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C.J.R. Hart

Publications and source records attributed to C.J.R. Hart.

4 recordsLinked to original sources

Source and redox controls on metallogenic variations in intrusion-related ore systems, Tombstone-Tungsten Belt, Yukon Territory, Canada

The Tombstone, Mayo and Tungsten plutonic suites of granitic intrusions, collectively termed the Tombstone-Tungsten Belt, form three geographically, mineralogically, geochemically and metallogenically distinct plutonic suites. The granites (sensu lato) intruded the ancient North American continental margin of the northern Canadian Cordillera as part of a single magmatic episode in the mid-Cretaceous (96-90 Ma). The Tombstone Suite is alkalic, variably fractionated, slightly oxidised, contains magnetite and titanite, and has primary, but no xenocrystic, zircon. The Mayo Suite is sub-alkalic, metaluminous to weakly peraluminous, fractionated, but with early felsic and late mafic phases, moderately reduced with titanite dominant, and has xenocrystic zircon. The Tungsten Suite is peraluminous, entirely felsic, more highly fractionated, reduced with ilmenite dominant, and has abundant xenocrystic zircon. Each suite has a distinctive petrogenesis. The Tombstone Suite was derived from an enriched, previously depleted lithospheric mantle, the Tungsten Suite is from the continental crust including, but not dominated by, carbonaceous pelitic rocks, and the Mayo Suite is from a similar sedimentary crustal source, but is mixed with a distinct mafic component from an enriched mantle source. Each suite has a distinctive metallogeny that is related to the source and redox characteristics of the magma. The Tombstone Suite has a Au-Cu-Bi association that is characteristic of most oxidised and alkalic magmas, but also has associated, and enigmatic, U-Th-F mineralisation. The reduced Tungsten Suite intrusions are characterised by world-class tungsten skarn deposits with less significant Cu, Zn, Sn and Mo anomalies. The Mayo Suite intrusions are characteristically gold-enriched, with associated As, Bi, Te and W associations. All suites also have associated, but distal and lower temperature Ag-Pb- and Sb-rich mineral occurrences. Although processes such as fractionation, volatile enrichment and phase separation are ultimately required to produce economic concentrations of ore elements from crystallising magmas, the nature of the source materials and their redox state play an important role in determining which elements are effectively concentrated by magmatic processes.

Transactions of the Royal Society of Edinburgh, Ea

Geochemical constraints on the genesis of the Scheelite dome intrusion-related gold deposit, Tombstone gold belt, Yukon, Canada

The Scheelite dome intrusion-related gold deposit, western Selwyn basin, Yukon, is hosted in hornfelsed metasedimentary strata that lie adjacent to the exposed apices of a monzogranite to quartz monzonite plutonic complex of the mid-Cretaceous Tombstone-Tungsten magmatic belt, Tintina gold province, Alaska and Yukon. A variety of mineralization styles occur throughout a 10- ?? 3-km east-trending corridor and include reduced Au- and W-rich skarns, Au, W- and Ag-Pb-Zn-Sb-rich quartz tension-vein arrays, and multiphase fault veins and isolated zones of Au-rich sericite-carbonate altered rock. Integrated U-Pb SHRIMP data for magmatic zircon and Ar-Ar data for magmatic and hydrotbermal biotite indicate that gold mineralization occurred within 1 to 2 m.y. of magma emplacement. Fluid inclusion, oxygen isotope, and arsenopyrite geothermometry data indicate that hydrothermal minerals formed at depths of 6 to 9 km over a temperature range from <300?? to >550??C. High-temperature Au-rich skarns formed at >400??C, whereas vein-hosted mineralization formed at 280?? to 380??C. In skarns, Au is strongly associated with enrichments of Bi, Te, W, and As, whereas a variety of Au-rich veins occur, with Asrich (type 1), and Te- and W-rich (type 2) end members. Silver-Pb-Zn-Sb veins are typically Au poor and represent the latest and lowest temperature phase in the hydrothermal paragenesis. The fluid inclusion data indicate that all mineralization styles were formed from low-salinity (???4 wt % NaCl equiv) aqueous-carbonic fluids, consistent with the composition of fluid inclusions within infilled miarolitic cavities in the intrusive rocks. However, the nonaqueous fluid was predominantly CH4 in skarn, CO2 in Au-Te and Au-W veins, and a fluid with roughly equal amounts Of CO2, CH4, and N2 in Au-As and Ag-Pb-Zn-Sb veins. Oxygen isotope data are consistent with a mineralizing fluid of predominantly magmatic origin that was variably modified to more positive ??18O values during interaction with 18O-enriched metasedimentary strata. Sulfur isotope data suggest two possible sources of sulfur, a magmatic source characterized by ??34S values of approximately -5 to 0 per mil and sulfur from the metasedimentary country rocks characterized by more negative ??34S values of approximately -15 to -10 per mil. Collectively the data indicate that gold at Scheelite Dome was deposited from a magmatic-hydrothermal system. Interaction of magmatic fluids with graphitic hornfels rocks resulted in reduction of the ore fluids, higher CH4/CO2 ratios, and modification of the oxygen and sulfur isotope values of the ore fluids toward those of the metasedimentary hornfels. Progressive reduction and cooling of hydrotbermal fluids, in addition to phase separation in vein-hosted mineralization, were the mechanisms for gold deposition. Compared to other intrusion-related gold deposits associated with the Tombstone-Tungsten magmatic belt magmatism, exposed mineralization at Scheelite Dome is predominantly hosted by hornfelsed metasedimentary rocks. This results in more diverse mineralization styles and a greater spread of isotope and fluid inclusion data. ?? 2006 Society of Economic Geologists, Inc.

Economic Geology

Gold deposits in metamorphic belts: Overview of current understanding, outstanding problems, future research, and exploration significance

Metamorphic belts are complex regions where accretion or collision has added to, or thickened, continental crust. Gold-rich deposits can be formed at all stages of orogen evolution, so that evolving metamorphic belts contain diverse gold deposit types that may be juxtaposed or overprint each other. This partly explains the high level of controversy on the origin of some deposit types, particularly those formed or overprinted/remobilized during the major compressional orogeny that shaped the final geometry of the hosting metamorphic belts. These include gold-dominated orogenic and intrusion-related deposits, but also particularly controversial gold deposits with atypical metal associations. There are a number of outstanding problems for all types of gold deposits in metamorphc belts. These include the following: (1) definitive classifications, (2) unequivocal recognition of fluid and metal sources, (3) understanding of fluid migration and focusing at all scales, (4) resolution of the precise role of granitoid magmatism, (5) precise gold-depositional mechanisms, particularly those producing high gold grades, and (6) understanding of the release of CO2-rich fluids from subducting slabs and subcreted oceanic crust and granitoid magmas at different crustal levels. Research needs to be better coordinated and more integrated, such that detailed fluid-inclusion, trace-element, and isotopic studies of both gold deposits and potential source rocks, using cutting-edge technology, are embedded in a firm geological framework at terrane to deposit scales. Ultimately, four-dimensional models need to be developed, involving high-quality, three-dimensional geological data combined with integrated chemical and fluid-flow modeling, to understand the total history of the hydrothermal systems involved. Such research, particularly that which can predict superior targets visible in data sets available to exploration companies before discovery, has obvious spin-offs for global- to deposit-scale targeting of deposits with superior size and grade in the covered terranes that will be the exploration focus of the twenty-first century.

Economic Geology

Porphyry deposits of the Canadian Cordillera

Porphyry deposits are intrusion-related, large tonnage low grade mineral deposits with metal assemblages that may include all or some of copper, molybdenum, gold and silver. The genesis of these deposits is related to the emplacement of intermediate to felsic, hypabyssal, generally porphyritic intrusions that are commonly formed at convergent plate margins. Porphyry deposits of the Canadian Cordillera occur in association with two distinctive intrusive suites: calc-alkalic and alkalic. In the Canadian Cordillera, these deposits formed during two separate time periods: Late Triassic to Middle Jurassic (early Mesozoic), and Late Cretaceous to Eocene (Mesozoic-Cenozoic). Deposits of the early Mesozoic period occur in at least three different arc terranes (Wrangellia, Stikinia and Quesnellia) with a single deposit occurring in the oceanic assemblage of the Cache Creek terrane. These terranes were located outboard from continental North America during formation of most of their contained early Mesozoic porphyry deposits. Some of the deposits of this early period may have been emplaced during terrane collisions. Metal assemblages in deposits of the calc-alkalic suite include Mo-Cu (Brenda), Cu-Mo (Highland Valley, Gibraltar), Cu-Mo-Au-Ag (Island Copper, Schaft Creek) and Cu-Au (Kemess, Kerr).The alkalic suite deposits are characterized by a Cu-Au assemblage (Copper Mountain, Afton-Ajax, Mt. Milligan, Mount Polley, Galore Creek). Although silver is recovered from calc-alkalic and alkalic porphyry copper mining operations, silver data are seldom included in the published reserve figures. Those available are in the range of 1-2 grams per tonne (g??t-1). Alkalic suite deposits are restricted to the early Mesozoic and display distinctive petrology, alteration and mineralization that suggest a similar tectonic setting for both Quesnellia and Stikinia in Early Jurassic time. The younger deposits, late Mesozoic to Cenozoic in age, formed in an intracontinental setting, after the outboard host arc and related terranes accreted to the western margin of North America. These deposits are interpreted to occur in continental arc settings, and individual deposits are hosted by a variety of older country rocks. These younger deposits also show a spectrum of metal associations: Cu-Mo (Huckleberry, Berg), Cu-Au (-Mo) (Bell, Granisle, Fish Lake, Casino), Mo (Endako, Boss Mountain, Kit-sault, Quartz Hill), Mo-W (Logtung), Au-W (Dublin Gulch) and Au (Ft. Knox). There may be a continuum between Mo, Mo-W, Au-Mo-W and Au deposits. The distribution and timing of these post-accretion deposits likely reflect major crustal structures and subduction geometry. Cordilleran porphyry metallic deposits show the full range of morphological and depth relationships found in porphyry deposits worldwide. In addition, the Cordillera contains numerous alkalic suite deposits, which are rare worldwide: the unusual, possibly syntectonic Gibraltar deposit; and end-member gold-rich granite-hosted deposits, such as Ft. Knox (Alaska).

Geoscience Canada