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Celia Zamora

Publications and source records attributed to Celia Zamora.

11 recordsLinked to original sources
USGS2017

A hybrid machine learning model to predict and visualize nitrate concentration throughout the Central Valley aquifer, California, USA

Intense demand for water in the Central Valley of California and related increases in groundwater nitrate concentration threaten the sustainability of the groundwater resource. To assess contamination risk in the region, we developed a hybrid, non-linear, machine learning model within a statistical learning framework to predict nitrate contamination of groundwater to depths of approximately 500 m below ground surface. A database of 145 predictor variables representing well characteristics, historical and current field and landscape-scale nitrogen mass balances, historical and current land use, oxidation/reduction conditions, groundwater flow, climate, soil characteristics, depth to groundwater, and groundwater age were assigned to over 6000 private supply and public supply wells measured previously for nitrate and located throughout the study area. The boosted regression tree (BRT) method was used to screen and rank variables to predict nitrate concentration at the depths of domestic and public well supplies. The novel approach included as predictor variables outputs from existing physically based models of the Central Valley. The top five most important predictor variables included two oxidation/reduction variables (probability of manganese concentration to exceed 50 ppb and probability of dissolved oxygen concentration to be below 0.5 ppm), field-scale adjusted unsaturated zone nitrogen input for the 1975 time period, average difference between precipitation and evapotranspiration during the years 1971–2000, and 1992 total landscape nitrogen input. Twenty-five variables were selected for the final model for log-transformed nitrate. In general, increasing probability of anoxic conditions and increasing precipitation relative to potential evapotranspiration had a corresponding decrease in nitrate concentration predictions. Conversely, increasing 1975 unsaturated zone nitrogen leaching flux and 1992 total landscape nitrogen input had an increasing relative impact on nitrate predictions. Three-dimensional visualization indicates that nitrate predictions depend on the probability of anoxic conditions and other factors, and that nitrate predictions generally decreased with increasing groundwater age.

California↗
USGS2014

Documentation of a groundwater flow model (SJRRPGW) for the San Joaquin River Restoration Program study area, California

To better understand the potential effects of restoration flows on existing drainage problems, anticipated as a result of the San Joaquin River Restoration Program (SJRRP), the U.S. Geological Survey (USGS), in cooperation with the U.S. Bureau of Reclamation (Reclamation), developed a groundwater flow model (SJRRPGW) of the SJRRP study area that is within 5 miles of the San Joaquin River and adjacent bypass system from Friant Dam to the Merced River. The primary goal of the SJRRP is to reestablish the natural ecology of the river to a degree that restores salmon and other fish populations. Increased flows in the river, particularly during the spring salmon run, are a key component of the restoration effort. A potential consequence of these increased river flows is the exacerbation of existing irrigation drainage problems along a section of the river between Mendota and the confluence with the Merced River. Historically, this reach typically was underlain by a water table within 10 feet of the land surface, thus requiring careful irrigation management and (or) artificial drainage to maintain crop health. The SJRRPGW is designed to meet the short-term needs of the SJRRP; future versions of the model may incorporate potential enhancements, several of which are identified in this report. The SJRRPGW was constructed using the USGS groundwater flow model MODFLOW and was built on the framework of the USGS Central Valley Hydrologic Model (CVHM) within which the SJRRPGW model domain is embedded. The Farm Process (FMP2) was used to simulate the supply and demand components of irrigated agriculture. The Streamflow-Routing Package (SFR2) was used to simulate the streams and bypasses and their interaction with the aquifer system. The 1,300-square mile study area was subdivided into 0.25-mile by 0.25-mile cells. The sediment texture of the aquifer system, which was used to distribute hydraulic properties by model cell, was refined from that used in the CVHM to better represent the natural heterogeneity of aquifer-system materials within the model domain. In addition, the stream properties were updated from the CVHM to better simulate stream-aquifer interactions, and water-budget subregions were refined to better simulate agricultural water supply and demand. External boundary conditions were derived from the CVHM. The SJRRPGW was calibrated for April 1961 to September 2003 by using groundwater-level observations from 133 wells and streamflow observations from 19 streamgages. The model was calibrated using public-domain parameter estimation software (PEST) in a semi-automated manner. The simulated groundwater-level elevations and trends (including seasonal fluctuations) and surface-water flow magnitudes and trends reasonably matched observed data. The calibrated model is planned to be used to assess the potential effects of restoration flows on agricultural lands and the relative capabilities of proposed SJRRP actions to reduce these effects.

California↗
USGS2013

Methods, quality assurance, and data for assessing atmospheric deposition of pesticides in the Central Valley of California

The U.S. Geological Survey monitored atmospheric deposition of pesticides in the Central Valley of California during two studies in 2001 and 2002–04. The 2001 study sampled wet deposition (rain) and storm-drain runoff in the Modesto, California, area during the orchard dormant-spray season to examine the contribution of pesticide concentrations to storm runoff from rainfall. In the 2002–04 study, the number and extent of collection sites in the Central Valley were increased to determine the areal distribution of organophosphate insecticides and other pesticides, and also five more sample types were collected. These were dry deposition, bulk deposition, and three sample types collected from a soil box: aqueous phase in runoff, suspended sediment in runoff, and surficial-soil samples. This report provides concentration data and describes methods and quality assurance of sample collection and laboratory analysis for pesticide compounds in all samples collected from 16 sites. Each sample was analyzed for 41 currently used pesticides and 23 pesticide degradates, including oxygen analogs (oxons) of 9 organophosphate insecticides. Analytical results are presented by sample type and study period. The median concentrations of both chloryprifos and diazinon sampled at four urban (0.067 micrograms per liter [μg/L] and 0.515 μg/L, respectively) and four agricultural sites (0.079 μg/L and 0.583 μg/L, respectively) during a January 2001 storm event in and around Modesto, Calif., were nearly identical, indicating that the overall atmospheric burden in the region appeared to be fairly similar during the sampling event. Comparisons of median concentrations in the rainfall to those in the McHenry storm-drain runoff showed that, for some compounds, rainfall contributed a substantial percentage of the concentration in the runoff; for other compounds, the concentrations in rainfall were much greater than in the runoff. For example, diazinon concentrations in rainfall were about 70 percent of the diazinon concentration in the runoff, whereas the chlorpyrifos concentration in the rain was 1.8 times greater than in the runoff. The more water-soluble pesticides—carbaryl, metolachlor, napropamide, and simazine—followed the same pattern as diazinon and had lower concentrations in rain compared to runoff. Similar to chlorpyrifos,compounds with low water solubilities and higher soil-organic carbon partition coefficients, including dacthal, pendimethalin, and trifluralin, were found to have higher concentrations in rain than in runoff water and were presumed to partition to the suspended sediments and organic matter on the ground. During the 2002–04 study period, the herbicide dacthal had the highest detection frequencies for all sample types collected from the Central Valley sites (67–100 percent). The most frequently detected compounds in the wet-deposition samples were dacthal, diazinon, chlorpyrifos, and simazine (greater than 90 percent). The median wet-deposition amounts for these compounds were 0.044 micrograms per square meter per day (μg/m 2 /day), 0.209 μg/m 2 /day, 0.079 μg/m 2 /day, and 0.172 μg/m 2 /day, respectively. For the dry-deposition samples, detection frequencies were greater than 73 percent for the compounds dacthal, metolachor, and chlorpyrifos, and median deposition amounts were an order of magnitude less than for wet deposition. The differences between wet deposition and dry deposition appeared to be closely related to the Henry’s Law (H) constant of each compound, although the mass deposited by dry deposition takes place over a much longer time frame. Pesticides detected in rainfall usually were detected in the aqueous phase of the soil-box runoff water, and the runoff concentrations were generally similar to those in the rainfall. For compounds detected in the aqueous phase and suspended-sediment samples of soil-box runoff, concentrations of pesticides in the aqueous phase generally were detected in low concentrations and had few corresponding detections in the suspended- sediment samples. Dacthal, diazinon, chlorpyrifos, and simazine were the most frequently detected pesticides (greater than 83 percent) in the aqueous-phase samples, with median concentrations of 0.010 μg/L, 0.045 μg/L, 0.016 μg/L, and 0.077 μg/L, respectively. Simazine was the most frequently detected compound in the suspended-sediment samples (69 percent), with a median concentration of 0.232 μg/L. Results for compounds detected in the surficial-soil samples collected throughout the study period showed that there was an increase in concentration for some compounds, indicating atmospheric deposition of these compounds onto the soil-box surface. In the San Joaquin Valley, the compounds chlorpyrifos, dacthal, and iprodione were detected at higher concentrations (between 1.4 and 2 times greater) than were found in the background samples collected from the San Joaquin Valley soil-box sites. In the Sacramento Valley, the compounds chlorpyrifos, dacthal, iprodione, parathionmethyl, and its oxygen analog, paraoxon-methyl, were detected in samples collected during the study period in low concentrations, but were not detected in the background concentration of the Sacramento Valley soil mix.

California↗
USGS2013

Groundwater contributions of flow, nitrate, and dissolved organic carbon to the lower San Joaquin River, California, 2006-08

The influence of groundwater on surface-water quality in the San Joaquin River, California, was examined for a 59-mile reach from the confluence with Salt Slough to Vernalis. The primary objective of this study was to quantify the rate of groundwater discharged to the lower San Joaquin River and the contribution of nitrate and dissolved organic carbon concentrations to the river. Multiple lines of evidence from four independent approaches were used to characterize groundwater contributions of nitrogen and dissolved organic carbon. Monitoring wells (in-stream and bank wells), streambed synoptic surveys (stream water and shallow groundwater), longitudinal profile surveys by boat (continuous water-quality parameters in the stream), and modeling (MODFLOW and VS2DH) provided a combination of temporal, spatial, quantitative, and qualitative evidence of groundwater contributions to the river and the associated quality. Monitoring wells in nested clusters in the streambed (in-stream wells) and on both banks (bank wells) along the river were monitored monthly from September 2006 to January 2009. Nitrate concentrations in the bank wells ranged from less than detection—that is, less than 0.01 milligrams per liter (mg/L) as nitrogen (N)—to approximately 13 mg/L as N. Nitrate was not detected at 17 of 26 monitoring wells during the study period. Dissolved organic carbon concentrations among monitoring wells were highly variable, but they generally ranged from 1 to 4 mg/L. In a previous study, 14 bank wells were sampled once in 1988 following their original installation. With few exceptions, specific conductivity and nitrate concentrations measured in this study were virtually identical to those measured 20 years ago. Streambed synoptic measurements were made by using a temporarily installed drive-point piezometer at 113 distinct transects across the stream during 4 sampling events. Nitrate concentrations exceeded the detection limit of 0.01 mg/L as N in 5 percent of groundwater samples collected from the in-stream wells as part of the synoptic surveys. Only 7 of the 113 cross-sectional transects had nitrate concentrations greater than 1 mg/L as N. In contrast, surface waters in the San Joaquin River tended to have nitrate concentrations in the 1–3 mg/L as N range. A zone of lower oxygen (less than 2 mg/L) in the streambed could limit nitrate contributions from regional groundwater flow because nitrate can be converted to nitrogen gas within this zone. Appreciable concentrations of ammonium (average concentration was 1.92 mg/L as N, and 95th percentile was 10.34 mg/L as N) in the shallow groundwater, believed to originate from anoxic mineralization of streambed sediments, could contribute nitrogen to the overlying stream as nitrate following in-stream nitrification, however. Dissolved organic carbon concentrations were highly variable in the shallow groundwater below the river (1 to 6 ft below streambed) and generally ranged between 1 and 5 mg/L, but had maximum concentrations in the 15–25 mg/L range. The longitudinal profile surveys were not particularly useful in identifying groundwater discharge areas. However, the longitudinal approach described in this report was useful as a baseline survey of measured water-quality parameters and for identifying tributary inflows that affect surface-water concentrations of nitrate. Results of the calibrated MODFLOW model indicated that the simulated groundwater discharge rate was approximately 1.0 cubic foot per second per mile (cfs/mi), and the predominant horizontal groundwater flow direction between the deep bank wells was westward beneath the river. The modeled (VS2DH) flux values (river gain versus river loss) were calculated for the irrigation and non-irrigation season, and these fluxes were an order of magnitude less than those from MODFLOW. During the irrigation season, the average river gain was 0.11 cfs/mi, and the average river loss was −0.05 cfs/mi. During the non-irrigation season, the average river gain was 0.10 cfs/mi, and the average river loss was -0.08 cfs/mi. Information on groundwater interactions and water quality collected for this study was used to estimate loads of nitrate and dissolved organic carbon from the groundwater to the San Joaquin River. Estimated loads of dissolved inorganic nitrogen and dissolved organic carbon were calculated by using concentrations measured during four streambed synoptic surveys and the estimated groundwater discharge rate to the San Joaquin River from MODFLOW of 1 cfs/mi. The estimated groundwater loads to the San Joaquin River for dissolved inorganic nitrogen and dissolved organic carbon were 300 and 350 kilograms per day, respectively. These loads represent 9 and 7 percent, respectively, of the estimated instantaneous surface-water loads for dissolved inorganic nitrogen and dissolved organic carbon at the most downstream site, Vernalis, measured during the four streambed synoptic surveys.

California↗
USGS2008

Estimating Water Fluxes Across the Sediment-Water Interface in the Lower Merced River, California

The lower Merced River Basin was chosen by the U.S. Geological Survey?s (USGS) National Water Quality Assessment Program (NAWQA) to be included in a national study on how hydrological processes and agricultural practices interact to affect the transport and fate of agricultural chemicals. As part of this effort, surface-water?ground-water (sw?gw) interactions were studied in an instrumented 100-m reach on the lower Merced River. This study focused on estimating vertical rates of exchange across the sediment?water interface by direct measurement using seepage meters and by using temperature as a tracer coupled with numerical modeling. Temperature loggers and pressure transducers were placed in monitoring wells within the streambed and in the river to continuously monitor temperature and hydraulic head every 15 minutes from March 2004 to October 2005. One-dimensional modeling of heat and water flow was used to interpret the temperature and head observations and deduce the sw?gw fluxes using the USGS numerical model, VS2DH, which simulates variably saturated water flow and solves the energy transport equation. Results of the modeling effort indicate that the Merced River at the study reach is generally a slightly gaining stream with small head differences (cm) between the surface water and ground water, with flow reversals occurring during high streamflow events. The average vertical flux across the sediment?water interface was 0.4?2.2 cm/day, and the range of hydraulic conductivities was 1?10 m/day. Seepage meters generally failed to provide accurate data in this high-energy system because of slow seepage rates and a moving streambed resulting in scour or burial of the seepage meters. Estimates of streambed hydraulic conductivity were also made using grain-size analysis and slug tests. Estimated hydraulic conductivity for the upstream transect determined using slug tests ranged from 40 to 250 m/day, whereas the downstream transect ranged from 10 to 100 m/day. The range in variability was a result of position along each transect. A relative percent difference was used to describe the variability in estimates of hydraulic conductivity by grain-size analysis and slug test. Variability in applied methods at the upstream transect ranged from 0 to 9 percent, whereas the downstream transect showed greater variability, with a range of 80 to 133 percent.

Scientific Investigations Report↗
USGS2006

Assessment of hydrologic and water quality data collected in Abbotts Lagoon watershed, Point Reyes National Seashore, California, during water years 1999 and 2000

Abbotts Lagoon is part of Point Reyes National Seashore, located about 40 miles northwest of San Francisco and about 20 miles south of Bodega Bay. Water-quality samples were collected quarterly during water year 1999 at a site in each of three connected lagoons that make up Abbotts Lagoon and at a site in its most significant tributary. The quarterly samples were analyzed for major ions, nutrients, and chlorophyll-a. A bed-sediment sample was collected in each lagoon during August 1999 and was analyzed for organic carbon, iron, and total phosphorus. Seven tributaries were sampled during a February 1999 storm and four during an April 1999 storm. These samples were analyzed only for nutrients. One storm sample collected in April 1999 from a tributary downstream of the I Ranch dairy was analyzed for a suite of 47 compounds indicative of wastewater. Continuous water-level recorders were installed in the most significant tributary and the two largest lagoons for portions of the study. A water budget analysis for an April 2000 storm indicated that the main tributary accounted for 85 percent of surface inflows to Abbotts Lagoon. The portion of the surface inflow from the main tributary was lower in the February 1999 storms and is a function of upstream storage and vegetative growth in the tributary basins. Another water budget analysis for a period of no surface inflow (June and July 2000) indicated that the net ground-water contribution was an outflow (seepage) from Abbotts Lagoon of about 0.3 ft3/s. Salinity increased and nutrient concentrations decreased from upstream to downstream in the chain of lagoons. The lower lagoon, nearest the ocean, had less organic carbon and total phosphorus in the bed sediment than the upper lagoons. The two tributaries originating in the I Ranch dairy had the highest concentrations of nutrients in storm runoff, and the highest loading rates and yields of ammonia and phosphorus. These tributaries account for only 10.3 percent of the area drained by the sampled tributaries, but contributed 83 percent of the ammonia load and 79 percent of the orthophosphate load. The basins with the highest nutrient loading rates and yields had the highest percentage of dairy and (or) ranching impacted land use and, to a lesser extent, grazing land use. The ratios of inorganic nitrogen to phosphorus in the lagoons ranged from 0.1 to 9.5 in the upper lagoon, 0.10 to 0.15 in the middle lagoon, and 0.05 to 0.10 in the lower lagoon. Thus, there is an abundance of phosphorus in the lagoons, and nitrogen appears to be limiting the growth of phytoplankton. Two sterols indicative of fecal material were among 11 compounds detected in the sample collected for analysis of wastewater indicators from a tributary downstream of the I Ranch dairy.

California↗
USGS2004

Occurrence, Distribution, Instantaneous Loads, and Yields of Dissolved Pesticides in the San Joaquin River Basin, California, During Summer Conditions, 1994 and 2001

Water samples were collected from 22 drainage basins for analysis of 48 dissolved pesticides during summer flow conditions in 1994 and 2001. Of the 48 pesticides, 31 were reported applied in the basin in the 28 days preceding the June 1994 sampling, 25 in the 28 days preceding the June 2001 sampling, and 24 in the 28 days preceding the August 2001 sampling. The number of dissolved pesticides detected was similar among sampling periods: 26 were detected in June 1994, 28 in June 2001, and 27 in August 2001. Concentrations of chlorpyrifos exceeded the California criterion for the protection of aquatic life from acute exposure at six sites in June 1994 and at five sites in June 2001. There was a single exceedance of the criterion for diazinon in June 1994. The number of pesticides applied in tributary basins was highly correlated with basin area during each sampling period (Spearman's r = 0.85, 0.70, and 0.84 in June 1994, June 2001, and August 2001, respectively, and p < 0.01 in all cases). Larger areas likely include a wider variety of crops, resulting in more varied pesticide use. Jaccard's similarities, cluster analysis, principal components analysis, and instantaneous load calculations generally indicate that west-side tributary basins were different from east-side tributary basins. In general, west-side basins had higher concentrations, instantaneous loads, and instantaneous yields of dissolved pesticides than east-side basins, although there were a number of exceptions. These differences may be related to a number of factors, including differences in basin size, soil texture, land use, irrigation practices, and stream discharge.

Scientific Investigations Report↗
USGS2004

Sources and Transport of Nutrients, Organic Carbon, and Chlorophyll-a in the San Joaquin River Upstream of Vernalis, California, during Summer and Fall, 2000 and 2001

Oxidizable materials from the San Joaquin River upstream of Vernalis can contribute to low dissolved oxygen episodes in the Stockton Deep Water Ship Channel that can inhibit salmon migration in the fall. The U.S. Geological Survey collected and analyzed samples at four San Joaquin River sites in July through October 2000 and June through November 2001, and at eight tributary sites in 2001. The data from these sites were supplemented with data from samples collected and analyzed by the University of California at Davis at three San Joaquin River sites and eight tributary sites as part of a separate study. Streamflows in the San Joaquin River were slightly above the long-term average in 2000 and slightly below average in 2001. Nitrate loads at Vernalis in 2000 were above the long-term average, whereas loads in 2001 were close to average. Total nitrogen loads in 2000 were slightly above average, whereas loads in 2001 were slightly below average. Total phosphorus loads in 2000 and 2001 were well below average. These nutrient loads correspond with the flow-adjusted concentration trends--nitrate concentrations significantly increased since 1972 (p < 0.01), whereas total nitrogen and total phosphorus concentrations did not (p > 0.05). Loading rates of nutrients and dissolved organic carbon increased in the San Joaquin River in the fall with the release of wetland drainage into Mud Slough and with increased reservoir releases on the Merced River. During August 2000 and September 2001, the chlorophyll-a loading rates and concentrations in the San Joaquin River declined and remained low during the rest of the sampling period. The most significant tributary sources of nutrients were the Tuolumne River, Harding Drain, and Mud Slough. The most significant tributary sources of dissolved organic carbon were Salt Slough, Mud Slough, and the Tuolumne and Stanislaus Rivers. Compared with nutrients and dissolved organic carbon, the tributaries were minor sources of chlorophyll-a, suggesting that most of the chlorophyll-a was produced in the San Joaquin River rather than its tributaries. On the basis of the carbon-to-nitrogen ratios and the d13C of particulate organic matter in the San Joaquin River and tributaries, the particulate organic matter in the river was mostly phytoplankton. On the basis of the d15N values of the particulate organic matter, and of total dissolved nitrogen and nitrate, the nitrate in the San Joaquin River probably was a significant nutrient source for the phytoplankton. The range of d15N and d18O values of nitrate in the San Joaquin River and tributaries suggest that animal waste or sewage was a significant source of nitrate in the river at the time the samples were collected.

Water-Resources Investigations Report↗
USGS2003

Selenium and sediment loads in storm runoff in Panoche Creek, California, February 1998

Five to nine samples were collected per storm throughout the hydrograph of four storms in February 1998 from Panoche Creek at Interstate 5, California. The rainfall total of 10.40 inches for the month was greater than any other month during 1957 to 2000, and peak streamflows on February 3 and 7 exceeded the previous peak streamflow of record. Concentrations of suspended sediment, which were highly variable during the storms, ranged from 32,900 to 251,000 mg/L (milligram per liter) with a median of 126,000 mg/L. Dissolved selenium concentrations in the storm samples ranged from 16 to 60 μg/L (microgram per liter), with a median of 30 μg/L. These concentrations were considerably higher during the first storm than during subsequent storms. Total selenium concentrations in the storm samples ranged from 57 to 320 μg/L, with a median of 115 μg/L. Total selenium in four replicate and four rerun samples was highly variable (relative percent differences ranged from 0 to 57 percent), probably due to the extremely high concentrations of suspended sediment in the samples and possible interferences from other compounds. The calculated concentration of selenium attached to suspended sediment was less variable than suspended sediment or total selenium concentrations during storm runoff; concentrations ranged from 0.50 to 2.1 μg/g (microgram per gram) with a median of 0.89 μg/g. The logarithms of suspended sediment and total selenium concentrations were closely correlated to the logarithm of streamflow (R2 = 0.82, R2 = 0.71, respectively for all storm data). These relations for the first storm were significantly different from the later three storms. Because of these correlations, the logarithm of suspended sediment loading rate and the logarithm of total selenium loading rate were closely correlated to the logarithm of streamflow (R2 = 0.982 for both for all storm data). Loads of suspended sediment and total selenium were calculated for each of the four storms in three ways, including simple linear regression with streamflow for all storms, simple linear regressions for the first storm and the combined later three storms, and integration under the instantaneous load curves. The resulting suspended sediment loads for all four storms ranged from 1,793,000 to 2,555,000 tons; total selenium ranged from 4,909 to 5,830 lb (pound). Dissolved selenium concentrations correlated significantly with both the logarithm of streamflow and specific conductance. Simple linear regression with the logarithm of streamflow had an R2 of 0.45, and a multiple linear regression with the logarithm of streamflow and specific conductance had an adjusted R2 of 0.48 for all storm data. The relation between streamflow and specific conductance for the first storm and for the later three storms were significantly different. As for suspended sediment and total selenium, dissolved selenium loads were calculated three ways. The resulting loads for all four storms ranged from 773 to 1,007 lb. No significant storm occurred during the remainder of the study period (water years 1998 to 2000), and thus, no additional storm sampling took place. Assuming that future sediment and selenium transport is similar to that of 1998, a reasonable estimate of loading rates can be calculated from the streamflow record at the Interstate 5 gage. Additional storm sampling would improve the estimates and possibly allow for separate equations for the rising and falling limbs of storm hydrographs.

California↗
USGS2002

Diazinon and chlorpyrifos loads in the San Joaquin River basin, California, January and February 2000

The application of diazinon and chlorpyrifos on dormant orchards in 2000 in the San Joaquin River Basin was less than 21 percent of application in 1993 and 1994. A total of 13 sites were sampled weekly during nonstorm periods and more frequently during two storm periods. The sites included five major river and eight minor tributary sites. The highest concentrations of diazinon and chlorpyrifos occurred during the storm periods. Four samples from major river sites (Tuolumne River and two San Joaquin River sites) had diazinon concentrations greater than 0.08 microgram per liter, the concentration being considered by the state of California as its criterion maximum concentration for the protection of aquatic habitat. One sample from a major river site (San Joaquin River) exceeded the equivalent State guideline of 0.02 microgram per liter for chlorpyrifos. At the eight minor tributary sites, 24 samples exceeded the diazinon guideline and four samples exceeded the chlorpyrifos guideline. The total diazinon load in the San Joaquin River near Vernalis during January and February 2000 was 19.6 pounds active ingredient; of this, 8.17 pounds active ingredient was transported during two storms. In 1994, 27.4 pounds active ingredient was transported during two storms. The total chlorpyrifos load in the San Joaquin River near Vernalis during January and February 2000 was 5.68 pounds active ingredient; of this, 2.17 pounds active ingredient was transported during the two storms. During the frequently sampled February 2000 storm, the main sources of diazinon in the San Joaquin River Basin were the San Joaquin River near Stevinson Basin (25 percent), Tuolumne River Basin (14 percent), and the Stanislaus River Basin (10 percent). The main sources of chlorpyrifos in the San Joaquin River Basin were the San Joaquin River near Stevinson Basin (17 percent), Tuolumne River Basin (13 percent), and the Merced River Basin (11 percent). The total January and February diazinon load in the San Joaquin River near Vernalis was 0.17 percent of dormant application; total January and February chlorpyrifos load was 0.16 percent of dormant application.

Water-Resources Investigations Report↗