Geology topics

Brent T. Aulenbach

Publications and source records attributed to Brent T. Aulenbach.

At least 19 recordsLinked to original sources

USGS2026

Methods for estimating selected low-flow frequency and mean annual flow statistics at gaged and ungaged locations on streams in Georgia, North Carolina, and South Carolina

The U.S. Geological Survey, in cooperation with the Georgia Department of Natural Resources (Environmental Protection Division), North Carolina Department of Environmental Quality (Division of Water Resources), North Carolina Department of Public Safety (Office of Recovery and Resiliency), and South Carolina Department of Environmental Services, updated low-flow frequency, mean annual flow, and flow-duration statistics at 843 streamgages in and near Georgia, North Carolina, and South Carolina. The low-flow frequency statistics are annual minimum 1-day average flow with a 10-year recurrence interval (1Q10), annual minimum 7-day average flow for 2- and 10-year recurrence intervals (7Q2 and 7Q10, respectively), and annual minimum 30-day average flow with 2- and 3-year recurrence intervals (30Q2 and 30Q3, respectively). Monthly 1Q10 and 7Q10, and W7Q10 flow statistics for the winter period (November–March) also are presented. By using data from 604 of the streamgages on streams with streamflows that are not substantially affected by regulation or diversion and are not tidally influenced, regional regression equations were developed to predict flow statistics with prediction intervals at ungaged locations on streams with those same criteria. The regional regression analysis included data from 132 streamgages from adjacent States Alabama, Florida, Tennessee, and Virginia. The final regional regression equations include variables such as drainage area, streamflow variability, precipitation, percentage of impervious area, and percentage of the basin in various ecoregions. The low-flow statistics for the streamgages analyzed and the regional regression equations will be integrated into the U.S. Geological Survey StreamStats application ( https://www.usgs.gov/streamstats ) for Georgia, North Carolina, and South Carolina. StreamStats generates basin characteristics needed to compute low-flow frequency statistics for ungaged locations. A trend analysis of annual minimum 7-day average flows was done for 78 streamgages with at least 30 years of continuous record. Trends were evaluated for 30-, 50‑, 70-, and 90-year periods, ending in climate year 2021, and independence and short- and long-term persistence assumptions were considered. For all trend analysis assumptions, most streamgages did not exhibit significant trends in annual minimum 7-day average flows. Trends in annual precipitation and air temperature were similarly evaluated for the period 1895–2021 to assess the variability of climate for Georgia, North Carolina, and South Carolina.

Georgia, North Carolina, South Carolina↗

USGS2025

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia↗

USGS2023

Hydrology, water-quality, and watershed characteristics in 15 watersheds in Gwinnett County, Georgia, water years 2002–20

The U.S. Geological Survey, in cooperation with Gwinnett County Department of Water Resources, established the Long-Term Trend Monitoring program in 1996 to monitor and analyze the hydrologic and water-quality conditions in Gwinnett County, Georgia. Gwinnett County is a suburban to urban area northeast of the city of Atlanta in north-central Georgia. The monitoring program currently consists of 15 watersheds ranging in size from 1.3 to about 161 square miles. This report synthesizes watershed characteristics and hydrologic and water-quality monitoring data collected for water years (WYs) 2002–20. The 15 study watersheds were characterized for land-surface elevations, average land-surface slopes, septic densities, sanitary sewer densities, and detention pond areas. Temporal patterns in watershed characteristics were determined for land cover (2001–19), percent imperviousness (2000–20), population density (2000–20), and building density (1950–2022). In 2001, most of the watersheds had at least 45 percent of their land cover composed of developed land cover groups, and by 2019, at least 59 percent of each watershed was developed. Land cover changes occurred most rapidly between 2004 and 2008 at most watersheds. Percent imperviousness in the study watersheds varied substantially and ranged from 14.75 to 55.13 percent in 2019. Precipitation and runoff were quantified at all study watersheds for WYs 2002–20, and the hydrologic cycle was evaluated both annually and seasonally. Several 1-year or longer droughts occurred during this period. Study area precipitation averaged 51.5 inches per year and runoff averaged 22.5 inches per year. Variations in annual runoff were largely determined by annual precipitation but were also dependent upon watershed storage. Runoff varied seasonally because of high evapotranspiration rates in the summer and changes in base flow associated with seasonal changes in watershed storage. Fifty-one percent of runoff in the study area occurred as base flow. Watersheds with higher imperviousness had higher stormflows because of increased surface runoff and lower base flows because of reduced infiltration that recharges watershed storage. Turbidity, water temperature, and specific conductance were continuously measured at each study site. These constituents varied seasonally, diurnally, and with streamflow. A minimum of two base-flow and six stormflow samples were collected per year at each watershed and were analyzed for 21 water-quality constituents (water temperature, laboratory specific conductance, pH, and turbidity, biochemical and chemical oxygen demand, suspended sediments, nutrients, base cations, trace metals, and total dissolved solids). Concentrations of most particulate constituents were approximately one-half or more orders of magnitude higher in stormflow samples than in base-flow samples. Total copper and zinc stormflow concentrations exceeded the national recommended aquatic life criteria for acute conditions to varying degrees. Annual loads and yields were estimated for 12 constituents (which include suspended sediments, nutrients, base cations, trace metals, and total dissolved solids) using a surrogate regression model approach and the Beale load estimator. Loads were typically higher for years with higher runoff. The proportional range of annual loads for total suspended solids, suspended-sediment concentrations, total phosphorus, and total lead, however, were 3.2 to 4.8 times larger than for annual runoff. Higher-than-expected annual sediment loads occurred in the years that also had some of the highest peak flows during the period, indicating that large storms are responsible for much of the sediment transport. Large development projects in proximity to streams also were related to years with high sediment loads. Yields from the Crooked Creek and North Fork Peachtree Creek watersheds were typically among the highest for 8 of the 12 constituents. These watersheds had the two highest amounts of developed medium plus high intensity land cover and the two highest percentages of imperviousness. Moderate to strong correlations were identified between seven of the constituent yields and the percentage of developed medium and high intensity land cover groups. Temporal trends in concentrations and loads were identified for 140 of the 300 possible watershed-time period-constituent combinations. There were substantially more negative than positive temporal trends identified during WYs 2003–10, whereas the number of negative and positive temporal trends were similar during WYs 2010–20. Measures of sediment transport had the most negative temporal trends. A few watersheds had consistent trends across several constituents; however, these trends did not appear to be associated with temporal changes in development or imperviousness. This study provides a thorough assessment of watershed characteristics, hydrology, and water-quality conditions and trends for the 15 study watersheds and can be used to identify possible factors that affect runoff and water quality and determine changes in water-quality conditions. Watershed managers can use these data and analyses to inform management decisions regarding the designated uses of streams, minimization of flooding, protection of aquatic habitats, and optimization of the effectiveness of best management practices.

Georgia↗

USGS2023

Evaluating the spatial and temporal variability of groundwater uptake by riparian vegetation in a humid southeastern US catchment

In environments with shallow water tables, vegetation may use groundwater to support transpiration (T G ). This process has been carefully studied in some arid climates but rarely in humid climates—even those with severe droughts and seasonal water deficits. As such, the role of T G in humid-catchment hydrology is poorly constrained. We analysed water table fluctuations from nine monitoring wells along three transects in a second-order forested catchment to estimate T G at plot and whole-riparian zone scales. Average T G estimated around all well locations ranged from 1.06 to 4.95 mm d −1 and did not change systematically as a function of distance from stream channel or with plot-scale tree basal area. Counter to some previous studies, we found that T G was greater when the water table depth was deeper. Furthermore, the pattern of T G with water table depth was not monotonic at all locations. The ratio of T G to potential evapotranspiration tended to increase over the growing season, reflecting the progressive decrease in soil moisture storage and a greater reliance by vegetation on groundwater. Due to the lack of consistent spatial patterns in T G , we explored the number of monitoring wells needed to consistently estimate average T G within the 95% confidence bounds of the true mean. Based on this analysis, six or more wells were needed to consistently fall within the 95% confidence interval of the true mean. While this is based on the observed variability at a single site, it provides information for others considering this approach in similar upland forested catchments in humid regions.

Ecohydrology↗

USGS2022

Hydrology and water quality in 15 watersheds in DeKalb County, Georgia, 2012–16

The U.S. Geological Survey, in cooperation with DeKalb County Department of Watershed Management, established a long-term water-quantity and water-quality monitoring program in 2012 to monitor and analyze the hydrologic and water-quality conditions of 15 watersheds in DeKalb County, Georgia—an urban and suburban area located in north-central Georgia that includes the easternmost part of the City of Atlanta. This report synthesizes the watershed characteristics and monitoring data collected for the first 5 years of the program, 2012 through 2016. The study area was predominantly medium-density residential (43.9 percent), commercial/industrial/institutional (21.4 percent), forest/park/agriculture (13.6 percent), and high-density residential (11.5 percent) land uses. Land-surface slope averaged 8.7 percent, imperviousness averaged 25.3 percent, and population density averaged 2,936 people per square mile. Watershed imperviousness ranged from 8.7 to 36.6 percent. In the study area for 2014 to 2016 (when streamflow data were available for all watersheds), runoff represented 40.9 percent of precipitation. Hydrograph separations indicated that 43 percent of runoff occurred as base flow, whereas the remainder occurred as stormflow. Higher watershed imperviousness was significantly related to higher amounts of runoff (Pearson product-moment correlation coefficient [ r ] = 0.517), higher runoff ratios ( r = 0.646), and lower amounts ( r = −0.637) and proportions ( r = −0.898) of base-flow runoff. Stormwater best management practices have been implemented in the study watersheds; however, these practices do not appear to fully mitigate the effects of urban development and land use on stream hydrology. Total copper, lead, and zinc concentrations in base-flow and stormflow samples exceeded the national recommended aquatic life criteria for chronic and acute conditions, respectively, to varying degrees. Escherichia coli density predictive regression models indicated that the U.S. Environmental Protection Agency’s Beach Action Value was exceeded at individual watersheds between 44.6 and 100 percent of the time. Exceedance of the Beach Action Value indicates possible unsafe conditions for primary contact recreation and could be used for timely notification of the potential health risks. Annual loads and yields were estimated for 15 constituents. Loads were typically higher for years with higher runoff while variations among watershed yields appear associated with watershed and land use characteristics. The lowest yields for almost all constituents occurred in the Stone Mountain Creek watershed—likely the result of the retention of sediment and reduction of nutrients in Stone Mountain Lake and two smaller downstream reservoirs within the watershed. The Little Stone Mountain Creek watershed also had some of the lowest yields for most constituents, likely due to the lack of many pollutant sources associated with its predominantly medium-density residential land use (95.5 percent), but had the highest total nitrate plus nitrite yields. The Intrenchment Creek watershed consistently had some of the highest yields across all constituents except for total nitrate plus nitrite. The high yields may be related to its high percentage of impervious area (36.0 percent) and high amount of heavily developed land use (high-density residential, 29.9 percent and commercial/industrial/institutional, 26.0 percent). Mean watershed constituent yields in this study were significantly higher than those from a similar analysis of 13 suburban to urban watersheds in adjacent Gwinnett County for 6 of the 10 constituents compared. This study provides a thorough assessment of watershed characteristics, hydrology, and water-quality conditions of the 15 study watersheds and can be used to identify possible factors that affect runoff and water quality. Watershed managers can use these data and analyses to inform management decisions regarding the designated uses of streams, minimization of flooding, protection of aquatic habitats, and optimization of the effectiveness of best management practices.

Georgia↗

USGS2021

The evolving perceptual model of streamflow generation at the Panola Mountain Research Watershed

The Panola Mountain Research Watershed (PMRW) is a 41‐hectare forested catchment within the Piedmont Province of the Southeastern United States. Observations, experimentation, and numerical modelling have been conducted at Panola over the past 35 years. But to date, these studies have not been fully incorporated into a more comprehensive synthesis. Here we describe the evolving perceptual understanding of streamflow generation mechanisms at the PMRW. We show how the long‐term study has enabled insights that were initially unforeseen but are also unachievable in short‐term studies. In particular, we discuss how the accumulation of field evidence, detailed site characterization, and modelling enabled a priori hypotheses to be formed, later rejected, and then further refined through repeated field campaigns. The extensive characterization of the soil and bedrock provided robust process insights not otherwise achievable from hydrometric measurements and numerical modelling alone. We focus on two major aspects of streamflow generation: the role of hillslopes (and their connection to the riparian zone) and the role of catchment storage in controlling fluxes and transit times of water in the catchment. Finally, we present location‐independent hypotheses based on our findings at PMRW and suggest ways to assess the representativeness of PMRW in the broader context of headwater watersheds.

Georgia↗

USGS2020

Monitoring and real-time modeling of Escherichia coli bacteria for the Chattahoochee River, Chattahoochee River National Recreation Area, Georgia, 2000–2019

The Chattahoochee River National Recreation Area (CRNRA) is a National Park Service unit/park with 48 miles of urban waterway in the Atlanta metropolitan area. The Chattahoochee River within the CRNRA is a popular place for water-based recreation but is known to periodically experience elevated levels of fecal-coliform bacteria associated with warm-blooded animals that can result in a variety of pathogen-related human illnesses. In 2000, the National Park Service entered into a public-private partnership with the U.S. Geological Survey (USGS) and the Chattahoochee Riverkeeper, called the Chattahoochee River BacteriALERT program, to monitor Escherichia coli ( E. coli ), which is a fecal indicator bacteria and a proxy for human health risk from waterborne pathogens. The BacteriALERT network monitors E. coli densities at three stations on the Chattahoochee River within the CRNRA, at Norcross (USGS station 02335000), Powers Ferry (USGS station 02335880), and Atlanta (USGS station 02336000). E. coli densities determined from water samples were compared to the U.S. Environmental Protection Agency’s Beach Action Value (BAV) of 235 colony forming units per 100 milliliters to assess whether conditions were considered safe for freshwater, primary contact recreational use. Sample E. coli densities exceeded the BAV for 15.5 percent of the samples collected at Norcross (n = 1,969) and 30.3 percent of the samples at Atlanta (n = 1,938) for the study period October 23, 2000, to May 23, 2019, and 33.6 percent of the samples from Powers Ferry (n = 134) for the study period May 5, 2016, to May 23, 2019. Models to predict E. coli densities in near real-time were developed for the three BacteriALERT stations. Models were developed using forward-stepwise multiple linear regression with the Bayesian Information Criteria and were calibrated with samples collected between October 4, 2007, and May 23, 2019. Explanatory variables included season, turbidity, water temperature, streamflow, upstream tributary streamflows, and temporal trend. The most statistically significant explanatory variables in the models were turbidity, upstream tributary streamflows, and season. The Norcross model had an increasing trend in E. coli densities of 2.3 percent per year. A significant trend was not detected for the Atlanta station, while trends were not assessed for Powers Ferry models due to the short (3-year) calibration period. Model adjusted R 2 s ranged from 0.686 (Atlanta) to 0.795 (Norcross with time trend) indicating that the models explained a substantial portion of the variations in E. coli densities. Evaluation of model predictions and residuals indicated that models were well posed and exhibited little bias. The models performed well in accurately determining compliance and exceedance of the BAV with low misidentification rates ranging from 3.5 percent (Norcross) to 11.3 percent (Powers Ferry). Misidentification was most common for densities near the BAV, and misidentification rates in the study were low despite fairly low model precisions because E. coli densities were infrequently near the BAV. The precisions of the models developed herein were comparable to the more complex models developed by Lawrence (2012) that were never implemented in the BacteriALERT program due to their computational complexity. The predictive E. coli models developed herein will improve the ability to assess the health risks of water-based recreational activities in the CRNRA in near real-time.

Georgia↗

USGS2019

Effects of climate-related variability in storage on streamwater solute concentrations and fluxes in a small forested watershed in the Southeastern United States

Streamwater quality can be affected by climate-related variability in hydrologic state, which controls flow paths and affects biogeochemical processes. Thirty-one years of input/output solute fluxes at Panola Mountain Research Watershed, a small, forested, seasonally water-limited watershed near Atlanta, Georgia, were used to quantify the effects of climatic-related variability in storage on streamwater solute concentrations and fluxes. Streamwater fluxes were estimated for ten solutes from weekly and event sample concentrations using regression-based methods. The most pertinent storage attribute (current or antecedent watershed, shallow, and deep storage) for each solute was determined by fitting separate concentration relationships. The concentration-discharge relationships varied more for reactive solutes such as potassium, sulfate, and DOC and less for weathering products (base cations and dissolved silica) and conservative chloride. Many solutes exhibited higher concentrations when storage levels were lower or wetting up, which was likely the result of the concentrating effects of evapotranspiration and/or the buildup and flushing of weathering products associated with longer residence times. The impacts of storage modeling on annual fluxes varied by solute, ranging from about 5% (magnesium) to 52% (nitrate) as relative standard deviations, and sufficiently removed climate-related patterns observed in streamwater concentrations. Sulfate was particularly mobilized following growing season droughts but only if deep storage was sufficiently recharged, possibly indicating that sulfides in the deep storage pool were oxidized to sulfate during droughts and mobilized when re-wetted. The lack of streamwater sulfate response to 61% declines in atmospheric deposition indicates the importance of watershed biogeochemical processes on controls of streamwater export of sulfate. The approach of explicitly incorporating storage in the streamwater concentration modeling elucidated the effects of climate on streamwater water-quality and may provide insight into the effects of climatic change on future fluxes.

Georgia↗

USGS2018

Quantifying climate-related interactions in shallow and deep storage and evapotranspiration in a forested, seasonally water-limited watershed in the Southeastern United States

The Southeastern United States experiences recurring hydrological droughts, which can reduce water availability and can result in water-limiting conditions. Long-term monitoring at Panola Mountain Research Watershed, a small, forested, seasonally water-limited watershed near Atlanta, Georgia, was used to quantify the interactions of climatic variability with shallow and deep storage and evapotranspiration. Watershed storage (WS) and actual evapotranspiration (AET) were estimated monthly from 1985 through 2015 using a water-budget approach combined with a WS-baseflow relationship. Shallow storage (SS) was assessed from a soil moisture profile. Soil moisture transitioned from recharge to surplus as SS increased from its field capacity to a nearly saturated state during the dormant season, and transitioned from utilization to climatic water deficits as SS declined from its field capacity to its wilting point during the growing season. Deeper storage was unavailable to AET during dry conditions. The majority of deeper storage recharge occurred during the dormant season and required SS to be wet. WS was an effective drought indicator. Growing season droughts typically occurred when WS was below normal at the end of the dormant season and growing season precipitation (P) was below or near normal. A hydrologic persistence analysis found that monthly-standardized WS was significantly correlated (p-value <0.05) with past monthly-standardized WS for the previous 19 months and with past monthly P for the previous 11 months, indicating the importance of past hydrologic conditions on WS. Expected climatic changes affected recharge during the dormant season and deficits during the growing season.

Water Resources Research↗

USGS2017

Hydrology and water quality in 13 watersheds in Gwinnett County, Georgia, 2001–15

The U.S. Geological Survey (USGS), in cooperation with Gwinnett County Department of Water Resources, established a Long-Term Trend Monitoring (LTTM) program in 1996. The LTTM program is a comprehensive, long-term, water-quantity and water-quality monitoring program designed to document and analyze the hydrologic and water-quality conditions of selected watersheds in Gwinnett County, Georgia. Water-quality monitoring initially began in six watersheds and currently [2016] includes 13 watersheds. As part of the LTTM program, streamflow, precipitation, water temperature, specific conductance, and turbidity were measured every 15 minutes for water years 2001–15 at 12 of the 13 watershed monitoring stations and for water years 2010–15 at the other watershed. In addition, discrete water-quality samples were collected seasonally from May through October (summer) and November through April (winter), including one base-flow and three stormflow event composite samples, during the study period. Samples were analyzed for nutrients (nitrogen and phosphorus), total organic carbon, trace elements (total lead and total zinc), total dissolved solids, and total suspended sediment (total suspended solids and suspended-sediment concentrations). The sampling scheme was designed to identify variations in water quality both hydrologically and seasonally. The 13 watersheds were characterized for basin slope, population density, land use for 2012, and the percentage of impervious area from 2000 to 2014. Several droughts occurred during the study period—water years 2002, 2007–08, and 2011–12. Watersheds with the highest percentage of impervious areas had the highest runoff ratios, which is the portion of precipitation that occurs as runoff. Watershed base-flow indexes, the ratio of base-flow runoff to total runoff, were inversely correlated with watershed impervious area. Flood-frequency estimates were computed for 13 streamgages in the study area that have 10 or more years of annual peak flow data through water year 2015, using the expected moments algorithm to fit a Pearson Type III distribution to logarithms of annual peak flows. Kendall’s tau nonparametric test was used to determine the statistical significance of trends in the annual peak flows, with none of the 13 streamgages exhibiting significant trends. A comparison of base-flow and stormflow water-quality samples indicates that turbidity and concentrations of total ammonia plus organic nitrogen, total nitrogen, total phosphorus, total organic carbon, total lead, total zinc, total suspended solids, and suspended-sediment concentrations increased with increasing discharge at all watersheds. Specific conductance decreased during stormflow at all watersheds, and total dissolved solids concentrations decreased during stormflow at a few of the watersheds. Total suspended solids and suspended-sediment concentrations typically were two orders of magnitude higher in stormflow samples, turbidities were about 1.5 orders of magnitude higher, total phosphorus and total zinc were about one order of magnitude higher, and total ammonia plus organic nitrogen, total nitrogen, total organic carbon, and total lead were about twofold higher than in base-flow samples. Seasonality and long-term trends were identified for the period water years 2001–15 for 10 constituents—total nitrogen, total nitrate plus nitrite, total phosphorus, dissolved phosphorus, total organic carbon, total suspended solids, suspended-sediment concentration, total lead, total zinc, and total dissolved solids. Seasonal patterns were present in most watersheds for all constituents except total dissolved solids, and the watersheds had fairly similar patterns of higher concentrations in the summer and lower concentrations in the winter. A linear long-term trend analysis of residual concentrations from the flow-only load estimation model (without time-trend terms) identified significant trends in 67 of the 130 constituent-watershed combinations. Seventy percent of the significant trends were negative. Total organic carbon and total dissolved solids had predominantly positive trends. Total phosphorus, total suspended solids, suspended-sediment concentration, total lead, and total zinc had only negative trends. The other three constituents exhibited fewer trends, both positive and negative. Streamwater loads were estimated annually for the 13-year period water years 2003–15 for the same 10 constituents in the trend analysis. Loads were estimated using a regression-model-based approach developed by the USGS for the Gwinnett County LTTM program that accommodates the use of storm-event composited samples. Concentrations were modeled as a function of discharge, base flow, time, season, and turbidity to improve model predictions and reduce errors in load estimates. Total suspended solids annual loads have been identified in Gwinnett County’s Watershed Protection Plan for target performance criterion. Although the amount of annual runoff was the primary factor in variations in annual loads, climatic conditions (classified as dry, average, or wet) affected annual loads beyond what was attributed to climatic-related variations in annual runoff. Significant negative trends in loads were estimated for the combined area of the watersheds for all constituents except dissolved phosphorus, total organic carbon, and total dissolved solids. The trend analysis indicated that total suspended solids and suspended-sediment concentration loads in the study area were decreasing by 57,000 and 87,000 pounds per day per year, respectively. Variations in constituent yields between watersheds appeared to be related to various watershed characteristics. Suspended sediment (as either total suspended solids or suspended-sediment concentrations), along with constituents transported predominately in solid phase (total phosphorus, total organic carbon, total lead, and total zinc), and total dissolved solids typically had higher yields from watersheds that had high percentages of impervious areas or high basin slope. High total nitrogen yields were also associated with watersheds with high percentages of impervious areas. Low total nitrogen, total suspended solids, total lead, and total zinc yields appeared to be associated with watersheds that had a low percentage of high-density development.

Georgia↗

USGS2017

Effects of impervious area and BMP implementation and design on storm runoff and water quality in eight small watersheds

The effects of increases in effective impervious area (EIA) and the implementation of water quality protection designed detention pond best management practices (BMPs) on storm runoff and stormwater quality were assessed in Gwinnett County, Georgia, for the period 2001-2008. Trends among eight small watersheds were compared, using a time trend study design. Significant trends were detected in three storm hydrologic metrics and in five water quality constituents that were adjusted for variability in storm characteristics and climate. Trends in EIA ranged from 0.10 to 1.35, and changes in EIA treated by BMPs ranged from 0.19 to 1.32; both expressed in units of percentage of drainage area per year. Trend relations indicated that for every 1% increase in watershed EIA, about 2.6, 1.1, and 1.5% increases in EIA treated by BMPs would be required to counteract the effects of EIA added to the watersheds on peak streamflow, stormwater yield, and storm streamflow runoff, respectively. Relations between trends in EIA, BMP implementation, and water quality were counterintuitive. This may be the result of (1) changes in constituent inputs in the watersheds, especially downstream of areas treated by BMPs; (2) BMPs may have increased the duration of stormflow that results in downstream channel erosion; and/or (3) spurious relationships between increases in EIA, BMP implementation, and constituent inputs with development rates.

Journal of the American Water Resources Associatio↗

USGS2016

Spatial and temporal patterns of dissolved organic matter quantity and quality in the Mississippi River Basin, 1997–2013

Recent studies have found insignificant or decreasing trends in time-series dissolved organic carbon (DOC) datasets, questioning the assumption that long-term DOC concentrations in surface waters are increasing in response to anthropogenic forcing, including climate change, land use, and atmospheric acid deposition. We used the weighted regressions on time, discharge, and season (WRTDS) model to estimate annual flow-normalized concentrations and fluxes to determine if changes in DOC quantity and quality signal anthropogenic forcing at 10 locations in the Mississippi River Basin. Despite increases in agriculture and urban development throughout the basin, net increases in DOC concentration and flux were significant at only 3 of 10 sites from 1997 to 2013 and ranged between −3.5% to +18% and −0.1 to 19%, respectively. Positive shifts in DOC quality, characterized by increasing specific ultraviolet absorbance at 254 nm, ranged between +8% and +45%, but only occurred at one of the sites with significant DOC quantity increases. Basinwide reductions in atmospheric sulfate deposition did not result in large increases in DOC either, likely because of the high buffering capacity of the soil. Hydroclimatic factors including annual discharge, precipitation, and temperature did not significantly change during the 17-year timespan of this study, which contrasts with results from previous studies showing significant increases in precipitation and discharge over a century time scale. Our study also contrasts with those from smaller catchments, which have shown stronger DOC responses to climate, land use, and acidic deposition. This temporal and spatial analysis indicated that there was a potential change in DOC sources in the Mississippi River Basin between 1997 and 2013. However, the overall magnitude of DOC trends was not large, and the pattern in quantity and quality increases for the 10 study sites was not consistent throughout the basin.

Hydrological Processes↗

USGS2016

Approaches to stream solute load estimation for solutes with varying dynamics from five diverse small watershed

Estimating streamwater solute loads is a central objective of many water-quality monitoring and research studies, as loads are used to compare with atmospheric inputs, to infer biogeochemical processes, and to assess whether water quality is improving or degrading. In this study, we evaluate loads and associated errors to determine the best load estimation technique among three methods (a period-weighted approach, the regression-model method, and the composite method) based on a solute's concentration dynamics and sampling frequency. We evaluated a broad range of varying concentration dynamics with stream flow and season using four dissolved solutes (sulfate, silica, nitrate, and dissolved organic carbon) at five diverse small watersheds (Sleepers River Research Watershed, VT; Hubbard Brook Experimental Forest, NH; Biscuit Brook Watershed, NY; Panola Mountain Research Watershed, GA; and Río Mameyes Watershed, PR) with fairly high-frequency sampling during a 10- to 11-yr period. Data sets with three different sampling frequencies were derived from the full data set at each site (weekly plus storm/snowmelt events, weekly, and monthly) and errors in loads were assessed for the study period, annually, and monthly. For solutes that had a moderate to strong concentration–discharge relation, the composite method performed best, unless the autocorrelation of the model residuals was <0.2, in which case the regression-model method was most appropriate. For solutes that had a nonexistent or weak concentration–discharge relation (model R 2 < about 0.3), the period-weighted approach was most appropriate. The lowest errors in loads were achieved for solutes with the strongest concentration–discharge relations. Sample and regression model diagnostics could be used to approximate overall accuracies and annual precisions. For the period-weighed approach, errors were lower when the variance in concentrations was lower, the degree of autocorrelation in the concentrations was higher, and sampling frequency was higher. The period-weighted approach was most sensitive to sampling frequency. For the regression-model and composite methods, errors were lower when the variance in model residuals was lower. For the composite method, errors were lower when the autocorrelation in the residuals was higher. Guidelines to determine the best load estimation method based on solute concentration–discharge dynamics and diagnostics are presented, and should be applicable to other studies.

Ecosphere↗

USGS2015

The river as a chemostat: fresh perspectives on dissolved organic matter flowing down the river continuum

A better understanding is needed of how hydrological and biogeochemical processes control dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) composition from headwaters downstream to large rivers. We examined a large DOM dataset from the National Water Information System of the US Geological Survey, which represents approximately 100 000 measurements of DOC concentration and DOM composition at many sites along rivers across the United States. Application of quantile regression revealed a tendency towards downstream spatial and temporal homogenization of DOC concentrations and a shift from dominance of aromatic DOM in headwaters to more aliphatic DOM downstream. The DOC concentration–discharge (C-Q) relationships at each site revealed a downstream tendency towards a slope of zero. We propose that despite complexities in river networks that have driven many revisions to the River Continuum Concept, rivers show a tendency towards chemostasis (C-Q slope of zero) because of a downstream shift from a dominance of hydrologic drivers that connect terrestrial DOM sources to streams in the headwaters towards a dominance of instream and near-stream biogeochemical processes that result in preferential losses of aromatic DOM and preferential gains of aliphatic DOM.

Canadian Journal of Fisheries and Aquatic Sciences↗

USGS2014

Concentrations and transport of suspended sediment, nutrients, and pesticides in the lower Mississippi-Atchafalaya River subbasin during the 2011 Mississippi River flood, April through July

High streamflow associated with the April–July 2011 Mississippi River flood forced the simultaneous opening of the three major flood-control structures in the lower Mississippi-Atchafalaya River subbasin for the first time in history in order to manage the amount of water moving through the system. The U.S. Geological Survey (USGS) collected samples for analysis of field properties, suspended-sediment concentration, particle-size, total nitrogen, nitrate plus nitrite, total phosphorus, orthophosphate, and up to 136 pesticides at 11 water-quality stations and 2 flood-control structures in the lower Mississippi-Atchafalaya River subbasin from just above the confluence of the upper Mississippi and Ohio Rivers downstream from April through July 2011. Monthly fluxes of suspended sediment, suspended sand, total nitrogen, nitrate plus nitrite, total phosphorus, orthophosphate, atrazine, simazine, metolachlor, and acetochlor were estimated at 9 stations and 2 flood-control structures during the flood period. Although concentrations during the 2011 flood were within the range of what has been observed historically, concentrations decreased during peak streamflow on the lower Mississippi River. Prior to the 2011 flood, high concentrations of suspended sediment and nitrate were observed in March 2011 at stations downstream of the confluence of the upper Mississippi and Ohio Rivers, which probably resulted in a loss of available material for movement during the flood. In addition, the major contributor of streamflow to the lower Mississippi-Atchafalaya River subbasin during April and May was the Ohio River, whose water contained lower concentrations of suspended sediment, pesticides, and nutrients than water from the upper Mississippi River. Estimated fluxes for the 4-month flood period were still quite high and contributed approximately 50 percent of the estimated annual suspended sediment, nitrate, and total phosphorus fluxes in 2011; the largest fluxes were estimated at the water-quality station located at Vicksburg, Mississippi. The majority of the suspended-sediment flux introduce into the lower Mississippi-Atchafalaya River subbasin during the 2011 flood was in the form of fine-grained particles from the upper Mississippi River—77 percent of the suspended-sediment flux compared to 23 percent from the Ohio River. As water moved downstream along the lower Mississippi River, there were losses in suspended-sediment flux because of deposition and backwater areas. Fluxes showed a greater response to increased streamflow in the Atchafalaya River than in the lower Mississippi River. The result was a gain in suspended-sediment flux with distance downstream in the Atchafalaya River because of resuspension of previously deposited materials—particularly sand particles. Overall, 13 percent less suspended sediment left the lower Mississippi-Atchafalaya River subbasin than entered it from the confluence of the upper Mississippi and Ohio Rivers during the flood. The loss in suspended-sediment flux during the flood accounted for 14 percent of the 2011 annual suspended-sediment flux loss within the lower Mississippi-Atchafalaya River subbasin. Nitrate composed approximately 70 percent of the total nitrogen flux at all of the sampled water-quality stations, excluding the Arkansas River. Almost 2.4 times more nitrate flux entered the lower Mississippi-Atchafalaya River subbasin from the upper Mississippi River than from the Ohio River. As nitrate moved down the lower Mississippi River and the Atchafalaya River, there were no substantial losses or gains in flux, indicating that nitrate moved conservatively within the subbasin during the 2011 flood. Although streamflow was the largest on record, nitrate flux during the flood period resulted in a zone of hypoxia in the Gulf of Mexico that was only the tenth largest on record. The flux of total phosphorus in the lower Mississippi-Atchafalaya River subbasin during the 2011 flood was strongly related to suspended-sediment flux at most of the stations. There were significant gains in total phosphorus flux in the Atchafalaya River during the flood period and losses between the stations along the lower Mississippi River. Overall, however, the amount of total phosphorus flux that left the lower Mississippi-Atchafalaya River subbasin was only 1.7 percent less than the flux that entered it from the upper Mississippi River and the Ohio River, indicating that total phosphorus flux within the subbasin during the flood was conservative. As streamflow was decreasing within the lower Mississippi-Atchafalaya River subbasin, orthophosphate composed an increasing percentage of the total phosphorus concentration, probably because of the return of waters low in oxygen concentration from areas such as inundated lands, backwater streams, and floodways. Poorly oxygenated waters promote the release of sediment-bound phosphorus into the more-readily available dissolved form (measured as orthophosphate in this study). Because of processing within the subbasin during the flood period, there was a 25-percent gain in orthophosphate flux between the confluence of the upper Mississippi and Ohio Rivers and the outlet of the subbasin. Of the 136 pesticide compounds and degradates that were analyzed, only 18 were detected above the method reporting level. The 18 compounds that were detected fell into three categories: (1) compounds that were frequently detected and showed a response in concentration to the flood; (2) compounds that were detected in almost every sample at every station but at low concentrations; and (3) compounds that were infrequently detected. Fluxes for the most frequently detected pesticides having the highest concentrations (atrazine, metolachlor, acetochlor, and simazine) were within the low-to-middle range of historic fluxes. An average of 66,450 cubic feet per second of streamflow was diverted from the lower Mississippi River through the Morganza Floodway into the Atchafalaya River from May 14 through July 7, 2011. Dissolved oxygen concentrations in the floodway decreased with the amount of time that the flood control structure was open, which affected nitrate and orthophosphate concentrations. As dissolved oxygen concentrations decreased in the floodway, nitrate concentrations decreased and orthophosphate concentrations increased. Oil and gas samples were also collected at 1 station upstream and 1 station downstream from the outlet of the Morganza Floodway into the Atchafalaya River. There were no detections of petroleum hydrocarbons in the upstream or downstream samples. All concentrations of oil and grease were relatively low, and the effect of water from the floodway on water quality in the Atchafalaya River could not be determined because oil and grease samples were not collected from the floodway.

Lower Mississippi-atchafalaya River Subbasin;Missi↗

USGS2014

Watershed characteristics and water-quality trends and loads in 12 watersheds in Gwinnett County, Georgia

The U.S. Geological Survey, in cooperation with Gwinnett County Department of Water Resources, established a Long-Term Trend Monitoring (LTTM) program in 1996. The LTTM program is a comprehensive, long-term, water-quantity and water-quality monitoring program designed to document and analyze the hydrologic and water-quality conditions of selected watersheds of Gwinnett County, Georgia. Water-quality monitoring initially began in six watersheds and was expanded to another six watersheds in 2001. As part of the LTTM program, streamflow, precipitation, water temperature, specific conductance, and turbidity were measured continuously at the 12 watershed monitoring stations for water years 2004–09. In addition, discrete water-quality samples were collected seasonally from May through October (summer) and November through April (winter), including one base-flow and three stormflow event composite samples, during the study period. Samples were analyzed for nutrients (nitrogen and phosphorus), total organic carbon, trace elements (total lead and total zinc), total dissolved solids, and total suspended sediment (total suspended solids and suspended-sediment concentrations). The sampling scheme was designed to identify variations in water quality both hydrologically and seasonally. The 12 watersheds were characterized for basin slope, population density, land use for 2009, and the percentage of impervious area from 2000 to 2009. Precipitation in water years 2004–09 was about 18 percent below average, and the county experienced exceptional drought conditions and below average runoff in water years 2007 and 2008. Watershed water yields, the percentage of precipitation that results in runoff, typically are lower in low precipitation years and are higher for watersheds with the highest percentages of impervious areas. A comparison of base-flow and stormflow water-quality samples indicates that turbidity and concentrations of total ammonia plus organic nitrogen, total nitrogen, total phosphorus, total organic carbon, total lead, total zinc, total suspended solids, and suspended-sediment concentrations increased with increasing discharge at all watersheds. Specific conductance, however, decreased during stormflow at all watersheds, and total dissolved solids concentrations decreased during stormflow at a few of the watersheds. Total suspended solids and suspended-sediment concentrations typically were two orders of magnitude higher in stormflow samples, turbidities were about 1.5 orders of magnitude higher, total phosphorus and total zinc were about one order of magnitude higher, and total ammonia plus organic nitrogen, total nitrogen, total organic carbon, and total lead were about twofold higher than in base-flow samples. Seasonal patterns and long-term trends in flow-adjusted water-quality concentrations were identified for five representative constituents—total nitrogen, total phosphorus, total zinc, total dissolved solids, and total suspended solids. Seasonal patterns for all five constituents were fairly similar, with higher concentrations in the summer and lower concentrations in the winter. Significant linear long-term trends in stormflow composite concentrations were identified for 36 of the 60 constituent-watershed combinations (5 constituents multiplied by 12 watersheds) for the period of record through water year 2011. Significant trends typically were decreasing for total nitrogen, total phosphorus, total suspended solids, and total zinc and increasing for total dissolved solids. Total dissolved solids and total suspended solids trends had the largest magnitude changes per year. Stream water loads were estimated for 10 water-quality constituents. These estimates represent the cumulative effects of watershed characteristics, hydrologic processes, biogeochemical processes, climatic variability, and human influences on watershed water quality. Yields, in load per unit area, were used to compare loads from watersheds with different sizes. A load estimation approach developed for the Gwinnett County LTTM program that incorporates storm-event composited samples was used with some minor modifications. This approach employs the commonly used regression-model method. Concentrations were modeled as a function of discharge, time, season, and turbidity to improve model predictions and reduce errors in load estimates. Total suspended solids annual loads have been identified in Gwinnett County’s Watershed Protection Plan for target performance criterion. The amount of annual runoff is the primary factor in determining the amount of annual constituent loads. Below average runoff during water years 2004–09, especially during water years 2006–08, resulted in corresponding below average loads. Variations in constituent yields between watersheds appeared to be related to various watershed characteristics. Suspended sediment (total suspended solids and suspended-sediment concentrations) along with constituents transported predominately in solid phase (total phosphorus, total organic carbon, total lead, and total zinc) and total dissolved solids typically had higher yields from watersheds that had high percentages of impervious areas or high basin slope. High total nitrogen yields were also associated with watersheds with high percentages of impervious areas. Low total nitrogen, total suspended solids, total lead, and total zinc yields appear to be associated with watersheds that have a low percentage of high-density development. Total suspended solids yields were lower in drought years, water years 2007–08, from the combined effects of less runoff and the result of fewer, lower magnitude storms, which likely resulted in less surface erosion and lower stream sediment transport.

Georgia↗

USGS2013

Evaluation of high-frequency mean streamwater transit-time estimates using groundwater age and dissolved silica concentrations in a small forested watershed

Many previous investigations of mean streamwater transit times (MTT) have been limited by an inability to quantify the MTT dynamics. Here, we draw on (1) a linear relation ( r 2 = 0.97) between groundwater 3 H/ 3 He ages and dissolved silica (Si) concentrations, combined with (2) predicted streamwater Si concentrations from a multiple-regression relation ( R 2 = 0.87) to estimate MTT at 5-min intervals for a 23-year time series of streamflow [water year (WY) 1986 through 2008] at the Panola Mountain Research Watershed, Georgia. The time-based average MTT derived from the 5-min data was ~8.4 ± 2.9 years and the volume-weighted (VW) MTT was ~4.7 years for the study period, reflecting the importance of younger runoff water during high flow. The 5-min MTTs are normally distributed and ranged from 0 to 15 years. Monthly VW MTTs averaged 7.0 ± 3.3 years and ranged from 4 to 6 years during winter and 8–10 years during summer. The annual VW MTTs averaged 5.6 ± 2.0 years and ranged from ~5 years during wet years (2003 and 2005) to >10 years during dry years (2002 and 2008). Stormflows are composed of much younger water than baseflows, and although stormflow only occurs ~17 % of the time, this runoff fraction contributed 39 % of the runoff during the 23-year study period. Combining the 23-year VW MTT (including stormflow) with the annual average baseflow for the period (~212 mm) indicates that active groundwater storage is ~1,000 mm. However, the groundwater storage ranged from 1,040 to 1,950 mm using WY baseflow and WY VW MTT. The approach described herein may be applicable to other watersheds underlain by granitoid bedrock, where weathering is the dominant control on Si concentrations in soils, groundwater, and streamwater.

Georgia↗

USGS2013

Improving regression-model-based streamwater constituent load estimates derived from serially correlated data

A regression-model based approach is a commonly used, efficient method for estimating streamwater constituent load when there is a relationship between streamwater constituent concentration and continuous variables such as streamwater discharge, season and time. A subsetting experiment using a 30-year dataset of daily suspended sediment observations from the Mississippi River at Thebes, Illinois, was performed to determine optimal sampling frequency, model calibration period length, and regression model methodology, as well as to determine the effect of serial correlation of model residuals on load estimate precision. Two regression-based methods were used to estimate streamwater loads, the Adjusted Maximum Likelihood Estimator (AMLE), and the composite method, a hybrid load estimation approach. While both methods accurately and precisely estimated loads at the model’s calibration period time scale, precisions were progressively worse at shorter reporting periods, from annually to monthly. Serial correlation in model residuals resulted in observed AMLE precision to be significantly worse than the model calculated standard errors of prediction. The composite method effectively improved upon AMLE loads for shorter reporting periods, but required a sampling interval of at least 15-days or shorter, when the serial correlations in the observed load residuals were greater than 0.15. AMLE precision was better at shorter sampling intervals and when using the shortest model calibration periods, such that the regression models better fit the temporal changes in the concentration–discharge relationship. The models with the largest errors typically had poor high flow sampling coverage resulting in unrepresentative models. Increasing sampling frequency and/or targeted high flow sampling are more efficient approaches to ensure sufficient sampling and to avoid poorly performing models, than increasing calibration period length.

Illinois↗