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A.J. Naldrett

Publications and source records attributed to A.J. Naldrett.

3 recordsLinked to original sources

ReOs isotope systematics of NiCu sulfide ores, Sudbury Igneous Complex, Ontario: Evidence for a major crustal component

Sudbury Igneous Complex sublayer ores from the Levack West, Falconbridge and Strathcona mines were analyzed for their Re and Os concentrations and Os isotopic compositions. The Re-Os isotope systematics of three ores from the different mines give isochron ages of1 840 ± 60 Ma, 1770 ± 60 Ma and 1780 ± 110 Ma, suggesting that the Re-Os system became closed at the time of, or soon after the 1850 ± 1 Ma crystallization age of the complex. The Os isotopic compositions of different portions of the complex at the time of crystallization varied considerably, with initial 187 Os/ 186 Os 1850 ranging from 4.64 at Levack West to 7.55 at Strathcona. These heterogeneities require that the Os, and probably also the other platinum-group elements contained in the ores, were derived from at least two sources. In addition, the high initial 187 Os/ 186 Os ratios indicate that the Os was derived predominantly from ancient crust. Previous studies have suggested that the complex either crystallized from a mixture of mantle-derived basaltic melt and ancient continental crust, or was derived exclusively from the fusion of ancient continental crust resulting from a meteorite impact. Results of modelling suggest that if a contemporaneous mantle-derived basaltic melt was involved in the origin of the SIC, it likely contributed < 50% of the Os to all three ores. The large percentage of ancient crust involved in the production of the ores is most consistent with an interpretation of substantial crustal fusion resulting from meteorite impact.

Earth and Planetary Science Letters

Platinum metals in magmatic sulfide ores

Platinum-group elements (PGE) are mined predominantly from deposits that have formed by the segregation of molten iron-nickel-copper sulfides from silicate magmas. The absolute concentrations of PGE in sulfides from different deposits vary over a range of five orders of magnitude, whereas those of other chalcophile elements vary by factors of only 2 to 100. However, the relative proportions of the different PGE in a given deposit are systematically related to the nature of the parent magma. The absolute and relative concentrations of PGE in magmatic sulfides are explained in terms of the degree of partial melting of mantle peridotite required to produce the parent magma and the processes of batch equilibration and fractional segregation of sulfides. The Republic of South Africa and the U.S.S.R. together possess more than 97 percent of the world PGE reserves, but significant undeveloped resources occur in North America. The Stillwater complex in Montana is perhaps the most important example.

Science