Geology topics

Adam S. Wymore

Publications and source records attributed to Adam S. Wymore.

5 recordsLinked to original sources

USGS2025

GlASS - Global Aggregation of Stream Silica

Riverine silicon (Si) plays a vital role in governing primary production, water quality, and carbon cycling. Climate and land cover change have altered how dissolved Si (DSi) is processed on land, transported to rivers, and cycled through aquatic ecosystems. The Global Aggregation of Stream Silica (GlASS) database was constructed to assess changes in river Si concentrations and fluxes, their relationship to other nutrients (nitrogen (N) and phosphorus (P)), and to evaluate mechanisms driving the availability of Si. GlASS includes concentrations of DSi, dissolved inorganic N (NO 3 , NO x , and NH 4 ), and dissolved inorganic P (as soluble reactive P or PO 4 -P) at daily to quarterly time steps from 1963 to 2024; daily discharge; and watershed characteristics for 421 rivers spanning eight climate zones. Original data sources are cited, data quality assurance workflows are public, and input files to a common load model are provided. GlASS offers critical data to address questions about patterns, controls, and trajectories of global river Si biogeochemistry and stoichiometry.

Scientific Data↗

USGS2024

Climate, hydrology, and nutrients control the seasonality of Si concentrations in rivers

The seasonal behavior of fluvial dissolved silica (DSi) concentrations, termed DSi regime , mediates the timing of DSi delivery to downstream waters and thus governs river biogeochemical function and aquatic community condition. Previous work identified five distinct DSi regimes across rivers spanning the Northern Hemisphere, with many rivers exhibiting multiple DSi regimes over time. Several potential drivers of DSi regime behavior have been identified at small scales, including climate, land cover, and lithology, and yet the large-scale spatiotemporal controls on DSi regimes have not been identified. We evaluate the role of environmental variables on the behavior of DSi regimes in nearly 200 rivers across the Northern Hemisphere using random forest models. Our models aim to elucidate the controls that give rise to (a) average DSi regime behavior, (b) interannual variability in DSi regime behavior (i.e., Annual DSi regime), and (c) controls on DSi regime shape (i.e., minimum and maximum DSi concentrations). Average DSi regime behavior across the period of record was classified accurately 59% of the time, whereas Annual DSi regime behavior was classified accurately 80% of the time. Climate and primary productivity variables were important in predicting Average DSi regime behavior, whereas climate and hydrologic variables were important in predicting Annual DSi regime behavior. Median nitrogen and phosphorus concentrations were important drivers of minimum and maximum DSi concentrations, indicating that these macronutrients may be important for seasonal DSi drawdown and rebound. Our findings demonstrate that fluctuations in climate, hydrology, and nutrient availability of rivers shape the temporal availability of fluvial DSi.

Journal of Geophysical Research Biogeosciences↗

USGS2024

Establishing fluvial silicon regimes and their stability across the Northern Hemisphere

Fluvial silicon (Si) plays a critical role in controlling primary production, water quality, and carbon sequestration through supporting freshwater and marine diatom communities. Geological, biogeochemical, and hydrological processes, as well as climate and land use, dictate the amount of Si exported by streams. Understanding Si regimes—the seasonal patterns of Si concentrations—can help identify processes driving Si export. We analyzed Si concentrations from over 200 stream sites across the Northern Hemisphere to establish distinct Si regimes and evaluated how often sites moved among regimes over their period of record. We observed five distinct regimes across diverse stream sites, with nearly 60% of sites exhibiting multiple regime types over time. Our results indicate greater spatial and interannual variability in Si seasonality than previously recognized and highlight the need to characterize the watershed and climate variables that affect Si cycling across diverse ecosystems.

Limnology and Oceanography Letters↗

USGS2023

Long-term changes in concentrations and yield of riverine dissolved silicon from the poles to the tropics

Riverine exports of silicon (Si) influence global carbon cycling through the growth of marine diatoms, which account for ∼25% of global primary production. Climate change will likely alter river Si exports in biome-specific ways due to interacting shifts in chemical weathering rates, hydrologic connectivity, and metabolic processes in aquatic and terrestrial systems. Nonetheless, factors driving long-term changes in Si exports remain unexplored at local, regional, and global scales. We evaluated how concentrations and yields of dissolved Si (DSi) changed over the last several decades of rapid climate warming using long-term data sets from 60 rivers and streams spanning the globe (e.g., Antarctic, tropical, temperate, boreal, alpine, Arctic systems). We show that widespread changes in river DSi concentration and yield have occurred, with the most substantial shifts occurring in alpine and polar regions. The magnitude and direction of trends varied within and among biomes, were most strongly associated with differences in land cover, and were often independent of changes in river discharge. These findings indicate that there are likely diverse mechanisms driving change in river Si biogeochemistry that span the land-water interface, which may include glacial melt, changes in terrestrial vegetation, and river productivity. Finally, trends were often stronger in months outside of the growing season, particularly in temperate and boreal systems, demonstrating a potentially important role of shifting seasonality for the flux of Si from rivers. Our results have implications for the timing and magnitude of silica processing in rivers and its delivery to global oceans.

Global Biogeochemical Cycles↗

USGS2019

Hysteretic response of solutes and turbidity at the event scale across forested tropical montane watersheds

Concentration-discharge relationships are a key tool for understanding the sourcing and transport of material from watersheds to fluvial networks. Storm events in particular provide insight into variability in the sources of solutes and sediment within watersheds, and the hydrologic pathways that connect hillslope to stream channel. Here we examine high-frequency sensor-based specific conductance and turbidity data from multiple storm events across two watersheds (Quebrada Sonadora and Rio Icacos) with different lithology in the Luquillo Mountains of Puerto Rico, a forested tropical ecosystem. Our analyses include Hurricane Maria, a category 5 hurricane. To analyze hysteresis, we used a recently developed set of metrics to describe and quantify storm events including the hysteresis index (HI), which describes the directionality of hysteresis loops, and the flushing index (FI), which can be used to infer whether the mobilization of material is source or transport limited. We also examine the role of antecedent discharge to predict hysteretic behavior during storms. Overall, specific conductance and turbidity showed contrasting responses to storms. The hysteretic behavior of specific conductance was very similar across sites, displaying clockwise hysteresis and a negative flushing index indicating proximal sources of solutes and consistent source limitation. In contrast, the directionality of turbidity hysteresis was significantly different between watersheds, although both had strong flushing behavior indicative of transport limitation. Overall, models that included antecedent discharge did not perform any better than models with peak discharge alone, suggesting that the magnitude and trajectory of an individual event was the strongest driver of material flux and hysteretic behavior. Hurricane Maria produced unique hysteresis metrics within both watersheds, indicating a distinctive response to this major hydrological event. The similarity in response of specific conductance to storms suggests that solute sources and pathways are similar in the two watersheds. The divergence in behavior for turbidity suggests that sources and pathways of particulate matter vary between the two watersheds. The use of high-frequency sensor data allows the quantification of storm events while index-based metrics of hysteresis allow for the direct comparison of complex storm events across a heterogeneous landscape and variable flow conditions.

Luquillo Mountains↗