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A. K. Kronenberg

Publications and source records attributed to A. K. Kronenberg.

7 recordsLinked to original sources

Deformation of clinopyroxenite: Evidence for a transition in flow mechanisms and semibrittle behavior

A systematic suite of constant strain rate experiments was performed on a vacuum-dried, high-purity, fine-grained clinopyroxenite using NaCl and NaF as confining media in a Griggs-type piston-cylinder apparatus. The experiments were carried out over a range of temperatures from 400° to 1100°C, strain rates from 10 −3 to 10 −7 s −1 , and confining pressures from 170 to 1990 MPa. At T = 600°C and = 1.1 × 10 −5 s −1 , three modes of deformation occur with increasing confining pressure: (1) Macroscopic faulting associated with low strength and stress drops, (2) stable microfracturing and plastic deformation associated with pressure-dependent strength, and (3) plastic deformation (mechanical twinning and 〈001〉 slip) with high strengths which are insensitive to pressure variations. In experiments at P = 1500 MPa, within this high-pressure plastic mode, two regimes of flow are clearly defined. At low to intermediate temperatures and high strain rates, flow strengths are insensitive to changes in strain rate and temperature. Optical and transmission electron microscope observations indicate that plastic strain is accomplished by mechanical twinning on (100) and (001) and by {100}〈001〉 slip. In contrast, at high temperatures and low strain rates the flow stress is strongly dependent on temperature and strain rate. Specimens deformed in this regime show evidence of recovery, multiple slip, and recrystallization; and plastic strain is much more homogeneous. The flow data within each regime can be satisfactorily fit to thermally activated power laws. In the low-temperature regime n (the stress exponent) = 83 ± 16 and E * (the activation energy for flow) = 220 ± 40 kJ/mol. We believe that these parameters reflect flow dominated by the kinetics of dislocation glide associated with mechanical twinning and (100)〈001〉 slip. In the high-temperature regime, n = 5.3 ± 1.1 and E * = 380 ± 30 kJ/mol. These parameters describe creep by multiple slip accompanied by increased rates of diffusion and recovery.

Journal of Geophysical Research Solid Earth

Basal slip and mechanical anisotropy of biotite

The basal slip systems of biotite and their mechanical expressions have been investigated by shortening single crystals oriented to maximize and minimize shear stresses on (001). Samples loaded at 45° to (001) exhibit gentle external rotations associated with dislocation glide. High‐angle kink bands in these samples, unlike those developed in micas loaded parallel to (001), are limited to sample corners. Samples shortened perpendicular to (001) show no evidence of nonbasal slip and fail by fracture over all conditions tested. The mechanical response of biotite shortened at 45° to (001) is nearly perfectly elastic‐plastic; stress‐strain curves are characterized by a steep elastic slope, a sharply defined yield point, and continued deformation at low (mostly 1%. Stresses measured beyond the yield point are insensitive to confining pressure over the range 200 to 500 MPa and exhibit weak dependencies upon strain rate and temperature. Assuming an exponential relationship between differential stress σ and strain rate of the form , the data collected over strain rates and temperatures of 10−7 to 10−4 s−1 and 20° to 400°C, respectively, are best fit by an exponential constant α of 0.41±0.08 MPa‐1 and an activation energy of 82±13 kJ/mol. A power law fits the data equally well with = 18±4 and = 51±9 kJ/mol. Samples oriented favorably for slip in directions [100] and [110] are measurably weaker than those shortened at 45° to [010] and [310], consistent with the reported Burgers vectors 〈100〉, 1/2 〈110〉, and 1/2 〈110〉. The anisotropy of biotite is further revealed by contrasting these plastic strengths with results of samples deformed parallel and perpendicular to (001). Previous studies have shown that biotite loaded in the (001) plane is strong prior to the nucleation of kink bands. The strength of biotite shortened perpendicular to (001) exceeds that measured parallel to (001) and is pressure dependent. Application of the results to deformation within the continental crust suggests that biotite oriented favorably for slip is much weaker than most other silicates over a wide range of geologic conditions. Its presence within foliated rocks and shear zones may limit locally the stresses that can be supported.

Journal of Geophysical Research B: Solid Earth

Rheology of the lithosphere: Selected topics

We review recent results concerning the rheology of the lithosphere with special attention to the following topics: 1) the flexure of the oceanic lithosphere, 2) deformation of the continental lithosphere resulting from vertical surface loads and forces applied at plate margins, 3) the rheological stratification of the continents, 4) strain localization and shear zone development, and 5) strain-induced crystallographic preferred orientations and anisotropies in body-wave velocities. We conclude with a section citing the 1983–1986 rock mechanics literature by category.

Reviews of Geophysics

Hydrogen defects in α-Al2O3 and water weakening of sapphire and alumina ceramics between 600°C and 1000°C: II. Mechanical properties

Hydrogen impurities in alumina have been introduced by hydrothermal annealing (see part I). In this paper, we report on reductions in the flow strength of α -Al 2 O 3 single crystals and polycrystals associated with hydrogen incorporation. Prior to deformation, α -Al 2 O 3 single crystal and ceramic specimens were annealed in the presence of supercritical water at 850° or 900°C, under 1500 MPa pressure. Sapphire and alumina ceramics were plastically deformed between 600° and 1000°C under 1500 MPa pressure, by the addition of a uniaxial stress. Flow stresses are reduced by a factor of two, due to the presence of water, for sapphire and large grain (30–50 μm) polycrystals, as a result of enhanced dislocation mobility. Flow stresses of fine-grained (3–5 μm) polycrystals are reduced by water by a factor of six. This large reduction in strength is attributed to a change in mechanism from dislocation glide under dry conditions to grain boundary sliding under hydrothermal conditions.

Acta Materialia

Ionic conductivity of quartz: DC time dependence and transition in charge carriers

The time dependence of DC electrical conductivity in the c-axis direction of quartz can be accounted for by a transition in charge carriers from interstitial alkali impurities to interstitial H. The diffusive transport rates of Li, Na, and K are rapid parallel to c and have been shown to be responsible for the highly anisotropic electrical conductivity measured at short times. With increasing time, however, conductivities parallel to c decrease progressively to values that are roughly equal to those measured perpendicular to c. Comparison of these ultimate, nearly isotropic conductivities with those derived from recent measurements of H diffusion parallel and perpendicular to c suggests that H interstitials are the principal charge carriers at long times. The transient decrease in conductivities parallel to c is interpreted to result from depletion of initial alkali impurities, whereas the steady-state conductivities measured at long times may be sustained by the steady supply of H by the dissociation of atmospheric water vapor. The mobility of H along the c axis is anomalously low and at variance with the trend of increasing mobility with decreasing ionic radius exhibited by Cs, Rb, K, Na, and Li. Although the elastic lattice distortions required for H transport are insignificant in comparison with those required by the larger alkali impurities, the strong association of H interstitials with Al substitutions for Si may be responsible for the relatively low H mobilities.

American Mineralogist

Deformation microstructures of Barre granite: An optical, Sem and Tem study

New scanning electron microscope techniques have been developed for characterizing ductile deformation microstructures in felsic rocks. In addition, the thermomechanical history of the macroscopically undeformed Barre granite (Vermont, U.S.A.) has been reconstructed based on examination of deformation microstructures using optical microscopy, scanning electron microscopy, and transmission electron microscopy. The microstructures reveal three distinct events: 1. (1) a low-stress, high-temperature event that produced subgrains in feldspars, and subgrains and recrystallized grains in quartz; 2. (2) a high-stress, low-temperature event that produced a high dislocation density in quartz and feldspars; and 3. (3) a lowest-temperature event that produced cracks, oriented primarily along cleavage planes in feldspars, and parallel to the macroscopic rift in quartz. The first two events are believed to reflect various stages in the intrusion and cooling history of the pluton, and the last may be related to the last stages of cooling, or to later tectonism.

Vermont