Search USGS⌕ Search

Geology topics

B. Kurylyk

Publications and source records attributed to B. Kurylyk.

5 recordsLinked to original sources

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts↗

An ecohydrological typology for thermal refuges in streams and rivers

Thermal refuges are thermally distinct riverscape features used by aquatic organisms during unfavorable thermal events, facilitating resilience in marginal environments. However, the thermal refuge concept is nebulous, and the often interchangeable use of the term ‘thermal refugia’ creates additional ambiguity. We argue that lexical differences resulting from divergent scholarly trainings hinder holistic understanding of thermal refuges; thus, existing studies would benefit from a structured framework for thermal refuge conceptualization. Herein, we articulate an ecohydrological typology for defining and characterizing thermal refuges in streams and rivers by identifying key hydrological and thermal characteristics and variations in ecological function described in the literature. We use concepts that are easily definable, measurable, and transferable across disciplines, riverscapes, and species to discriminate among thermal refuge types. Future work can use our typology as a basis for more informed interdisciplinary discussion and interpretation of thermal refuges’ role in riverscapes through more hypothesis‐driven research and conservation‐focused management.

Ecohydrology↗

Using heat to trace vertical water fluxes in sediment experiencing concurrent tidal pumping and groundwater discharge

Heat has been widely applied to trace groundwater‐surface water exchanges in inland environments, but it is infrequently applied in coastal sediment where head oscillations induce periodicity in water flux magnitude/direction and heat advection. This complicates interpretation of temperatures to estimate water fluxes. We investigate the convolution of thermal and hydraulic signals to assess the viability of using heat as a tracer in environments with tidal head oscillations superimposed on submarine groundwater discharge. We first generate sediment temperature and head time series for conditions ranging from no tide to mega‐tidal using a numerical model (SUTRA) forced with periodic temperature and tidal head signals. We then analyze these synthetic temperature time series using heat tracing software (VFLUX2 and 1DTempPro) to evaluate if conventional terrestrial approaches to infer fluxes from temperatures are applicable for coastal settings. We consider high‐frequency water flux variability within a tidal signal and averaged over tidal signals. Results show that VFLUX2 analytical methods reasonably estimated the mean discharge fluxes in most cases but could not reproduce the flux variability within tidal cycles. The model results further reveal that high‐frequency time series of water fluxes varying in magnitude and direction can be accurately estimated if paired temperature and hydraulic head are analyzed using numerical models (e.g. 1DTempPro) that consider both dynamic hydraulic gradients and thermal signals. These results point to the opportunity to incorporate pressure sensors within heat tracing instrumentation to better assess sub‐daily flux oscillations and associated reactive processes.

Water Resources Research↗

Small atoll fresh groundwater lenses respond to a combination of natural climatic cycles and human modified geology

Freshwater lenses underlying small ocean islands exhibit spatial variability and temporal fluctuations in volume, influencing ecologic management. For example, The Palmyra Atoll National Wildlife Refuge harbors one of the few surviving native stands of Pisonia grandis in the central Pacific Ocean, yet these trees face pressure from groundwater salinization, with little basic groundwater data to guide decision making. Adding to natural complexity, the geology of Palmyra was heavily altered by dredge and fill activities. Our study based at this atoll combines geophysical and hydrological field measurements from 2008 to 2019 with groundwater modeling to study the drivers of observed freshwater lens dynamics. Electromagnetic induction (EMI) field data were collected on the main atoll islands over repeat transects in 2008 following ‘strong’ La Niña conditions (wet) and in 2016 during ‘very strong’ El Niño conditions (dry). Shallow monitoring wells were installed adjacent to the geophysical transects in 2013 and screened within the fresh/saline groundwater transition zone. Temporal EMI and monitoring well data showed a strong contraction of the freshwater lens in response to El Niño conditions, and indicated a thicker lens toward the ocean side, an opposite spatial pattern to that observed for many other Pacific islands. On an outer islet where a stand of mature Pisonia trees exist, EMI surveys revealed only a thin (<3 m from land surface) layer of brackish groundwater during El Niño. Numerical groundwater simulations were performed for a range of permeability distributions and climate conditions at Palmyra. Results revealed that the observed atypical lens asymmetry is likely due to more efficient submarine groundwater discharge on the lagoon side as a result of lagoon dredging and filling with high-permeability material. Simulations also predict large decreases (40%) in freshwater lens volume during dry cycles and highlight threats to the Pisonia trees, yielding insight for atoll ecosystem management worldwide.

Science of the Total Environment↗

Quantitative guidance for efficient vertical flow measurements at the sediment-water interface using temperature-depth profiles

Upward discharge to surface water bodies can be quantified using analytical models based on temperature-depth (T-z) profiles. The use of sediment T-z profiles is attractive as discharge estimates can be obtained using point-in-time data that are collected inexpensively and rapidly. Previous studies have identified that T-z methods can only be applied at times of the year when there is significant difference between the streambed-water interface and deeper sediment temperatures (e.g., winter and summer). However, surface water temperatures also vary diurnally, and the influence of these variations on discharge estimates from T-z methods is poorly understood. For this study, synthetic T-z profiles were generated numerically using measured streambed interface temperature data to assess the influence of diurnal temperature variations on discharge estimation and provide insight into the suitable application of T-z methods. Results show that the time of day of data collection can have a substantial influence on vertical flux estimates using T-z methods. For low groundwater discharge fluxes (e.g. 0.1 m d-1), daily transience in streambed temperatures led to relatively large errors in estimated flow magnitude and direction. For higher discharge fluxes (1.5 m d-1), the influence of transient streambed temperatures on discharge estimates was strongly reduced. Discharge estimates from point-in-time T-z profiles were most accurate when the uppermost point in the T-z profile was near the bed interface daily mean (two time periods daily). Where temperature time series data are available, daily averaged T-z profiles can produce accurate discharge estimates across a wide range of discharge rates. Seasonality in shallow groundwater temperature generally had a negligible influence on vertical flow estimates. These findings can be used to plan field campaigns and provide guidance on the optimal application of T-z methods to quantify vertical groundwater discharge to surface water bodies.

Hydrological Processes↗