial laser scanning was used to produce centimeter-scale, three-dimensional maps of the complex outcrop surface, which was composed of an upper erosional area (cliff and over-steepened slope) and a lower depositional area (colluvial slope). The outcrop could not be mapped non-destructively or in sufficient detail by traditional surveying techniques. The study site, which was approximately 70 meters long, 30 meters wide and 20 meters high, was surveyed four times in 2 years (December 15, 2011; October 25, 2012; January 4, 2013; and November 22, 2013) to determine volumetric differences in the upper erosional and lower depositional areas between surveys. Measured changes in volume for the upper erosional area and lower depositional area were multiplied by the corresponding sediment density so that a mass-balance relationship, between the eroded and deposited sediment during each period, could be used to estimate the amount of mercury-contaminated sediment that was transported to below the base of the colluvial slope, where it could be mobilized by the South Yuba River during a flood having a 5-to-10-year recurrence interval. On December 2, 2012, a flood of this estimated magnitude reached the base of the colluvial slope. Between the first and second surveys (December 15, 2011–October 25, 2012), an estimated mass of 18±9.2 kilograms of sediment was transported from steeper slopes to the gently sloping river bank below the base of the colluvial slope. Between the second and third surveys (October 25, 2012–January 4, 2013), an atmospheric river caused heavy precipitation at the study site during late November and early December 2012. This short-duration, high-intensity rain resulted in a large amount of erosion and deposition at the study site and also caused high streamflow (flood stage) in the South Yuba River. From October 2012 to January 2013, 51±31 kilograms of sediment was transported to below the base of the colluvial slope, that is, below the high-water mark of December 2, 2012. Between the third and fourth surveys (January 4, 2013–November 22, 2013), an additional 10±26 kilograms of sediment was transported to below the base of the colluvial slope. During the 24 months of the study, the total mass of sediment delivered below the base of the colluvial slope and the high-water mark of December 2, 2012, was 79±66 kilograms. In any given year there is a 10–20-percent chance (5-to-10-year recurrence interval) of a flood equal to or greater than that of the December 2, 2012, flood, which could transport mercury-contaminated sediment at the study site into the South Yuba River. Hydraulically modeled estimates of the South Yuba River stage during floods having a 50- and 100-year recurrence interval (2- and 1-percent annual exceedance probability, respectively) indicated that resulting river stages could be 2.2–3.0 meters above the base of the colluvial slope, or 2.2–3.0 meters above the high-water mark of December 2, 2012. Such high river stages would be likely to inundate the lower half of the colluvial slope and mobilize a substantial volume of mercury-contaminated sediment to downstream areas.

California↗
USGS2018

Geochemical data for water, streambed sediment, and fish tissue from the Sierra Nevada Mercury Impairment Project, 2011–12

This report presents geochemical data for surface water, streambed sediment, and fish tissue samples collected during low-flow conditions in 20 to 24 Sierra Nevada streams during 2011 and 2012. The dataset is part of a larger study designed to assess the factors that control mercury concentrations in fish tissue and to develop a model that predicts mercury concentration in the tissue of selected fish species in Sierra Nevada streams. The ranges of total mercury concentration observed in different matrices of water and sediment from 24 locations were as follows: below detection to 0.86 nanograms per liter in filtered water, below detection to 4.06 nanograms per liter in suspended particulates (greater than 0.3 micrometer in diameter), 1.1 to 381 nanograms per gram in bed sediment less than 2 millimeters, and 28.1 to 1,410 nanograms per gram in bed sediment less than 0.063 millimeters. The ratio of monomethyl mercury to total mercury ranged as follows: below detection to 19.2 percent in filtered water, below detection to 51.7 percent in suspended particles (greater than 0.3 micrometer), and below detection to 7.6 percent in streambed sediment less than 2 millimeters. Fish from 3 species collected at 20 locations had the following range in total mercury concentration (all concentrations wet weight): 10 to 292 nanograms per gram in rainbow trout (293 fish, 19 locations), 13 to 386 nanograms per gram in brown trout (33 fish, 10 locations), and 159 nanograms per gram in hardhead (1 fish). Concentrations of selenium in fish (wet weight) ranged from 60 to 420 nanograms per gram in rainbow trout (66 fish, 19 locations) and from 180 to 240 nanograms per gram in brown trout (6 fish, 2 locations).

Sierra Nevada↗
USGS2017

Geochemistry of mercury and other constituents in subsurface sediment—Analyses from 2011 and 2012 coring campaigns, Cache Creek Settling Basin, Yolo County, California

Cache Creek Settling Basin was constructed in 1937 to trap sediment from Cache Creek before delivery to the Yolo Bypass, a flood conveyance for the Sacramento River system that is tributary to the Sacramento–San Joaquin Delta. Sediment management options being considered by stakeholders in the Cache Creek Settling Basin include sediment excavation; however, that could expose sediments containing elevated mercury concentrations from historical mercury mining in the watershed. In cooperation with the California Department of Water Resources, the U.S. Geological Survey undertook sediment coring campaigns in 2011–12 (1) to describe lateral and vertical distributions of mercury concentrations in deposits of sediment in the Cache Creek Settling Basin and (2) to improve constraint of estimates of the rate of sediment deposition in the basin. Sediment cores were collected in the Cache Creek Settling Basin, Yolo County, California, during October 2011 at 10 locations and during August 2012 at 5 other locations. Total core depths ranged from approximately 4.6 to 13.7 meters (15 to 45 feet), with penetration to about 9.1 meters (30 feet) at most locations. Unsplit cores were logged for two geophysical parameters (gamma bulk density and magnetic susceptibility); then, selected cores were split lengthwise. One half of each core was then photographed and archived, and the other half was subsampled. Initial subsamples from the cores (20-centimeter composite samples from five predetermined depths in each profile) were analyzed for total mercury, methylmercury, total reduced sulfur, iron speciation, organic content (as the percentage of weight loss on ignition), and grain-size distribution. Detailed follow-up subsampling (3-centimeter intervals) was done at six locations along an east-west transect in the southern part of the Cache Creek Settling Basin and at one location in the northern part of the basin for analyses of total mercury; organic content; and cesium-137, which was used for dating. This report documents site characteristics; field and laboratory methods; and results of the analyses of each core section and subsample of these sediment cores, including associated quality-assurance and quality-control data.

California↗
USGS2017

Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California↗