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USGS2024

Comparison of water quality in shallow groundwater near agricultural areas in the Delaware Coastal Plain, 2014 and 2019

The State of Delaware has encouraged agricultural conservation practices to improve nutrient uptake by crops and mitigate nutrient transport to groundwater in the surficial aquifer. To study recent changes in groundwater quality, the U.S. Geological Survey and the Delaware Department of Agriculture (DDA) developed a network of shallow wells near agricultural areas throughout the Delaware Coastal Plain. This network was designed to characterize water quality related to agricultural practices and to detect any recent changes in shallow groundwater quality, in particular groundwater nitrate concentrations. The shallow well network was first sampled in 2014 and resampled in 2019. In 2019, field parameters (including dissolved oxygen, pH, specific conductance, and temperature), major ions, nutrients, stable isotopes of water, and isotopes of nitrate were measured in groundwater samples collected between October and December. Wells were organized into three groups based on their geochemical characteristics measured in 2014: the Agricultural, Urban, and Mixed Groups. Results from the 2019 sampling showed little change in water quality from the 2014 sampling. Land-use factors continued to be the driving influence between groups. Groundwater moves slowly and changes in groundwater quality are likely to respond slowly to changes in conservation practices. Continued sampling of both groundwater quality in this network and monitoring land management practices can help detect groundwater quality trends in the future.

Delaware↗

USGS2021

Occurrence and distribution of PFAS in sampled source water of public drinking-water supplies in the surficial aquifer in Delaware, 2018; PFAS and groundwater age-dating results

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (1) describe the occurrence and distribution of PFAS, and (2) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Delaware Coastal Plain between 2000 and 2008 and between 2008 and 2018. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November 2018. Groundwater collected from the wells was analyzed for the occurrence and distribution of 18 per- and polyfluorinated alkyl substances (PFAS) as well as groundwater age. Descriptive statistical analyses were performed to assess PFAS analytical results within the well network and the combined perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) concentrations were compared to the U.S. Environmental Protection Agency’s (EPA) health advisory level (HAL) for informational purposes only and not for evidence of compliance or noncompliance with Federal regulations. The EPA’s HAL is a health-based reference level for public drinking water as supplied to customers and is not applied to source (raw) water. Groundwater-age data were compared for sites sampled in 2000, 2008, and 2018 to document any changes. All samples were analyzed for 18 PFAS using EPA Method 537 (modified). Forty-four percent of the analyzed PFAS were detected in the study well network. Sixteen of the sampled wells have one or more PFAS detections, and as many as eight different PFAS were found in a single sample. Wells with a higher number of PFAS detected (five or more) were in New Castle and Sussex Counties. The PFAS most frequently detected were PFOA, with 47 percent detection; perfluorohexanoic acid (PFHxA), with 33 percent detection; and PFOS and perfluorohexane sulfonate (PFHxS), with 27 percent detection each. PFAS concentrations were below 1,000 parts per trillion (ppt). Two wells exceeded the EPA’s lifetime-drinking water health advisory level of 70 ppt for combined concentrations of PFOA and PFOS. The average age of groundwater entering the screens of the supply wells sampled in 2018 ranged from 8.2 to 45.8 years, with a median groundwater age of 25.7 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Groundwater age and PFAS concentrations were negatively correlated in the Columbia aquifer. Data from the 23 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2018 was generally 5 years older than the average groundwater age from samples collected in 2008. The same pattern was found during cycle two (2008) of this study, where the 2008 groundwater age was on average 7 years older than the samples collected in 2000. The distribution of groundwater sample ages among the 17 trend wells and during the three study cycles (2000, 2008, and 2018) indicates that sample-age medians were statistically different from zero; well-water sample-age data show a slight increase in groundwater sample age.

Delaware↗

USGS2018

Monitoring the water-quality response of agricultural conservation practices in the Bucks Branch watershed, Sussex County, Delaware, 2014–16

The purpose of this study was to evaluate the effects of irrigation and cover crops as conservation practices on water quality in groundwater and streams. Bucks Branch, a stream in the Nanticoke River watershed in southwestern Delaware, was identified as having one of the highest concentrations of nitrate in all surface-water sites sampled by the Delaware Department of Natural Resources and Environmental Control (DNREC). The study site is on two adjacent fields bordering Bucks Branch, one that has used irrigation since 2000 and one with dryland farming; both under conservation tillage and long-term rotation of corn, soybean, and small grain crops. A streamgage was installed near the study site fields to measure streamflow and water quality. The study area is typical of farming practices and environmental conditions throughout much of the intensively farmed agricultural land of the Coastal Plain of Delaware and surrounding parts of Maryland. Monitoring was conducted from January 2014 through June 2016. Corn was grown on both fields during the two growing seasons of the study period, and cover crops were planted before or shortly after harvest on both fields. During the second year of data collection, the effects of radish and rye grass cover crops on nutrient transport were studied. The combined results from data collected for this study show that water and nitrate moved below the root zone year round when soil moisture was high, especially after significant rainfall and frequently after irrigation. Soil water sampled 2 to 3 weeks after nutrients were applied had nitrate concentrations greater than 50 milligrams per liter as nitrogen (mg/L as N) and may be a significant source of nitrate to groundwater. Whereas recharge containing elevated nitrate concentrations also occurred under the dryland field, it was less frequent and of lower concentration than recharge under the irrigated field. Nitrate was present in all groundwater samples from these sites. Groundwater estimated to have recharged within 10 years or less had higher median concentrations of nitrate than in older water samples. The oldest groundwater encountered was over 30 years old, and had traveled along the longest, deep flowpaths from upland fields to the stream. The median nitrate concentration was 18 mg/L as N in younger water (less than 10 years old) beneath the irrigated field, compared to about 10 mg/L as N in younger water beneath the dryland field. Samples from the shallow upland wells in both study fields showed little, if any, evidence of denitrification. Several samples from deeper wells and from wells near forested riparian zone wetlands that border both fields did show partial denitrification. A mixing model estimated that between 12 and 22 percent of the nitrate discharging to the stream was lost through uptake and denitrification upstream of the streamgage on Bucks Branch. Continuous data collected at this site and evidence of denitrification in the surface-water samples showed a greater potential for loss of nitrate during the warmer months than the colder months. This pattern was similar to that seen below the streamgage at the most downstream site in the watershed. A mixed cover crop of radishes and rye was planted prior to removal (radishes) and just after harvest (rye) of the corn crop on the irrigated field. Rye grass was planted shortly after crop harvest on the dryland field. Cover crop biomass samples collected while radishes were growing and after they were killed by freezing temperatures indicates that the early planted radish crop effectively scavenged available nitrogen from the soil. Whereas radish biomass initially held more nitrogen than rye, at 55 to 8 pounds per acre, respectively, leaching of inorganic nitrate following radish die-off was minimal. Soil-water nitrate concentrations during the cover-crop growing period were lower than during the growing season prior to planting of the cover crop. There also was an increase in soil fertility and dissolved organic nitrate in samples of soil water that was likely related to increased soil microbial metabolism. Results indicate that cover crops stored plant nutrients over the winter and did not increase shallow groundwater concentrations of nitrate. Although conservation practices such as cover crops and nutrient management have been applied to these fields, there was still significant leaching of nitrate to groundwater, especially under the irrigated field. This will likely continue to be a challenge in this area and other parts of the Coastal Plain where soil moisture capacity is relatively low and managing irrigation around rainfall is difficult. Cover crops, when planted in standing corn, are one practice that can effectively pull nitrate from below the root zone to the top layer of soil, thus limiting the amount of potential nitrate leaching to groundwater. Irrigation management that would lower average soil moisture conditions during the growing season also could potentially limit nitrogen transport.

Delaware↗

USGS2016

Estimated use of water in the Delaware River Basin in Delaware, New Jersey, New York, and Pennsylvania, 2010

The Delaware River Basin (DRB) was selected as a Focus Area Study in 2011 by the U.S. Geological Survey (USGS) as part of the USGS National Water Census. The National Water Census is a USGS research program that focuses on national water availability and use and then develops new water accounting tools and assesses water availability at both the regional and national scales. One of the water management needs that the DRB study addressed, and that was identified by stakeholder groups from the DRB, was to improve the integration of state water use and water-supply data and to provide the compiled water use information to basin users. This water use information was also used in the hydrologic modeling and ecological components of the study. Instream and offstream water use was calculated for 2010 for the DRB based on information received from Delaware, New Jersey, New York, and Pennsylvania. Water withdrawal, interbasin transfers, return flow, and hydroelectric power generation release data were compiled for 11 categories by hydrologic subregion, basin, subbasin, and subwatershed. Data availability varied by state. Site-specific data were used whenever possible to calculate public supply, irrigation (golf courses, nurseries, sod farms, and crops), aquaculture, self-supplied industrial, commercial, mining, thermoelectric, and hydroelectric power withdrawals. Where site-specific data were not available, primarily for crop irrigation, livestock, and domestic use, various techniques were used to estimate water withdrawals. Total water withdrawals in the Delaware River Basin were calculated to be about 7,130 million gallons per day (Mgal/d) in 2010. Calculations of withdrawals by source indicate that freshwater withdrawals were about 4,130 Mgal/d (58 percent of the total) and the remaining 3,000 Mgal/d (42 percent) were from saline water. Total surface-water withdrawals were calculated to be 6,590 Mgal/d, or 92 percent of the total; about 54 percent (3,590 Mgal/d) of surface water withdrawn was freshwater. Total groundwater withdrawals were calculated to be 545 Mgal/d (8 percent of the total), all of which was freshwater. During 2010, calculated withdrawals by category, in decreasing order, were: thermoelectric power, 4,910 Mgal/d; public supply, 1,490 Mgal/d; self-supplied industrial, 350 Mgal/d; irrigation, 175 Mgal/d; self-supplied domestic, 117 Mgal/d; mining, 41.3 Mgal/d; aquaculture, 19.3 Mgal/d; livestock, 6.72 Mgal/d, and commercial, 5.89 Mgal/d. The amount of instream use for hydroelectric power generation purposes in 2010 was reported to be 273 Mgal/d for the Wallenpaupack Plant and 127 Mgal/d for the Mongaup River system. Total return flows in the DRB were 2,960 Mgal/d in 2010. Although municipal wastewater-treatment plants accounted for 539 (97 percent) of the return-flow sites, they accounted for about 70 percent of the total return flows in the DRB. There was limited information on return flows from thermoelectric power.

Delaware, New Jersey, New York, Pennsylvania↗

USGS2010

Occurrence and distribution of organic chemicals and nutrients and comparison of water-quality data from public drinking-water supplies in the Columbia aquifer in Delaware, 2000-08

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (a) describe the occurrence and distribution of selected contaminants, and (b) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Coastal Plain in Delaware between 2000 and 2008. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November of 2008. Twenty-two of the wells in the sampling network for this project were previously sampled in 2000. Eight new wells were selected to replace wells no longer in use. Groundwater collected from the wells was analyzed for the occurrence and distribution of selected pesticides, pesticide degradates, volatile organic compounds, nutrients, and major inorganic ions. Nine of the wells were analyzed for radioactive elements (radium-226, radium-228, and radon). Groundwater-quality data were compared for sites sampled in both 2000 and 2008 to document any changes in water quality. One or more pesticides were detected in samples from 29 of the 30 wells. There were no significant differences in pesticide and pesticide degradate concentrations and similar compounds were detected when comparing sampling results from 2000 and 2008. Pesticide and pesticide degradate concentrations were generally less than 1 microgram per liter. Twenty-four compounds, 14 pesticides, and 10 pesticide degradates were detected in at least one sample; the pesticide degradates, metolachlor ethanesulfonic acid, deethylatrazine, and alachlor ethanesulfonic acid were the most frequently detected compounds, each found in more than 50 percent of samples. Almost 80 percent of the detected pesticides were agricultural herbicides, which reflects the prevalence and wide distribution of agriculture in sampled areas, as well the dominance of agricultural pesticides among the target analytes for this study. No concentration of a pesticide or pesticide degradate exceeded any regulatory standard. Dieldrin, an insecticide that has been banned for several decades, was detected at a concentration that exceeded a non-regulatory health-based screening level of 0.002 micrograms per liter at nine sites. Volatile organic compounds (VOCs) were generally detected at concentrations of less than 1 microgram per liter, although 7 of the 31 detected VOCs had concentrations greater than 1 microgram per liter. There were no significant differences in VOC concentrations from 2000 to 2008; however, among the resampled wells, the mean number of VOCs detected per well was significantly different over the 8-year period. The number of VOCs detected per well decreased in 73 percent of the resampled wells; the decrease ranged from one to eight fewer detections in 2008 than in 2000. Chloroform and methyl tert-butyl ether were the most frequently detected VOCs, at 90 percent and 63 percent, respectively, among the 30 wells. Solvents were the most frequently detected class of VOCs. All measured concentrations of VOCs in groundwater were below established standards for drinking water and below other health-based guidelines. There were no significant differences in nutrient or major-ion concentrations between 2000 and 2008, however, the medians of two field measurements, pH and dissolved oxygen, were significantly higher in 2008 than in 2000 in the resampled wells. Although pH and dissolved oxygen were higher, water was still acidic and predominantly oxic. Nitrate was the predominant nutrient species in the Columbia aquifer, with a 90-percent detection frequency. The median nitrate concentration in groundwater was 4.88 milligrams per liter, which was slightly lower than, but not significantly different from, the median of 5.23 milligrams per liter for the 2000 samples. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level or Federal drinking-water standard of 10 milligrams per liter as nitrogen in samples from two wells. Eight of the 30 wells sampled had iron or manganese concentrations that exceeded the U.S. Environmental Protection Agency's Secondary Maximum Contaminant Level; nine samples exceeded the Health Advisory Limit set by the Delaware Division of Public Health of 20 milligrams per liter for sodium in drinking water. Two radiochemical isotopes, radium-226 and radon-222, were detected in all nine groundwater samples analyzed; five samples had detectable levels of radium-228 activity. None of the samples exceeded the U.S Environmental Protection Agency's Maximum Contaminant Level for radium or radon in drinking water. Although radioactive elements were more frequently detected in 2008 than in 2000, this increased detection frequency is more likely due to lower detection levels in 2008 than 2000. The average age of groundwater entering the screens of the production wells sampled in 2008 ranged from 6 to 35 years, with a median groundwater age of 22 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Data from the 22 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2008 was generally 7 years older than the average groundwater age from samples collected in 2000.

Delaware↗

USGS2009

Anthropogenic organic compounds in source and finished groundwater of community water systems in the Piedmont Physiographic Province, Potomac River Basin, Maryland and Virginia, 2003-04

A source- and finished-water-quality assessment of groundwater was conducted in the Piedmont Physiographic Province of Maryland and Virginia in the Potomac River Basin during 2003-04 as part of the U.S. Geological Survey's National Water-Quality Assessment Program. This assessment used a two-phased approach to sampling that allowed investigators to evaluate the occurrence of more than 280 anthropogenic organic compounds (volatile organic compounds, pesticides and pesticide degradates, and other anthropogenic organic compounds). Analysis of waters from 15 of the largest community water systems in the study area were included in the assessment. Source-water samples (raw-water samples collected prior to treatment) were collected at the well head. Finished-water samples (raw water that had been treated and disinfected) were collected after treatment and prior to distribution. Phase one samples, collected in August and September 2003, focused on source water. Phase two analyzed both source and finished water, and samples were collected in August and October of 2004. The results from phase one showed that samples collected from the source water for 15 community water systems contained 92 anthropogenic organic compounds (41 volatile organic compounds, 37 pesticides and pesticide degradates, and 14 other anthropogenic organic compounds). The 5 most frequently occurring anthropogenic organic compounds were detected in 11 of the 15 source-water samples. Deethylatrazine, a degradate of atrazine, was present in all 15 samples and metolachlor ethanesulfonic acid, a degradate of metolachlor, and chloroform were present in 13 samples. Atrazine and metolachlor were present in 12 and 11 samples, respectively. All samples contained a mixture of compounds with an average of about 14 compounds per sample. Phase two sampling focused on 10 of the 15 community water systems that were selected for resampling on the basis of occurrence of anthropogenic organic compounds detected most frequently during the first phase. A total of 48 different anthropogenic organic compounds were detected in samples collected from source and finished water. There were a similar number of compounds detected in finished water (41) and in source water (39). The most commonly detected group of anthropogenic organic compounds in finished water was trihalomethanes - compounds associated with the disinfection of drinking water. This group of compounds accounted for 30 percent of the detections in source water and 44 percent of the detections in finished water, and were generally found in higher concentrations in finished water. Excluding trihalomethanes, the number of total detections was about the same in source-water samples (33) as it was in finished-water samples (35). During both phases of the study, two measurements for human-health assessment were used. The first, the Maximum Contaminant Level for drinking water, is set by the U.S. Environmental Protection Agency and represents a legally enforceable maximum concentration of a contaminant permitted in drinking water. The second, the Health-Based Screening Level, was developed by the U.S. Geological Survey, is not legally enforceable, and represents a limit for more chronic exposures. Maximum concentrations for each detected compound were compared with either the Maximum Contaminant Level or the Health-Based Screening Level when available. More than half of the compounds detected had either a Maximum Contaminant Level or a Health-Based Screening Level. A benchmark quotient was set at 10 percent (greater than or equal to 0.1) of the ratio of the detected concentration of a particular compound to its Maximum Contaminant Level, or Health-Based Screening Level. This was considered a threshold for further monitoring. During phase one, when only source water was sampled, seven compounds (chloroform, benzene, acrylonitrile, methylene chloride, atrazine, alachlor, and dieldrin) met or exceeded a benchmark quotient.

Maryland, Virginia↗

USGS2008

Pesticides in Ground Water of Central and Western Maryland

Selected pesticides and degradates (products of pesticide degradation) are detectable in ground water in many parts of central and western Maryland, although concentrations are generally less than 0.1 micrograms per liter. Ground-water samples collected recently (1994-2003) from 72 wells in areas of Maryland underlain by consolidated carbonate, crystalline, or siliciclastic aquifers (areas north and west of the Fall Line) were analyzed for selected pesticides and degradates. Pesticides were typically detected in mixtures of multiple compounds in ground water, and degradates were commonly detected, often at greater concentrations than their respective parent compounds. No pesticides were observed at concentrations greater than established standards for drinking water, and nearly all observed concentrations were below other health-based guidelines. Although such standards and guidelines are generally much greater than measured concentrations in ground water, they do not exist for many detected compounds (particularly degradates), or for mixtures of multiple compounds. The distribution of pesticides and degradates in ground water is related to application practices, as well as chemical and environmental factors that affect the fate and movement of individual compounds.

Fact Sheet↗

USGS2008

Use of Light Detection and Ranging (LiDAR) to Obtain High-Resolution Elevation Data for Sussex County, Delaware

Sussex County, Delaware, occupies a 938-square-mile area of low relief near sea level in the Atlantic Coastal Plain. The county is bounded on the east by the Delaware Bay and the Atlantic Ocean, including a barrier-island system, and inland bays that provide habitat for valuable living resources. Eastern Sussex County is an area of rapid population growth with a long-established beach-resort community, where land elevation is a key factor in determining areas that are appropriate for development. Of concern to State and local planners are evacuation routes inland to escape flooding from severe coastal storms, as most major transportation routes traverse areas of low elevation that are subject to inundation. The western half of the county is typically rural in character, and land use is largely agricultural with some scattered forest land cover. Western Sussex County has several low-relief river flood-prone areas, where accurate high-resolution elevation data are needed for Federal Emergency Management Agency (FEMA) Digital Flood Insurance Rate Map (DFIRM) studies. This fact sheet describes the methods and techniques used to collect and process LiDAR elevation data, the generation of the digital elevation model (DEM) and the 2-foot contours, and the quality-assurance procedures and results. It indicates where to view metadata on the data sets and where to acquire bare-earth mass points, DEM data, and contour data.

Fact Sheet↗