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Barry P. Baldigo

Publications and source records attributed to Barry P. Baldigo.

At least 91 records · Page 5Linked to original sources

Regionalized equations for bankfull-discharge and channel characteristics of streams in New York State — Hydrologic Region 3 east of the Hudson River

Equations that relate drainage area to bankfull discharge and channel characteristics (such as width, depth, and cross-sectional area) at gaged sites are needed to define bankfull discharge and channel characteristics at ungaged sites and can be used for stream-restoration and protection projects, stream-channel classification, and channel assessments. These equations are intended to serve as a guide for streams in areas of similar hydrologic, climatic, and physiographic conditions. New York State contains eight hydrologic regions that were previously delineated on the basis of high-flow (flood) characteristics. This report presents predictive equations for bankfull characteristics (discharge and channel characteristics) for streams east of the Hudson River, referred to as Hydrologic Region 3. Stream-survey data and discharge records from 12 streamflow-gaging stations were used in regression analyses to relate drainage area to bankfull discharge and bankfull channel width, depth, and cross-sectional area. The four predictive equations are: (1) bankfull discharge, in cubic feet per second = 83.8*(drainage area, in square miles) 0.679 ; (2) bankfull channel width, in feet = 24.0*(drainage area, in square miles) 0.292 ; (3) bankfull channel depth, in feet = 1.66*(drainage area, in square miles) 0.210 ; and (4) bankfull channel cross-sectional area, in square feet = 39.8*(drainage area, in square miles) 0.503 . The coefficients of determination ( R 2 ) for these four equations are 0.93, 0.85, 0.77, and 0.92, respectively. The high coefficients of determination for bankfull discharge and cross-sectional area indicate that much of the range in the variables is explained by the size of the drainage area; the smaller correlation coefficients for bankfull channel width and depth indicate that other factors also affect these relations. Recurrence intervals for the estimated bankfull discharge of each stream ranged from 1.16 to 3.35 years; the mean recurrence interval was 2.08 years. The 12 surveyed streams were classified by Rosgen stream type; most were B and C type, with occasional E- and F-type cross sections. The Region 3 equation (curve) for bankfull discharge was compared with those previously obtained for seven other hydrologic regions in New York State. The differences confirm that the hydraulic geometry of streams is affected by local climatic and physiographic conditions.

New York

Acid rain effects on aluminum mobilization clarified by inclusion of strong organic acids

Assessments of acidic deposition effects on aquatic ecosystems have often been hindered by complications from naturally occurring organic acidity. Measurements of pH and ANCG, the most commonly used indicators of chemical effects, can be substantially influenced by the presence of organic acids. Relationships between pH and inorganic Al, which is toxic to many forms of aquatic biota, are also altered by organic acids. However, when inorganic Al concentrations are plotted against ANC (the sum of Ca2+, Mg 2+, Na+, and K+, minus SO42-, NO3-, and Cl-), a distinct threshold for Al mobilization becomes apparent. If the concentration of strong organic anions is included as a negative component of ANC, the threshold occurs at an ANC value of approximately zero, the value expected from theoretical charge balance constraints. This adjusted ANC is termed the base-cation surplus. The threshold relationship between the base-cation surplus and Al was shown with data from approximately 200 streams in the Adirondack region of New York, during periods with low and high dissolved organic carbon concentrations, and for an additional stream from the Catskill region of New York. These results indicate that (1) strong organic anions can contribute to the mobilization of inorganic Al in combination with SO42- and NO 3-, and (2) the presence of inorganic Al in surface waters is an unambiguous indication of acidic deposition effects. ?? 2007 American Chemical Society.

Environmental Science & Technology

Regionalized equations for bankfull-discharge and channel characteristics of streams in New York State—Hydrologic Region 7 in western New York

Computation of bankfull discharge and channel dimensions (width, depth, and cross-sectional area) at ungaged sites requires equations that relate bankfull discharge and channel dimensions to drainage-area at gaged sites. Bankfull-channel information commonly is needed for watershed assessments, stream channel classification, and the design of stream-restoration projects. Such equations are most accurate if they are derived on the basis of data from streams within a region of uniform hydrologic, climatic, and physiographic conditions and applied only within that region. New York State contains eight hydrologic regions that were previously delineated on the basis of high-flow (flood) characteristics. This report presents drainage areas and associated bankfull characteristics (discharge and channel dimensions) for surveyed streams in western New York (Region 7). Stream-survey data and discharge records from seven active and three inactive USGS streamflow-gaging stations were used in regression analyses to relate drainage area to bankfull discharge and to bankfull channel width, depth, and cross-sectional area. The resulting equations are: (1) bankfull discharge, in cubic feet per second = 37.1*(drainage area, in square miles) 0.765 ; (2) bankfull channel width, in feet = 10.8*(drainage area, in square miles) 0.458 ; (3) bankfull channel depth, in feet = 1.47*(drainage area, in square miles) 0.199 ; and (4) bankfull channel cross-sectional area, in square feet = 15.9*(drainage area, in square mile) 0.656 . The coefficients of determination (R 2 ) for these four equations were 0.94, 0.89, 0.52, and 0.96, respectively. The high coefficients of determination for three of these equations (discharge, width, and cross-sectional area) indicate that much of the range in the variables was explained by the drainage area. The low coefficient of determination for the equation relating bankfull depth to drainage area, however, suggests that other factors also affected water depth. Recurrence intervals for the estimated bankfull discharge of each stream ranged from 1.05 to 3.60 years; the mean recurrence interval was 2.13 years. The 10 surveyed streams were classified by Rosgen stream type; most were C- and E-type, with occasional B- and F-type cross sections. The equation (curve) for bankfull discharge for Region 7 was compared with those previously developed for four other hydrologic regions in New York State. The differences confirm that the hydraulic geometry of streams is affected by local climatic and physiographic conditions.

Scientific Investigations Report

Stream acidification and mortality of brook trout (Salvelinus fontinalis) in response to timber harvest in Catskill Mountain watersheds, New York, USA

Effects of clear-cut and timber-stand improvement (TSI) harvests on water chemistry and mortality of caged brook trout (Salvelinus fontinalis) were evaluated in a study of three Catskill Mountain streams, 1994-2000. Harvests removed 73% of tree basal area (BA) from a clearcut subbasin, 5% BA from a TSI subbasin, and 14% BA at a site below the confluence of both streams. A fourth nonharvested site served as a control. Water quality and trout mortality were affected only in the clearcut stream. Acidity and concentrations of nitrate and inorganic monomeric aluminum (Alim) increased sharply during high flows after the first growing season (fall 1997). Acid-Alim episodes were severe during this period and decreased steadily in magnitude and duration thereafter. All trout at this site died within 7 days during spring 1998 and 85% died during spring 1999. Only background mortality was observed in other years at this site and at the other three sites during all tests. The absence of mortality in TSI watersheds indicates that limited harvests should not harm brook trout populations in acid-sensitive streams. Effects of tree harvests on fish communities are of concern, however, because many stream-dwelling species are more sensitive to acidified waters than brook trout. ?? 2005 NRC.

Canadian Journal of Fisheries and Aquatic Sciences

Regionalized equations for bankfull-discharge and channel characteristics of streams in New York State—Hydrologic Region 5 in central New York

Equations that relate drainage area to bankfull discharge and channel dimensions (width, depth, and cross-sectional area) at gaged sites are needed to define bankfull discharge and channel dimensions at ungaged sites and to provide information for the design of stream-restoration projects. Such equations are most accurate if derived from streams within an area of uniform hydrologic, climatic, and physiographic conditions and applied only within that region. A study to develop equations to predict bankfull data for ungaged streams in New York established eight regions that coincided with previously defined hydrologic regions. This report presents drainage areas and bankfull characteristics (discharge and channel dimensions) for streams in central New York (Region 5) selected for this pilot study. Stream-survey data and discharge records from seven active (currently gaged) sites and nine inactive (discontinued gaged) sites were used in regression analyses to relate size of drainage area to bankfull discharge and bankfull channel width, depth, and cross-sectional area. The resulting equations are: (1) bankfull discharge, in cubic feet per second = 45.3*(drainage area, in square miles) 0.856 ; (2) bankfull channel width, in feet = 13.5*(drainage area, in square miles) 0.449 ; (3) bankfull channel depth, in feet = 0.801*(drainage area, in square miles) 0.373 ; and (4) bankfull channel cross-sectional area, in square feet = 10.8*(drainage area, in square miles) 0.823 . The high correlation coefficients (R 2 ) for these four equations (0.96, 0.92, 0.91, 0.98, respectively) indicate that much of the variation in the variables is explained by the size of the drainage area. Recurrence intervals for the estimated bankfull discharge of each stream ranged from 1.11 to 3.40 years; the mean recurrence interval was 1.51 years. The 16 surveyed streams were classified by Rosgen stream type; most were mainly C-type reaches, with occasional B- and F-type reaches. The Region 5 equation was compared with equations developed for six other large areas in the Northeast. The major differences among results indicate a need to refine equations so they can be applied by water-resources managers to local planning and design efforts.

Scientific Investigations Report

Regionalized equations for bankfull-discharge and channel characteristics of streams in New York State—Hydrologic Region 6 in the Southern Tier of New York

Equations that relate bankfull discharge and channel characteristics (width, depth, and cross-sectional area) to drainage-area size at gaged sites are needed to define bankfull discharge and channel dimensions at ungaged sites and to provide information for watershed assessments, stream-channel classification, and the design of stream-restoration projects. Such equations are most accurate if derived from streams within an area of uniform hydrologic, climatic, and physiographic conditions and applied only within that region. In New York State, eight hydrologic regions were previously defined on the basis of similar high-flow (flood) characteristics. This report presents drainage areas and associated bankfull characteristics (discharge and channel dimensions) for surveyed streams in southwestern New York (Region 6). Stream-survey data and discharge records from 11 active (currently gaged) sites and 3 inactive (discontinued) sites were used in regression analyses to relate bankfull discharge and bankfull channel width, depth, and cross-sectional area to the size of the drainage area. The resulting equations are: (1) bankfull discharge, in cubic feet per second = 48.0*(drainage area, in square miles) 0.842 ; (2) bankfull channel width, in feet = 16.9*(drainage area, in square miles) 0.419 ; (3) bankfull channel depth, in feet = 1.04*(drainage area, in square miles) 0.244 ; and (4) bankfull channel cross-sectional area, in square feet = 17.6*(drainage area, in square miles) 0.662 . The coefficient of determination (R 2 ) for these four equations were 0.90, 0.79, 0.64, and 0.89, respectively. The high correlation coefficients for bankfull discharge and cross-sectional area indicate that much of the variation in these variables is explained by the size of the drainage area. The smaller correlation coefficients for bankfull channel width and depth indicate that other factors also affect these relations. Recurrence intervals for the estimated bankfull discharge of each stream ranged from 1.01 to 2.35 years; the mean recurrence interval was 1.54 years. The 14 surveyed streams were classified by Rosgen stream type; most were C-type reaches, with occasional B-type reaches. The Region 6 equation (curve) for bankfull discharge was compared with equations previously developed for four other large areas in New York State and southeastern Pennsylvania. The differences among results indicate that, although the equations need to be refined by region before being applied by water-resources managers to local planning and design efforts, similar regions have similar relations between bankfull discharge and channel characteristics.

Scientific Investigations Report

Guidelines for surveying bankfull channel geometry and developing regional hydraulic-geometry relations for streams of New York State

Many disturbed streams within New York State are being restored in an effort to provide bank and bed stability and thereby decrease sedimentation and erosion. Efforts to identify and provide accurate indicators for stable-channel characteristics for ungaged streams have been hampered by the lack of regional equations or relations that relate drainage area to bankfull discharge and to channel depth, width, and cross-sectional area (bankfull hydraulic-geometry relations). Regional equations are needed to confirm bankfull hydraulic-geometry, assess stream stability, evaluate restoration needs, and verify restoration design for ungaged streams that lack stage-to-discharge ratings or historic peak-flow records. This report presents guidelines for surveying bankfull channel geometry at USGS stream gages and developing regional hydraulic-geometry relations (equations) for wadeable streams in New York. It summarizes methods to (1) compile and assess existing hydrologic, geometric, photographic, and topographic data, (2) conduct stream-reconnaissance inspections, (3) identify channel-bankfull characteristics, (4) conduct longitudinal and cross-section surveys, (5) measure stream discharge, (6) develop and refine bankfull hydraulic-geometry equations, and (7) analyze and assure data completeness and quality. The techniques primarily address wadeable streams with either active or discontinued surface-water and crest-stage gages. The relations can be applied to ungaged or actively gaged streams that are wadeable, and may be extended to non-wadeable streams (with some limitations) if they have drainage areas comparable to those used to develop the relations.

Open-File Report

Effects of stream acidification and habitat on fish populations of a North American river

Water quality, physical habitat, and fisheries at sixteen reaches in the Neversink River Basin were studied during 1991-95 to identify the effects of acidic precipitation on stream-water chemistry and on selected fish-species populations, and to test the hypothesis that the degree of stream acidification affected the spatial distribution of each fish-species population. Most sites on the East Branch Neversink were strongly to severely acidified, whereas most sites on the West Branch were minimally to moderately acidified. Mean density of fish populations ranged from 0 to 2.15 fish/m 2 ; biomass ranged from 0 to 17.5 g/m 2 . Where brook trout were present, their population density ranged from 0.04 to 1.09 fish/m 2 , biomass ranged from 0.76 to 12.2 g/m 2 , and condition (K) ranged from 0.94 to 1.07. Regression analyses revealed strong relations ( r 2 ± 0.41 to 0.99; p ≤ 0.05) between characteristics of the two most common species (brook trout and slimy sculpin) populations and mean concentrations of inorganic monomeric aluminum (Al im ), pH, Si, K + , NO 3 - , NH 4 + , DOC, Ca 2+ , and Na + ; acid neutralizing capacity (ANC); and water temperature. Stream acidification may have adversely affected fish populations at most East Branch sites, but in other parts of the Neversink River Basin these effects were masked or mitigated by other physical habitat, geochemical, and biological factors.

New York

Controls of stream chemistry and fish populations in the Neversink watershed, Catskill Mountains, New York

The Neversink Watershed Study was initiated in 1991 to develop an understanding of the key natural processes that control water quality within the forested, 166 km 2 (64 mi 2 ), Neversink River watershed; part of the New York City drinking water supply system, in the Catskill Mountain region of New York. The study entailed (1) hydrological investigations of water movement from the atmosphere to streams, (2) biogeochemical investigations of nitrogen and calcium, important nutrients in forest and aquatic ecosystems whose availability has been altered by acidic deposition, (3) an investigation of elevational patterns in atmospheric deposition, and (4) fisheries investigations to determine the relative importance of physical habitat and acidic deposition in controlling the abundance and diversity of fish species in the watershed. This report summarizes the results of these investigations, which have also been presented, in detail, in peer-reviewed technical articles and reports that are cited throughout the text.

New York

Copper avoidance and mortality of juvenile brown trout ( Salmo trutta ) in tests with copper-sulfate-treated water from West Branch Reservoir, Putnam County, New York

Copper-avoidance tests and acute-toxicity (mortality) tests on hatchery-reared, young-of- the-year brown trout ( salmo trutta ) were conducted with water from West Branch Reservoir to assess the avoidance response to copper sulfate treatment, which is used occasionally by New York City Department of Environmental Protection to decrease phytoplankton populations in the reservoir. Avoidance-test results indicate that juvenile brown trout tend to avoid dissolved copper concentrations greater than about 55 μg/L (micrograms per liter), which is the approximate avoidance-response threshold. The mean net avoidance response of brown trout to dissolved copper concentrations of 70 and 100 μg/L, and possibly 80 μg/L, was significantly different (at α= 0.1) from the mean net avoidance response of fish to control (untreated) water and to treated water at most other tested concentrations. Mortality-test results indicate that the 96-hr median lethal concentration (LC 50 ) of dissolved copper was 61.5 μg/L. All (100 percent) of the brown trout died at a dissolved copper concentration of 85 μg/L, many died at concentrations of 62 μg/L and 70 μg/L, and none died in the control waters (7 μg/L) or at concentrations of 10, 20, or 45 μg/L. The estimated concentration of dissolved copper that caused fish mortality (threshold) was 53.5 μg/L, virtually equivalent to the avoidance-response threshold. Additional factors that could affect the copper-avoidance and mortality response of individual brown trout and their populations in West Branch Reservoir include seasonal variations in certain water-quality parameters, copper-treatment regimes, natural fish distributions during treatment, and increased tolerance due to acclimation. These warrant additional study before the findings from this study can be used to predict the effects that copper sulfate treatments have on resident fish populations in New York City reservoirs.

New York

Composition of fish communities in relation to stream acidification and habitat in the Neversink River, New York

The effects of acidification in lotic systems are not well documented. Spatial and temporal variability of habitat and water quality complicate the evaluation of acidification effects in streams and rivers. The Neversink River in the Catskill Mountains of southeastern New York, the tributaries of which vary from well buffered to severely acidified, provided an opportunity to investigate the extent and magnitude of acidification effects on fish communities of headwater systems. Composition of fish communities, water quality, stream hydrology, stream habitat, and physiographic factors were characterized from 1991 to 1995 at 16 first- to fourth-order sites in the basin. Correlation and regression analyses were used to develop empirical models and to assess the relations among fish species richness, total fish density, and total fish biomass and environmental variables. Chronic and episodic acidification and elevated concentrations of inorganic monomeric aluminum were common, and fish populations were rare or absent from several sites in the upper reaches of the basin; as many as six fish species were collected from sites in the lower reaches of the basin. Species distributions and species richness were most highly related to stream pH, acid-neutralizing capacity (ANC), inorganic monomeric aluminum (Al im ), calcium (Ca) 2+ , and potassium (K) + concentrations, site elevation, watershed drainage area, and water temperature. Fish density was most highly related to stream pH, Al im , ANC, K + , Ca 2+ , and magnesium (Mg) 2+ concentrations. Fish biomass, unlike species richness and fish density, was most highly related to physical habitat characteristics, water temperature, and concentrations of Mg 2+ and silicon. Acidity characteristics were of secondary importance to fish biomass at all but the most severely acidified sites. Our results indicate that (1) the total biomass of fish communities was not seriously affected at moderately to strongly acidified sites; (2) species richness and total density of fish were adversely affected at strongly to severely acidified sites; and (3) possible changes in competitive interactions may mitigate negative effects of acidification on fish communities in parts of the Neversink River Basin.

New York

Soil calcium status and the response of stream chemistry to changing acidic deposition rates

Despite a decreasing trend in acidic deposition rates over the past two to three decades, acidified surface waters in the northeastern United States have shown minimal changes. Depletion of soil Ca pools has been suggested as a cause, although changes in soil Ca pools have not been directly related to long-term records of stream chemistry. To investigate this problem, a comprehensive watershed study was conducted in the Neversink River Basin, in the Catskill Mountains of New York, during 1991–1996. Spatial variations of atmospheric deposition, soil chemistry, and stream chemistry were evaluated over an elevation range of 817–1234 m to determine whether these factors exhibited elevational patterns. An increase in atmospheric deposition of SO 4 with increasing elevation corresponded with upslope decreases of exchangeable soil base concentrations and acid-neutralizing capacity of stream water. Exchangeable base concentrations in homogeneous soil incubated within the soil profile for one year also decreased with increasing elevation. An elevational gradient in precipitation was not observed, and effects of a temperature gradient on soil properties were not detected. Laboratory leaching experiments with soils from this watershed showed that (1) concentrations of Ca in leachate increased as the concentrations of acid anions in added solution increased, and (2) the slope of this relationship was positively correlated with base saturation. Field and laboratory soil analyses are consistent with the interpretation that decreasing trends in acid-neutralizing capacity in stream water in the Neversink Basin, dating back to 1984, are the result of decreases in soil base saturation caused by acidic deposition.

Ecological Applications

Trends in base flows and extreme flows in the Beaver Kill Basin, Catskill Mountains, New York, 1915-94

Long-term records from five streamflow-gaging stations within and near the 300-square mile Beaver Kill Basin were analyzed to determine whether construction and presence of New York State Route 17 (NY 17), which was completed in the late 1960's, could have altered hydrologic processes in the basin and thereby adversely affected the basin's trout populations. The hypothesis investigated is that NY 17 has altered surface-water and shallow ground-water flowpaths where it parallels the stream and has increased runoff rates and thereby (1) increased the range in stream discharge (prolonged the base flows, decreased the low flows, and increased the high flows), and (2) altered stream-channel morphology through increased volume and velocity of stormflows. Analyses of base flows, discharge-duration curves, stage-to-discharge relations, peak and bankfull discharges, and flow extremes at a downstream (Beaver Kill at Cooks Falls) and a small tributary (Little Beaver Kill at Livingston Manor) site provide only limited evidence that NY 17 affected hydrologic processes within the basin. These effects are best indicated by significant increases in the magnitude and (or) the frequency of moderate to large discharges (exceedence probabilities) on an instantaneous basis at the Beaver Kill at Cooks Falls site after 1965. Increases in stormflows can not be attributed solely to NY 17, however, because the trend was evident long before NY 17 was constructed. Changes in land use in parts of the watershed may have contributed to gradual and continuous increases in stormflows throughout the entire 80 (plus) years of record. Changes in most base-flow and low-flow statistics for the downstream (Beaver Kill at Cooks Falls) site after 1965 are not statistically significant, but, changes in flow-duration curves and annual peak flows are evident. Flow-duration curves at this site indicate that there is a 16 percent increase in average daily flows after 1965. Annual peak flow data indicate that peak flows from storms recurring at 2-year (and longer) intervals after 1965 are significantly larger than those that recur at the same frequencies before 1965. The lack of comparable increases in peak flows from several nearby reference sites after 1965 indicate that the observed increases in peak flows may be unique to the Beaver Kill Basin. Flow-duration curves and many base-flow and high-flow statistics for the small tributary paralleled by NY 17 in the in the upper reaches of the basin (Little Beaver Kill at Livingston Manor) appear to be considerably altered since NY 17 was constructed. Flow-duration curves at this site indicate that there is about a 54 percent increase in average daily flows after 1965. Increases in the ratio of average annual base flow to average annual flow until 1965 then subsequent decreases suggest an extreme affect of NY 17 on hydrology of the subbasin. The effect of NY 17 on hydrology of the Little Beaver Kill subbasin cannot be defined with certainty, however, because the flow record after 1965 is too short; discharge monitoring was discontinued in 1981. The increases in peak stormflows in the lower Beaver Kill basin through the period of record may have increased the rates of bed-sediment erosion (degradation) and deposition and accelerated changes in stream-channel morphology, however, these possible effects were not examined. Suggestions for further investigation of the effects of NY 17 and of other factors on hydrology, channel morphology, fish habitat, and fish populations in the Beaver Kill Basin include (1) addition of streamflow gages or a creststage gage network at critical locations, (2) a review of engineering records and other aerial photographs for indications of changes in channel morphology, (3) compilation of temperature data and modeling spatial extent and magnitude of stressful summer temperatures (to selected trout species), and (4) confirming the extent and severity of toxic thermal episodes using in-situ fish toxicity tests.

Open-File Report

Effect of stream acidification and inorganic aluminum on mortality of brook trout (Salvelinus fontinalis) in the Catskill Mountains, New York

Juvenile brook trout (Salvelinus fontinalis) were exposed in cages to fluctuating chemical conditions in four Catskill Mountain streams during the spring and fall of 1989 and the spring of 1990. Specific chemical constituents and characteristics of acidic episodes that correlated with increased fish mortality were identified. Mortality increased during acidic episodes in one poorly buffered stream when inorganic monomeric aluminum (Al(im)) concentrations increased; mortality was low in three other streams during acidic episodes of shorter duration and smaller magnitude than measured in the poorly buffered stream. Variation in mortality was attributed primarily to differences in concentrations of both Al(im) and dissolved organic carbon. Linear and logistic regression analyses indicate that either mean or median Al(im) concentrations could account for 73-99% of the variability in mortality. Regression analyses suggest that mortality was highly related (in order of importance) to Al(im), pH, dissolved organic carbon, calcium, and chloride concentration. Brook trout mortality was also highly related to durations of exposure above 0.225 and 0.250 mg/L Al(im) during test periods. Characteristics of acidic-Al(im) episodes that are critical to mortality of caged brook trout appear to be (i) Al(im) concentrations of at least 0.225 ?? 0.025 mg/L and (ii) exposure to these toxic Al(im) concentrations for at least 2 days.

Canadian Journal of Fisheries and Aquatic Sciences

Episodic acidification of small streams in the northeastern United States: Fish mortality in field bioassays

In situ bioassays were performed as part of the Episodic Response Project, to evaluate the effects of episodic stream acidification on mortality of brook trout (Salvelinus fontinalis) and forage fish species. We report the results of 122 bioassays in 13 streams of the three study regions: the Adirondack mountains of New York, the Catskill mountains of New York, and the Northern Appalachian Plateau of Pennsylvania. Bioassays during acidic episodes had significantly higher mortality than did bioassays conducted under nonacidic conditions, but there was little difference in mortality rates in bioassays experiencing acidic episodes and those experiencing acidic conditions throughout the test period. Multiple logistic regression models were used to relate bioassay mortality rates to summary statistics of time-varying stream chemistry (inorganic monomeric aluminum, calcium, pH, and dissolved organic carbon) estimated for the 20-d bioassay periods. The large suite of candidate regressors also included biological, regional, and seasonal factors, as well as several statistics summarizing various features of aluminum exposure duration and magnitude. Regressor variable selection and model assessment were complicated by multicolinearity and overdispersion. For the target fish species, brook trout, bioassay mortality was most closely related to time-weighted median inorganic aluminum. Median Ca and minimum pH offered additional explanatory power, as did stream-specific aluminum responses. Due to high multicollinearity, the relative importance of different aluminum exposure duration and magnitude variables was difficult to assess, but these variables taken together added no significant explanatory power to models already containing median aluminum. Between 59 and 79% of the variation in brook trout mortality was explained by models employing between one and five regressors. Simpler models were developed for smaller sets of bioassays that tested slimy and mottled sculpin (Cottus cognatus and C. bairdi) as well as blacknose dace (Rhinichthys atratulus). For these forage species a single inorganic aluminum exposure variable successfully accounted for 86-98% of the observed mortality. Even though field bioassays showed evidence of multiple toxicity factors, models results suggest that adequate mortality predictions can be obtained from a single index of inorganic Al concentrations during exposure periods.

Ecological Applications

Episodic acidification of small streams in the northeastern United states: Effects on fish populations

As part of the Episodic Response Project (ERP), we studied the effects of episodic acidification on fish in 13 small streams in the northeastern United States: four streams in the Adirondack region of New York, four streams in the Catskills, New York, and five streams in the northern Appalachian Plateau, Pennsylvania. In situ bioassays with brook trout (Salvelinus fontinalis) and a forage fish species (blacknose dace (Rhinichthys atratulus), mottled sculpin (Cottus bairdi), or slimy sculpin (Cottus cognatus), depending on the region) measured direct toxicity. Movements of individual brook trout, in relation to stream chemistry, were monitored using radiotelemetry. Electrofishing surveys assessed fish community status and the density and biomass of brook trout in each stream. During low flow, all streams except one had chemical conditions considered suitable for the survival and reproduction of most fish species (median pH 6.0-7.2 during low flow; inorganic Al < 60 μg/L). ERP streams with suitable conditions during low flow, but moderate-to-severe episodic acidification during high flow, had higher fish mortality in bioassays, net down-stream movement of brook trout during events, and lower brook trout density and biomass compared to nonacidic streams, and lacked acid-sensitive fish species (blacknose dace and sculpin). Movement of trout into refugia (areas with higher pH and lower Al) during episodes partially mitigated the adverse effects of episodes. Recolonization from alkaline tributaries or microhabitats can maintain low densities of fish in streams that experience severe acidic episodes, but it is not sufficient to sustain fish densities and community composition at levels expected in the absence of these episodes. Fish responses to acid-base chemistry were fairly consistent across regions. In general, trout abundance was reduced and acid-sensitive fish species were absent from ERP streams with median pH < 5.0-5.2 during high flow and inorganic Al > 100-200 μg/L. We conclude that episodic acidification can have long-term effects on fish communities in small streams.

Ecological Applications