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B. R. Doe

Publications and source records attributed to B. R. Doe.

At least 19 recordsLinked to original sources
USGS2012

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗
USGS2010

Zinc, copper, and lead geochemistry of oceanic igneous rocks - ridges, islands, and arcs

Variations in the abundances of Zn, Cu, and Pb are found to be useful in identifying tectonic regimes and separating oceanisland basalts into enriched- and depleted-source categories. The average Zn, Cu, and Pb contents of normal mid-ocean ridge basalts (N-MORB) are 84, 70, and 0.35 ppm, respectively. Differences in average Zn contents for various ridges reflect more the varying degrees of differentiation than variations of Zn content in the source rocks. At a Mg# of 70, or Mg# 70 , which is taken to represent primitive MORB, many MORB sequences converge at a Zn content of 58 ± 6 ppm, which is close to the value for primitive mantle (50 ppm) and ordinary chondrites (∼55 ppm). Values of 0.1 to 0.15 ppm Pb in MORB at Mg# 70 , best defined at the superfast-spreading Southern East Pacific Rise, are similar to estimates of Pb in the primitive mantle (0.12 to 0.18 ppm). They also are near the lower end of the range for ordinary chondrites. The very slow spreading Southwest Indian Ocean Ridge has a sequence with higher Pb contents, in addition to a more normal sequence, which has a visual best value of 0.4 ppm Pb at Mg# 70 . With the exception of the Walvis Ridge, Zn and Cu appear to be little affected by proximity to hotspots (i.e., E-MORB); however, Pb contents are higher and average about 0.6 ppm.

International Geology Review↗
USGS1999

Pollution damage to the Powell Building, Reston, Virginia

Concrete column segments of the Powell Building (Reston, VA) exposed to the elements and wetted by precipitation were `cleaned' and roughened, but sheltered portions of the columns retained their smoothness and pollution accumulates, similar to observations for limestone, marble, and sandstone. Weathering effects on the columns were dominated by precipitation run-off and not the acidity of the precipitation. The process may be dry deposition of sulfur dioxide (SO2) and nitric oxides (NOx) that formed soluble salts in the presence of humid air or dew, salts that were removed by precipitation run-off.

Materials Performance↗
USGS1994

Zinc, copper, and lead in mid-ocean ridge basalts and the source rock control on Zn/Pb in ocean-ridge hydrothermal deposits

The contents of Zn, Cu, and Pb in mid-ocean ridge basalts (MORB) and the MORB source-rock control on Zn/Pb in ocean-ridge hydrothermal deposits are examined. The values of Zn, Cu, and Pb for submarine mid-ocean ridge basalts (MORB) are, respectively (in ppm): average MORB—75, 75, and 0.7; West Valley, Juan de Fuca Ridge (JFR)—87, 64, and 0.5; southern JFR—120 and 0.5; and 21°N, East Pacific Rise (EPR)—73, 78, and 0.5. Values of Zn/Pb range from about 100–240 and Cu/ Pb from 100–156. In this study, Zn is found to correlate positively with TiO 2 + FeO (mean square of weighted deviates, MSWD, of 1.6 for JFR basalt), and inversely with Mg number (MSWD of 3.5). Therefore, contrary to statements in the literature that Zn should be compatible in MORB, Zn is a mildly incompatible element and must be enriched in the glass phase relative to olivine as Zn does not fit into the other major phenocryst phase, plagioclase. In the source of MORB, Zn likely is most enriched in oxides: spinel, magnetite, and titanomagnetite. Copper generally does not correlate well with other elements in most MORB data examined. When differentiation is dominated by olivine, Cu has a tendency to behave incompatibly (e.g., at Mg numbers > 70), but, overall, Cu shows some tendency towards being a compatible element, particularly along the Mid-Atlantic Ridge, a behavior presumably due to separation of sulfides in which Cu (but not Zn) is markedly enriched. Copper thus may be in dispersed sulfides in the source of MORB. Ocean ridges provide important data on source-rock controls for sulfide deposits because, in sediment-starved ridges, much is known about the possible source rocks and mineralization is presently occurring. In contrast to Zn/Pb ~5 in continental hot Cl-rich brines, Zn/Pb in the hottest sediment-starved ridge black smoker hydrothermal fluids at 21 °N, EPR is about 110, similar to local MORB (145), but Cu/Pb is closer to 30, possibly due to subsurface deposition of Cu. At the JFR, the best value of Zn/Pb in the hydrothermal fluids is about 175, again similar to local MORB (240), but Cu is very low in the fluids that are at temperatures less than 300°C. The large MORB-like Zn/Pb in the hottest black-smoker fluids suggests a source-rock control for the metals that prohibits significant galena in the black-smoker deposits of sediment-starved ridges. In contrast, exhalative deposits on sediment-swamped ridges have significant galena; its presence is suggestive of Pb derivation from sediments, an origin supported by Pb isotope studies of LeHuray and colleagues in 1988.

Geochimica et Cosmochimica Acta↗
USGS1985

The plumbotectonics of the West Shasta mining district, eastern Klamath Mountains, California

The tectonic setting comprising the West Shasta mining district has often been compared with that of primitive island arcs. Concentrations of uranium, thorium, and lead and lead isotope compositions were determined for Devonian ores and rocks of the West Shasta district, eastern Klamath Mountains, California, to help evaluate the tectonic classification. The lead isotope pattern is found to be complex. From comparison of the data with those on younger ores and rocks in the region and with those isotopic patterns found in modern tectonic terranes, however, a number of conclusions are possible. A lead isotope point for the Devonian oceanic mantle is now well established from this study on the West Shasta district. This isotopic composition is in agreement with that suggested by Slawson in 1983--i.e., from a sample of massive sulfide ore from the Golinsky deposit--with a 206 Pb/ 204 Pb of 17.830, a 207 Pb/ 204 Pb of 15.450, and a 208 Pb/ 204 Pb of 37.313. If the Devonian mantle is analogous to the modern mantle, the determined value is probably at the more radiogenic end of the Devonian oceanic mantle array.Some samples of volcanic rocks and ores that have elevated values of 207 Pb/ 204 Pb and 208 Pb/ 204 Pb indicate that subducted pelagic sediments or interaction of the magmas with other sediments downsection have been involved to varying degrees in the generation of magmas. The high ratios were not attained by addition of lead to the volcanic rocks or ores during subsequent magmatic events, such as intrusion of the Permian Pit River stock to the east or of the Cretaceous Shasta Bally batholith that crops out to the south and west and may underlie part of the district. Some values of 207 Pb/ 204 Pb are sufficiently high as to suggest that West Shasta may have developed nearer a continent than was previously supposed. Lead isotope data for Quaternary volcanic rocks are somewhat more radiogenic than for Cretaceous ores and plutonic rocks. Permo-Triassic ores are again a bit less radiogenic. The isotopic differences between the Permo-Triassic and Quaternary data could be accounted for by a value for 238 U/ 204 Pb of 10.42 in common source material. Using this value of 238 U/ 204 Pb to calculate even further back to 400 m.y., the resulting ratios are found to fall very close to the "best value" for the lead isotope mixing line between the Devonian mantle and pelagic sediments. We interpret this intersection to be the "mean value" for the assimilated Devonian sediment lead--18.250 for 206 Pb/ 204 Pb and 15.582 for 207 Pb/ 204 Pb. As deduced for the lead isotope composition for the Devonian mantle at this location, the pelagic sediment, lead isotope composition also is toward the more radiogenic end of the values expected for pelagic sediments in the Devonian. Lack of sediments in the observed volcanic section of the West Shasta district suggests a submerged volcanic-arc setting (as interpreted by others for the Troodos and Samail ophiolites) rather than an island-arc situation (such as the Green Tuff area of Japan) or an incipient spreading ridge setting (that might have grown to be a subaerial Iceland). The elevated values of 207 Pb/ 204 Pb for some samples suggest a submerged volcanic are whereas the exceedingly low values of thorium--which is not easily mobilized during alteration events--for both basaltic andesites and plagiorhyolites is suggestive of depleted source material such as is found for most oceanic spreading centers. Elevated values of 207 Pb/ 204 Pb are exceedingly rare in midocean ridge basalts and low contents of thorium are known in island arcs, so a submerged volcanic arc is the preferred interpretation. Some similarity exists between the 206 Pb/ 204 Pb values of Devonian ores having elevated values of 207 Pb/ 204 Pb and those of the Permo-Triassic ores of the East Shasta district, as mentioned by Slawson in 1983. This similarity is now confirmed to be a coincidence. We find it due first of all to some incorporation of sediment lead in the magmas, followed later by some migration of radiogenic lead--probably locally derived--into the ores during subsequent events. Because there was some postdepositional lead migration into the ores, some migration of copper also into the ores cannot be excluded. Lead, especially radiogenic lead, however, is more mobile than copper. As the migrating lead is deduced to have been locally derived from the observed section rather than exotically derived, any copper added was probably locally derived also.

Economic Geology↗
USGS1985

Geologic setting, petrology, and geochemistry of stratiform sphalerite-galena-barite deposits, Red Dog Creek and Drenchwater Creek areas, northwestern Brooks Range, Alaska

Similar stratiform sphalerite-galena-barite deposits occur in the Red Dog Creek area, De Long Mountains quadrangle, and in the Drenchwater Creek area, Howard Pass quadrangle, northwestern Brooks Range, Alaska. The deposits, located approximately 180 km apart, are hosted by Mississippian and Pennsylvanian strata of the Kagvik structural sequence of late Paleozoic and early Mesozoic age. This sequence is situated in the lowermost structural plate of a series of predominantly east-striking, shallow-dipping thrust plates that characterize the regional structure. The deposits occur in shale, tuff, tuffaceous sandstone, altered chert, and quartz exhalite. These units are in places interlayered with or adjacent to bedded or nodular barite or submarine keratophyre flows. Chert and shale commonly contain abundant highly altered, fine-grained feldspar, pumice lapilli, and mafic volcanic rock fragments.The main types of occurrences at Red Dog Creek are: (1) disseminated and stratiform sulfides thinly bedded in organic-rich Mississippian and Pennsylvanian shale and chert, (2) massive sulfide veins and breccia fillings in silicified Mississippian and Pennsylvanian shale, and (3) stratiform sulfide-bearing lenses subdivided into (3a) quartz-exhalite with up to several percent sulfides and barite, (3b) massive sulfide-quartz lenses with up to several percent barite, and (3c) barite-quartz lenses with up to several percent sulfides.At Drenchwater Creek sulfides and barite occur as: (1) disseminations in shale, chert, tuff, and tuffaceous sandstone; (2) disseminations to aggregates in quartz exhalite; and (3) occurrences in veins crosscutting cleavages in brecciated chert and shale.The stratiform sulfides occur in zones up to several thousand meters long and several tens of meters thick. Preliminary grades at Red Dog Creek are 17.1 percent zinc, 5.0 percent lead, and 2.4 oz silver per ton contained in at least 85 million tons.The range of sulfide sulfur isotope values at Red Dog Creek is -16.6 per mil to +3.6 per mil. Sphalerite averages 0.8 per mil. Pyrite is isotopically lighter than coexisting sphalerite in quartz exhalite and massive sulfide lenses. This isotopic relationship is compatible with paragenetic relationships which show pyrite crystallized both earlier and later than other sulfides. Galena is isotopically lighter than coexisting sphalerite. Three groups of geologically and isotopically distinct barites exist including isotopic values appropriate for derivation from late Paleozoic seawater sulfate.Early in the depositional sequence isotopically light pyrite formed from organically reduced seawater sulfate. Sphalerite, galena, late pyrite, and some barite precipitated from two sulfur-bearing solutions that mixed at the mineralization site. Isotopically light barite associated with sulfides precipitated from oxidized H 2 S without seawater sulfate contribution. Lead isotope data from Red Dog and Drenchwater Creeks are compatible with generation of lead in a Phanerozoic mature island-arc setting, a typical orogene, or possibly a back-arc type intracratonic basin.The stratiform sphalerite-galena-barite deposits probably formed in an incipient island-arc environment near a continental margin, containing magmas of keratophyric and andesitic composition, where metal-laden hydrothermal fluids discharged into a deep (?) water, low-energy environment. Later intense deformation, associated with plate docking and thrusting, disrupted and partly remobilized and stratiform deposits.

Alaska↗
USGS1984

U-Th-Pb isotope chronology of sulfide ores and rocks in the early Proterozoic metavolcanic belt of northern Wisconsin

Lead was probably derived from 3.7-b.y.-old source material about 1.8 to 1.9 b.y. ago. Data on metavolcanic and granitic rocks from the belt show that the U-Th-Pb systems in most were reset about 1.6 b.y. ago; a time of shearing and retrogressive metamorphism. A concordia plot of the whole-rock lead data shows that many of the rocks lost lead relative to uranium and thorium during the interval 200 to 400 m.y. ago. Similar ores might be sought between the northern Wisconsin metavolcanic belt and the Upper Mississippi Valley because the lead lost from the basement there might be available for ore formation in overlying units. The lead in the early Proterozoic metavolcanic belt of northern Wisconsin seems to have been derived from the same mantle parent as the late Archean metavolcanic belts of northeastern Minnesota and southern Ontario.

Economic Geology↗
USGS1983

The past is the key to the future

A new major frontier of geological research, which was initiated in the 1970's, involves predicting future geologic trends or events through study of the present and past, rather than trying to understand the past, often using what one knows about the present. Like most scientific frontiers, this one began from practical considerations—environmental concerns. The lack of formal recognition of this frontier results from fragmentation among many Federal agencies and highly focused mission-oriented programs ( e.g. , earthquake prediction, CO 2 , nuclear-energy safety, etc.). Most programs aim to predict only the next 50–100 years, but much longer periods of the past need to be studied to do this. Nuclear-waste disposal has sometimes been considered in terms of the next million years, a period of time permitting significant and broad geologic changes. Decreasing public interest in environmental concerns relegates many questions from the realm of applied research back to that of basic research. Most of these questions are so fascinating, however, that the frontier is still worth pursuing. Such questions include whether a phenomenon will or will not take place and the rates at which it can develop ( e.g. , how fast do rifts form, how fast can a caldera event begin, and how quickly can a glacial maximum arrive?). Common elements of all studies include the historic record, trends in the Quaternary, analogues in various periods of the geologic time scale, and allowance for phenomena never experienced before. Other examples of studies include the Cretaceous as a period of a climatic extreme, an especially interesting time period; establishing the amount of paleocloudiness, a particularly challenging and important research area; acid rain as a possible new phenomenon. Geochemistry has much to contribute to this frontier science.

Geochimica et Cosmochimica Acta↗
USGS1981

U-Th-Pb systematics in hydrothermally altered granites from the Granite Mountains, Wyoming

U-Th-Pb systematics were investigated in 15 samples representing two types of deuterically altered Archean granite (albitized and silicified-epidotized granite) from the Granite Mountains, Wyoming. The loss of K-feldspar during both types of deuteric alteration was accompanied by an extreme reduction of Pb content from roughly 40 ppm to less than 12 ppm in the most altered samples. Nine of the 15 samples yield anomalously young whole-rock Pb-Pb and Th-Pb ages compared to concordia ages for zircons and to whole-rock Pb-Pb and Th-Pb ages for samples of unaltered granite. The young ages are interpreted to be the result of radiogenic Pb loss during a middle Proterozoic metamorphism that disturbed several isotopic systems in the unaltered granite. The loss of radiogenic Pb from the whole-rock systems of the deuterically altered granites is most likely due to the absence of microcline. In many granitic rocks, potassium feldspar tends to act as a receptor for Pb that has been mobilized, and this effect may account for the closed-system behavior of Pb in whole-rock samples of the unaltered granite. It may also account for the apparent gain of radiogenic Pb during the Proterozoic by one sample which was collected at the edge of an alteration zone. The deuterically altered granites may have also lost U during the Proterozoic, but, except for two samples, the dominant U loss occurred relatively recently, probably during Tertiary uplift and erosion. The low common-Pb contents and rather high U and Th contents of the hydrothermally altered granites might seem to indicate that these rocks are well suited for geochronologic studies in the U-Th-Pb system because such rocks should have a high percentage of radiogenic Pb. Unfortunately, open-system behavior in response to post-crystallization metamorphism shows that apparent ages for these types of rocks must be interpreted with caution.

Geochimica et Cosmochimica Acta↗
USGS1981

Plumbotectonics-the model

Plumbotectonics is an attempt to model the geochemical behaviour of U, Th and Pb, among major terrestrial reservoirs in agreement with observational data. By recycling rock through the orogenic environment, a dynamically communicating upper crust, lower crust, and mantle can produce the required patterns of lead-isotope evolution.

Tectonophysics↗
USGS1980

A lead isotope study of mineralization in the Saudi Arabian Shield

New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation. The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics. In the eastern part of the shield, east of longitude 44??20???E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100??300 m.y. (2??). The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also from near Muscat in Oman. These data are the first to indicate such old continental material in these regions. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1979

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗
USGS1978

The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed. ?? 1978 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1974

Stable isotope and lead isotope study of the Cortez, Nevada, gold deposit and surrounding area

Isotope studies of sulfur, carbon, hydrogen, oxygen, and lead were carried out to clarify the age and origin of the Cortex gold deposit and the surrounding mineralized area. The hydrogen isotope data indicate that meteoric water was the dominant component of the ore-forming fluids at Cortez. The hydrogen isotope data support geologic evidence for a Tertiary age for the deposit. The oxidation of the ore probably occurred during the deposition of postore calcite and was caused by waters whose oxygen isotopic composition was distinctly different from that of the ore fluids. The carbon isotope data suggest that the only carbon present in the ore fluids was derived from solution of the host rock. The lead and sulfur data are consistent with a possible sedimentary derivation for the gold in the ore. Lead and sulfur isotope distributions indicate that much of the galena mineralization in the area occurred during the Jurassic.

Nevada↗