Geology topics

B. M. Kennedy

Publications and source records attributed to B. M. Kennedy.

11 recordsLinked to original sources

USGS2012

Helium isotope and gas discharge variations associated with crustal unrest in Long Valley Caldera, California, 1989-1992

The onset of anomalous seismic activity in 1989 beneath Mammoth Mountain on the southwestern rim of the Long Valley caldera, California, was followed within ∼4 months by a large increase in 3 He/ 4 He in vapor discharged from a fumarole on the north side of the mountain. The helium isotopic ratio at this vent rose to a maximum of 6.7 RA in July 1990 and subsequently declined to values near 5 R A . Potential sources of the 3 He‐rich vapors include degassing of fresh magma, degassing from fresh surfaces generated in newly fractured igneous rocks, and volatile release from a 3 He‐rich gas chamber situated above previously emplaced intrusives. The magnitude of the increase in helium isotopic composition (from 3.8 to 6.7 R A ), the persistence of relatively high values (>5 R A ) over a period of 3 years, the increase in the flux of total He relative to gases in air‐saturated water, and the increases in the rates of discharge of steam and gas from this fumarole indicate that magmatic intrusion did in fact begin in 1989 beneath Mammoth Mountain. Seismic activity and limited measurements of extensional deformation at the surface suggest that the depth of intrusion may be as shallow as 2 km, consistent with the prompt appearance of increased 3 He/ 4 He ratios in the fumarolic gas, and that the intrusive process may have persisted for ∼1 year. In contrast, a similar combination of magmatic intrusion and anomalous seismic activity beneath the resurgent dome‐south moat region during the 1989–1991 period resulted in at most relatively small changes in 3 He/ 4 He in fumarolic discharge at the southern edge of the resurgent dome. The more subdued response may result from a combination of greater intrusive depths and greater dilution of 3 He‐rich inputs to thermal fluid reservoirs in the shallow hydrothermal system in this area compared with Mammoth Mountain.

California↗

USGS2002

Tracing and quantifying magmatic carbon discharge in cold groundwaters: Lessons learned from Mammoth Mountain, USA

A major campaign to quantify the magmatic carbon discharge in cold groundwaters around Mammoth Mountain volcano in eastern California was carried out from 1996 to 1999. The total water flow from all sampled cold springs was ??? 1.8 ?? 107 m3/yr draining an area that receives an estimated 2.5 ?? 107 m3/yr of recharge, suggesting that sample coverage of the groundwater system was essentially complete. Some of the waters contain magmatic helium with 3He/4He ratios as high as 4.5 times the atmospheric ratio, and a magmatic component in the dissolved inorganic carbon (DIC) can be identified in virtually every feature sampled. Many waters have a 14C of 0-5 pmC, a ??13C near -5???, and contain high concentrations (20-50 mmol/1) of CO2(aq); but are otherwise dilute (specific conductance = 100-300 ??S/cm) with low pH values between 5 and 6. Such waters have previously escaped notice at Mammoth Mountain, and possibly at many other volcanoes, because CO2 is rapidly lost to the air as the water flows away from the springs, leaving neutral pH waters containing only 1-3 mmol/1 HCO-3. The total discharge of magmatic carbon in the cold groundwater system at Mammoth Mountain is ~ 20 000 t/yr (as CO2), ranging seasonally from about 30 to 90 t/day. Several types of evidence show that this high discharge of magmatic DIC arose in part because of shallow dike intrusion in 1989, but also demonstrate that a long-term discharge possibly half this magnitude (~ 10 000 t/yr) predated that intrusion. To sustain a 10 000 t/yr DIC discharge would require a magma intrusion rate of 0.057 km3 per century, assuming complete degassing of magma with 0.65 wt% CO2 and a density of 2.7 t/m3. The geochemical data also identify a small ( < 1 t/day) discharge of magmatic DIC that can be traced to the Inyo Domes area north of Mammoth Mountain and outside the associated Long Valley caldera. This research, along with recent studies at Lassen Peak and other western USA volcanoes, suggests that the amount of magmatic carbon in cold groundwaters is important to constraining rates of intrusion and edifice weathering at individual volcanoes and may even represent a significant fraction of the global carbon discharge from volcanoes. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2002

Mantle helium and carbon isotopes in Separation Creek geothermal springs, Three Sisters area, central Oregon: Evidence for renewed volcanic activity or a long term steady state system?

Here we present the helium and carbon isotope results from the initial study of a fluid chemistry-monitoring program started in the summer of 2001 near the South Sister volcano in central Oregon. The Separation Creek area which is several miles due west of the volcano is the locus of strong crustal uplift currently occurring at a rate of 4-5 cm/yr (Wicks, et. al. , 2001). Helium [R C /R A = 7.44 and 8.61 R A (R C /R A = ( 3 He/ 4 He) sample-air corrected /( 3 He/ 4 He) air ))] and carbon (δ 13 C = -11.59 to -9.03 ‰ vs PDB) isotope data and CO 2 / 3 He (5 and 9 x 10 9 ) show that bubbling cold springs in the Separation Creek area near South Sister volcano carry a strong mantle signal, indicating the presence of fresh basaltic magma in the volcanic plumbing system. There is no evidence though, to directly relate this signal to the crustal uplift that is currently taking place in the area, which started in 1998. The geothermal system in the area is apparently much longer lived and shows no significant changes in chemistry compared to data from the early 1990s. Hot springs in the area, which are relatively far removed from the volcanic edifice, do not carry a strong mantle signal in helium isotope ratios (2.79 to 5.08 R A ), unlike the cold springs, and also do not show any significant changes in helium isotope ratios compared to literature data for the same springs of over two decades ago. The cold springs of the Separation Creek area form a very diffuse but significant low temperature geothermal system, that should, due to its close vicinity to the center of up uplift, be more sensitive to changes in the deeper volcanic plumbing system than the far removed hot springs and therefore require much more study and consideration when dealing with volcano monitoring in the Cascade range or possibly with geothermal exploration in general.

Oregon↗

USGS2001

High CO2 emissions through porous media: Transport mechanisms and implications for flux measurement and fractionation

Diffuse emissions of CO 2 are known to be large around some volcanoes and hydrothermal areas. Accumulation-chamber measurements of CO 2 flux are increasingly used to estimate the total magmatic or metamorphic CO 2 released from such areas. To assess the performance of accumulation chamber systems at fluxes one to three orders of magnitude higher than normally encountered in soil respiration studies, a test system was constructed in the laboratory where known fluxes could be maintained through dry sand. Steady-state gas concentration profiles and fractionation effects observed in the 30-cm sand column nearly match those predicted by the Stefan-Maxwell equations, indicating that the test system was functioning successfully as a uniform porous medium. Eight groups of investigators tested their accumulation chamber equipment, all configured with continuous infrared gas analyzers (IRGA), in this system. Over a flux range of ∼200–12,000 g m −2 day −1 , 90% of their 203 flux measurements were 0–25% lower than the imposed flux with a mean difference of −12.5%. Although this difference would seem to be within the range of acceptability for many geologic investigations, some potential sources for larger errors were discovered. A steady-state pressure gradient of −20 Pa/m was measured in the sand column at a flux of 11,200 g m −2 day −1 . The derived permeability (50 darcies) was used in the dusty-gas model (DGM) of transport to quantify various diffusive and viscous flux components. These calculations were used to demonstrate that accumulation chambers, in addition to reducing the underlying diffusive gradient, severely disrupt the steady-state pressure gradient. The resultant diversion of the net gas flow is probably responsible for the systematically low flux measurements. It was also shown that the fractionating effects of a viscous CO 2 efflux against a diffusive influx of air will have a major impact on some important geochemical indicators, such as N 2 /Ar, δ 15 N–N 2 , and 4 He/ 22 Ne.

Chemical Geology↗

USGS1998

Carbon dioxide and helium emissions from a reservoir of magmatic gas beneath Mammoth Mountain, California

Carbon dioxide and helium with isotopic compositions indicative of a magmatic source ( δ 13 C = −4.5 to −5‰, 3 He/ 4 He = 4.5 to 6.7 R A ) are discharging at anomalous rates from Mammoth Mountain, on the southwestern rim of the Long Valley caldera in eastern California. The gas is released mainly as diffuse emissions from normal‐temperature soils, but some gas issues from steam vents or leaves the mountain dissolved in cold groundwater. The rate of gas discharge increased significantly in 1989 following a 6‐month period of persistent earthquake swarms and associated strain and ground deformation that has been attributed to dike emplacement beneath the mountain. An increase in the magmatic component of helium discharging in a steam vent on the north side of Mammoth Mountain, which also began in 1989, has persisted until the present time. Anomalous CO 2 discharge from soils first occurred during the winter of 1990 and was followed by observations of several areas of tree kill and/or heavier than normal needlecast the following summer. Subsequent measurements have confirmed that the tree kills are associated with CO 2 concentrations of 30–90% in soil gas and gas flow rates of up to 31,000 g m −2 d −1 at the soil surface. Each of the tree‐kill areas and one area of CO 2 discharge above tree line occurs in close proximity to one or more normal faults, which may provide conduits for gas flow from depth. We estimate that the total diffuse CO 2 flux from the mountain is approximately 520 t/d, and that 30–50 t/d of CO 2 are dissolved in cold groundwater flowing off the flanks of the mountain. Isotopic and chemical analyses of soil and fumarolic gas demonstrate a remarkable homogeneity in composition, suggesting that the CO 2 and associated helium and excess nitrogen may be derived from a common gas reservoir whose source is associated with some combination of magmatic degassing and thermal metamorphism of metasedimentary rocks. Furthermore, N 2 /Ar ratios and nitrogen isotopic values indicate that the Mammoth Mountain gases are derived from sources separate from those that supply gas to the hydrothermal system within the Long Valley caldera. Various data suggest that the Mammoth Mountain gas reservoir is a large, low‐temperature cap over an isolated hydrothermal system, that it predates the 1989 intrusion, and that it could remain a source of gas discharge for some time.

Journal of Geophysical Research B: Solid Earth↗

USGS1997

Mantle fluids in the San Andreas fault system, California

Fluids associated with the San Andreas and companion faults n central and south-central California have high 3He/4He ratios. The lack of correlation between helium isotopes and fluid chemistry or local geology requires that fluids enter the fault system from the mantle. Mantle fluids passing through the ductile lower crust must enter the brittle fault zone at or near lithostatic pressures; estimates of fluid flux based on helium isotopes suggest that they may thus contribute directly to fault-weakening high-fluid pressures at seismogenic depths.

Science↗

USGS1996

Hawaii scientific drilling protect: Summary of preliminary results

Petrological, geochemical, geomagnetic, and volcanological characterization of the recovered core from a 1056-m-deep well into the flank of the Mauna Kea volcano in Hilo, Hawaii, and downhole logging and fluid sampling have provided a unique view of the evolution and internal structure of a major oceanic volcano unavailable from surface exposures. Core recovery was ~90%, yielding a time series of fresh, subaerial lavas extending back to ~400 ka. Results of this 1993 project provide a basis for a more ambitious project to core drill a well 4.5 km deep in a nearby location with the goal of recovering an extended, high-density stratigraphic sequence of lavas.

Hawaii↗

USGS1995

Forest-killing diffuse CO2 emission at Mammoth Mountain as a sign of magmatic unrest

Mammoth Mountain, in the western United States, is a large dacitic volcano with a long history of volcanism that began 200 kyr ago and produced phreatic eruptions as recently as 500 ± 200 yr BP. Seismicity, ground deformation and changes in fumarole gas composition suggested an episode of shallow dyke intrusion in 1989–90. Areas of dying forest and incidents of near asphyxia in confined spaces, first reported in 1990, prompted us to search for diffuse flank emissions of magmatic CO 2 , as have been described at Mount Etna and Vulcano . Here we report the results of a soil-gas survey, begun in 1994, that revealed CO 2 concentrations of 30–96% in a 30-hectare region of killed trees, from which we estimate a total CO 2 flux of ≥1,200 tonnes per day. The forest die-off is the most conspicuous surface manifestation of magmatic processes at Mammoth Mountain, which hosts only weak fumarolic vents and no summit activity. Although the onset of tree kill coincided with the episode of shallow dyke intrusion, the magnitude and duration of the CO 2 flux indicates that a larger, deeper magma source and/or a large reservoir of high-pressure gas is being tapped.

California↗

USGS1994

Correlation of gold in siliceous sinters with 3He 4He in hot spring waters of Yellowstone National Park

Opaline sinter samples collected at Yellowstone National Park (YNP) were analyzed for gold by neutron activation and for other trace elements by the inductively coupled plasma optical emission spectroscopy (ICP-OES) method. No correlation was found between Au and As, Sb, or total Fe in the sinters, although the sample containing the highest Au also contains the highest Sb. There also was no correlation of Au in the sinter with the H 2 S concentration in the discharged hot spring water or with the estimated temperature of last equilibration of the water with the surrounding rock. The Au in rhyolitic tuffs and lavas at YNP found within the Yellowstone caldera show the same range in Au as do those outside the caldera, while thermal waters from within this caldera all have been found to contain relatively low dissolved Au and to deposit sinters that contain relatively little Au. Therefore, it is not likely that variations in Au concentrations among these sinters simply reflect differences in leachable Au in the rocks through which the hydrothermal fluids have passed. Rather, variations in [H 2 S], the concentration of total dissolved sulfide, that result from different physical and chemical processes that occur in different parts of the hydrothermal system appear to exert the main control on the abundance of Au in these sinters. Hydrothermal fluids at YNP convect upward through a series of successively shallower and cooler reservoirs where water-rock chemical and isotopic reactions occur in response to changing temperature and pressure. In some parts of the system the fluids undergo decompressional boiling, and in other parts they cool conductively without boiling. Mixing of ascending water from deep in the system with shallow groundwaters is common. All three processes generally result in a decrease in [H 2 S] and destabilize dissolved gold bisulfide complexes in reservoir waters in the YNP system. Thus, different reservoirs in rocks of similar composition and at similar temperatures may contain waters with different [H 2 S] and [Au]. The [H 2 S] in a subsurface reservoir water is difficult to assess on the basis of analyses of hot spring waters because of uncertainties about steam loss during fluid ascent. However, the same processes that result in low [H 2 S] in reservoir waters also tend to result in decreases in the ratio of 3 He 4 He(R) "> 3He4He(R) dissolved in that water. Values of R relative to this ratio in air ( Ra ) attain values > 15 in YNP thermal waters. To date, all of the thermal waters at YNP that have R Ra "> RRa values <9 have been found to deposit sinters with relatively low gold concentrations. These include all of the thermal waters that discharge from 180–215°C reservoirs at Upper, Midway, and Lower Geyser Basins within the western part of the Yellowstone caldera, and thermal waters at Norris Geyser Basin, outside the Yellowstone caldera, where some of the waters flow directly to the surface from a reservoir where the temperature is about 300°C. A high 3 He 4 He "> 3He4He ratio in thermal water discharged at the surface does not guarantee high gold concentrations in the sinter deposited by this water. Boiling with loss of steam (the gas phase takes a separate route to the surface) during rapid upflow from the shallowest reservoir to the surface decreases the [H 2 S] and total He dissolved in the residual liquid without appreciably changing the 3 He 4 He "> 3He4He ratio. This is because the isotopic composition of the He of the initial bulk fluid is unchanged and there is too little time for much radiogenic 4 He to build back into the liquid during this rapid ascent from the near-surface reservoir. However, if boiling with phase separation and loss of steam occurs deep in the system, the 3 He 4 He "> 3He4He ratio in the residual liquid, now depleted in H 2 S and total He, will be susceptible to dilution with radiogenic 4 He that is acquired during the longer residence time underground. Some or all of the Au that comes out of solution when an initial gold bisulfide complex breaks down as a result of loss of H 2 S may be swept up to the surface as solid (probably colloidal) particles, depending on the rate of flow of the mixture of water and steam, and the geometry of the channel. Where colloidal silica also forms as a result of this boiling, free Au apparently becomes attached to the colloidal silica and deposits where the silica deposits.

Wyoming↗

USGS1990

Coupled variations in helium isotopes and fluid chemistry: Shoshone Geyser Basin, Yellowstone National Park

Early studies of 3 He/ 4 He variations in geothermal systems have generally attributed these fluctuations to either differences in the source of the magmatic 3 He-rich helium or to local differences in the deep flux of magmatic 3 He-rich helium. Kennedy et al. (1987), however, show that near-surface processes such as boiling and dilution may also drastically affect 3 He 4 "> 3 He 4 He ratios of geothermal vapors. Helium isotope ratios were determined for several hot springs at Shoshone Geyser Basin of Yellowstone National Park for this study, along with other noble gas data. Stable isotope data and water and gas chemistry data for each spring were also compiled. The water chemistry indicates that there is one deep, hot thermal water in the area which is mixing with dilute meteoric water that has entered the system at depth. Spring HCO 3 − concentrations correlate with 3 He 4 He "> 3 He 4 He values, as in nearby Lower Geyser Basin. This correlation is attributed to variable amounts of deep dilution of thermal waters with a relatively cool water that inhibits boiling at depth, thus preventing the loss of CO 2 (and therefore HCO 3 − ) and magmatic He in the most diluted samples. Oxygen and hydrogen isotope data also support a boiling and dilution model, but to produce the observed fractionations, the boiling event would have to be extensive, with steam loss at the surface, whereas the boiling that affected the helium isotope ratios was probably a small scale event with steam loss at depth. It is possible that deep boiling occurred in the basin and that small amounts of steam escaped along fractures at about 500 m below the surface while all subsequently produced steam was lost near or at the surface.

Geochimica et Cosmochimica Acta↗

USGS1990

Geochemistry of reduced gas related to serpentinization of the Zambales ophiolite, Philippines

Methane-hydrogen gas seeps with mantle-like C and noble gas isotopic characteristics issue from partially serpentinized ultramafic rocks in the Zambales ophiolite, Philippines. New measurements of noble gas and 14 C isotope abundances, rock/mixed-volatile equilibrium calculations, and previous chemical and isotopic data suggest that these reduced gases are products of periodotite hydration. The gas seeps are produced in rock-dominated zones of serpentinization, and similar gases may be ubiquitous in ultramafic terranes undergoing serpentinization.

Applied Geochemistry↗