Geology topics

Andrew H. Manning

Publications and source records attributed to Andrew H. Manning.

At least 37 records · Page 2Linked to original sources

USGS2015

Using noble gas tracers to constrain a groundwater flow model with recharge elevations: A novel approach for mountainous terrain

Environmental tracers provide information on groundwater age, recharge conditions, and flow processes which can be helpful for evaluating groundwater sustainability and vulnerability. Dissolved noble gas data have proven particularly useful in mountainous terrain because they can be used to determine recharge elevation. However, tracer-derived recharge elevations have not been utilized as calibration targets for numerical groundwater flow models. Herein, we constrain and calibrate a regional groundwater flow model with noble-gas-derived recharge elevations for the first time. Tritium and noble gas tracer results improved the site conceptual model by identifying a previously uncertain contribution of mountain block recharge from the Coast Mountains to an alluvial coastal aquifer in humid southwestern British Columbia. The revised conceptual model was integrated into a three-dimensional numerical groundwater flow model and calibrated to hydraulic head data in addition to recharge elevations estimated from noble gas recharge temperatures. Recharge elevations proved to be imperative for constraining hydraulic conductivity, recharge location, and bedrock geometry, and thus minimizing model nonuniqueness. Results indicate that 45% of recharge to the aquifer is mountain block recharge. A similar match between measured and modeled heads was achieved in a second numerical model that excludes the mountain block (no mountain block recharge), demonstrating that hydraulic head data alone are incapable of quantifying mountain block recharge. This result has significant implications for understanding and managing source water protection in recharge areas, potential effects of climate change, the overall water budget, and ultimately ensuring groundwater sustainability.

Water Resources Research↗

USGS2015

Insights into controls on hexavalent chromium in groundwater provided by environmental tracers, Sacramento Valley, California, USA

Environmental tracers are useful for determining groundwater age and recharge source, yet their application in studies of geogenic Cr(VI) in groundwater has been limited. Environmental tracer data from 166 wells located in the Sacramento Valley, northern California, were interpreted and compared to Cr concentrations to determine the origin and age of groundwater with elevated Cr(VI), and better understand where Cr(VI) becomes mobilized and how it evolves along flowpaths. In addition to major ion and trace element concentrations, the dataset includes δ 18 O, δ 2 H, 3 H concentration, 14 C activity (of dissolved inorganic C), δ 13 C, 3 He/ 4 He ratio, and noble gas concentrations (He, Ne, Ar, Kr, Xe). Noble gas recharge temperatures (NGTs) were computed, and age-related tracers were interpreted in combination to constrain the age distribution in samples and sort them into six different age categories spanning from <60 yr old to >10,000 yr old. Nearly all measured Cr is in the form of Cr(IV). Concentrations range from <1 to 46 μg L −1 , with 10% exceeding the state of California’s Cr(VI) maximum contaminant level of 10 μg L −1 . Two groups with elevated Cr(VI) (⩾5 μg L −1 ) were identified. Group 1 samples are from the southern part of the valley and contain modern (<60 yr old) water, have elevated NO 3 − concentrations (>3 mg L −1 ), and commonly have δ 18 O values enriched relative to local precipitation. These samples likely contain irrigation water and are elevated due to accelerated mobilization of Cr(VI) in the unsaturated zone (UZ) in irrigated areas. Group 2 samples are from throughout the valley and typically contain water 1000–10,000 yr old, have δ 18 O values consistent with local precipitation, and have unexpectedly warm NGTs. Chromium(VI) concentrations in Group 2 samples may be elevated for multiple reasons, but the hypothesis most consistent with all available data (notably, the warm NGTs) is a relatively long UZ residence time due to recharge through a deep UZ near the margin of the basin. A possible explanation for why Cr(VI) may be primarily mobilized in the UZ rather than farther along flowpaths in the oxic portion of the saturated zone is more dynamic cycling of Mn in the UZ due to transient moisture and redox conditions.

California↗

USGS2013

Links between climate change, water-table depth, and water chemistry in a mineralized mountain watershed

Recent studies suggest that climate change is causing rising solute concentrations in mountain lakes and streams. These changes may be more pronounced in mineralized watersheds due to the sensitivity of sulfide weathering to changes in subsurface oxygen transport. Specific causal mechanisms linking climate change and accelerated weathering rates have been proposed, but in general remain entirely hypothetical. For mineralized watersheds, a favored hypothesis is that falling water tables caused by declining recharge rates allow an increasing volume of sulfide-bearing rock to become exposed to air, thus oxygen. Here, we test the hypothesis that falling water tables are the primary cause of an increase in metals and SO4 (100-400%) observed since 1980 in the Upper Snake River (USR), Colorado. The USR drains an alpine watershed geologically and climatologically representative of many others in mineralized areas of the western U.S. Hydrologic and chemical data collected from 2005 to 2011 in a deep monitoring well (WP1) at the top of the USR watershed are utilized. During this period, both water table depths and groundwater SO4 concentrations have generally increased in the well. A numerical model was constructed using TOUGHREACT that simulates pyrite oxidation near WP1, including groundwater flow and oxygen transport in both saturated and unsaturated zones. The modeling suggests that a falling water table could produce an increase in metals and SO4 of a magnitude similar to that observed in the USR (up to 300%). Future water table declines may produce limited increases in sulfide weathering high in the watershed because of the water table dropping below the depth of oxygen penetration, but may continue to enhance sulfide weathering lower in the watershed where water tables are shallower. Advective air (oxygen) transport in the unsaturated zone caused by seasonally variable recharge and associated water table fluctuations was found to have little influence on pyrite oxidation rates near WP1. However, this mechanism could be important in the case of a shallow dynamic water table and more abundant/reactive sulfides in the shallow subsurface. Data from WP1 and numerical modeling results are thus consistent with the falling water table hypothesis, and illustrate fundamental processes linking climate and sulfide weathering in mineralized watersheds.

Applied Geochemistry↗

USGS2012

Using geochemistry to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: Part 2

Montezuma Well is a unique natural spring located in a sinkhole surrounded by travertine. Montezuma Well is managed by the National Park Service, and groundwater development in the area is a potential threat to the water source for Montezuma Well. This research was undertaken to better understand the sources of groundwater to Montezuma Well. Strontium isotopes ( 87 Sr/ 86 Sr) indicate that groundwater in the recharge area has flowed through surficial basalts with subsequent contact with the underlying Permian aged sandstones and the deeper, karstic, Mississippian Redwall Limestone. The distinctive geochemistry in Montezuma Well and nearby Soda Springs (higher concentrations of alkalinity, As, B, Cl, and Li) is coincident with added carbon dioxide and mantle-sourced He. The geochemistry and isotopic data from Montezuma Well and Soda Springs allow for the separation of groundwater samples into four categories: (1) upgradient, (2) deep groundwater with carbon dioxide, (3) shallow Verde Formation, and (4) mixing zone. δ 18 O and δD values, along with noble gas recharge elevation data, indicate that the higher elevation areas to the north and east of Montezuma Well are the groundwater recharge zones for Montezuma Well and most of the groundwater in this portion of the Verde Valley. Adjusted groundwater age dating using likely 14 C and δ 13 C sources indicate an age for Montezuma Well and Soda Springs groundwaters at 5,400–13,300 years, while shallow groundwater in the Verde Formation appears to be older (18,900). Based on water chemistry and isotopic evidence, groundwater flow to Montezuma Well is consistent with a hydrogeologic framework that indicates groundwater flow by (1) recharge in higher elevation basalts to the north and east of Montezuma Well, (2) movement through the upgradient Permian and Mississippian units, especially the Redwall Limestone, and (3) contact with a basalt dike/fracture system that provides a mechanism for groundwater to flow to the surface. While the exact nature of the groundwater flow connections is still uncertain, the available data indicate that flow to Montezuma Well may be more susceptible to future groundwater development in the Redwall Limestone than from any other geologic unit. Overall, the shallow groundwater in the surrounding Verde Formation appears to be largely disconnected from deeper groundwater flowing to Montezuma Well.

Arizona↗

USGS2012

Climate-change-driven deterioration of water quality in a mineralized watershed

A unique 30-year streamwater chemistry data set from a mineralized alpine watershed with naturally acidic, metal-rich water displays dissolved concentrations of Zn and other metals of ecological concern increasing by 100–400% (400–2000 μg/L) during low-flow months, when metal concentrations are highest. SO 4 and other major ions show similar increases. A lack of natural or anthropogenic land disturbances in the watershed during the study period suggests that climate change is the underlying cause. Local mean annual and mean summer air temperatures have increased at a rate of 0.2–1.2 °C/decade since the 1980s. Other climatic and hydrologic indices, including stream discharge during low-flow months, do not display statistically significant trends. Consideration of potential specific causal mechanisms driven by rising temperatures suggests that melting of permafrost and falling water tables (from decreased recharge) are probable explanations for the increasing concentrations. The prospect of future widespread increases in dissolved solutes from mineralized watersheds is concerning given likely negative impacts on downstream ecosystems and water resources, and complications created for the establishment of attainable remediation objectives at mine sites.

Environmental Science & Technology↗

USGS2011

Classifying the water table at regional to continental scales

Water tables at regional to continental scales can be classified into two distinct types: recharge-controlled water tables that are largely disconnected from topography and topography-controlled water tables that are closely tied to topography. We use geomatic synthesis of hydrologic, geologic and topographic data sets to quantify and map water-table type over the contiguous United States using a dimensionless criterion introduced by Haitjema and Mitchell-Bruker (2005), called the water-table ratio, which differentiates water-table type. Our analysis indicates that specific regions of the United States have broadly contiguous and characteristic water-table types. Water-table ratio relates to water-table depth and the potential for regional groundwater flow. In regions with recharge-controlled water tables, for example the Southwest or Rocky Mountains, USA, water-tables depths are generally greater and more variable and regional groundwater flow is generally more important as a percentage of the watershed budget. Water-table depths are generally shallow and less variable, and regional groundwater flow is limited in areas with topography-controlled water tables such as the Northeast USA. The water-table ratio is a simple but powerful criterion for evaluating regional groundwater systems over broad areas.

Geophysical Research Letters↗

USGS2011

Mountain-block recharge, present and past, in the eastern Espanola Basin, New Mexico, USA

Noble gas recharge temperatures (NGTs) and radiocarbon ages were determined for 43 groundwater samples collected in the eastern Española Basin, New Mexico (USA), to identify mountain-block recharge in waters <10 thousand years (ka) old and to evaluate possible changes in mountain-block recharge over the past ∼35 ka. For Holocene samples from the southeastern area, NGTs are dominantly 2–4° cooler than the measured water-table temperature near the mountain front. Computed minimum mountain-block recharge fractions are dominantly 0.2–0.5, consistent with previous large mountain-block recharge estimates. NGTs do not display the distinct low during the last glacial maximum observed in other paleorecharge studies; samples recharged 15–25 ka ago are on average only 1.3° cooler than Holocene samples. Instead, samples with the coldest NGTs were recharged 25–35 ka ago. A proposed explanation is that higher precipitation rates during the last glacial maximum resulted in a lower mean recharge elevation for the basin, essentially buffering the effect of the lower mean annual air temperature and producing NGTs similar to the Holocene. In the period preceding the last glacial maximum, precipitation rates more like today’s resulted in Holocene-like mountain-block recharge fractions, producing a mean NGT ∼5° cooler than the Holocene, as expected.

New Mexico↗

USGS2011

Mapping permeability over the surface of the Earth

Permeability, the ease of fluid flow through porous rocks and soils, is a fundamental but often poorly quantified component in the analysis of regional‐scale water fluxes. Permeability is difficult to quantify because it varies over more than 13 orders of magnitude and is heterogeneous and dependent on flow direction. Indeed, at the regional scale, maps of permeability only exist for soil to depths of 1–2 m. Here we use an extensive compilation of results from hydrogeologic models to show that regional‐scale (>5 km) permeability of consolidated and unconsolidated geologic units below soil horizons (hydrolithologies) can be characterized in a statistically meaningful way. The representative permeabilities of these hydrolithologies are used to map the distribution of near‐surface (on the order of 100 m depth) permeability globally and over North America. The distribution of each hydrolithology is generally scale independent. The near‐surface mean permeability is of the order of ∼5 × 10 −14 m 2 . The results provide the first global picture of near‐surface permeability and will be of particular value for evaluating global water resources and modeling the influence of climate‐surface‐subsurface interactions on global climate change.

Geophysical Research Letters↗

USGS2011

Spring runoff water-chemistry data from the Standard Mine and Elk Creek, Gunnison County, Colorado, 2010

Water samples were collected approximately every two weeks during the spring of 2010 from the Level 1 portal of the Standard Mine and from two locations on Elk Creek. The objective of the sampling was to: (1) better define the expected range and timing of variations in pH and metal concentrations in Level 1 discharge and Elk Creek during spring runoff; and (2) further evaluate possible mechanisms controlling water quality during spring runoff. Samples were analyzed for major ions, selected trace elements, and stable isotopes of oxygen and hydrogen (oxygen-18 and deuterium). The Level 1 portal sample and one of the Elk Creek samples (EC-CELK1) were collected from the same locations as samples taken in the spring of 2007, allowing comparison between the two different years. Available meteorological and hydrologic data suggest that 2010 was an average water year and 2007 was below average. Field pH and dissolved metal concentrations in Level 1 discharge had the following ranges: pH, 2.90 to 6.23; zinc, 11.2 to 26.5 mg/L; cadmium, 0.084 to 0.158 mg/L; manganese, 3.23 to 10.2 mg/L; lead, 0.0794 to 1.71 mg/L; and copper, 0.0674 to 1.14 mg/L. These ranges were generally similar to those observed in 2007. Metal concentrations near the mouth of Elk Creek (EC-CELK1) were substantially lower than in 2007. Possible explanations include remedial efforts at the Standard Mine site implemented after 2007 and greater dilution due to higher Elk Creek flows in 2010. Temporal patterns in pH and metal concentrations in Level 1 discharge were similar to those observed in 2007, with pH, zinc, cadmium, and manganese concentrations generally decreasing, and lead and copper generally increasing during the snowmelt runoff period. Zinc and cadmium concentrations were inversely correlated with flow and thus apparently dilution-controlled. Lead and copper concentrations were inversely correlated with pH and thus apparently pH-controlled. Zinc, cadmium, and manganese concentrations near the mouth of Elk Creek did not display the pronounced increase observed during high flow in 2007, again perhaps due to remedial activities at the mine site or greater dilution in 2010. Zinc and cadmium loads near the mouth of Elk Creek were generally greater than those at the Level 1 portal for the six sample days in 2010. Whereas metal loads in September 2007 suggested that Level 1 portal discharge was the primary source of metals to the creek, metal loads computed for this study suggest that this may not have been the case in the spring of 2010. d18O values are well correlated with flow, becoming lighter (more negative) during snowmelt in both Level 1 discharge and Elk Creek. Seasonal variations in the chemistry of Level 1 discharge, along with portal flow tracking very closely with creek flow, are consistent with geochemical and environmental tracer data from 2007 that indicate short residence times (<1 year) for groundwater discharging from the Standard Mine.

Colorado↗

USGS2011

Using dissolved gases to observe the evolution of groundwater age in a mountain watershed over a period of thirteen years

Baseflows in snowmelt-dominated mountain streams are critical for sustaining ecosystems and water resources during periods of greatest demand. Future climate predictions for mountainous areas throughout much of the western U.S. include increasing temperatures, declining snowpacks, and earlier snowmelt periods. The degree to and rate at which these changes will affect baseflows in mountain streams remains unknown, largely because baseflows are groundwater-fed and the relationship between climate and groundwater recharge/discharge rates in mountain watersheds is uncertain. We use groundwater age determinations from multiple dissolved gas tracers (CFCs, SF6, and 3H/3He) to track changes in groundwater age over a period of thirteen years in the Sagehen Creek watershed, Sierra Nevada Mountains, CA. Data were collected from springs and wells in 2009 and 2010 and combined with those obtained in prior studies from 1997 to 2003. Apparent ages range from 0 to >60 years. Comparison between variations in age and variations in snow water equivalent (SWE) and mean annual air temperature reveals the degree of correlation between these climate variables and recharge rate. Further, comparison of apparent ages from individual springs obtained at different times and using different tracers helps constrain the age distribution in the sampled waters. The age data are generally more consistent with an exponential age distribution than with piston-flow. However, many samples, even those with relatively old mean ages, must have a disproportionately large very young fraction that responds directly to annual SWE variations. These findings have important implications for how future baseflows may respond to decreasing SWE.

California↗

USGS2011

Potential climate change effects on water tables and pyrite oxidation in headwater catchments in Colorado

A water, energy, and biogeochemical model (WEBMOD) was constructed to simulate hydrology and pyrite oxidation for the period October 1992 through September 1997. The hydrologic model simulates processes in Loch Vale, a 6.6-km² granitic watershed that drains the east side of the Continental Divide. Parameters describing pyrite oxidation were derived sulfate concentrations measured in pore water and stream water in Handcart Gulch, a naturally acidic watershed in the Colorado Mineral Belt. Average monthly differences in precipitation and temperature between current and future climates, as predicted by using six global circulation models and three carbondioxide emission scenarios, were input into WEBMOD to identify possible shifts in the quantity and quality of the water flowing from the watershed for the period 2005 through 2100. Initial results suggest that increased air temperatures will result in earlier snowmelt compared to current conditions. Average sulfate concentrations and acidity in streams draining hydrothermally altered terrain may decrease as water tables rise in response to greater overall precipitation and earlier snowmelt, although a net increase of sulfate load was simulated as a result of greater overall discharge. Evapotranspiration is expected to increase but not enough to offset the increase in precipitation.

Colorado↗

USGS2010

Geophysical characterization of subsurface properties relevant to the hydrology of the Standard Mine in Elk Basin, Colorado

Geophysical data were collected at the Standard Mine in Elk Basin near Crested Butte, Colorado, to help improve the U.S. Environmental Protection Agency's understanding of the hydrogeologic controls in the basin and how they affect surface and groundwater interactions with nearby mine workings. These data are discussed in the context of geologic observations at the site, the details of which are provided in a separate report. This integrated approach uses the geologic observations to help constrain subsurface information obtained from the analysis of surface geophysical measurements, which is a critical step toward using the geophysical data in a meaningful hydrogeologic framework. This approach combines the benefit of many direct but sparse field observations with spatially continuous but indirect measurements of physical properties through the use of geophysics. Surface geophysical data include: (1) electrical resistivity profiles aimed at imaging variability in subsurface structures and fluid content; (2) self-potentials, which are sensitive to mineralized zones at this site and, to a lesser extent, shallow-flow patterns; and (3) magnetic measurements, which provide information on lateral variability in near-surface geologic features, although there are few magnetic minerals in the rocks at this site. Results from the resistivity data indicate a general two-layer model in which an upper highly resistive unit, 3 to 10 meters thick, overlies a less resistive unit that is imaged to depths of 20 to 25 meters. The high resistivity of the upper unit likely is attributed to unsaturated conditions, meaning that the contact between the upper and lower units may correspond to the water table. Significant lateral heterogeneity is observed because of the presence of major features such as the Standard and Elk fault veins, as well as highly heterogeneous joint distributions. Very high resistivities (greater than 10 kiloohmmeters) are observed in locations that may correspond to more silicified, lower porosity rock. Several thin (2 to 3 meters deep and up to tens of meters wide) low-resistivity features in the very near surface coincide with observed surface-water drainage features at the site. These are limited to depths less than 3 meters and may indicate surface and very shallow groundwater flowing downhill on top of less permeable bedrock. The data do not clearly point to discrete zones of high infiltration, but these cannot be ruled out given the heterogeneous nature of joints in the shallow subsurface. Disseminated and localized electrically conductive mineralization do not appear to play a strong role in controlling the resistivity values, which generally are high throughout the site. The self-potential analysis highlights the Standard fault vein, the northwest (NW) Elk vein near the Elk portal, and several polymetallic quartz veins. These features contain sulfide minerals in the subsurface that form an electrochemical cell that produces their distinct self-potential signal. A smaller component of the self-potential signal is attributed to relatively moderate topographically driven shallow groundwater flow, which is most prevalent in the vicinity of Elk Creek and to a lesser extent in the area of surface-water drainage below the Level 5 portal. Given the anomalies associated with the electrochemical weathering near the Standard fault vein, it is not possible to completely rule out downward infiltration of surface water and shallow groundwater intersected by the fault, though this is an unlikely scenario given the available data. Magnetic data show little variation, consistent with the mostly nonmagnetic host rocks and mineralization at the site, which is verified by magnetic susceptibility measurements and X-ray diffraction mineralogy data on local rock samples. The contact between the Ohio Creek Member of the Mesaverde Formation and Wasatch Formation coincides with a change in character of the magnetic signature, though

Colorado↗

USGS2010

Characterization of Geologic Structures and Host Rock Properties Relevant to the Hydrogeology of the Standard Mine in Elk Basin, Gunnison County, Colorado

The Standard Mine Superfund Site is a source of mine drainage and associated heavy metal contamination of surface and groundwaters. The site contains Tertiary polymetallic quartz veins and fault zones that host precious and base metal sulfide mineralization common in Colorado. To assist the U.S. Environmental Protection Agency in its effort to remediate mine-related contamination, we characterized geologic structures, host rocks, and their potential hydraulic properties to better understand the sources of contaminants and the local hydrogeology. Real time kinematic and handheld global positioning systems were used to locate and map precisely the geometry of the surface traces of structures and mine-related features, such as portals. New reconnaissance geologic mapping, field and x-ray diffraction mineralogy, rock sample collection, thin-section analysis, and elemental geochemical analysis were completed to characterize hydrothermal alteration, mineralization, and subsequent leaching of metallic phases. Surface and subsurface observations, fault vein and fracture network characterization, borehole geophysical logging, and mercury injection capillary entry pressure data were used to document potential controls on the hydrologic system.

Open-File Report↗

USGS2009

Geochemistry of standard mine waters, Gunnison County, Colorado, July 2009

In many hard-rock-mining districts water flowing from abandoned mine adits is a primary source of metals to receiving streams. Understanding the generation of adit discharge is an important step in developing remediation plans. In 2006, the U.S. Environmental Protection Agency listed the Standard Mine in the Elk Creek drainage basin near Crested Butte, Colorado as a superfund site because drainage from the Standard Mine enters Elk Creek, contributing dissolved and suspended loads of zinc, cadmium, copper, and other metals to the stream. Elk Creek flows into Coal Creek, which is a source of drinking water for the town of Crested Butte. In 2006 and 2007, the U.S. Geological Survey undertook a hydrogeologic investigation of the Standard Mine and vicinity and identified areas of the underground workings for additional work. Mine drainage, underground-water samples, and selected spring water samples were collected in July 2009 for analysis of inorganic solutes as part of a follow-up study. Water analyses are reported for mine-effluent samples from Levels 1 and 5 of the Standard Mine, underground samples from Levels 2 and 3 of the Standard Mine, two spring samples, and an Elk Creek sample. Reported analyses include field measurements (pH, specific conductance, water temperature, dissolved oxygen, and redox potential), major constituents and trace elements, and oxygen and hydrogen isotopic determinations. Overall, water samples collected in 2009 at the same sites as were collected in 2006 have similar chemical compositions. Similar to 2006, water in Level 3 did not flow out the portal but was observed to flow into open workings to lower parts of the mine. Many dissolved constituent concentrations, including calcium, magnesium, sulfate, manganese, zinc, and cadmium, in Level 3 waters substantially are lower than in Level 1 effluent. Concentrations of these dissolved constituents in water samples collected from Level 2 approach or exceed concentrations of Level 1 effluent suggesting that water-rock interaction between Levels 3 and 1 can account for the elevated concentration of metals and other constituents in Level 1 portal effluent. Ore minerals (sphalerite, argentiferous galena, and chalcopyrite) are the likely sources of zinc, cadmium, lead, and copper and are present within the mine in unmined portions of the vein system, within plugged ore chutes, and in muck piles.

Colorado↗

USGS2009

Ground-Water Temperature, Noble Gas, and Carbon Isotope Data from the Espanola Basin, New Mexico

Ground-water samples were collected from 56 locations throughout the Espanola Basin and analyzed for general chemistry (major ions and trace elements), carbon isotopes (delta 13C and 14C activity) in dissolved inorganic carbon, noble gases (He, Ne, Ar, Kr, Xe, and 3He/4He ratio), and tritium. Temperature profiles were measured at six locations in the southeastern part of the basin. Temperature profiles suggest that ground water generally becomes warmer with distance from the mountains and that most ground-water flow occurs at depths <250 m below ground surface. The two dominant water types in the basin are Ca/CO3+HCO3 and Na/CO3+HCO3, followed by mixed-cation/CO3+HCO3. Waters generally evolve from Ca/CO3+HCO3 to Na/CO3+HCO3 with increasing residence time through Ca-Na cation exchange with clay minerals. Basin ground water can be divided into four hydrochemical zones based on chemical and isotopic composition: West, Southeast, Northeast, and Central Deep. Hydrochemical zone boundaries are roughly correlated with contacts between geologic units or lithosome transitions within the Tesuque Formation. Geochemical mass-transfer modeling was performed using NETPATH and 14C ages were adjusted accordingly. Isotopic input parameters were varied within reasonable limits to assess uncertainty in the adjusted 14C ages. For each sample, a preferred adjusted age was selected from multiple possible adjusted ages based primarily on the fit between measured and modeled delta 13C values. The range of possible age adjustments for most samples is about 6,000 years or less, indicating that the preferred adjusted age for most samples has a total range of uncertainty of <6,000 years. Preferred adjusted ages range from 0 to 35,400 years. First-order trends in the age distribution include older ages generally occurring farther from rivers on the east side of the basin and farther from the mountains, consistent with both mountain-front recharge and recharge on the basin floor in the form of stream-loss and arroyo recharge. Ages also increase with depth in the Southeast zone, the only area where discrete-depth samples could be collected. Recharge temperatures derived from noble gas concentrations were used in conjunction with an empirically derived local relationship between recharge temperature and elevation to constrain recharge elevation and to estimate fractions of mountain-block recharge (MBR) in sampled waters of Holocene age. Noble gas recharge temperatures indicate that ground water in the Southeast zone contains a significant fraction of MBR, commonly 20-50 percent or more. The same is apparently true for the Northeast zone, though only two data points could be used to evaluate the MBR fraction in this area. Recharge temperatures indicate that the upper 30 m of the regional aquifer on the Pajarito Plateau typically contain little or no MBR. Tritium concentrations and apparent 3H/3He ages indicate that water in the mountain block is dominantly <50 years old, and water in the basin-fill is dominantly >50 years old, consistent with the 14C ages. Terrigenic He (Heterr) concentrations in ground water are high (log Delta Heterr of 2 to 5) throughout much of the basin. High Heterr concentrations are probably caused by in situ production in the Tesuque Formation from locally high concentrations of U-bearing minerals (Northeast zone only), or by upward diffusive/advective transport of crustal- and mantle-sourced He possibly enhanced by basement piercing faults, or by both. The 3He/4He ratio of Heterr (Rterr) is commonly high (Rterr/Ra of 0.3-2.0, where Ra is the 3He/4He ratio in air) suggesting that Espanola Basin ground water commonly contains mantle-sourced He. The 3He/4He ratio of Heterr is generally the highest in the western and southern parts of the basin, closest to the western border fault system and the Quaternary to Miocene volcanics of the Jemez Mountains and Cerros del Rio.

Scientific Investigations Report↗

USGS2009

U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300– 1,200 ft deep), 4 bedrock (100–170 ft deep) and 5 shallow (10–30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of alpine watersheds. Additionally, despite the complexity of the fracture controlled aquifer system, it appears that it can be represented with a relatively simple conceptual model and can be treated as an equivalent porous medium at the watershed scale. Interpretation of existing data, collection of new monitoring data, and efforts to link geochemical and hydrologic processes through modeling are ongoing at the site.

Colorado↗

USGS2008

Regional groundwater flow in mountainous terrain: Three‐dimensional simulations of topographic and hydrogeologic controls

This study uses numerical simulations to define the salient controls on regional groundwater flow in 3‐D mountainous terrain by systematically varying topographic and hydrogeologic variables. Topography for idealized multiple‐basin mountainous terrain is derived from geomatic data and literature values. Water table elevation, controlled by the ratio of recharge to hydraulic conductivity, largely controls the distribution of recharged water into local, regional, and perpendicular flow systems, perpendicular flow being perpendicular to the regional topographic gradient. Both the relative (%) and absolute (m 3 /d) values of regional flow and perpendicular flow are examined. The relationship between regional flow and water table elevation is highly nonlinear. With lower water table elevations, relative and absolute regional flow dramatically increase and decrease, respectively, as the water table is lowered further. However, for higher water table elevations above the top of the headwater stream, changes in water table elevation have little effect on regional flow. Local flow predominates in high water table configurations, with regional and perpendicular flow <15% and <10%, respectively, of total recharge in the models tested. Both the relative and the maximum absolute regional flow are directly controlled by the degree of incision of the mountain drainage network; the elevation of mountain ridges is considerably less important. The percentage of the headwater stream with perennial streamflow is a potentially powerful indicator of regional flow in all water table configurations and may be a good indicator of the susceptibility of mountain groundwater systems to increased aridity.

Water Resources Research↗

USGS2008

Ground- and surface-water chemistry of Handcart Gulch, Park County, Colorado, 2003-2006

As part of a multidisciplinary project to determine the processes that control ground-water chemistry and flow in mineralized alpine environments, ground- and surface-water samples from Handcart Gulch, Colorado were collected for analysis of inorganic solutes and water and dissolved sulfate stable isotopes in selected samples. The primary aim of this study was to document variations in ground-water chemistry in Handcart Gulch and to identify changes in water chemistry along the receiving stream of Handcart Gulch. Water analyses are reported for ground-water samples collected from 12 wells in Handcart Gulch, Colorado. Samples were collected between August 2003 and October 2005. Water analyses for surface-water samples are reported for 50 samples collected from Handcart Gulch and its inflows during a low-flow tracer injection on August 6, 2003. In addition, water analyses are reported for three other Handcart Gulch stream samples collected in September 2005 and March 2006. Reported analyses include field parameters (pH, specific conductance, temperature, dissolved oxygen, and Eh), major and trace constituents, oxygen and hydrogen isotopic composition of water and oxygen and sulfur isotopic composition of dissolved sulfate. Ground-water samples from this study are Ca-SO4 type and range in pH from 2.5 to 6.8. Most of the samples (75 percent) have pH values between 3.3 and 4.3. Surface water samples are also Ca-SO4 type and have a narrower range in pH (2.7?4.0). Ground- and surface-water samples vary from relatively dilute (specific conductance of 68 ?S/cm) to concentrated (specific conductance of 2,000 ?S/cm).

Colorado↗