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Chao Yang

Publications and source records attributed to Chao Yang.

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Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin

Geology and undiscovered resource assessment of the potash-bearing Pripyat and Dnieper-Donets Basins, Belarus and Ukraine

Undiscovered potash resources in the Pripyat Basin, Belarus, and Dnieper-Donets Basin, Ukraine, were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The Pripyat Basin (in Belarus) and the Dnieper-Donets Basin (in Ukraine and southern Belarus) host stratabound and halokinetic Upper Devonian (Frasnian and Famennian) and Permian (Cisuralian) potash-bearing salt. The evaporite basins formed in the Donbass-Pripyat Rift, a Neoproterozoic continental rift structure that was reactivated during the Late Devonian and was flooded by seawater. Though the rift was divided, in part by volcanic deposits, into the separate Pripyat and Dnieper-Donets Basins, both basins contain similar potash‑bearing evaporite sequences. An Early Permian (Cisuralian) sag basin formed over the rift structure and was also inundated by seawater resulting in another sequence of evaporite deposition. Halokinetic activity initiated by basement faulting during the Devonian continued at least into the Permian and influenced potash salt deposition and structural evolution of potash-bearing salt in both basins. Within these basins, four areas (permissive tracts) that permit the presence of undiscovered potash deposits were defined by using geological criteria. Three tracts are permissive for stratabound potash-bearing deposits and include Famennian (Upper Devonian) salt in the Pripyat Basin, and Famennian and Cisuralian (lower Permian) salt in the Dnieper-Donets Basin. In addition, a tract was delineated for halokinetic potash-bearing Famennian salt in the Dnieper-Donets Basin. The Pripyat Basin is the third largest source of potash in the world, producing 6.4 million metric tons of potassium chloride (KCl) (the equivalent of about 4.0 million metric tons of potassium oxide or K 2 O) in 2012. Potash production began in 1963 in the Starobin #1 mine, near the town of Starobin, Belarus, in the northwestern corner of the basin. Potash is currently produced from six potash mines in the Starobin area. Published reserves in the Pripyat Basin area are about 7.3 billion metric tons of potash ore (about 1.3 billion metric tons of K 2 O) mostly from potash-bearing salt horizons in the Starobin and Petrikov mine areas. The 15,160-square-kilometer area of the Pripyat Basin underlain by Famennian potash-bearing salt contains as many as 60 known potash-bearing salt horizons. Rough estimates of the total mineral endowment associated with stratabound Famennian salt horizons in the Pripyat Basin range from 80 to 200 billion metric tons of potash-bearing salt that could contain 15 to 30 billion metric tons of K 2 O. Parameters (including the number of economic potash horizons, grades, and depths) for these estimates are not published so the estimates are not easily confirmed. Historically, reserves have been estimated above a depth of 1,200 meters (m) (approximately the depths of conventional underground mining). Additional undiscovered K 2 O resources could be significantly greater in the remainder of the Fammenian salt depending on the extents and grades of the 60 identified potash horizons above the USGS assessment depth of 3,000 m in the remainder of the tract. Increasing ambient temperatures with increasing depths in the eastern parts of the Pripyat Basin may require a solution mining process which is aided by higher temperatures. No resource or reserve data have been published and little is known about stratabound Famennian and Frasnian salt in the Dnieper-Donets Basin. These Upper Devonian salt units dip to the southeast and extend to depths of 15–19 kilometers (km) or greater. The tract of stratabound Famennian salt that lies above a depth of 3 km, the depth above which potash is technically recoverable by solution mining, underlies an area of about 15,600 square kilometers (km 2 ). If Upper Devonian salt units in the Dnieper-Donets Basin contain potash-bearing strata similar to salt of the same age in the Pripyat Basin, then the stratabound Famennian tract in the Dnieper-Donets Basin could contain significant undiscovered potash resources. The Cisuralian evaporite sequence in the Dnieper-Donets Basin consists of 10 evaporite cycles with the upper 3 cycles containing potash-bearing salt (mainly as sylvite and carnallite) in several subbasins and polyhalite in the sulfate bearing parts of the identified tract. The area of the Cisuralian tract is 62,700 km 2 . Potash-bearing cycles are as much as 40 m thick. One subbasin is reported to contain 794 million metric tons of “raw or crude” potash-bearing salt which could contain 50 to 150 million metric tons of K 2 O, depending on the grade. Undiscovered potash resources in the remainder of this permissive tract may be significantly greater. Depths to the Permian salt range from less than 100 to about 1,500 m. Undiscovered resources of halokinetic potash-bearing salt in the Dnieper-Donets Basin were assessed quantitatively for this study by using the standard USGS three-part form of mineral resource assessment (Singer, 2007a; Singer and Menzie, 2010). Delineation of the permissive tract was based on distributions of mapped halokinetic salt structures. This tract contains at least 248 diapiric salt structures with a total area of 7,840 km 2 that occupies approximately 8 percent of the basin area. The vertical extent of these salt structures is hundreds of meters to several kilometers. This assessment estimated that a total mean of 11 undiscovered deposits contain an arithmetic mean estimate of about 840 million metric tons of K 2 O in the halokinetic salt structures of the Dnieper-Donets Basin for which the probabilistic estimate was made.

Dnieper-Donets Basin, Pripyat Basin

Potash: a global overview of evaporate-related potash resources, including spatial databases of deposits, occurrences, and permissive tracts

Potash is mined worldwide to provide potassium, an essential nutrient for food crops. Evaporite-hosted potash deposits are the largest source of salts that contain potassium in water-soluble form, including potassium chloride, potassium-magnesium chloride, potassium sulfate, and potassium nitrate. Thick sections of evaporitic salt that form laterally continuous strata in sedimentary evaporite basins are the most common host for stratabound and halokinetic potash-bearing salt deposits. Potash-bearing basins may host tens of millions to more than 100 billion metric tons of potassium oxide (K 2 O). Examples of these deposits include those in the Elk Point Basin in Canada, the Pripyat Basin in Belarus, the Solikamsk Basin in Russia, and the Zechstein Basin in Germany. This report describes a global, evaporite-related potash deposits and occurrences database and a potash tracts database. Chapter 1 summarizes potash resource history and use. Chapter 2 describes a global potash deposits and occurrences database, which contains more than 900 site records. Chapter 3 describes a potash tracts database, which contains 84 tracts with geology permissive for the presence of evaporite-hosted potash resources, including areas with active evaporite-related potash production, areas with known mineralization that has not been quantified or exploited, and areas with potential for undiscovered potash resources. Chapter 4 describes geographic information system (GIS) data files that include (1) potash deposits and occurrences data, (2) potash tract data, (3) reference databases for potash deposit and tract data, and (4) representative graphics of geologic features related to potash tracts and deposits. Summary descriptive models for stratabound potash-bearing salt and halokinetic potash-bearing salt are included in appendixes A and B, respectively. A glossary of salt- and potash-related terms is contained in appendix C and a list of database abbreviations is given in appendix D. Appendix E describes GIS data files, and appendix F is a guide to using the geodatabase.

Scientific Investigations Report