Geology topics

Allen K. Andersen

Publications and source records attributed to Allen K. Andersen.

11 recordsLinked to original sources

USGS2026

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois↗

USGS2026

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California↗

USGS2025

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana↗

USGS2025

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming↗

USGS2025

The role of alkali bicarbonate-sulfate brines in the genesis of carbonatite REE resources at the Bear Lodge Alkaline Complex, Wyoming

Rare-earth element (REE) resources in the Bear Lodge Alkaline Complex, Wyoming, are hosted in a variably leached carbonatite dike swarm spatially related to bodies of diatreme breccia. This study examines fluid inclusions in carbonatite dikes, peripheral fluorite breccias, and smoky quartz veins to reconstruct the physiochemical conditions of REE mineralization. Results reveal a multi-stage evolution of carbonatitic fluids: 1) high-temperature (330–432°C), CO 2 -rich magmatic fluids, 2) REE-enriched alkali bicarbonate-sulfate brines, and 3) low-temperature meteoric (117–182°C) or diluted magmatic fluids. Multiphase inclusions (stage-2) contain burbankite, nahcolite, and alkali sulfate daughter crystals, linking the brines to early burbankite [(Na,Ca) 3 (Sr,Ba,REE) 3 (CO 3 ) 5 ] mineralization in carbonatite. REE mobility has been linked to the stability of aqueous complexes with ligands such as Cl-, SO 4 2- , and HCO 3 - . However, light REEs were not initially transported significant distances, rather they crystallized as burbankite from brines or brine-melts associated with the carbonatite magma. Crystallization of burbankite removed Na from the system, leaving residual fluids with high K/Na ratios and promoting potassic fenitization throughout the complex. Fractionation of light and heavy REEs and involvement of low temperature (<300°C), high K/Na bicarbonate brines may have facilitated transport and formation of peripheral occurrences that are more enriched in heavy REEs at Bear Lodge.

Wyoming↗

USGS2023

Tungsten resources of the northern Rocky Mountains, Montana and Idaho— A synthesis and quantitative assessment of skarn-hosted resources

Mineral resource assessments performed by the U.S. Geological Survey provide a synthesis of available information about the location of known and suspected mineral deposits. This study focuses on skarn-hosted tungsten resources in the northern Rocky Mountain region of east-central Idaho and western Montana which have seen moderate tungsten trioxide production in the past from a variety of mineralization styles including skarn, vein and replacement, and wolframite-quartz veins. The area’s geology is dominated by large Cretaceous and Tertiary plutons that are emplaced into a belt of Mesoproterozoic to Permian sedimentary rock and affected by tectonism related to the Sevier and later Laramide orogenies. Known tungsten skarn mineral sites are associated with contacts between Cretaceous plutons and calcareous and argillaceous sedimentary or metasedimentary rocks, including two skarn deposits in Montana (Calvert and Browns Lake) that are consistent with an updated grade and tonnage model. This study (1) delineates permissive tracts where undiscovered tungsten skarn deposits may occur within 1 kilometer of the surface; (2) presents a tungsten mineral site dataset from a variety of public sources; (3) evaluates currently available geochemical, geophysical, and radiometric age data in support of tract delineation; (4) provides probabilistic estimates of the amount of tungsten and tungsten-mineralized rock that could be contained in undiscovered deposits within one major tract; (5) estimates the value of total undiscovered deposits using economic filter analysis; and (6) provides a synthesis of metallogenic controls on regional tungsten skarn and granitoid-related mineral deposits. Two permissive tracts were delineated: the Great Falls tectonic zone (GFTZ)-Cretaceous tract, for which a quantitative assessment was performed, and the Bitterroot tract, which was assessed in a qualitative manner. The quantitative three-part assessment, conducted in August 2019, indicates that undiscovered tungsten resources might exist in skarn-type deposits within the study area. Using a negative binomial function, a mean of 4 undiscovered deposits was calculated from panel estimates. Simulation results that combine an updated grade and tonnage model with estimates of undiscovered deposits include the amounts of ore and contained tungsten trioxide at different levels of uncertainty. A mean of 250,000 metric tons and median of 200,000 metric tons contained tungsten trioxide was calculated for the undiscovered deposits within the GFTZ-Cretaceous tract. The value of undiscovered deposits was estimated using a new economic filter that considers factors such as mine type, deposit depth, deposit geometry, metallurgical recovery rate, cutoff grade, and tract area. A review of the regional Archean to Paleogene geology suggests that ore metal (copper, molybdenum, and tungsten) variations in intrusion-related deposits of Montana and Idaho may be controlled by a number of factors including the age and composition of underlying basement terranes, depth of emplacement, pluton chemistry and degree of fractionation, redox conditions, and aqueous fluid-melt partition coefficients.

Idaho, Montana↗

USGS2023

Stable isotope constraints on the source of ore fluids for the Hicks Dome REE+Y-HFSE-fluorspar deposit

Hicks Dome is comprised of coarse crystalline Mississippi Valley Type deposits at shallow levels and an enigmatic, fine-grained fluorite, rare earth elements, Y, high field strength elements, Be, and Ba rich deposit at deeper levels. Phyllosilicates from a lamprophyre dike and a breccia from two Hicks Dome drill cores were sampled to resolve the fluid history of the entire deposit using light stable isotopes. Silicate fluorination coupled with isotope ratio mass spectrometry give δ18O values from +6.9 to +16.0 ‰ (Vienna Standard Mean Ocean Water). Temperature conversion elemental analyzer and gas chromatography-isotope ratio mass spectrometry give δ2H values from -54 to -33 ‰ (Vienna Standard Mean Ocean Water). Muscovite from metasomatized dikes and breccias are relatively enriched in 18O compared to phlogopite from lamprophyre. Calculated isotopic compositions of the fluids from which the phyllosilicates precipitated indicate that phlogopite retained a magmatic composition while muscovite likely formed from magmatic fluids that exchanged with carbonate host rocks or from magmatic fluids that mixed with basinal brines. Enrichment of deuterium in fluids calculated from muscovite suggest that fluids were derived from hypothesized carbonatites or were acidic. These data demonstrate that the Hicks Dome critical mineral resource is magmatic hydrothermal in origin.

Illinois↗

USGS2022

Focus areas for data acquisition for potential domestic resources of 13 critical minerals in the conterminous United States and Puerto Rico — Antimony, barite, beryllium, chromium, fluorspar, hafnium, helium, magnesium, manganese, potash, uranium, vanadium, and zirconium

The Earth Mapping Resources Initiative (Earth MRI) is conducted in phases to identify areas for acquiring new geologic framework data to identify potential domestic resources of the 35 mineral materials designated as critical minerals for the United States. This report describes the data sources and summary results for 13 critical minerals evaluated in the conterminous United States and Puerto Rico during phase 3 of the study (antimony, barite, beryllium, chromium, fluorspar, hafnium, helium, magnesium, manganese, potash, uranium, vanadium, and zirconium). Phases 1 and 2 of the Earth MRI addressed aluminum, cobalt, graphite, lithium, niobium, platinum-group elements (PGEs), rare earth elements (REEs), tantalum, tin, titanium, and tungsten. Critical minerals in Alaska are covered in a separate report. No focus areas for phase 3 critical minerals are delineated for Hawaii. The geologic, geochemical, topographic, and geophysical mapping provided by the Earth MRI documents geologic features that reflect the extent of individual mineral systems and provides information about critical mineral deposits that may not have been previously considered. The mineral-systems approach links critical mineral commodities to deposit types that represent the manifestations of large mineral systems. Each of the 13 critical mineral commodities for phase 3 of the Earth MRI is discussed in terms of its importance to the Nation’s economy, modes of occurrence, mineral systems, and deposit types, and is accompanied by maps and tables listing examples of focus areas in the conterminous United States and Puerto Rico. Examples of important mineral systems for this group of 13 critical minerals include basin brine path systems for barite and fluorspar, Carlin-type systems and Coeur d’Alene systems for antimony, chemical weathering and volcanogenic seafloor systems for manganese, Climax-type systems for beryllium, mafic magmatic systems for chromium, marine evaporite systems for potash and magnesium, meteoric recharge systems for uranium, petroleum systems for helium, and placer systems for zirconium and hafnium.

Open-File Report↗

USGS2020

Precious and base metal mineralization within the lower stratigraphy of the Stillwater Complex: New targets defined and old targets revisited

Group Ten Metals is exploring for base and precious metals within the Stillwater Complex, a 2.7 Ga layered mafic/ultramafic intrusion, host to the world-class Sibanye platinum group element (PGE) mines. Group Ten controls approximately 25 kilometers of strike length of prospective mafic and ultramafic rocks in the western portion of the Complex. The property includes multiple target types and individual prospects. Stillwater Complex magmatic stratigraphy is divided into three major series based on the proportions of cumulus minerals—Basal, Ultramafic and Banded. Group Ten explores primarily within the lower third of the intrusion, from the Basal Series at the footwall contact, upwards into the Ultramafic Series which is divided into a lower Peridotite Zone and an upper Bronzitite Zone. Rocks of the Peridotite Zone are repetitive, laterally continuous and layered sequences of olivine, chromite and pyroxene cumulates. This model was developed in the eastern portion of the Complex. Mapping in the western portion of the Complex indicates that the Peridotite Zone is thinner than to the east and with cyclic units not as regularly developed. Group Ten has reviewed data from over 50 years of historical exploration in light of different commodity focus, land positions, analytical menus, and petrogenetic models to define a series of exploration targets. A six hole, 1,600 meter diamond drilling program targeting the Iron Mountain sector was completed in 2019; results are discussed in more detail below. At Iron Mountain the primary targets are Ni-Cu-PGE magmatic sulfides located within the Basal Series and lower Peridotite Zone, near the basal contact of the Complex. Important objectives included establishing the PGE tenor of sulfide mineralization drilled by AMAX in the 1970’s and penetrating basement rock rafts known to conceal mineralized (but not previously analyzed) ultramafic rocks beneath. Drilling also tested the PGE-enriched A-B chromitite package which rests stratigraphically above the previously tested zones. At Chrome Mountain, magmatic layering was disturbed or destroyed over large areas along a WNW axis that may be an artifact of early magma chamber deformation or result from much later, Laramide tectonism. Correlation of marker units, for example chromitite seams, are problematic in the disturbed area; these rocks are termed the Hybrid Unit. In addition, normal igneous stratigraphy appears to be intruded by discordant dunite masses, pyroxenite pegmatoids and magmatic breccias. This unusual assemblage of rock types is accompanied by significant and previously underappreciated PGE mineralization related to chromite schlieren and minor but persistent base metal sulfides.

Conference Paper↗

USGS2019

C–O stable isotope geochemistry and 40Ar/39Ar geochronology of the Bear Lodge carbonatite stockwork, Wyoming, USA

The carbonatite dike swarm and vein stockwork at the center of the Paleogene Bear Lodge alkaline complex (BLAC), Wyoming, USA, is host to diverse REE mineral assemblages that are largely a result of subsolidus modification and REE redistribution. Pseudomorphic replacement of primary burbankite by an assemblage of ancylite, strontianite, and barite is the result of interaction with late-stage hydrothermal fluids that added Sr, Ba, S, F, and REE, analogous to the replacement processes described for some carbonatite complexes of Russia's Kola Peninsula. Carbon and oxygen stable isotope ratios indicate that the primary carbonatite mineralogy experienced degassing/pneumatolysis and alteration by fluids of variable temperature, CO 2 /H 2 O ratios, and/or meteoric water content. Isotopic differences of matrix calcite between Group 1 carbonatites (avg. δ 13 C = −7.3‰; δ 18 O = 9.1‰) and Group 2 carbonatites (avg. δ 13 C = −9.9‰; δ 18 O = 10.2‰) are consistent with loss of CO 2 during degassing. The open-system alteration of burbankite caused a pronounced positive δ 18 O-shift in bulk ancylite pseudomorphs (δ 18 O: 14.3–25.7‰) relative to matrix calcite (δ 18 O: 8.7–11.2‰). Oxygen isotope compositions of biotite (δ 18 O: 4.5–5.9‰) and K-feldspar (δ 18 O: 7.3–7.9‰) in unoxidized carbonatite are typical of primary magmatic silicates and suggest that fluids responsible for the burbankite-to-ancylite conversion remained predominantly magmatic (carbohydrothermal). Concomitant increases toward the surface in 13 C and 18 O, oxidation, matrix carbonate dissolution, and the replacement of REE carbonates (ancylite, carbocernaite, and burbankite) by Ca-REE fluorocarbonates (bastnäsite, parisite, synchysite) suggest interaction with late-stage, low temperature (<250 °C) fluids characterized by lower CO 2 /H 2 O ratios, and an increasing meteoric water component. The first 40 Ar/ 39 Ar ages from carbonatite-hosted biotite and K-feldspar at the BLAC are between 51.45 ± 0.08 and 51.89 ± 0.14 Ma. Although carbonatite is commonly observed as the final intrusive phase in alkaline igneous complexes, relative-age relationships and previously published geochronology for Bear Lodge rocks indicate that alkaline silicate magmatism both preceded and followed carbonatite emplacement.

Wyoming↗

USGS2009

A preliminary study of older hot spring alteration in Sevenmile Hole, Grand Canyon of the Yellowstone River, Yellowstone Caldera, Wyoming

Erosion in the Grand Canyon of the Yellowstone River, Yellowstone Caldera (640 ka), Wyoming, has exposed a cross section of older hydrothermal alteration in the canyon walls. The altered outcrops of the post-collapse tuff of Sulphur Creek (480 ka) extend from the canyon rim to more than 300 m beneath it. The hydrothermal minerals are zoned, with an advanced argillic alteration consisting of an association of quartz (opal) + kaolinite ± alunite ± dickite, and an argillic or potassic alteration association with quartz + illite ± adularia. Disseminated fine-grained pyrite or marcasite is ubiquitous in both alteration types. These alteration associations are characteristic products of shallow volcanic epithermal environments. The contact between the two alteration types is about 100 m beneath the rim. By analogy to other active geothermal systems including active hydrothermal springs in the Yellowstone Caldera, the transition from kaolinite to illite occurred at temperatures in the range 150 to 170 °C. An 40 Ar/ 39 Ar age on alunite of 154,000 ± 16,000 years suggests that hydrothermal activity has been ongoing since at least that time. A northwest-trending linear array of extinct and active hot spring centers in the Sevenmile Hole area implies a deeper structural control for the upflowing hydrothermal fluids. We interpret this deeper structure to be the Yellowstone Caldera ring fault that is covered by the younger tuff of Sulphur Creek. The Sevenmile Hole altered area lies at the eastern end of a band of hydrothermal centers that may mark the buried extension of the Yellowstone Caldera ring fault across the northern part of the Caldera.

Wyoming↗