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Carol Becker

Publications and source records attributed to Carol Becker.

At least 19 recordsLinked to original sources
USGS2021

Load estimation and trend analysis for nitrogen, phosphorus, and suspended sediment in the Eucha-Spavinaw drainage area, northeastern Oklahoma and northwestern Arkansas, 2011–18

Lake Eucha is a source of water for public supply and recreation for the residents of Tulsa and other municipalities in northeastern Oklahoma. Beaty Creek and Spavinaw Creek flow into Lake Eucha and drain about 388 square miles of agricultural and forested land in northeastern Oklahoma and northwestern Arkansas. Beginning in the 1990s, eutrophication of Lake Eucha characterized by excessive algal blooms resulted in taste and odor problems associated with lake water when it is used for public supply. The predominant sources of phosphorus in the Eucha-Spavinaw drainage area were identified by previous investigators as runoff from fertilized agricultural areas (nonpoint sources) and treated effluent from a wastewater-treatment plant (point source). To further evaluate the transport of nitrogen, phosphorus, and suspended sediment in the Eucha-Spavinaw drainage area, the U.S. Geological Survey (USGS), in collaboration with the City of Tulsa, estimated the loads and computed temporal trends of these constituents from water-quality and streamflow data collected at five USGS streamgages in the Beaty Creek and Spavinaw Creek subbasins. Estimates and comparisons of total nitrogen, total phosphorus, and suspended-sediment loads from the Beaty Creek and Spavinaw Creek subbasins to Lake Eucha during 2011–18 were made by using different types of regression equations. The first type of regression equation is referred to as “daily mean load regression equations” and was developed from water-quality data obtained from periodic water-quality samples and daily mean streamflow data collected at five USGS streamgages. The second type of regression equation is referred to as “instantaneous continuous load regression equations.” In addition to water-quality data obtained from periodic water-quality samples, continuous real-time (every 15 minutes) measurements of physicochemical properties (specific conductance, water temperature, and turbidity), and continuous streamflow data were used to estimate instantaneous continuous loads of total nitrogen, total phosphorus, and suspended sediment at two of the same five streamgages where daily mean loads were estimated. The use of these two types of regression equations was documented by previous investigators who estimated loads of total nitrogen, total phosphorus, and suspended sediment in the study area by using data collected during 2002–10. The regression equations used to estimate constituent loads that were based on water-quality data obtained from periodic water-quality samples and continuous water-quality and streamflow data (instantaneous continuous load regression equations) better described the temporal variance in constituent loads compared to the regression equations based only on periodic water-quality data and daily mean streamflows (daily mean load regression equations). Estimates computed using instantaneous continuous load regression equations showed that mean annual loads of 1,844,000 pounds of total nitrogen, 150,300 pounds of total phosphorus, and 78,735,000 pounds of suspended sediment were transported into Lake Eucha from the Beaty Creek and Spavinaw Creek subbasins. Most of the estimated mean annual loads from the Beaty Creek and Spavinaw Creek subbasins entered Lake Eucha during runoff conditions, including about 80 percent of total nitrogen, 95 percent of total phosphorus, and 98 percent of suspended sediment. Daily, annual, and mean annual load estimates varied substantially, depending on streamflow conditions and the independent variables used to develop the regression equations. Daily and annual loads estimated from instantaneous continuous load regression equations that included specific conductance, water temperature, turbidity, and streamflow described the variability in the field data better than did loads estimated from daily mean load regression equations that included streamflow, seasonality, and time. Loads estimated from the instantaneous continuous load regression equations generally were greater than those estimated from the daily mean load regression equations. Temporal trends in total nitrogen concentrations showed statistically significant (probability value less than or equal to 0.05) downward trends during both base-flow and runoff conditions at all five USGS streamgages except for the streamgage 07191179 Spavinaw Creek near Cherokee City, Ark. Temporal trends in total phosphorus concentrations were not consistent between streamgages over the study period, showing upward and downward trends throughout the Eucha-Spavinaw drainage area. Total phosphorus concentrations during base-flow and runoff conditions showed statistically significant upward trends at USGS streamgages 07191160 Spavinaw Creek near Maysville, Ark., and 07191222 Beaty Creek near Jay, Okla. Total phosphorus concentrations showed a statistically significant downward trend during base-flow conditions at USGS streamgage 071912213 Spavinaw Creek near Colcord, Okla., and in both base-flow and runoff conditions at USGS streamgage 07191179 Spavinaw Creek near Cherokee City, Ark. Temporal trends in suspended-sediment concentrations were not consistent between streamgages over the study period and were similar to temporal trends in total phosphorus concentrations.

Arkansas, Oklahoma↗
USGS2021

Hydrogeology and model-simulated groundwater availability in the Salt Fork Red River aquifer, southwestern Oklahoma, 1980–2015

The 1973 Oklahoma Water Law (82 OK Stat § 82-1020.5) requires that the Oklahoma Water Resources Board (OWRB) conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin (hereinafter referred to as an “aquifer”). The maximum annual yield allocated per acre of land is known as the equal-proportionate-share (EPS) pumping rate. At present (2021), the OWRB has not yet established a maximum annual yield and EPS pumping rate for the Salt Fork Red River aquifer. To provide updated information to the OWRB that could support evaluation and determination of an appropriate maximum annual yield, the U.S. Geological Survey (USGS), in cooperation with the OWRB, conducted a hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater availability in the Salt Fork Red River aquifer. The Salt Fork Red River aquifer in Greer, Harmon, and Jackson Counties of southwestern Oklahoma is composed of about 274.5 square miles of alluvium and terrace deposits associated with the Salt Fork Red River. The mean annual recharge rate to the Salt Fork Red River aquifer for the period 1980–2015 was estimated to be about 2.94 inches per year, or 10.0 percent of the mean annual precipitation for the same period (29.4 inches per year). This 1980–2015 mean annual recharge rate is equivalent to a mean annual recharge rate of about 38,000 acre-feet per year (acre-ft/yr) for the Salt Fork Red River aquifer excluding about 19,764 acres comprising the Mulberry Creek and Horse Creek terraces. The mean annual recharge rates upgradient and downgradient from USGS streamgage 07300500 Salt Fork Red River at Mangum, Okla. (hereinafter referred to as the “Mangum gage”), apportioned by aquifer area (41.5 and 58.5 percent, respectively), were about 16,000 and 22,000 acre-ft/yr, respectively. Mean annual groundwater use for the study period (1980–2015) was 3,532.7 acre-ft/yr; about 77 percent of that groundwater use was for irrigation, and about 23 percent was for public supply. Most groundwater use for irrigation was associated with wells in the Martha terrace. A hydrogeologic framework was developed for the Salt Fork Red River aquifer and included a definition of the aquifer extent and potentiometric surface, as well as a description of the textural and hydraulic properties of aquifer materials. The hydrogeologic framework was used in the construction of the numerical groundwater-flow model of the Salt Fork Red River aquifer described in this report. A conceptual model for the Salt Fork Red River aquifer that reasonably represents the groundwater-flow system was developed to constrain the construction and calibration of the numerical model. The conceptual-model water budget estimated mean annual inflows to, and outflows from, the Salt Fork Red River aquifer for the period 1980–2015 and included a subaccounting of mean annual inflows and outflows for the portions of the aquifer that were upgradient and downgradient from the Mangum gage. The numerical groundwater-flow model of the Salt Fork Red River aquifer was constructed by using MODFLOW-2005 with the Newton formulation solver. The model of the Salt Fork Red River aquifer was spatially discretized into 1,050 rows, 1,125 columns, about 170,000 active cells measuring 200 by 200 feet (ft), and a single convertible layer. The model was temporally discretized into 432 monthly transient stress periods (each with two time steps to improve model stability). An initial steady-state stress period represented mean annual inflows to, and outflows from, the aquifer and produced a solution that was used as the initial condition for subsequent transient stress periods as well as some groundwater-availability scenarios. The model was calibrated to water-table-altitude observations at selected wells and base-flow observations at selected streamgages. The simulated saturated thickness of the Salt Fork Red River aquifer was determined by subtracting the altitude of the aquifer base from the simulated water-table altitude at the end of the numerical-model period (2015). The simulated saturated thickness was more than 75 ft in a paleochannel in the Dodson terrace near the Texas border. The mean aquifer thickness (sum of saturated and unsaturated) was 49.62 ft, and the mean saturated thickness was 28.55 ft. A simulated mean transmissivity of 1,024 feet squared per day was computed from the calibrated hydraulic conductivity and saturated thickness of each cell. The simulated available water in storage at the end of the numerical-model period (2015) was 526,117 acre-feet (acre-ft); about 42 percent of that total was available upgradient from the Mangum gage, and about 58 percent of that total was available downgradient from the Mangum gage (including the Mangum terrace). Three types of groundwater-availability scenarios were run using the calibrated numerical model. These scenarios were used to (1) estimate the EPS pumping rate that ensures a minimum 20-, 40-, and 50-year life of the aquifer, (2) quantify the potential effects of projected well withdrawals on groundwater storage over a 50-year period, and (3) simulate the potential effects of a hypothetical 10-year drought on base flow and groundwater storage. The 20-, 40-, and 50-year EPS pumping rates under normal recharge conditions were about 0.51, 0.48, and 0.48 acre-foot per acre per year, respectively. Given the 155,929-acre modeled aquifer area, these rates correspond to annual yields of about 78,800, 74,900, and 74,700 acre-ft/yr, respectively. For the 20-year EPS scenario, decreasing and increasing recharge by 10 percent resulted in a 6-percent change in the EPS pumping rate in both cases; for the 40- and 50-year EPS scenarios, decreasing and increasing recharge by 10 percent resulted in a 7-percent change in the EPS pumping rate in both cases. Projected 50-year pumping scenarios were used to simulate the effects of selected well withdrawal rates on groundwater storage of the Salt Fork Red River aquifer and base flows in the Salt Fork Red River. The effects of well withdrawals were evaluated by quantifying differences in groundwater storage and base flow in four 50-year scenarios, which applied (1) no groundwater pumping, (2) mean pumping rates for the study period (1980–2015), (3) 2015 pumping rates, and (4) increasing demand pumping rates at simulated wells. The increasing demand pumping rates assumed a cumulative 20.4-percent increase in pumping over 50 years based on 2010–60 demand projections for southwestern Oklahoma. Groundwater storage after 50 years with no pumping was 535,000 acre-ft, or 8,900 acre-ft (1.7 percent) greater than the initial groundwater storage; this groundwater storage increase is equivalent to a mean water-table-altitude increase of 0.48 ft. Groundwater storage after 50 years of pumping at the mean rate for the study period (1980–2015) was 519,900 acre-ft, or 6,200 acre-ft (1.2 percent) less than the initial groundwater storage; this groundwater storage decrease is equivalent to a mean water-table-altitude decline of 0.34 ft. Groundwater storage at the end of the 50-year period with 2015 pumping rates was 513,100 acre-ft, or 13,000 acre-ft (2.5 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean water-table-altitude decline of 0.71 ft. Groundwater storage at the end of the 50-year period with increasing demand pumping rates was 509,700 acre-ft, or 16,500 acre-ft (3.1 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean water-table-altitude decline of 0.89 ft. A hypothetical 10-year drought scenario was used to simulate the effects of a prolonged period of reduced recharge on groundwater storage. The period January 1983–December 1992 was chosen as the simulated drought period. Drought effects were quantified by comparing the results of the drought scenario to those of the calibrated numerical model (no drought) at the end of the simulated drought period (1992). To simulate the hypothetical drought, recharge in the calibrated numerical model was reduced by 50 percent during the simulated drought period (1983–92). Upstream inflows from the Salt Fork Red River, Turkey Creek, and Bitter Creek were reduced by 75 percent. Groundwater storage at the end of the drought period (1992) was 479,200 acre-ft, or 53,200 acre-ft (10.0 percent) less than the groundwater storage of the calibrated numerical model at the end of the drought period. This decrease in groundwater storage is equivalent to a mean water-table-altitude decline of 2.9 ft. At the end of the 10-year hypothetical drought period, simulated base flows at the Mangum gage and USGS streamgage 07301110 Salt Fork Red River near Elmer, Okla., had decreased by about 80 and 70 percent, respectively.

Oklahoma↗
USGS2020

Water resources in the Cheyenne and Arapaho Tribal jurisdictional area, west-central Oklahoma, with an analysis of data gaps through 2015

This report provides an overview of existing hydrologic information describing the quality, quantity, and extent of the major surface-water and groundwater resources in the Cheyenne and Arapaho Tribal jurisdictional area, west-central Oklahoma. Hydrologic information is provided for five major river systems (Cimarron River, North Canadian River, Canadian River, Washita River, and North Fork Red River), two reservoirs (Foss Reservoir and Canton Lake), and eight aquifers consisting of the alluvial aquifers associated with each of the five major river systems and three major bedrock aquifers (Ogallala aquifer, Elk City aquifer, and Rush Springs aquifer). Types of information provided about rivers and reservoirs for the Cheyenne and Arapaho Tribal jurisdictional area include diversion sites and amounts of water allocated and diverted for permitted uses in 2015; treated wastewater discharge sites and amounts discharged in 2015; and characteristics describing water-quality field properties, major ions, nutrients, and selected trace elements. Major ions, nutrients, and selected trace elements are compared to secondary maximum contaminant levels and maximum contaminant levels for finished drinking water. Additionally, statistics are provided describing daily, monthly, and annual streamflow characteristics at 12 U.S. Geological Survey streamgages. Streamflow statistics include the magnitudes and frequencies of floods, base-flow characteristics, and long-term streamflow trends. Types of information provided about the aquifers include amounts of water allocated and pumped for permitted uses in 2015; characteristics of groundwater describing water-quality field properties, major ions, nitrate (measured as nitrogen), and selected trace elements with comparisons to secondary maximum contaminant levels and maximum contaminant levels for finished drinking water; groundwater levels and long-term changes in water levels; and ranges of hydraulic conductivity, aquifer recharge, specific yield, transmissivity, and well yields from reports and groundwater-flow models. Surface water is used primarily for irrigation and mining and other nonconsumptive uses in the Cheyenne and Arapaho Tribal jurisdictional area, except from the Washita and North Fork Red Rivers, where water is treated for use as a public-water supply. Large concentrations of dissolved solids are the primary limiting factor affecting the use of surface water. Median concentrations of dissolved solids in surface water range from less than 1,000 milligrams per liter (mg/L) in samples from the North Canadian River to greater than 9,000 mg/L in samples from the Cimarron River. Large dissolved solids concentrations are correlated with hard water. Median hardness as calcium carbonate concentrations in surface water ranges from 427 mg/L in samples from Canton Lake to 1,000 mg/L in samples from the Washita River. In 2015, groundwater was used at more than twice the rate of surface water in the Cheyenne and Arapaho Tribal jurisdictional area. Although the alluvial aquifers are considered reliably good sources of water in the Cheyenne and Arapaho Tribal jurisdictional area, concentrations of nitrate (measured as nitrogen) exceed the maximum contaminant level of 10 mg/L established by the U.S. Environmental Protection Agency for finished drinking water in parts of all of the alluvial aquifers. Water from the three major bedrock aquifers is used for irrigation, mining, public-water supply, and other uses; however, large concentrations of dissolved solids, nitrate (measured as nitrogen), and naturally occurring trace elements such as arsenic and uranium may limit the use of groundwater as a source of public-water supply in some areas. As of 2015, the depletion of groundwater from the major aquifers in west-central Oklahoma is a minor concern to the Oklahoma Water Resources Board. Groundwater levels and other hydrologic information show that recharge rates exceed the rates of water pumped from aquifers, except in areas that may be affected locally by groundwater depletions.

Oklahoma↗
USGS2016

Geologic and geophysical models for Osage County, Oklahoma, with implications for groundwater resources

This report summarizes a three-dimensional (3-D) geologic model that was constructed to provide a framework to investigate groundwater resources of the Osage Nation in northeastern Oklahoma. This report also presents an analysis of an airborne electromagnetic (AEM) survey that assessed the spatial variation of electrical resistivity to depths as great as 300 meters in the subsurface. The report and model provide support for a countywide assessment of groundwater resources, emphasizing the Upper Pennsylvanian rock units in the shallow subsurface of central and eastern Osage County having electrical resistivity properties that may indicate aquifers. Surface outcrops and subsurface stratigraphic picks on wire-line geophysical logs of Upper Pennsylvanian–Lower Permian sedimentary rock were used to construct a 3-D model of the geologic subsurface as an aid for evaluating groundwater resources in Osage County. Quaternary alluvium and terraces along major streams and the Arkansas River are included in the geologic framework model. Data from the AEM survey were subjected to quality-control procedures, truncated at depth of investigation (DOI), and then used to build a 3-D electrical resistivity model making use of secondary and tertiary interpolation profiles between primary data profiles. The AEM data highlight westward-inclined resistivity gradients that parallel the shallow dip of bedrock strata; bodies have resistivity >30 ohm-meters, and extend as much as 10 kilometers (km) down the dip of host geologic units. Volume analysis and internal imaging of an integrated 3-D geology and electrical resistivity model give a proxy for likely aquifer units with large relative volumes of high resistivity: Quaternary alluvium, Elgin Sandstone Lentil in the upper part of the Vamoosa Group, Tallant Formation, and parts of a combined Wann-Iola-Chanute Formation. Less voluminous, high-resistivity bodies correspond to intervals in the lower part of the Vamoosa Group in the east-central part of the county and probable limestone intervals in the upper part of the Vanoss Group in the northwest part of the county. Northwestern and eastern troughs of potable water previously defined for central Osage County generally correspond to down-dip projections of high-resistivity bodies associated with the Elgin Sandstone Lentil of the Vamoosa Group and Tallant Formation, respectively.

Oklahoma↗
USGS2016

Summary of U.S. Geological Survey studies conducted in cooperation with the Citizen Potawatomi Nation, central Oklahoma, 2011–14

The U.S. Geological Survey conducted hydrologic studies and published three U.S. Geological Survey scientific investigations reports in cooperation with the Citizen Potawatomi Nation from 2011 to 2014 to characterize the quality and quantity of water resources. The study areas of those reports consisted of approximately 960 square miles in parts of three counties in central Oklahoma. This study area has multiple abundant sources of water, being underlain by three principal aquifers (alluvial/terrace, Central Oklahoma, and Vamoosa-Ada), being bordered by two major rivers (North Canadian and Canadian), and having several smaller drainages including the Little River in the central part of the study area and Salt Creek in the southeastern part of the study area. The Central Oklahoma aquifer (also referred to as the “Garber-Wellington aquifer”) underlies approximately 3,000 square miles in central Oklahoma in parts of Cleveland, Logan, Lincoln, Oklahoma, and Pottawatomie Counties and much of the study area. Water from these aquifers is used for municipal, industrial, commercial, agricultural, and domestic supplies. Much of the water in the study area is of good quality; however, in some parts of this area water quality was impaired by very hard surface water and groundwater, large chloride concentrations in some smaller streams, relatively large concentrations of nitrogen and phosphorus nutrients and large counts of fecal-indicator bacteria in the North Canadian River, and uranium concentrations that exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 30 micrograms per liter for public water supplies in water samples collected from a small number of wells. Most stream-water samples collected from the Little River by the U.S. Geological Survey in 2012–13 had dissolved solids concentrations exceeding the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level for public water supplies of 500 milligrams per liter. Larger numbers of organic compounds were measured in water samples collected from the North Canadian River than the Little River. Numerical groundwater-flow models were created to characterize flow systems in aquifers underlying this study area and areas of particular interest within the study area. Those models were used to estimate sustainable groundwater yields from parts of the North Canadian River alluvial aquifer, characterize groundwater/surface-water interactions, and estimate the effects of a 10-year simulated drought on streamflows and water levels in alluvial and bedrock aquifers. Pumping of wells at the Iron Horse Industrial Park was estimated to cause negligible infiltration of water from the adjoining North Canadian River. A 10-year simulated drought of 50 percent of normal recharge was tested for the period 1990–2000. For this period, the total amount of groundwater in storage was estimated to decrease by 8.6 percent in the North Canadian River alluvial aquifer and approximately 0.2 percent in the Central Oklahoma aquifer, and groundwater flow to streams was estimated to decrease by 28–37 percent. This volume of groundwater loss showed that the Central Oklahoma aquifer is a bedrock aquifer that has relatively low rates of recharge from the land surface. The simulated drought decreased simulated streamflow, composed of base flow, in the North Canadian River at Shawnee, Okla., which did not recover to predrought conditions until the relatively wet year of 2007 after the simulated drought period.

Oklahoma↗
USGS2014

Stream-water and groundwater quality in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area, Pottawatomie County, Oklahoma, 2012-13

The Citizen Potawatomi Nation needs to characterize their existing surface-water and groundwater resources in and near their tribal jurisdictional area to complete a water-resource management plan. Water resources in this area include surface water from the North Canadian and Little Rivers and groundwater from the terrace and alluvial aquifers and underlying bedrock aquifers. To assist in this effort, the U.S. Geological Survey (USGS), in cooperation with the Citizen Potawatomi Nation, collected water-quality samples at 4 sites on 3 streams and from 30 wells during 2012 and 2013 in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area in central Oklahoma. Stream samples were collected eight times on the North Canadian River at the upstream USGS streamflow-gaging station North Canadian River near Harrah, Okla. (07241550); at the downstream USGS streamflow-gaging station North Canadian River at Shawnee, Okla. (07241800); and on the Little River at the USGS streamflow-gaging station Little River near Tecumseh, Okla., (07230500). Stream samples also were collected three times at an ungaged site, Deer Creek near McLoud, Okla. (07241590). Water properties were measured, and water samples were analyzed for concentrations of major ions, nutrients, trace elements, counts of fecal-indicator bacteria, and 69 organic compounds. The highest concentrations of dissolved solids and chlorides were measured in stream-water samples collected at the Little River near Tecumseh station. The Secondary Maximum Contaminant Level (SMCL) for dissolved solids in drinking water of 500 milligrams per liter (mg/L) was exceeded in 7 of 8 stream-water samples, with a median concentration of 844 mg/L at that station. The 250-mg/L SMCL for chloride was exceeded in 5 of the 8 stream-water samples collected at that station. Median concentrations of total dissolved nitrogen were about an order of magnitude higher in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved nitrogen were 4.36 and 2.89 mg/L in stream-water samples collected at the two North Canadian River stations, 0.35 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.76 mg/L in stream-water samples collected at the Deer Creek site. Similar to nitrogen, median concentrations of total dissolved phosphorus were higher by about two orders of magnitude in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved phosphorus were 1.05 and 0.805 mg/L in stream-water samples collected at the two North Canadian River stations, 0.007 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.032 mg/L from the Deer Creek site. Dissolved concentrations of total nitrogen, nitrate-nitrogen, orthophosphorus, and total phosphorus were highest in stream-water samples collected at the two North Canadian River stations at low streamflows, indicating that wastewater effluent may have been a notable source of these nutrients. Concentrations of most trace elements increased with increasing streamflow in stream-water samples collected at the two North Canadian River stations, indicating that most trace elements are washed into the river by runoff from the land surface or resuspended from streambed sediments. In general, most trace-element concentrations were below respective Maximum Contaminant Levels (MCLs) for public drinking-water supplies, except for one stream-water sample with an arsenic concentration of 10.1 micrograms per liter (µg/L) collected from the North Canadian River and one stream-water sample with a barium concentration of 2,690 µg/L collected from the Little River. At least one stream-water sample from each of the four stream sites sampled in this study contained a lead concentration exceeding the SMCL of 15 µg/L. All of these samples were collected during high streamflows. A greater number of organic compounds were detected in stream-water samples collected at the two stations on the North Canadian River than in stream-water samples collected at the Tecumseh station and Deer Creek site. In the 8 stream-water samples collected at the upstream Harrah station, 213 detections of organic compounds were measured, whereas in 8 samples collected at the downstream Shawnee station, 203 detections of organic compounds were measured. In contrast, 59 detections of organic compounds were measured in the 8 stream-water samples collected at the Tecumseh station, and 25 detections of organic compounds were measured in the 3 stream-water samples collected at the Deer Creek site; however, the 8 detections of 7 organic compounds in the 2 equipment-blank samples is problematic for evaluating these data, especially for the Deer Creek and Little River samples because of the comparatively low detection frequency and should be taken into consideration when evaluating these results. Groundwater samples also were collected once from 30 wells producing water from the Garber-Wellington aquifer; Admire, Chase, and Council Grove Groups; the Vanoss Formation; and the terrace and alluvial aquifers along the North Canadian River. Water properties were measured, and samples were analyzed for concentrations of major ions, nutrients, trace elements, and selected radionuclides in groundwater. Of 30 wells sampled for this study, 26 were completed in bedrock aquifers, and 4 were completed in terrace and alluvial aquifers. In general, groundwater in the study area is very hard, with a median concentration of 180 mg/L as calcium carbonate in water samples collected from the 30 wells. Concentrations of sulfate exceeded the 250-mg/L SMCL in two groundwater samples, and dissolved solids concentrations exceeded the 500-mg/L SMCL in nine groundwater samples. Trace-element concentrations did not exceed respective MCLs in the 30 groundwater samples collected for this study. Concentrations of the radionuclide uranium ranged from 0.03 to 79.5 µg/L, with a median concentration of 1.9 µg/L in the 30 groundwater samples collected. Two of the groundwater samples collected for this study had uranium concentrations exceeding the MCL of 30 µg/L, with concentrations of 79.5 and 31.1 µg/L. Generally, uranium concentrations were highest in water samples collected from wells completed in the Wellington Formation and the Chase, Council Grove, and Admire Groups in the southern and eastern parts of the study area.

Oklahoma↗
USGS2013

Groundwater quality and water-well characteristics in the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 1948--2011

In 2012, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, compiled historical groundwater-quality data collected from 1948 to 2011 and water-well completion information in parts of Lincoln, Oklahoma, and Pottawatomie Counties in central Oklahoma to support the development of a comprehensive water-management plan for the Tribe’s jurisdictional area. In this study, water-quality data from 155 water wells, collected from 1948 to 2011, were retrieved from the U.S. Geological Survey National Water Information System database; these data include measurements of pH, specific conductance, and hardness and concentrations of the major ions, trace elements, and radionuclides that have Maximum Contaminant Levels or Secondary Maximum Contaminant Levels in public drinking-water supplies. Information about well characteristics includes ranges of well yield and well depth of private water wells in the study area and was compiled from the Oklahoma Water Resources Board Multi-Purpose Well Completion Report database. This report also shows depth to water from land surface by using shaded 30-foot contours that were created by using a geographic information system and spatial layers of a 2009 potentiometric surface (groundwater elevation) and land-surface elevation. Wells in the study area produce water from the North Canadian River alluvial and terrace aquifers, the underlying Garber Sandstone and Wellington Formation that compose the Garber–Wellington aquifer, and the Chase, Council Grove, and Admire Groups. Water quality varies substantially between the alluvial and terrace aquifers and bedrock aquifers in the study area. Water from the alluvial aquifer has relatively high concentrations of dissolved solids and generally is used for livestock only, whereas water from the terrace aquifer has low concentrations of dissolved solids and is used extensively by households in the study area. Water from the bedrock aquifer also is used extensively by households but may have high concentrations of trace elements, including uranium, in some areas where groundwater pH is above 8.0. Well yields vary and are dependent on aquifer characteristics and well-completion practices. Well yields in the unconsolidated alluvial and terrace aquifers generally are higher than yields from bedrock aquifers but are limited by the thickness and extent of these river deposits. Well yields in the alluvium and terrace aquifers commonly range from 50 to 150 gallons per minute and may exceed 300 gallons per minute, whereas well yields in the bedrock aquifers commonly range from 25 to 50 gallons per minute in the western one-third of study area (Oklahoma County) and generally less than 25 gallons per minute in the eastern two-thirds of the study area (Lincoln and Pottawatomie Counties).

Oklahoma↗
USGS2013

Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011

From 1999 to 2007, the Indian Health Service reported that gross alpha-particle activities and concentrations of uranium exceeded the Maximum Contaminant Levels for public drinking-water supplies in water samples from six private wells and two test wells in a rural residential neighborhood in the Kickapoo Tribe of Oklahoma Jurisdictional Area, in central Oklahoma. Residents in this rural area use groundwater from Quaternary-aged terrace deposits and the Permian-aged Garber-Wellington aquifer for domestic purposes. Uranium and other trace elements, specifically arsenic, chromium, and selenium, occur naturally in rocks composing the Garber-Wellington aquifer and in low concentrations in groundwater throughout its extent. Previous studies have shown that pH values above 8.0 from cation-exchange processes in the aquifer cause selected metals such as arsenic, chromium, selenium, and uranium to desorb (if present) from mineral surfaces and become mobile in water. On the basis of this information, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, conducted a study in 2011 to describe the occurrence of selected trace elements and radionuclides in groundwater and to determine if pH could be used as a surrogate for laboratory analysis to quickly and inexpensively identify wells that might contain high concentrations of uranium and other trace elements. The pH and specific conductance of groundwater from 59 private wells were measured in the field in an area of about 18 square miles in Lincoln and Pottawatomie Counties. Twenty of the 59 wells also were sampled for dissolved concentrations of major ions, trace elements, gross alpha-particle and gross beta-particle activities, uranium, radium-226, radium-228, and radon-222 gas. Arsenic concentrations exceeded the Maximum Contaminant Level of 10 micrograms per liter in one sample having a concentration of 24.7 micrograms per liter. Selenium concentrations exceeded the Maximum Contaminant Level of 50 micrograms per liter in one sample having a concentration of 147 micrograms per liter. Both samples had alkaline pH values, 8.0 and 8.4, respectively. Uranium concentrations ranged from 0.02 to 383 micrograms per liter with 5 of 20 samples exceeding the Maximum Contaminant Level of 30 micrograms per liter; the five wells with uranium concentrations exceeding 30 micrograms per liter had pH values ranging from 8.0 to 8.5. Concentrations of uranium and radon-222 and gross alpha-particle activity showed a positive relation to pH, with the highest concentrations and activity in samples having pH values of 8.0 or above. The groundwater samples contained dissolved oxygen and high concentrations of bicarbonate; these characteristics are also factors in increasing uranium solubility. Concentrations of radium-226 and radium-228 (combined) ranged from 0.03 to 1.7 picocuries per liter, with a median concentration of 0.45 picocuries per liter for all samples. Radon-222 concentrations ranged from 95 to 3,600 picocuries per liter with a median concentration of 261 picocuries per liter. Eight samples having pH values ranging from 8.0 to 8.7 exceeded the proposed Maximum Contaminant Level of 300 picocuries per liter for radon-222. Eight samples exceeded the 15 picocuries per liter Maximum Contaminant Level for gross alpha-particle activity at 72 hours (after sample collection) and at 30 days (after the initial count); those samples had pH values ranging from 8.0 to 8.5. Gross beta-particle activity increased in 15 of 21 samples during the interval from 72 hours to 30 days. The increase in gross beta-particle activity over time probably was caused by the ingrowth and decay of uranium daughter products that emit beta particles. Water-quality data collected for this study indicate that pH values above 8.0 are associated with potentially high concentrations of uranium and radon-222 and high gross alpha-particle activity in the study area. High pH values also are associated with potentially high concentrations of arsenic, chromium, and selenium in groundwater when these elements occur in the aquifer matrix along groundwater-flow paths.

Oklahoma↗
USGS2013

Analysis of environmental setting, surface-water and groundwater data, and data gaps for the Citizen Potawatomi Nation Tribal Jurisdictional Area, Oklahoma, through 2011

The Citizen Potawatomi Nation Tribal Jurisdictional Area, consisting of approximately 960 square miles in parts of three counties in central Oklahoma, has an abundance of water resources, being underlain by three principal aquifers (alluvial/terrace, Central Oklahoma, and Vamoosa-Ada), bordered by two major rivers (North Canadian and Canadian), and has several smaller drainages. The Central Oklahoma aquifer (also referred to as the Garber-Wellington aquifer) underlies approximately 3,000 square miles in central Oklahoma in parts of Cleveland, Logan, Lincoln, Oklahoma, and Pottawatomie Counties and much of the tribal jurisdictional area. Water from these aquifers is used for municipal, industrial, commercial, agricultural, and domestic supplies. The approximately 115,000 people living in this area used an estimated 4.41 million gallons of fresh groundwater, 12.12 million gallons of fresh surface water, and 8.15 million gallons of saline groundwater per day in 2005. Approximately 8.48, 2.65, 2.24, 1.55, 0.83, and 0.81 million gallons per day of that water were used for domestic, livestock, commercial, industrial, crop irrigation, and thermoelectric purposes, respectively. Approximately one-third of the water used in 2005 was saline water produced during petroleum production. Future changes in use of freshwater in this area will be affected primarily by changes in population and agricultural practices. Future changes in saline water use will be affected substantially by changes in petroleum production. Parts of the area periodically are subject to flooding and severe droughts that can limit available water resources, particularly during summers, when water use increases and streamflows substantially decrease. Most of the area is characterized by rural types of land cover such as grassland, pasture/hay fields, and deciduous forest, which may limit negative effects on water quality by human activities because of lesser emissions of man-made chemicals on such areas than in more urbanized areas. Much of the water in the area is of good quality, though some parts of this area have water quality impaired by very hard surface water and groundwater; large chloride concentrations in some smaller streams; relatively large concentrations of nutrients and counts of fecal-indicator bacteria in the North Canadian River; and chloride, iron, manganese, and uranium concentrations that exceed primary or secondary drinking-water standards in water samples collected from small numbers of wells. Substantial amounts of hydrologic and water-quality data have been collected in much of this area, but there are gaps in those data caused by relatively few streamflow-gaging stations, uneven distribution of surface-water quality sampling sites, lack of surface-water quality sampling at high-flow and low-flow conditions, and lack of a regularly measured and sampled groundwater network. This report summarizes existing water-use, climatic, geographic, hydrologic, and water-quality data and describes several means of filling gaps in hydrologic data for this area.

Oklahoma↗
USGS2011

Characterizing contaminant concentrations with depth by using the USGS well profiler in Oklahoma, 2003-9

Since 2003, the U.S. Geological Survey (USGS) Oklahoma Water Science Center has been using the USGS well profiler to characterize changes in water contribution and contaminant concentrations with depth in pumping public-supply wells in selected aquifers. The tools and methods associated with the well profiler, which were first developed by the USGS California Water Science Center, have been used to investigate common problems such as saline water intrusion in high-yield irrigation wells and metals contamination in high-yield public-supply wells. The USGS well profiler is a slim (less than 1 inch in diameter), high-pressure hose that can be raised and lowered between the production pipe and casing (or borehole) of a well by using a motorized hose reel. Use of this tool is considerably less expensive than use of standard methods of depth-dependent sampling, and the USGS well profiler generally requires less downtime of the well. In terms of data quality, the greatest advantage of the USGS well profiler is that all data collection is performed under production pumping rates. In Oklahoma, the USGS well profiler has been modified and adapted for use in low-yield (150?350 gallons per minute) wells of various construction types common in Oklahoma. This tool has been used in selected public-supply wells in Hinton, Moore, and Norman to identify which producing zones are contaminated by naturally occurring arsenic. The tool and method also can be used to investigate other nonvolatile contaminants of interest, including uranium, radium, barium, boron, lead, selenium, sulfate, chloride, fluoride, nitrate, and chromium. In 2007, the USGS well profiler was used to investigate saline water intrusion in a deep public-supply well completed in the Ozark (Roubidoux) aquifer. In northeast Oklahoma, where the Ozark aquifer is known to be susceptible to contamination from mining activities, the well profiler also could be used to investigate sources (depths) of metals contamination and to identify routes of entry of metals to production wells.Water suppliers can consider well rehabilitation as a potential remediation strategy because of the ability to identify changes in contaminant concentrations with depth in individual wells with the USGS well profiler. Well rehabilitation methods, which are relatively inexpensive compared to drilling and completing new wells, involve modifying the construction or operation of a well to enhance the production of water from zones with lesser concentrations of a contaminant or to limit the production of water from zones with greater concentrations of a contaminant. One of the most effective well rehabilitation methods is zonal isolation, in which water from contaminated zones is excluded from production through installation of cement plugs or packers. By using relatively simple and inexpensive well rehabilitation methods, water suppliers may be able to decrease exposure of customers to contaminants and avoid costly installation of additional wells, conveyance infrastructure, and treatment technologies.

Fact Sheet↗
USGS2011

Assessment of conservation practices in the Fort Cobb Reservoir watershed, southwestern Oklahoma

The Fort Cobb Reservoir watershed encompasses about 813 square kilometers of rural farm land in Caddo, Custer, and Washita Counties in southwestern Oklahoma. The Fort Cobb Reservoir and six stream segments were identified on the Oklahoma 1998 303(d) list as not supporting designated beneficial uses because of impairment by nutrients, suspended solids, sedimentation, pesticides, and unknown toxicity. As a result, State and Federal agencies, in collaboration with conservation districts and landowners, started conservation efforts in 2001 to decrease erosion and transport of sediments and nutrients to the reservoir and improve water quality in tributaries. The U.S. Department of Agriculture selected the Fort Cobb Reservoir watershed in 2003 as 1 of 14 benchmark watersheds under the Conservation Effectiveness Assessment Project with the objective of quantifying the environmental benefits derived from agricultural conservation programs in reducing inflows of sediments and phosphorus to the reservoir. In November 2004, the Biologic, Geographic, Geologic, and Water Disciplines of the U.S. Geological Survey, in collaboration with the Agricultural Research Service, Grazinglands Research Laboratory in El Reno, Oklahoma, began an interdisciplinary investigation to produce an integrated publication to complement this program. This publication is a compilation of 10 report chapters describing land uses, soils, geology, climate, and water quality in streams and the reservoir through results of field and remote sensing investigations from 2004 to 2007. The investigations indicated that targeting best-management practices to small intermittent streams draining to the reservoir and to the Cobb Creek subwatershed may effectively augment efforts to improve eutrophic to hypereutrophic conditions that continue to affect the reservoir. The three major streams flowing into the reservoir contribute nutrients causing eutrophication, but minor streams draining cultivated fields near the reservoir appeared to be disproportionate contributors of nutrients. Increasing conservation practices on small streams may have a greater effect in mitigating eutrophication in the reservoir than additional installation of such measures on the larger creeks.

Oklahoma↗
USGS2011

Comparison of load estimation techniques and trend analysis for nitrogen, phosphorus, and suspended sediment in the Eucha-Spavinaw Basin, northwestern Arkansas and northeastern Oklahoma, 2002-10

The City of Tulsa, Oklahoma, uses water from Lake Eucha and Spavinaw Lake in the Eucha-Spavinaw basin of northwestern Arkansas and northeastern Oklahoma for public water supply. Increases in algal biomass, which cause taste and odor problems in drinking water produced from the lakes, may be attributable to increases in nitrogen and phosphorus concentrations in the lakes and in streams discharging to the lakes. To evaluate transport of nitrogen, phosphorus, and suspended sediment in this basin, loads and temporal trends were evaluated for five streamflow-gaging stations in the Spavinaw and Beaty Creek basins. Two approaches were used to develop regression equations for estimation of loads and yields of nitrogen, phosphorus, and sediment. The first approach used regression equations referred to as daily mean load (DM L ) regressions, developed from water-quality samples and daily mean streamflow data collected from 2002 through 2010 at five streamflow-gaging stations in the basin. This approach was updated to compare loading results with those used in previous investigations. The second approach used regression equations, referred to as instantaneous continuous (INST C ) regressions, developed from continuous measurements of physical water-quality constituents (specific conductance, temperature, and turbidity, and streamflow data) obtained from 2004 through 2010 to estimate loads of nitrogen, phosphorus, and sediment at two of the streamflow-gaging stations, Spavinaw Creek near Colcord, Okla., and Beaty Creek near Jay, Okla. Daily, annual, and mean annual loads estimated from these two regression methods were compared for the period 2005–10. Based on estimates obtained using DM L regressions, mean annual loads of 1,640,000 pounds of nitrogen, 99,900 pounds of phosphorus, and 116,000,000 pounds of sediment were transported into Lake Eucha from the Spavinaw and Beaty Creek basins. Estimated annual loads of nitrogen and phosphorus delivered to Lake Eucha from the Spavinaw and Beaty Creek basins during 2002–10 were 2.5 to 7.8 percent less, respectively, than the loads of those constituents discharged to Lake Eucha from 2002–09, indicating that nitrogen and phosphorus loads in 2010 were less than loads typical for the period 2002–09. Daily, annual, and mean annual load estimates varied substantially, depending on streamflow conditions and the independent variables used to develop regressions. Daily and annual loads estimated from INST C regressions that included turbidity, streamflow, temperature, specific conductance, and seasonality fit better with the field data than loads estimated from DM L regressions that included streamflow, seasonality, and time. Loads estimated from the INST C regression generally were greater than those estimated from the DM L regression. Relative percent differences in the mean annual total nitrogen load estimated by the INST C and DM L regressions were within 2 percent for Spavinaw Creek near Colcord, and Beaty Creek near Jay, Okla. The relative percent difference between the two types of regressions for estimates of mean annual total phosphorus loads at the two streamflow-gaging stations was 27.7 for Spavinaw Creek near Colcord, Okla., and only -2.6 percent for Beaty Creek near Jay, Okla. The relative percent difference between mean annual suspended-sediment loads at the streamflow-gaging stations was -38.6 percent for Spavinaw Creek near Colcord, Okla., and -122.7 percent for Beaty Creek near Jay, Okla. The DM L regression may have substantially underestimated phosphorus load at the Spavinaw Creek near Colcord, Okla., streamflow-gaging station in wet years and overestimated sediment load at both streamflow-gaging stations in wet years. Temporal trends in flow-adjusted nitrate-nitrogen, nitrogen, phosphorus, and suspended-sediment concentrations were analyzed for the five streamflow-gaging stations for the period 2001–10. No significant trends were observed for nitrate plus nitrite-nitrogen or total nitrogen concentrations at any streamflow-gaging station. There were significant upward trends in phosphorus concentrations in water samples collected during base-flow conditions at the Spavinaw Creek near Maysville, Okla., streamflow-gaging station and during runoff conditions for the Beaty Creek near Jay, Okla., streamflow-gaging station (3.5 to 4.2 percent per year). There were significant downward trends in phosphorus concentrations in base-flow and runoff samples collected at the Spavinaw Creek near Cherokee City, Sycamore, and Colcord, Okla., streamflow-gaging stations (-4.9 to -12.9 percent per year). There were significant downward trends in suspended-sediment concentration at the Spavinaw Creek near Maysville, and Sycamore, Okla., and the Beaty Creek near Jay, Okla., streamflow-gaging stations (-1.5 to -1.8 percent per year). No significant trends were detected in suspended-sediment concentration for the Spavinaw Creek near Cherokee City, and Colcord, Okla., streamflow-gaging stations. Possible causes for downward trends in phosphorus concentrations include decreases in phosphorus discharges from a wastewater-treatment plant upstream from the Spavinaw Creek near Cherokee City, Okla., streamflow-gaging station, and implementation of best management practices in the basin. Downward trends in sediment concentrations may be related to effects of best management practices in the basin.

Arkansas, Oklahoma↗
USGS2010

Arsenic-related water quality with depth and water quality of well-head samples from production wells, Oklahoma, 2008

The U.S. Geological Survey well profiler was used to describe arsenic-related water quality with well depth and identify zones yielding water with high arsenic concentrations in two production wells in central and western Oklahoma that yield water from the Permian-aged Garber-Wellington and Rush Springs aquifers, respectively. In addition, well-head samples were collected from 12 production wells yielding water with historically large concentrations of arsenic (greater than 10 micrograms per liter) from the Garber-Wellington aquifer, Rush Springs aquifer, and two minor aquifers: the Arbuckle-Timbered Hills aquifer in southern Oklahoma and a Permian-aged undefined aquifer in north-central Oklahoma. Three depth-dependent samples from a production well in the Rush Springs aquifer had similar water-quality characteristics to the well-head sample and did not show any substantial changes with depth. However, slightly larger arsenic concentrations in the two deepest depth-dependent samples indicate the zones yielding noncompliant arsenic concentrations are below the shallowest sampled depth. Five depth-dependent samples from a production well in the Garber-Wellington aquifer showed increases in arsenic concentrations with depth. Well-bore travel-time information and water-quality data from depth-dependent and well-head samples showed that most arsenic contaminated water (about 63 percent) was entering the borehole from perforations adjacent to or below the shroud that overlaid the pump. Arsenic concentrations ranged from 10.4 to 124 micrograms per liter in 11 of the 12 production wells sampled at the well head, exceeding the maximum contaminant level of 10 micrograms per liter for drinking water. pH values of the 12 well-head samples ranged from 6.9 to 9. Seven production wells in the Garber-Wellington aquifer had the largest arsenic concentrations ranging from 18.5 to 124 micrograms per liter. Large arsenic concentrations (10.4-18.5) and near neutral to slightly alkaline pH values (6.9-7.4) were detected in samples from one well in the Garber-Wellington aquifer, three production wells in the Rush Springs aquifer, and one well in an undefined Permian-aged aquifer. All well-head samples were oxic and arsenate was the only species of arsenic in water from 10 of the 12 production wells sampled. Arsenite was measured above the laboratory reporting level in water from a production well in the Garber-Wellington aquifer and was the only arsenic species measured in water from the Arbuckle-Timbered Hills aquifer. Fluoride and uranium were the only trace elements, other than arsenic, that exceeded the maximum contaminant level for drinking water in well-head samples collected for the study. Uranium concentrations in four production wells in the Garber-Wellington aquifer ranged from 30.2 to 99 micrograms per liter exceeding the maximum contaminant level of 30 micrograms per liter for drinking water. Water from these four wells also had the largest arsenic concentrations measured in the study ranging from 30 to 124 micrograms

Scientific Investigations Report↗
USGS2010

A Reconnaissance of selected organic compounds in streams in tribal lands in Central Oklahoma, January-February 2009

The U.S. Geological Survey worked in cooperation with the U.S. Environmental Protection Agency and the Kickapoo Tribe of Oklahoma on two separate reconnaissance projects carried out concurrently. Both projects entailed the use of passive samplers as a sampling methodology to investigate the detection of selected organic compounds at stream sites in jurisdictional areas of several tribes in central Oklahoma during January-February 2009. The focus of the project with the U.S. Environmental Protection Agency was the detection of pesticides and pesticide metabolites using Semipermeable Membrane Devices at five stream sites in jurisdictional areas of several tribes. The project with the Kickapoo Tribe of Oklahoma focused on the detection of pesticides, pesticide metabolites, polycyclic aromatic hydrocarbons, polychlorinated biphenyl compounds, and synthetic organic compounds using Semipermeable Membrane Devices and Polar Organic Chemical Integrative Samplers at two stream sites adjacent to the Kickapoo tribal lands. The seven stream sites were located in central Oklahoma on the Cimarron River, Little River, North Canadian River, Deep Fork, and Washita River. Extracts from SPMDs submerged at five stream sites, in cooperation with the U.S. Environmental Protection Agency, were analyzed for 46 pesticides and 6 pesticide metabolites. Dacthal, a pre-emergent herbicide, was detected at all five sites. Pendimethalin, also a pre-emergent, was detected at one site. The insecticides chlorpyrifos and dieldrin were detected at three sites and p,p'-DDE, a metabolite of the insecticide DDT, also was detected at three sites. SPMDs and POCIS were submerged at the upstream edge and downstream edge of the Kickapoo tribal boundaries. Both sites are downstream from the Oklahoma City metropolitan area and multiple municipal wastewater treatment plants. Extracts from the passive samplers were analyzed for 62 pesticides, 10 pesticide metabolites, 3 polychlorinated biphenyl compounds, 35 polycyclic aromatic hydrocarbons, and 49 synthetic organic compounds. Ten pesticides and four pesticide metabolites were detected at the upstream site and seven pesticides and four pesticide metabolites were detected at the downstream site. Pesticides detected at both sites were atrazine, chlorpyrifos, dacthal, dieldrin, metolachlor, pendimethalin, and trans-nonachlor. Additionally at the upstream site, heptachlor, pentachlorophenol, and prometon were detected. The pesticide metabolites p,p'-DDE, cis-chlordane, and trans-chlordane also were detected at both sites. Polychlorinated biphenyl compounds aroclor-1016/1242, aroclor-1254, and aroclor-1260 were detected at both sites. The upstream site had 16 polycyclic aromatic hydrocarbon detections and the downstream site had 8 detections. Because of chromatographic interference during analysis, a positive identification of 17 polycyclic aromatic hydrocarbons could not be made. Consequently, there may have been a greater number of these compounds detected at both sites. A total of 36 synthetic organic compounds were detected at the two sites adjacent to the Kickapoo tribal lands. The upstream site had 21 synthetic organic compound detections: three detergent metabolites, two fecal indicators, three flame retardants, seven industrial compounds, five compounds related to personal care products, and beta-sitosterol, a plant sterol. Fifteen synthetic organic compounds were detected at the downstream site and included: one fecal indicator, three flame retardants, six industrial compounds, and five compounds related to personal care products.

Scientific Investigations Report↗
USGS2008

Digital atlas of the upper Washita River basin, southwestern Oklahoma

Numerous types of environmental data have been collected in the upper Washita River basin in southwestern Oklahoma. However, to date these data have not been compiled into a format that can be comprehensively queried for the purpose of evaluating the effects of various conservation practices implemented to reduce agricultural runoff and erosion in parts of the upper Washita River basin. This U.S. Geological Survey publication, 'Digital atlas of the upper Washita River basin, southwestern Oklahoma' was created to assist with environmental analysis. This atlas contains 30 spatial data sets that can be used in environmental assessment and decision making for the upper Washita River basin. This digital atlas includes U.S. Geological Survey sampling sites and associated water-quality, biological, water-level, and streamflow data collected from 1903 to 2005. The data were retrieved from the U.S. Geological Survey National Water Information System database on September 29, 2005. Data sets are from the Geology, Geography, and Water disciplines of the U.S. Geological Survey and cover parts of Beckham, Caddo, Canadian, Comanche, Custer, Dewey, Grady, Kiowa, and Washita Counties in southwestern Oklahoma. A bibliography of past reports from the U.S. Geological Survey and other State and Federal agencies from 1949 to 2004 is included in the atlas. Additionally, reports by Becker (2001), Martin (2002), Fairchild and others (2004), and Miller and Stanley (2005) are provided in electronic format.

Data Series↗
USGS2006

Comparison of ground-water quality in samples from selected shallow and deep wells in the central Oklahoma aquifer, 2003-2005

The aquifer units of the Central Oklahoma aquifer underlie about 2,890 square miles of central Oklahoma and are used extensively to supply water for municipal, domestic, industrial, and agricultural needs. The Central Oklahoma aquifer also is commonly referred to as the Garber-Wellington aquifer because the Garber Sandstone and Wellington Formation yield the greatest quantities of usable water for domestic and high-capacity wells. The major water-quality concerns for the Central Oklahoma aquifer described by the U.S. Geological Survey National Water Quality Assessment Program (1987 to 1992) were elevated concentrations of nitrate nitrogen in shallow water and the occurrence of arsenic, chromium, and selenium in parts of the aquifer. The quality of water from deep public-water supply wells in the Central Oklahoma aquifer is monitored by the State of Oklahoma. The chemical quality of water from shallow domestic wells is not monitored, and, therefore, there is a concern that well owners may be unknowingly ingesting water with nitrate nitrogen, arsenic, chromium, selenium, and other chemical constituents at concentrations that are considered harmful. As a result of this concern, the Oklahoma Department of Environmental Quality and the U.S. Geological Survey collaborated on a study to sample water during June 2003 through August 2005 from 23 shallow wells (less than 200 feet in depth) and 28 deep wells (200 feet or greater in depth) completed in the bedrock aquifer units of the Central Oklahoma aquifer. The objectives of the study were to describe the chemical quality of water from shallow and deep wells and to determine if the differences in constituent concentrations are statistically significant. Water from shallow wells had significantly higher concentrations of calcium, magnesium, bicarbonate, sulfate, chloride, and nitrate nitrogen than water from deep wells. There were no significant differences between concentrations of dissolved solids, sodium, and fluoride in water from shallow and deep wells. Water from 9 shallow wells had nitrate nitrogen concentrations greater than 2 milligrams per liter, suggesting nitrogen sources at land surface have had an effect on water from these wells. Water from three shallow wells (13 percent) exceeded the nitrate nitrogen maximum contaminant level of 10 milligrams per liter in drinking water. Water from shallow wells had significantly lower concentrations of arsenic, chromium, iron, and selenium than water from deep wells, whereas, concentrations of barium, copper, manganese, and zinc were similar. Water-quality data indicate that arsenic frequently occurs in shallow ground water from the Central Oklahoma aquifer, but at low concentrations (<10 micrograms per liter). The occurrence of chromium and selenium in water from shallow wells was infrequent and at low concentrations in this study. It does not appear that the quality of water from a shallow well can be predicted based on the quality of water from a nearby deep well. The results show that in general terms, shallow ground water has significantly higher concentrations of most major ions and significantly lower concentrations of arsenic, chromium, and selenium than water from deep wells.

Scientific Investigations Report↗
USGS2004

Reconnaissance of Surface-Water Quality and Possible Sources of Nutrients and Bacteria in the Turkey Creek Watershed, Northwest Oklahoma, 2002-2003

The U.S. Geological Survey in cooperation with the Oklahoma Department of Environmental Quality and the U.S. Environmental Protection Agency investigated the distribution of surface-water quality and possible sources of nutrients and Escherichia coli bacteria to surface water in Turkey Creek, which flows about 70 miles through mostly rural agricultural areas in northwest Oklahoma. Results show that discharge on the main stem of Turkey Creek increased during low-flow conditions from an average of 5.4 cubic feet per second at the upper most site to 39 cubic feet per second at the lower most site in the watershed, indicating that Turkey Creek gains water from ground-water discharge. A portion of the increase in stream discharge may be from discharges of treated effluent from city sewage lagoons. However, the volume and frequency of discharges are unknown. Surface-water-quality samples show that specific conductance ranged from 1,180 to 1,740 microsiemens per centimeter at 25 degrees Celsius during low-flow conditions and in general, decreased downstream with site 1 or site 2 having the largest measurement and site 5 having the lowest. The pH values were slightly alkaline and ranged from 6.8 to 8.5 with a median of 8.2. Dissolved oxygen ranged from 9.3 to 15.9 milligrams per liter in samples collected in the months of November, February, and March and ranged from 5.3 to 13.9 milligrams per liter in samples collected in the months of June, July, and August. Surface-water-quality samples show that the median concentrations of nitrite plus nitrate as nitrogen (1.16 milligrams per liter) and total phosphorus (0.275 milligram per liter) are larger than the average median concentrations of 0.35 and 0.083 milligram per liter, respectively, calculated from water-quality sites in Oklahoma and part of Arkansas (excluding sites in the Ozark Highland and the Ouachita Mountains ecoregions) having similar stream orders and stream slopes. Concentrations of nitrite plus nitrate as nitrogen increased slightly in the winter months and decreased in the summer months, whereas, concentrations of total phosphorus and orthophosphate as phosphorus tended to increase during the summer months and decrease in the winter months. During high-flow conditions total phosphorus increased 7.7 times above the average concentration of 0.261 milligram per liter in low-flow samples. Orthophosphate concentrations increased 3.5 to 4 times during high-flow conditions. Almost all low-flow samples showed 15N values between 4 and 10 parts per thousand, above the range for atmospheric nitrogen and synthetic fertilizer and below the range for animal waste. These samples may represent a mixture of nitrate from these two sources and other sources enriched with 15N, such as soils and plants. Results of the bacterial source tracking indicated that the two source groups having the greatest number of ribopattern matches with surface-water isolates were the cattle group, 53 isolates or 23.5 percent, and the human group, 41 isolates or 18.2 percent. Fewer surface-water isolates matched the deer and horse groups, 8.0 percent and 3.5 percent, respectively. About 43 percent or 96 surface-water isolates were not matched to any source group.

Scientific Investigations Report↗