Geology topics

B. C. Scudder

Publications and source records attributed to B. C. Scudder.

6 recordsLinked to original sources

USGS2009

Mercury cycling in stream ecosystems. 3. Trophic dynamics and methylmercury bioaccumulation

Trophic dynamics (community composition and feeding relationships) have been identified as important drivers of methylmercury (MeHg) bioaccumulation in lakes, reservoirs, and marine ecosystems. The relative importance of trophic dynamics and geochemical controls on MeHg bioaccumulation in streams, however, remains poorly characterized. MeHg bioaccumulation was evaluated in eight stream ecosystems across the United States (Oregon, Wisconsin, and Florida) spanning large ranges in climate, landscape characteristics, atmospheric Hg deposition, and stream chemistry. Across all geographic regions and all streams, concentrations of total Hg (THg) in top predator fish and forage fish, and MeHg in invertebrates, were strongly positively correlated to concentrations of filtered THg (FTHg), filtered MeHg (FMeHg), and dissolved organic carbon (DOC); to DOC complexity (as measured by specific ultraviolet absorbance); and to percent wetland in the stream basins. Correlations were strongest for nonurban streams. Although regressions of log[Hg] versus δ 15 N indicate that Hg in biota increased significantly with increasing trophic position within seven of eight individual streams, Hg concentrations in top predator fish (including cutthroat, rainbow, and brown trout; green sunfish; and largemouth bass) were not strongly influenced by differences in relative trophic position. Slopes of log[Hg] versus δ 15 N, an indicator of the efficiency of trophic enrichment, ranged from 0.14 to 0.27 for all streams. These data suggest that, across the large ranges in FTHg (0.14−14.2 ng L −1 ), FMeHg (0.023−1.03 ng L −1 ), and DOC (0.50−61.0 mg L −1 ) found in this study, Hg contamination in top predator fish in streams likely is dominated by the amount of MeHg available for uptake at the base of the food web rather than by differences in the trophic position of top predator fish.

Environmental Science & Technology↗

USGS2007

Mercury accumulation in periphyton of eight river ecosystems

In 2003, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program and U.S. Environmental Protection Agency studied total mercury (THg) and methylmercury (MeHg) concentrations in periphyton at eight rivers in the United States in coordination with a larger USGS study on mercury cycling in rivers. Periphyton samples were collected using trace element clean techniques and NAWQA sampling protocols in spring and fall from targeted habitats (streambed surface-sediment, cobble, or woody snags) at each river site. A positive correlation was observed between concentrations of THg and MeHg in periphyton (r2 = 0.88, in log-log space). Mean MeHg and THg concentrations in surface-sediment periphyton were significantly higher (1,333 ng/m2 for MeHg and 53,980 ng/m2 for THg) than cobble (64 ng/m2 for MeHg and 1,192 ng/m2 for THg) or woody snag (71 ng/m2 for MeHg and 1,089 ng/m2 for THg) periphyton. Concentrations of THg in surface-sediment periphyton had a strong positive correlation with concentrations of THg in sediment (dry weight). The ratio of MeHg:THg in surface-sediment periphyton increased with the ratio of MeHg:THg in sediment. These data suggest periphyton may play a key role in mercury bioaccumulation in river ecosystems. ?? 2007 American Water Resources Association.

Journal of the American Water Resources Associatio↗

USGS1997

Trace elements and synthetic organic compounds in biota and streambed sediment of the Western Lake Michigan Drainages, 1992-1995

Sampling was conducted in 1992,1994, and 1995 to determine the occurrence of a broad suite of trace elements and synthetic organic compounds in biota and streambed sediment in selected streams in the Western Lake Michigan Drainages a study unit of the National Water- Quality Assessment (NAWQA) Program of the U.S. Geological Survey. Sediment was sampled at 31 sites for trace elements and 23 sites for synthetic organic compounds; biota were collected at a subset of sites. Some of the variability in trace elements and synthetic organic compounds was related to land use, and many differences in trace element concentration by land use category were statistically significant. The spatial distribution of some trace elements was related to a combination of land use and surficial deposits and (or) bedrock type. Urban land use was likely the dominant factor influencing high sediment concentrations of Cd, Cu, Hg, and Pb. Forested land use was related to high concentrations of As in sediment and biota and high Se in sediment; however, bedrock type was an additional factor for As and surficial deposits type was a factor for Se. Land use, surficial deposits, and bedrock type appeared to influence Ni and Zn concentrations, and Cr concentrations did not directly reflect any of these factors. Most occurrences of organochlorine compounds in sediment and biota were related to urban land use. DDT and related compounds were detected at sites spanning all land uses. PCBs were detected in sediment at large-river sites and at one urban site in the Milwaukee area; the highest concentrations of PCBs in fish were found at two of four large river sites. A larger number of SVOCs were detected at urban sites and large river sites compared to agricultural and forested sites.

Michigan, Wisconsin↗

USGS1996

Benthic invertebrates of benchmark streams in agricultural areas of eastern Wisconsin — Western Lake Michigan drainages

This study describes the benthic invertebrate communities of 20 benchmark streams in agricultural areas of eastern Wisconsin. Streams with minimal adverse effects from human activity were selected from four agricultural areas with differing surficial deposits and bedrock types (relatively homogeneous units, or RHU's). Most aquatic invertebrate orders were well represented in the 20 benchmark stream samples; 217 species and 151 genera within 56 families were identified. Diptera was the best represented order (96 species), followed by Trichoptera (42 species) and Ephemeroptera (26 species). Diptera were the most abundant organisms in terms of numbers of individuals in the sample (28 percent of the total) followed by Trichoptera (25 percent) and Ephemeroptera (13 percent). Nine species of freshwater mussels were found, but only in 5 of the 20 benchmark streams. Community measures were calculated for the following: total number of individuals; number of species; number of families; Margalef's diversity index; percent dominant family; percent Ephemeroptera-Plecoptera-Trichoptera (EPT); ratio of EPT to Chironomidae; percent shredders; ratio of scrapers to collectors-gatherers-filterers; Hilsenhoff's Biotic Index; Hilsenhoff's family level biotic index; and mean tolerance value. The S AS statistical software package was used for calculations of variance and correlations, normality checks, and principal components analysis of these measures and to find relations between benthic-invertebrate data and environmental-setting, habitat, and water-quality data. Coefficients of variation within the RHU's were as great or greater than those for all 20 streams for most measures and RHU's. The specific taxa assemblages present at the sites did not show distinct differences between RHU's or similarities within the RHU's. The covariance and the Kruskal-Wallis tests showed that the benthic invertebrate measures were not related to RHU. These results all indicate that the combined effect of the RHU variables (bedrock geology, texture of surficial deposits, and land use/land cover) were not elemental in describing invertebrate communities in the study-area streams. A principal components analysis (PCA) was done on the 20 benchmark streams which used the invertebrate population measures as variables. A three-dimensional ordination plot of these components revealed that 18 of the 20 streams could be divided into three groups relative to stream size, available habitat, and water quality. The three classifications of streams include large, warmer streams with slight pollution; deep, mixed-water streams with minimal pollution; and small, cold, pristine headwater streams. The two streams not defined by the three PCA groupings were not suitable to represent benchmark conditions. One site lacked suitable quality habitat or sufficient nutrients to support a healthy population of invertebrates, causing low measures of diversity. The other site appeared to be affected by sedimentation and low flows. The classification groupings did not show any significant relations to percentage agricultural land use. Percentage of agricultural land use varied greatly within each group and the means for each group were similar. All streams in this study had some level of protection from agricultural practices in their basins. Although the intensity of agriculture is known to be a factor causing deterioration of invertebrate populations in past studies, the finding in this study indicated that the level of protection the stream received and other factors such as environmental setting and habitat could be more important to benthic invertebrates than the percentage of agriculture in the basin. Information gathered from these benchmark streams can be used as a regional reference for comparison with other streams in agricultural areas, based on communities of aquatic biota, habitat, and water quality.

Wisconsin↗

USGS1996

Summary of biological investigations relating to water quality in the Western Lake Michigan Drainages, Wisconsin and Michigan

This report summarizes aquatic biological studies relevant to water-quality assessment that have been done in the Western Lake Michigan Drainages from 1891 to 1996. The objective of the summary was to compile sources of biological data for the U.S. Geological Survey's National Water-Quality Assessment Program. The studies are divided into four categories: (1) populations and community structure of aquatic biota, (2) health of aquatic biota, (3) chemical concentrations in tissues of aquatic biota, and (4) toxicity tests by use of aquatic biota. Studies are further categorized by subbasin, spatial scale (regional or local), types of biota, and, if applicable, effect or contaminant investigated. For the purposes of this report, the study area is divided into five subbasins. The subbasins, from north to south, are (1) the Ford/Escanaba Subbasin in Michigan's Upper Peninsula, and in Wisconsin, (2) the Menominee/ Oconto/Peshtigo Subbasin, (3) the Fox/Wolf Subbasin, (4) the Sheboygan/Manitowoc/Twin Subbasin, and (5) the Milwaukee Subbasin. Most biological studies related to waterquality conditions in the Western Lake Michigan Drainages have focused on populations and community structure of aquatic biota. Chemical concentrations in tissues of aquatic biota have been the next most common area of research. Our review suggests a paucity of data related to the health of all types of aquatic biota, especially amphibians, invertebrates, and reptiles; toxicity studies also were relatively uncommon. Overall, organisms primarily studied have been fish and invertebrates, although birds are most frequently examined in studies of organism health. The Fox/ Wolf Subbasin has been the focus of many more studies than the other subbasins, most likely because of the greater extent and severity of known water-quality problems in the Lower Fox River/Green Bay area over the past several decades and because it is the largest subbasin. Studies in the other subbasins are needed to adequately assess the water quality of these areas.

Michigan, Wisconsin↗

USGS1990

Trace elements in Corbicula fluminea from the San Joaquin River, California

(i) Trace element concentrations in soft tissue of the benthic bivalve, Corbicula fluminea, from the San Joaquin River and its major tributaries were examined during the primary irrigation season in relation to the spatial variation in concentrations of major, minor and trace constituents in riverwater and sediments. (ii) Selenium concentrations in Corbicula from perennial flow reaches of the San Joaquin River and its major tributaries varied directly with the solute (??? 0.45 ??m) Se concentrations of riverwater. Elevated concentrations occurred in clams from sites with substantial discharge originating as subsurface drainage and irrigation return flows. Both tissue and solute Se concentrations declined from June through the end of the primary irrigation season. (iii) Arsenic concentrations in Corbicula from perennial flow reaches of the San Joaquin River varied directly with the HNO3-extractable (pH 2) As:Fe ratio of suspended matter, providing evidence that sorption to oxyhydroxide surfaces is an important control on the biological availability of As. However, Corbicula from several tributaries draining alluvium derived from the Sierra Nevada had lower As concentrations than would be predicted by the relation developed for perennial flow sites of the San Joaquin River. Arsenic concentrations in Corbicula from the Tuolumne and Merced Rivers and upstream reaches of the San Joaquin River were higher than in clams from the downstream perennial flow reaches of the San Joaquin River. Concentrations of As in clams from downstream perennial flow reaches of the San Joaquin River increased from June through the end of the primary irrigation season. (iv) Mercury concentrations in Corbicula were elevated in upstream reaches of the San Joaquin River, in the Merced and Tuolumne Rivers, and in tributaries draining the Coast Ranges. Mean Cd and Cu concentrations in Corbicula were elevated in the Merced and Tuolumne Rivers, Orestimba Creek and a perennial flow reach of the San Joaquin River which receives water directly from the Delta Mendota Canal. Concentrations of Ni in clams from the San Joaquin River decreased downstream of the Delta Mendota Pool. (v) Boron and Mo were not accumulated by Corbicula despite high solute concentrations (means as high as 2960 ??g B l-1 and 9 ??g Mo l-1) in riverwater during the primary irrigation season. This bivalve may not be an appropriate bioindicator of B and Mo enrichment. Concentrations of Cr, Pb, Ag, V and Zn in Corbicula exhibited little geographic variability in the drainage. (vi) Regression analysis revealed no clear evidence of synergistic or antagonistic interactions among As, Cd, Cu, Hg, Ni and Se in their uptake by Corbicula.

Conference Paper↗