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C. Gazis

Publications and source records attributed to C. Gazis.

3 recordsLinked to original sources

Oxygen isotopic and geochemical evidence for a short-lived, high-temperature hydrothermal event in the Chegem caldera, Caucasus Mountains, Russia

Within the 2.8 Ma Chegem ash-flow caldera (11 ?? 15 km), a single cooling unit of rhyolitic to dacitic welded tuff more than 2 km thick is exposed in deep valleys incised during recent rapid uplift of the Caucasus Mountains. The intracaldera tuff is mineralogically fresh and unaltered, and is overlain by andesite lavas and cut by a resurgent granodiorite intrusion. Major- and trace-element compositions for a 1405-m stratigraphic section of intracaldera tuff display trends of upwardly increasing Na2O, CaO, Al2O3, total Fe, MgO, TiO2, Sr and Zr and decreasing SiO2, K2O and Rb. This mafic-upward zoning (from 76.1 to 69.9% SiO2) reflects an inverted view of the upper part of the source magma chamber. Oxygen isotope studies of 35 samples from this 1405-m section define a striking profile with "normal" igneous ??18O values (+7.0 to +8.5) in the lower 600 m of tuff, much lower ??18O values (-4.0 to +4.3) in a 700-m zone above that and a shift to high ??18O values (+4.4 to -10.9) in the upper 100 m of caldera-fill exposure. Data from two other partial stratigraphic sections indicate that these oxygen isotope systematics are probably a caldera-wide phenomenon. Quartz and feldspar phenocrysts everywhere have "normal" igneous ??18O values of about +8.5 and +7.5, respectively, whereas groundmass and glass ??18O values range from -7.7 to +12.3. Consequently, the ??18O values of coexisting feldspar, groundmass and glass form a steep array in a plot of ??feldspar vs. ??groundmass/glass. Such pronounced disequilibrium between coexisting feldspar and groundmass or glass has never before been observed on this scale. It requires a hydrothermal event involving large amounts of low-18O H2O at sufficiently high temperatures and short enough time (tens of years or less) that glass exchanges thoroughly but feldspar does not. The most likely process responsible for the O depletions at Chegem is a very high temperature (500-600??C), short-lived, vigorous meteoric-hydrothermal event that was focused within the upper 750 m of intracaldera tuff. Mass balance calculations indicate fluid fluxes of = 6 ?? 10-6 mol cm-2 s-1. We believe that the closest historical analogue to this Chegem hydrothermal event is the situation observed in the Valley of Ten Thousand Smokes (Alaska, USA), where hundreds of steam fumaroles with measured temperatures as high as 645??C persisted for 10 to 15 years in the much smaller welded ash-flow tuff sheet (??? 200 m thick) produced by the 1912 Katmai eruption.

Journal of Volcanology and Geothermal Research↗

40Ar/39Ar and 18O/16O studies of the Chegem ash-flow caldera and the Eldjurta Granite: Cooling of two late Pliocene igneous bodies in the Greater Caucasus Mountains, Russia

Volcanic and intrusive rocks of the Chegem caldera and the nearby Eldjurta (Eldzhurtinskiy) Granite record a late Pliocene episode of silicic magmatism in the north-central Caucasus Mountains. Surface exposures, created by the recent rapid uplift and erosion of the Caucasus Mountains, span a 2 km vertical section of Chegem caldera fill and 1150 m of the Eldjurta Granite; cored mineral-exploration drillholes in the Eldjurta Granite extend the sampling to a depth of 4 km. The unique sampling range available in these two young igneous bodies affords an excellent opportunity to study their denudation and cooling histories, which we examine by means of 40 Ar/ 39 Ar and 18 O/ 16 O measurements on an extensive sample suite. Total-fusion biotite and sanidine ages from eight Chegem Tuff samples, both intracaldera and outflow, are analytically indistinguishable with a weighted mean of 2.82 ± 0.02 Ma. A cross-cutting granodiorite porphyry intrusion has a sanidine total fusion age of 2.84 ± 0.03 Ma, and whole-rock incremental heating of a post-caldera andesite flow, which caps the caldera fill, yields an age of 2.82 ± 0.02 Ma. Thus, caldera formation and post-caldera resurgence and volcanism all occurred within a very short time (< 50,000 yr). Biotite total-fusion ages of ten Eldjurta Granite samples, including seven from ∼ 500 m intervals in the 4 km deep drillhole, show a systematic linear decrease in age with depth from 1.90 Ma near the roof contact of the granite to 1.56 Ma at a depth of 3700 m. Assuming these ages were set at the same temperature, this age/depth gradient implies an isotherm migration rate of 13 mm/yr between 1.90 and 1.56 Ma. This migration rate is due to a combination of rapid denudation and downward relaxation of isotherms, with cooling rates between 200 and 500°C/Ma during this period. Oxygen isotopic compositions of quartz, K-feldspar, plagioclase and biotite from the drillhole samples below the 800 m depth are fairly uniform and record primary igneous δ 18 O values with little evidence for subsolidus hydrothermal activity. However, in surface outcrop samples and in the shallowest drillhole sample, mineral δ 18 O values have been lowered by up to 3‰ by interaction with an external (meteoric-hydrothermal?) fluid. The primary mineral δ 18 O values of the Eldjurta Granite are distinctly higher than the corresponding phenocryst δ 18 O values in the Chegem volcanic rocks, indicating that the two bodies evolved as separxate magma batches.

Caucasus Mountains, Chegem Caldera↗

2.8-Ma ash-flow caldera at Chegem River in the northern Caucasus Mountains (Russia), contemporaneous granites, and associated ore deposits

Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ?? 0.02 Ma (sanidine and biotite 40Ar/39Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical calderas of continental-margin volcanic arcs. Erosional remnants of the outflow Chegem Tuff sheet extend at least 50 km north from the source caldera in the upper Chegem River. These outflow remnants were previously interpreted by others as erupted from several local vents, but petrologic similarities indicate a common origin and correlation with thick intracaldera Chegem Tuff. The 11 ?? 15 km caldera and associated intrusions are superbly exposed over a vertical range of 2,300 m in deep canyons above treeline (elev. to 3,800 m). Densely welded intracaldera Chegem Tuff, previously described by others as a rhyolite lava plateau, forms a single cooling unit, is > 2 km thick, and contains large slide blocks from the caldera walls. Caldera subsidence was accommodated along several concentric ring fractures. No prevolcanic floor is exposed within the central core of the caldera. The caldera-filling tuff is overlain by andesitic lavas and cut by a 2.84 ?? 0.03-Ma porphyritic granodiorite intrusion that has a cooling age analytically indistinguishable from that of the tuffs. The Eldjurta Granite, a pluton exposed low in the next large canyon (Baksan River) 10 km to the northwest of the caldera, yields variable K-feldspar and biotite ages (2.8 to 1.0 Ma) through a 5-km vertical range in surface and drill-hole samples. These variable dates appear to record a prolonged complex cooling history within upper parts of another caldera-related pluton. Major W-Mo ore deposits at the Tirniauz mine are hosted in skarns and hornfels along the roof of the Eldjurta Granite, and associated aplitic phases have textural features of Climax-type molybdenite porphyries in the western USA. Similar 40Ar/39Ar ages, mineral chemistry, and bulk-rock compositions indicate that the Chegem Tuff, intracaldera intrusion, and Eldjurta Granite are all parts of a large magmatic system that broadly resembles the middle Tertiary Questa caldera system and associated Mo deposits in northern New Mexico, USA. Because of their young age and superb three-dimensional exposures, rocks of the Chegem-Tirniauz region offer exceptional opportunities for detailed study of caldera structures, compositional gradients in volcanic rocks relative to cogenetic granites, and the thermal and fluid-flow history of a large young upper-crustal magmatic system. ?? 1993.

Journal of Volcanology and Geothermal Research↗