Geology topics

Albert H. Hofstra

Publications and source records attributed to Albert H. Hofstra.

At least 37 records · Page 2Linked to original sources

USGS2021

Calcite U-Pb dating unravels the age and hydrothermal history of the giant Shuiyindong Carlin-type gold deposit in the Golden Triangle, south China

The ages of Carlin-type gold deposits in the Golden Triangle of South China have long been questioned due to the general lack of minerals unequivocally linked to gold deposition that can be precisely dated using conventional radiogenic isotope techniques. Recent advances in U-Pb methods show that calcite can be used to constrain the ages of hydrothermal processes, but few studies have been applied to ore deposits. Herein, we show that this approach can be used to constrain the timing of hydrothermal activity that generated and overprinted the giant Shuiyindong Carlin-type gold deposit in the Golden Triangle. Three stages of calcite (Cal-1, Cal-2, and Cal-3) have been recognized in this deposit based on crosscutting relationships, cathodoluminescence colors, and chemical (U, Pb, and rare earth element [REE]) and isotope (C, O, Sr) compositions. Cal-1 is texturally associated with ore-stage jasperoid and disseminated Au-bearing arsenian pyrite in hydrothermally altered carbonate rocks, which suggests it is synmineralization. Cal-2 fills open spaces and has a distinct orange cathodoluminescence, suggesting that it precipitated during a second fluid pulse. Cal-1 and Cal-2 have similar carbonate rock-buffered chemical and isotopic compositions. Cal-3 occurs in veins that often contain realgar and/or orpiment and are chemically (low U, Pb, and REE) and isotopically (higher δ 13 C, lower δ 18 O and Sr i values) distinct from Cal-1 and Cal-2, suggesting that it formed from a third fluid. U-Pb isotope analyses, by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) for U-rich Cal-1 and Cal-2 and by LA-multicollector (MC)-ICP-MS for U-poor Cal-3, yield well-defined age constraints of 204.3 to 202.6, 191.9, and 139.3 to 137.1 Ma for Cal-1, Cal-2, and Cal-3, respectively. These new ages suggest that the Shuiyindong gold deposit formed in the late Triassic and was overprinted by hydrothermal events in the early Jurassic and early Cretaceous. Given the association of Cal-3 with orpiment and realgar, and previous geochronologic studies of several other major gold deposits in the Golden Triangle, we infer that the latest stage of calcite may be associated with an early Cretaceous regional gold metallogenic event. Combined with existing isotopic ages in the region, these new ages lead us to propose that Carlin-type gold deposits in the Golden Triangle formed during two metallogenic episodes in extensional settings, associated with the late Triassic Indochina orogeny and early Cretaceous paleo-Pacific plate subduction. This study shows that the calcite U-Pb method can be used to constrain the timing of Carlin-type gold deposits and successive hydrothermal events.

Golden Triangle, south China↗

USGS2020

Focus areas for data acquisition for potential domestic resources of 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico—Aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, rare earth elements, tantalum, tin, titanium, and tungsten

In response to a need for information on potential domestic sources of critical minerals, the Earth Mapping Resources Initiative (Earth MRI) was established to identify and prioritize areas for acquisition of new geologic mapping, geophysical data, and elevation data to improve our knowledge of the geologic framework of the United States. Phase 1 of Earth MRI concentrated on those geologic terranes favorable for hosting the rare earth elements (REEs). Phase 2 continued to address the REEs and also identified focus areas for potential domestic sources of 10 more of the 35 critical minerals on the U.S. critical minerals list (aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, tantalum, tin, titanium, tungsten). This report describes the methodology, data sources, and summary results for mineral systems that host these 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico; Alaska is covered in a separate report. The mineral systems framework adopted for this study links critical mineral commodities to families of genetically related mineral deposit types. The mineral systems approach is an efficient approach, providing a simultaneous evaluation of geologic terranes through aggregation of genetically related mineral deposit types that are much larger than individual ore deposits. Geologic, geochemical, topographic, and geophysical mapping provided by Earth MRI will document geologic features that reflect the extent of individual mineral systems and provide information about critical mineral deposits that may not have been recognized previously. Each critical mineral commodity is discussed in terms of importance to the Nation’s economy, modes of occurrence, mineral systems, and deposit types along with maps and tables listing examples of focus areas for each critical mineral. Important mineral systems for these critical minerals include chemical weathering systems for aluminum (bauxite); placer systems for titanium and REEs; metamorphic systems for graphite; mafic magmatic systems for platinum-group elements and cobalt; lacustrine evaporite and porphyry tin systems for lithium; and copper-molybdenum-gold (Cu-Mo-Au) systems for tungsten. REEs occur in many different mineral systems. Focus areas were developed by scientists from the U.S. Geological Survey in collaboration with scientists from State geological surveys and other institutions. This first national-scale compilation of focus areas represents an initial step in addressing the Nation’s critical mineral needs by screening areas for acquisition of new data to provide the geologic framework necessary for identifying domestic sources of critical minerals.

Open-File Report↗

USGS2020

Systems-deposits-commodities-critical minerals table for the earth mapping resources initiative

To define and prioritize focus areas across the United States with resource potential for 35 critical minerals in a few years’ time, the U.S Geological Survey Earth Mapping Resources Initiative (Earth MRI) required an efficient approach to streamline workflow. A mineral systems approach based on current understanding of how ore deposits that contain critical minerals form and relate to broader geologic frameworks and the tectonic history of the Earth was used to satisfy this Earth MRI need. This report describes the rationale for, and structure of, a table developed for Earth MRI that relates critical minerals and principal commodities to the deposit types and mineral systems in which they are concentrated. The hierarchical relationship between systems, deposits, commodities, and critical minerals makes it possible to define and prioritize each system-based focus area once for all of the critical minerals that it may contain. This approach is advantageous because mineral systems are much larger than individual ore deposits and they generally have geologic features that can be “imaged” by the topographic, geologic, geochemical, and geophysical mapping techniques deployed by Earth MRI.

Open-File Report↗

USGS2020

Noble gases fingerprint the source and evolution of ore-forming fluids of Carlin-type gold deposits in the Golden Triangle, south China

Precise constraints on the source and evolution of ore-forming fluids of Carlin-type gold deposits in the Golden Triangle (south China) are of critical importance for a better understanding of the ore genesis and a refined genetic model for gold mineralization. However, constraints on the source of ore fluid components have long been a challenge due to the very fine grained nature of the ore and gangue minerals in the deposits. Here we present He, Ne, and Ar isotope data of fluid inclusion extracts from a variety of ore and gangue minerals (arsenian pyrite, realgar, quartz, calcite, and fluorite) representing the main and late ore stages of three well-characterized major gold deposits (Shuiyindong, Nibao, and Yata) to provide significant new insights into the source and evolution of ore-forming fluids of this important gold province. Measured He isotopes have R/R A ratios ranging from 0.01 to 0.4 that suggest a maximum of 5% mantle helium with an R/R A of 8. The Ne and Ar isotope compositions are broadly comparable to air-saturated water, with a few analyses indicating the presence of an external fluid containing nucleogenic 38 Ar and radiogenic 40 Ar. Plotted on the 20 Ne/ 4 He vs. helium R/R A and 3 He/ 20 Ne vs. 4 He/ 20 Ne diagrams, the results define two distinct arrays that emanate from a common sedimentary pore fluid or deeply sourced metamorphic fluid end-member containing crustal He. The main ore-stage fluids are interpreted as a mixture of magmatic fluid containing mantle He and sedimentary pore fluid or deeply sourced metamorphic fluid with predominantly crustal He, whereas the late ore-stage fluids are a mixture of sedimentary pore fluid or deeply sourced metamorphic fluid bearing crustal He and shallow meteoric groundwater containing atmospheric He. Results presented here, when combined with independent evidence, support a magmatic origin for the ore-forming fluids. The ascending magmatic fluid mixed with sedimentary pore fluid or deeply sourced metamorphic fluid in the ore stage and subsequently mixed with the meteoric groundwater in the late ore stage, eventually producing the Carlin-type gold deposits in the Golden Triangle.

Golden Triangle, south China↗

USGS2019

Tourmaline boron and strontium isotope systematics reveal magmatic fluid pulses and external fluid influx in a giant iron oxide-apatite (IOA) deposit

Tourmaline is a common boron-bearing mineral in hydrothermal system and has been widely used as a mineral probe to reconstruct geological processes because of its broad range in composition and resistance to metasomatic alteration. The origin of Kiruna-type iron oxide-apatite (IOA) deposits, commonly linked to andesitic subvolcanic or volcanic rocks, is highly controversial. Constraints on the evolution of these mineralizing systems are needed to advance understanding of the ore-forming process. In this study, we apply in situ elemental and combined B-Sr isotopic analyses of tourmaline to elucidate the nature and evolution of the subsurface hydrothermal system associated with IOA mineralization in the giant Taocun deposit, eastern China. Taocun is hosted at the top of a diorite intrusion and exhibits three stages of hydrothermal alteration that contain tourmaline: pre-ore Na alteration (Tur I), syn-ore magnetite formation and associated Ca-Fe alteration (Tur II), and post-ore Ca-Mg alteration with sulfide veins (Tur III). Compositional data for each stage of tourmaline plot along the “oxy-dravite”–povondraite join, which is indicative of precipitation from relatively oxidizing fluids. Ranges of Sr-isotopic compositions in Tur I (0.7065–0.7078) and Tur II (0.7068–0.7076) are identical to those of the igneous host rocks, indicating precipitation from magmatic-hydrothermal fluids. The range of B-isotopic compositions in Tur I (δ 11 B values of −6.3‰ to −1.2‰) is also consistent with a magmatic source. Higher δ 11 B values (−2.4‰ to 5.4‰) obtained from Tur II are mainly ascribed to Rayleigh fractionation in the magmatic-hydrothermal system as tourmaline precipitated. Post-ore Tur III has a wide range of mostly lower B-isotopic compositions (−8.5‰ to 0.8‰) that record another pulse of magmatic fluid input. This interpretation is supported by the enrichment of Na, Li, Be, W, Sn, V, and Ti in Tur III, relative to Tur I and II. However, the higher Sr-isotope composition (0.7076–0.7086) of Tur III and available O-isotope composition (−7‰ to 3.5‰) of fluids of this stage record the infiltration of meteoric ground water from adjacent sedimentary country rocks. The results suggest that the Taocun IOA deposit formed in a magmatic-hydrothermal system characterized by two (or more) pulses of magmatic fluid discharge from subvolcanic diorite intrusions, followed by the influx of external ground water as the system waned. This study highlights the utility of tourmaline as a robust geochemical and isotopic monitor of ore-forming processes in such systems.

Ningwu IOA district↗

USGS2019

Crustal architecture beneath the southern Midcontinent (USA) and controls on Mesoproterozoic iron-oxide mineralization from 3D geophysical models

Several types of critical mineral-bearing ore deposits in the southern Midcontinent region of the U.S. are hosted in Mesoproterozoic igneous rocks largely concealed beneath Paleozoic cover. Discerning the architecture of igneous intrusions and volcanic centers in the crust is fundamental to understanding the geologic evolution of this vast region and its mineral resources. To advance the understanding of the geologic framework beneath the Southeast Missouri Iron Metallogenic Province, we invert continental-scale magnetic and gravity anomaly data to three-dimensional (3D) physical property models. The regional models image altered and mineralized igneous rocks near the Precambrian basement surface and underlying intrusive complexes that extend down to the Moho. At shallow crustal levels, our models confirm that iron oxide-apatite ± rare earth element (IOA±REE) deposits and iron oxide-copper-gold ± cobalt (IOCG) deposits occur within or near the edges of large low density/low susceptibility early Mesoproterozoic (ca 1.4 Ga) silicic calderas and (ca 1.3 Ga) granitic plutons. Previous isotopic and geochemical studies conclude that the iron deposits and their volcanic host rocks originated from mantle-derived and crustal melts that erupted during regional extension. Extension was associated with thermal event(s) that produced the large-scale silicic magmatism related to the ca 1.45 Ga Eastern Granite Rhyolite Province (EGRP) and the 1.35 Ga Southern Granite Rhyolite Province (SGRP). We postulate that early in the evolution of the EGRP, several trans-crustal magmatic plumbing systems developed that are evident in the 3D models. The Southeast Missouri Metallogenic Province is underlain by one such magmatic system that is expressed as a northwest-trending ~ 50 km-wide by 200 km-long elongate track of high susceptibility at deep crustal levels. The high susceptibility corridor splays upward through the crust to the Precambrian surface where the iron deposits are the epigenetic manifestation of this magmatic event. Our findings confirm that the iron deposits, with no distinct connection at the surface, are connected to one large magmatic system at depth. We propose that other similar susceptibility tracks, which are present along the top of the mantle, mark additional feeder zones that allowed magma to ascend to the main eruptive centers that produced the Granite Rhyolite Provinces. The early Mesoproterozoic extensional tectonic framework established crustal-scale pathways that controlled the distribution of subsequent magmatic activity, including the ca 1.4 Ga calderas and underlying intrusions, ca 1.3 Ga silicic plutons and Phanerozoic alkaline intrusions. If these interpretations are correct, our study has identified large areas that are prospective for critical mineral-bearing ore deposits and, importantly, suggests that the Mesoproterozoic architecture may have influenced subsequent magmatism and hydrothermal activity in the southern Midcontinent of the U.S.

Ore Geology Reviews↗

USGS2019

Geochemistry of hematite veins in IOA-IOCG deposits of SE Missouri, USA: Relation to felsic magmatism and caldera lakes

The paragenesis, textures, and chemical compositions of secondary hematite in regional potassic altered rhyolites, four IOA deposits, the sedimentary iron deposit at Pilot Knob and the Boss IOCG deposit in SE Missouri were determined and compared to primary magnetite from the IOA and IOCG deposits. Magnetite is composed of elements characteristics of mafic to intermediate intrusions whereas hematite is enriched in elements characteristic of felsic igneous rocks. These results suggest that magnetite formed from fluids discharged from mafic to intermediate composition intrusions. Hematite precipitated from fluids discharged from felsic intrusions or fluids that evolved in caldera lakes. Hematite in the sedimentary iron deposit at Pilot Knob formed in an evaporative caldera lake with fluid inputs from felsic intrusions.

Missouri↗

USGS2019

Absence of magnetite microlites, geochemistry of magnetite veins and replacements in IOA deposits, SE Missouri, USA: Relations to intermediate intrusions

The paragenesis, textures, and chemical compositions of magnetite in two mafic to intermediate intrusions and four IOA deposits in SE Missouri were studied to discriminate between igneous and hydrothermal sources. In this study, we found that replacement magnetite with mineral inclusion-rich cores yields erroneously high Ti, Al, Si, Mg, and Mn contents as determined by EMP and LA-ICP-MS due to rutile and silicate inclusions. Thus, identification of high-Ti microlites on the basis of inclusion-rich cores with high Ti contents is an analytical artefact. Since the high-Ti magnetite microlite flotation model is critically dependent on this type of analysis, it may be invalid. The presence of coarse-grained high-Ti vein magnetite with ilmenite lamellae enveloped by replacement magnetite with inclusion-rich cores in ore zones suggests that the veins were high-temperature conduits for low-temperature replacement ores. The trace element compositions of vein and replacement magnetite suggest that iron was sourced from mafic to intermediate intrusions. These results support a magmatic-hydrothermal origin for IOA systems in SE Missouri.

Missouri↗

USGS2017

The Valmy thrust sheet: A regional structure formed during the protracted assembly of the Roberts Mountains allochthon, Nevada, USA

A synthesis of field, biostratigraphic, detrital zircon geochronologic, and remote sensing data across north-central Nevada, United States, defines a thick, regionally extensive sheet of Middle–Upper Ordovician Valmy Formation quartzite that structurally overlies deformed early Paleozoic units of the Roberts Mountains allochthon. Late Paleozoic regional unconformities that record tectonic disruptions have been recognized in the foreland of central and eastern Nevada and locally within the Roberts Mountains allochthon; these identify multiple, regional tectonic events between the Devonian–Mississippian initiation of the Antler orogeny and the Permian–Triassic Sonoma orogeny. However, few studies have documented the regional kinematic history of the Robert Mountains allochthon sensu stricto. In the Independence Mountains of northern Nevada, emplacement of the Roberts Mountains allochthon is restricted to the Mississippian. In the Tuscarora Mountains, the range west and southwest of the Independence Mountains, several deformation events have been identified, and emplacement of the thrust sheet containing the Valmy Formation is restricted to the Late Pennsylvanian–Early Permian. These structural and temporal relations, reflected in the Antler foreland basin adjacent to the Roberts Mountains allochthon and overlap sequences, suggest that the Roberts Mountains allochthon is a composite stratigraphic terrane assembled along the Cordilleran margin during two or more late Paleozoic contractional events. Valmy Formation deposits likely represent the development of coalescing submarine fans below or within bypass channels in a deep slope or rise environment. Petrographic characteristics, biostratigraphy, and detrital zircon U-Pb age populations of the Valmy Formation link it to coeval slope and rise turbidites of the Vinini Formation and shelfal Eureka Quartzite; Valmy Formation detrital zircon age populations are dissimilar to the rift-to-drift facies of the Neoproterozoic–Cambrian Prospect Mountain Quartzite. Throughout north-central Nevada, the Valmy Formation is in fault contact with units of the Roberts Mountains allochthon, including the Devonian–Mississippian Slaven Chert, Silurian–Devonian Elder Sandstone, and Cambrian(?)–Ordovician Vinini Formation, which were deformed prior to, or during, emplacement of the thrust sheet containing Valmy Formation quartzite. Our mapping and data synthesis, guided by regional quartz maps based on remote sensing (Advanced Spaceborne Thermal Emission and Reflection Radiometer [ASTER]) data, delineate similar structural relationships discontinuously for >200 km along strike of the Roberts Mountains allochthon. Exploration for concealed gold deposits within reach of drilling requires knowledge of the relative thicknesses of the Roberts Mountains allochthon and the Valmy Formation. Overall thicknesses of deformed Roberts Mountains allochthon units between the Valmy Formation and underlying carbonate rocks, which host large, world-class Carlin-type gold deposits, vary by hundreds of meters, but are generally less than 700 m in three of the areas studied here. Recognition of windows through and klippen of the Roberts Mountains allochthon is essential for identification of areas where deposits may be at or near the surface. Correspondingly, most ongoing exploration for Carlin-type gold deposits subjacent to the Roberts Mountains allochthon targets concealed deposits. The model proposed in this study is applicable to determining depth to rocks prospective for undiscovered deposits.

Nevada↗

USGS2017

Isotopic data for Late Cretaceous intrusions and associated altered and mineralized rocks in the Big Belt Mountains, Montana

The quartz monzodiorite of Mount Edith and the concentrically zoned intrusive suite of Boulder Baldy constitute the principal Late Cretaceous igneous intrusions hosted by Mesoproterozoic sedimentary rocks of the Newland Formation in the Big Belt Mountains, Montana. These calc-alkaline plutonic masses are manifestations of subduction-related magmatism that prevailed along the western edge of North America during the Cretaceous. Radiogenic isotope data for neodymium, strontium, and lead indicate that the petrogenesis of the associated magmas involved a combination of (1) sources that were compositionally heterogeneous at the scale of the geographically restricted intrusive rocks in the Big Belt Mountains and (2) variable contamination by crustal assimilants also having diverse isotopic compositions. Altered and mineralized rocks temporally, spatially, and genetically related to these intrusions manifest at least two isotopically distinct mineralizing events, both of which involve major inputs from spatially associated Late Cretaceous igneous rocks. Alteration and mineralization of rock associated with the intrusive suite of Boulder Baldy requires a component characterized by significantly more radiogenic strontium than that characteristic of the associated igneous rocks. However, the source of such a component was not identified in the Big Belt Mountains. Similarly, altered and mineralized rocks associated with the quartz monzodiorite of Mount Edith include a component characterized by significantly more radiogenic strontium and lead, particularly as defined by 207 Pb/ 204 Pb values. The source of this component appears to be fluids that equilibrated with proximal Newland Formation rocks. Oxygen isotope data for rocks of the intrusive suite of Boulder Baldy are similar to those of subduction-related magmatism that include mantle-derived components; oxygen isotope data for altered and mineralized equivalents are slightly lighter.

Montana↗

USGS2017

Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source

The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected 3 He/ 4 He ratios (with atmospheric He removed) range widely from 0.05 to 35.8 times the air 3 He/ 4 He ratio (R A ), with a median of 1.43 R A . Forty-one percent of measured 3 He/ 4 He ratios are ≥4 R A , corresponding to ≥50% mantle He assuming a mantle ratio of 8 R A . These results suggest that mafic magmas were part of the magmatic-hydrothermal system underlying Goldfield and Tonopah, and that associated mantle-sourced volatiles may have played a role in ore formation. The three highest corrected 3 He/ 4 He ratios of 17.0, 23.7, and 35.8 R A indicate a primitive mantle He source and are the highest yet reported for any epithermal-porphyry system and for the Cascades arc region. Compiled 3 He/ 4 He measurements from epithermal-porphyry systems in subduction-related magmatic arcs around the world (n = 209) display a statistically significant correlation between 3 He/ 4 He and Au-Ag grade. The correlation suggests that conditions which promote higher fluid inclusion 3 He/ 4 He ratios (abundance of mantle volatiles and focused upward volatile transport) have some relation to conditions that promote higher Au-Ag grades (focused flow of metal-bearing fluids and efficient chemical traps). Results of this and previous investigations of He isotopes in epithermal-porphyry systems are consistent with the hypothesis posed in recent studies that mafic magmas serve an important function in the formation of these deposits.

Cascades Arc↗

USGS2016

Mineral thermometry and fluid inclusion studies of the Pea Ridge iron oxide-apatite–rare earth element deposit, Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri, USA

Mineral thermometry and fluid inclusion studies were conducted on variably altered and mineralized samples from the Mesoproterozoic Pea Ridge iron oxide-apatite (IOA)-rare earth element (REE) deposit in order to constrain P-T conditions, fluid chemistry, and the source of salt and volatiles during early magnetite and later REE mineralization. Scanning electron microscopy (SEM)-cathodoluminescence and SEM-backscatter electron images show that quartz and rutile precipitated before, during, and after magnetite and REE mineral growth. Ti-in-quartz and Zr-in-rutile equilibration temperatures range from ≤350° to 750°C in the amphibole, magnetite, hematite, and silicified zones where T increased during magnetite and quartz growth and dropped precipitously after fracturing and brecciation. Late drusy quartz cements within a REE-rich breccia pipe record the lowest T (≤315°–400°C). Liquid-, vapor-rich, and hypersaline (±hematite, calcite) fluid inclusions are common and liquid CO 2 is present locally. Salinities define three populations: saline (10–27 wt % NaCl equiv), hypersaline (34–>60 wt % NaCl equiv), and dilute (0–10 wt % NaCl equiv ). The wide range of eutectic melting temperatures (−67° to −19°C) suggests that saline inclusions trapped variable proportions of a CaCl-MgCl-FeCl-bearing fluid end member and an NaCl-KCl fluid end member. Homogenization temperatures and pressures of these saline inclusions suggest they were trapped when fluids unmixed into brine and vapor at T <350°C, P <15 MPa, and a depth of ~1.5 km. Hypersaline inclusions were trapped at low T and P (~200°C and ~1 MPa) along the V + L + H curve when the system vented to the paleosurface. Data for dilute inclusions in late drusy quartz from the REE-rich breccia pipe are indicative of a boiling epithermal environment. The Na/Cl, Na/K, and Cl/Br ratios of fluid inclusion extracts provide evidence for mixtures of magmatic hydrothermal fluids and evaporated seawater. Extracts from magnetite, hematite, and pyrite plot in the magmatic-hydrothermal field, indicating that Fe was derived from a magmatic source. Their enrichments in Mg and Ca are consistent with a mafic magmatic source. The positive correlation between Na/Mg and Na/Ca ratios may be due to halite saturation or albitization of igneous rocks. Extracts from barite in the REE-rich breccia pipes are enriched in Na and Br and plot near the seawater evaporation trend. He is highly enriched relative to Ne and Ar in fluid inclusion extracts, which precludes air as a source of He. Although the He is mostly of crustal origin, pyrite with a 3 He/ 4 He (R/R A ) of 0.1 contains up to 12% mantle He. Many extracts have low 20 Ne/ 22 Ne ratios due to nucleogenic production of 22 Ne in high F/O minerals such as fluorapatite or F biotite. The arrays of data for 3 He/ 4 He (R/R A ) and 22 Ne/ 20 Ne suggest that volatiles were derived from two sources, a moderate F mafic magma containing mantle He and a high F silicic magma with crustal He. Together with other evidence cited in this report, these data (1) support a magmatic hydrothermal origin for the Mesoproterozoic magnetite-apatite deposit with ore fluids derived from a concealed mafic to intermediate-composition intrusion, (2) suggest that the REE minerals in breccia pipes were either derived from apatite or precipitated in response to decompression and cooling during breccia pipe formation, (3) provide evidence for the influx of basinal brine, magmatic fluids from granitic intrusions, and meteoric water after breccia pipe formation, and (4) show that Pea Ridge was relatively unaffected by the late Paleozoic Mississippi Valley-type (MVT) Pb-Zn system in overlying Cambrian sedimentary rocks.

Missouri↗

USGS2016

Geology and mineral resources of the Sheldon-Hart Mountain National Wildlife Refuge Complex (Oregon and Nevada), the Southeastern Oregon and North-Central Nevada, and the Southern Idaho and Northern Nevada (and Utah) Sagebrush Focal Areas: Chapter B in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of selected locatable minerals in lands proposed for withdrawal that span the Nevada, Oregon, Idaho, and Utah borders. In this report, the four study areas evaluated were (1) the Sheldon-Hart Mountain National Wildlife Refuge Complex SFA in Washoe County, Nevada, and Harney and Lake Counties, Oregon; (2) the Southeastern Oregon and North-Central Nevada SFA in Humboldt County, Nevada, and Harney and Malheur Counties, Oregon; (3) the Southern Idaho and Northern Nevada SFA in Cassia, Owyhee, and Twin Falls Counties, Idaho, Elko County, Nevada, and Box Elder County, Utah; and (4) the Nevada additions in Humboldt and Elko Counties, Nevada.

Idaho, Nevada, Oregon, Utah↗

USGS2016

Geology and mineral resources of the North-Central Idaho Sagebrush Focal Area: Chapter C in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of locatable minerals in the North-Central Idaho SFA, which extends from east-central to south-central Idaho. The geologically complex area is composed of many different rock units that locally contain potential mineral resources.

Idaho↗

USGS2016

Critical elements in Carlin, epithermal, and orogenic gold deposits

Carlin, epithermal, and orogenic gold deposits, today mined almost exclusively for their gold content, have similar suites of anomalous trace elements that reflect similar low-salinity ore fluids and thermal conditions of metal transport and deposition. Many of these trace elements are commonly referred to as critical or near-critical elements or metals and have been locally recovered, although typically in small amounts, by historic mining activities. These elements include As, Bi, Hg, In, Sb, Se, Te, Tl, and W. Most of these elements are now solely recovered as by-products from the milling of large-tonnage, base metal-rich ore deposits, such as porphyry and volcanogenic massive sulfide deposits. A combination of dominance of the world market by a single country for a single commodity and a growing demand for many of the critical to near-critical elements could lead to future recovery of such elements from select epithermal, orogenic, or Carlin-type gold deposits. Antimony continues to be recovered from some orogenic gold deposits and tellurium could potentially be a primary commodity from some such deposits. Tellurium and indium in sphalerite-rich ores have been recovered in the past and could be future commodities recovered from epithermal ores. Carlin-type gold deposits in Nevada are enriched in and may be a future source for As, Hg, Sb, and/or Tl. Some of the Devonian carbonaceous host rocks in the Carlin districts are sufficiently enriched in many trace elements, including Hg, Se, and V, such that they also could become resources. Thallium may be locally enriched to economic levels in Carlin-type deposits and it has been produced from Carlin-like deposits elsewhere in the world (e.g., Alsar, southern Macedonia; Lanmuchang, Guizhou province, China). Mercury continues to be recovered from shallow-level epithermal deposits, as well as a by-product of many Carlin-type deposits where refractory ore is roasted to oxidize carbon and pyrite, and mercury is then captured in air pollution control devices.

Book chapter↗

USGS2015

Extreme variation of sulfur isotopic compositions in pyrite from the Qiuling sediment-hosted gold deposit, West Qinling orogen, central China: An in situ SIMS study with implications for the source of sulfur

High spatial resolution textural (scanning electron microscope (SEM)), chemical (electron microprobe (EMP)) and laser ablation-inductively coupled plasma-mass spec- trometry (LA-ICP-MS)), and sulfur isotopic (secondary ion mass spectrometry (SIMS)) analyses of pyrite from the Qiuling sediment-hosted gold deposit (232±4 Ma) in the West Qinling orogen, central China were conducted to distinguish pyrite types and gain insights into the source and evolution of sulfur in hydrothermal fluids. The results reveal an enormous variation (−27.1 to +69.6‰) in sulfur isotopic composition of pyrite deposited during three paragenetic stages. Pre-ore framboidal pyrite, which is characterized by low concentra- tions of As, Au, Cu, Co, and Ni, has negative δ34S values of −27.1 to −7.6‰ that are interpreted in terms of bacterial re- duction of marine sulfate during sedimentation and diagenesis of the Paleozoic carbonate and clastic sequences, the predom- inant lithologies in the deposit area, and the most important hosts of many sediment-hosted gold deposits throughout the West Qinling orogen. The ore-stage hydrothermal pyrite con- tains high concentrations of Au, As, Cu, Sb, Tl, and Bi and hasa relatively narrow range of positive δ34S values ranging from +8.1 to +15.2‰. The sulfur isotope data are comparable to those of ore pyrite from many Triassic orogenic gold deposits and Paleozoic sedimentary exhalative (SEDEX) Pb-Zn de- posits in the West Qinling orogen, both being hosted mainly in the Devonian sequence. This similarity indicates that sulfur, responsible for the auriferous pyrite at Qiuling, was largely derived from the metamorphic devolatization of Paleozoic marine sedimentary rocks. Post-ore-stage pyrite, which is sig- nificantly enriched in Co and Ni but depleted in Au and As, has unusually high δ34S values ranging from +37.4 to +69.6 ‰, that are interpreted to result from thermochemical reduc- tion of evaporite sulfates in underlying Cambrian sedimentary rocks with very high δ34S values. The variations in Au content and sulfur isotopic compositions across a single ore-stage py- rite grain may reflect displacement of indigenous groundwater with low δ34S values by auriferous metamorphic fluids with high δ34S values. The very low-grade metamorphism of the host rocks and the metamorphic derivation of sulfur for the ore pyrite indicate that the Qiuling sediment-hosted gold deposit is an epizonal manifestation of an orogenic gold system in the West Qinling orogen.

Mineralium Deposita↗

USGS2015

Pre-eruptive conditions of the Hideaway Park topaz rhyolite: Insights into metal source and evolution of magma parental to the Henderson porphyry molybdenum deposit, Colorado

The Hideaway Park tuff is the only preserved extrusive volcanic unit related to the Red Mountain intrusive complex, which produced the world-class Henderson porphyry Mo deposit. Located within the Colorado Mineral Belt, USA, Henderson is the second largest Climax-type Mo deposit in the world, and is therefore an excellent location to investigate magmatic processes leading to Climax-type Mo mineralization. We combine an extensive dataset of major element, volatile, and trace element abundances in quartz-hosted melt inclusions and pumice matrix glass with major element geochemistry from phenocrysts to reconstruct the pre-eruptive conditions and the source and evolution of metals within the magma. Melt inclusions are slightly peraluminous topaz rhyolitic in composition and are volatile-charged (≤6 wt % H 2 O, ≤600 ppm CO 2 , &sim;0·3–1·0 wt % F, &sim;2300–3500 ppm Cl) and metal-rich (&sim;7–24 ppm Mo, &sim;4–14 ppm W, &sim;21–52 ppm Pb, &sim;28–2700 ppm Zn, <0·1–29 ppm Cu, &sim;0·3–1·8 ppm Bi, &sim;40–760 ppb Ag, &sim;690–1400 ppm Mn). Melt inclusion and pumice matrix glass chemistry reveal that the Hideaway Park magma evolved by large degrees of fractional crystallization (≤60–70%) during quartz crystallization and melt inclusion entrapment at pressures of ≤300 MPa (≤8 km depth), with little to no crystallization upon shallow ascent and eruption. Filter pressing, crystal settling, magma recharge and mixing of less evolved rhyolite melt, and volatile exsolution were important processes during magma evolution; the low estimated viscosities (&sim;10 5 –10 10  Pa s) of these H 2 O- and F-rich melts probably enhanced these processes. A noteworthy discrepancy between the metal contents in the pumice matrix glass and in the melt inclusions suggests that after quartz crystallization ceased upon shallow magma ascent and eruption, the Hideaway Park magma exsolved an aqueous fluid into which Mo, Bi, Ag, Zn, Mn, Cs, and Y strongly partitioned. Given that the Henderson deposit contains anomalous abundances of not only Mo, but also W, Pb, Zn, Cu, Bi, Ag, and Mn, we suggest that these metals were sourced from similar fluids exsolved from unerupted portions of the same magmatic system. Trace element ratios imply that Mo was sourced deep, from either the lower crust or metasomatized mantle. The origin of sulfur remains unresolved; however, given the extremely low S solubility of rhyolite melts in the shallow crust we favor the possibility that another source of S might supplement or account for that present in the ore deposit, probably the comagmatic, mantle-derived lamprophyres that occur in minor quantities with the voluminous topaz rhyolites in the area. To account for the 437 Mt of MoS 2 (&sim;1·0 × 10 6  t Mo) present in the Henderson ore deposit, a volume of &sim;45 km 3 of Hideaway Park rhyolite magma would have been necessary to supply the Mo (a cylindrical pluton measuring 3·1 km × 6·0 km) along with sparging of &sim;6·8 × 10 5  t of S from &sim;0·05 km 3 of lamprophyre magma. Based on a weighted mean 40 Ar/ 39 Ar age of 27·58 ± 0·24 Ma, similar melt geochemistry, and characteristically F-rich biotite phenocrysts, we conclude that the Hideaway Park tuff was cogenetic with the intrusions at Red Mountain that formed the Henderson deposit.

Colorado↗

USGS2013

Silicate melt inclusion evidence for extreme pre-eruptive enrichment and post-eruptive depletion of lithium in silicic volcanic rocks of the western United States: implications for the origin of lithium-rich brines

To evaluate whether anatectic and/or highly fractionated lithophile element-enriched rhyolite tuffs deposited in arid lacustrine basins lose enough lithium during eruption, lithification, and weathering to generate significant Li brine resources, pre-eruptive melt compositions, preserved in inclusions, and the magnitude of post-eruptive Li depletions, evident in host rhyolites, were documented at six sites in the western United States. Each rhyolite is a member of the bimodal basalt-rhyolite assemblage associated with extensional tectonics that produced the Basin and Range province and Rio Grande rift, an evolving pattern of closed drainage basins, and geothermal energy or mineral resources. Results from the 0.8 Ma Bishop tuff (geothermal) in California, 1.3 to 1.6 Ma Cerro Toledo and Upper Bandelier tephra (geothermal) and 27.9 Ma Taylor Creek rhyolite (Sn) in New Mexico, 21.7 Ma Spor Mountain tuff (Be, U, F) and 24.6 Ma Pine Grove tuff (Mo) in Utah, and 27.6 Ma Hideaway Park tuff (Mo) in Colorado support the following conclusions. Melt inclusions in quartz phenocrysts from rhyolite tuffs associated with hydrothermal deposits of Sn, Mo, and Be are extremely enriched in Li (1,000s of ppm); those from Spor Mountain have the highest Li abundance yet recorded (max 5,200 ppm, median 3,750 ppm). Forty-five to 98% of the Li present in pre-eruptive magma was lost to the environment from these rhyolite tuffs. The amount of Li lost from the small volumes (1–10 km3) of Li-enriched rhyolite deposited in closed basins is sufficient to produce world-class Li brine resources. After each eruption, meteoric water leaches Li from tuff, which drains into playas, where it is concentrated by evaporation. The localized occurrence of Li-enriched rhyolites may explain why brines in arid lacustrine basins seldom have economic concentrations of Li. Considering that hydrothermal deposits of Sn, Mo, Be, U, and F may indicate potential for Li brines in nearby basins, we surmise that the world’s largest Li brine resource in the Salar de Uyuni (10 Mt) received Li from nearby rhyolite tuffs in the Bolivian tin belt.

California;Colorado;New Mexico;Utah↗